• Title/Summary/Keyword: rheological and physical properties

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Study on Rheological Characteristics of Self-Compacting Concrete using Glass Bubble (글라스 버블을 사용한 자기 충전 콘크리트의 레올로지 특성에 관한 연구)

  • Lee, Han-Yong;Yoon, Seob;Seo, Tae-Seok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.73-74
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    • 2017
  • In this study, unlike high flowing concrete, using glass bubble to develop self-compacting concrete(hereinafter referred to as "SCC") with excellent filler performance by evaluating both flowability and yield stress, viscosity An experiment was conducted. Experimental results show that when 1 kg of glass bubbles are used, it is effective in stabilizing the physical properties of concrete, reducing the yield stress and viscosity.

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Rheological Characteristics of Highly Concentrated Polymer Bonded Explosive Simulant: Wall Slip, Thixotropy, and Flow Instability (고농축 복합화약 시뮬란트의 유변학적 특성: 벽면 미끄러짐, 틱소트로피, 유동불안정성)

  • Lee, Sangmook;Hong, In-Kwon;Ahn, Youngjoon;Lee, Jae Wook
    • Polymer(Korea)
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    • v.38 no.2
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    • pp.213-219
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    • 2014
  • The rheological characteristics of highly concentrated polymer bonded explosive simulant were studied. Hydroxyl terminated polybutadiene (HTPB) and polyethylene plastomer (Exact) were used as binders. Sugar and Dechlorane particles whose physical properties are similar to research department explosive (RDX) were used as fillers. When HTPB was used, diethyl hexyl adipate (DEHA or DOA) was used as a plasticizer together for some cases. Highly concentrated suspensions were mixed in a batch melt mixer (Rheomixer 600, Haake) and rheological properties were measured by plate-plate and capillary rheometers. Wall slip phenomena, thixotropy with shear hysteresis, and flow instability were investigated as shear rate and amount of fillers changed.

Tuning the rheological properties of colloidal microgel controlled with degree of cross-links (가교도가 제어된 콜로이드 마이크로겔의 유변학적 물성 분석)

  • Han, Sa Ra;Shin, Sung Gyu;Oh, Seung Joo;Cho, Sung Woo;Jung, Naseul;Kang, Bu Kyeung;Jeong, Jae Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.2
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    • pp.645-655
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    • 2019
  • In this study, colloidal microgel with viscoelasticity were prepared by using dispersion containing physical crosslinking agents and microgels with various strengths depending on the degree of cross-links.As the chemical crosslinking agent PEGDA400 content increased, hydrogels have various physical properties the swelling ratio decreased from $2.0{\times}10^4%$ to $6.0{\times}10^3%$ and increased viscosity by about 60%. The colloidal microgel was prepared with micro hydrogel grinded to $100{\mu}m$ size and the rheological behavior was confirmed with physical cross linking agent. A colloidal microgel having various viscosities was prepared by controlling starch and alginate based on micro-hydrogel containing 0.75% (w/v) of PEGDA400. In conclusion, these results would be highly useful for applying as a product that can give various physical properties to the colloidal suspensions, cosmetics, paint, and food industry.

Mechanical Properties of Rice Plants Under the Transverse Loading -Creep and Recovery Behavior- (측방향하중(側方向荷重)에 의한 벼줄기의 역학적특성(力學的特性)에 관한 연구(硏究)(II) -크리이프 및 회복 거동-)

  • Huh, Yun Kun
    • Korean Journal of Agricultural Science
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    • v.23 no.2
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    • pp.233-241
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    • 1996
  • The mechanical properties of biological materials depend on numerous factors. The majority of these relationships are still unknown today, especially with regard to their quantitative characteristics. The reason is that biological materials constitute biomechanical systems of very complex construction, whose behavior cannot be characterized by simple physical constants, as for example can that of engineering materials. The objectives of this investigation were to determine the compression creep and recovery properties of rice stalks at various levels of applied load The compression creep and recovery behavior of the rice stalk could be predicted precisely by rheological model which approached closely to the measured values. But the coefficients of the Burgers recovery model were different from those of the creep model. The Steady state creep behavior occurred at the higher level of force and the logarithmic creep behavior occurred at the lower level of force. The mechanical model being expected the creep behavior in relation with the level of applied load, which was well explained that the rice stalk might be visco-elastic material.

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Studies on the Correlation between Coated Paper and Physical Properties of Latices (라덱스의 물성이 도공지 품질에 미치는 상관성에 대한 연구)

  • 박동국;조교동;고문찬;윤재한;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.1
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    • pp.22-29
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    • 2002
  • The coated paper was greatly affected by the basic physical properties of the binder as well as the amount of the coating formula. High glass transition temperature (Tg) of the styrene-butadiene (SB) latex, selected as the binder in our study, gave the high stiffness to the coated paper, but lowered the binding force and print gloss. The average particle size of the SB latex also greatly affected to the coated paper so that the smaller particle size improved the rheological property of the coating formula and increased the binding force and print gloss. Another property of the SBR latex, gel content, was important because when its value was small, the latex was easily deformed at the high temperature and increased air permeability to the coated paper. Therefore, the lower gel content consequently resulted in the higher blistering resistance, especially in the web paper. The larger portion of the SB latex in the coated formula improved the binding force and print gloss, but decreased the ink set-off and ink-trapping to the coated paper. The heavier coating improved optical properties such as opacity, paper gloss and paper smoothness, to the coated paper.

New Hyperbranched Polyimides and Polyamides: Synthesis, Chain-End Functionalizations, Curing Studies, and Some Physical Properties (새로운 Hyperbranchedpolyimidesandpolyamides: 합성, 말단기 변형, 경화 연구, 그리고 물리적 성질)

  • Baek, Jong-Beom;Chris B. Lyon;Tan, Loon-Seng
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.1-2
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    • 2003
  • While aromatic polyimides and polyamides have found widespread use as high performance polymers, the present work addressed the need for organosoluble materials through the use of a hyperbranching scheme. The $AB_2$ monomers were prepared. The $AB_2$ monomers were then polymerized via aromatic fluoride-displacement and Yamazaki reactions to afford the corresponding hydroxyl-terminated hyperbranched polyimides (HT-PAEKI) and amine-terminated hyperbranched polyamides, respectively. HT-FAEKI was then functionalized with allyl and propargyl bromides as well as epichlorohydrin to afford allyl-terminated AT-PAEKI, propargyl-terminated PT-PAEKI, and epoxy (glycidyl)-terminated ET-PAEKI, in that order. All hyperbranched poly(ether-ketone-imide)s were soluble in common organic solvents. AT-PAEKI was blended with a bisphenol-A-based bismaleimide (BFA-BMI) in various weight ratios. Thermal, rheological, and mechanical properties of these blend systems were evaluated. Two characteristic hyperbranched polyamides, which the one has para-electron donating groups to the surface amine groups and the other has para-electron withdrawing groups to the surface amine groups, were selected to compare BMI curing behaviors. The electron rich polymer displayed ordinary Michael addition type exothermic reaction, while electron deficient polymer did display unusual curing behaviors. Based on analytical data, the later system provided the strong evidences to support room temperature curing of BMI by reactive intermediates instead of reactive primary amine groups on the macromolecule surface.

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Effect of Homogenization Pressure and Supplementation with Sucrose Fatty Acid Ester on the Physical Properties of Dairy Cream-based Emulsions

  • Seo, Chan-Won;Kang, Shin-Ho;Shin, Yong-Kook;Yoo, Byoungseung
    • Food Science of Animal Resources
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    • v.38 no.3
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    • pp.476-486
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    • 2018
  • In this study, the droplet size distribution, rheological properties, and stability of dairy cream-based emulsions homogenized with different sucrose fatty acid ester (SFAE, a non-ionic small-molecule emulsifier) concentrations (0.08%, 0.16%, and 0.24% w/w) at different homogenization pressures (10 MPa and 20 MPa) were examined. Homogenization at a high pressure resulted in a smaller droplet size and narrower droplet size distribution. The D[4,3] (volume-weighted mean) and D[3,2] (surface-weighted mean) values of the emulsions decreased with an increase in the SFAE concentration. The flow properties of the emulsions homogenized with SFAE showed shear-thinning (n=0.21-0.46) behavior. The apparent viscosity (${\eta}_{a,10}$) and consistency index (K) of the homogenized emulsions were lower than those of the control sample that is non-homogenized and without SFAE, and decreased with an increase in SFAE concentration. The storage modulus (G') and loss modulus (G") of all emulsions homogenized with SFAE were also lower than those of the control sample. The stability of all emulsions with SFAE did not show any significant change for 30 d at $5^{\circ}C$. However, the emulsions stored at $40^{\circ}C$ were unstable over the storage period. Therefore, the addition of SFAE enhanced the stability of dairy cream emulsions during storage at refrigeration temperature ($5^{\circ}C$).

Effect of Surface Treated Magneto-responsible Particle on the Property of Magneto-rheological Elastomer Based on Silicone Rubber

  • Choi, Soyeon;Chung, Kyungho;Kwon, Seunghyuk;Choi, Hyoungjin
    • Elastomers and Composites
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    • v.51 no.2
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    • pp.113-121
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    • 2016
  • Magneto-rheological elastomer (MRE) is a material which shows reversible and various modulus under magnetic field. Comparing to conventional rubber vibration isolator, MREs are able to absorb broader frequency range of vibration. These characteristic phenomena result from the orientation of magnetic particle (i.e., chain-like formation) in rubber matrix. In this study, silicone rubber was used as a matrix of MREs. Carbonyl iron particle (CIP) was used to give magnetic field reactive modulus of MRE. The surface of the CIP was modified with chemical reactants such as silane coupling agent and poly(glycidyl methacrylate), to improve interfacial adhesion between matrix and CIP. The mechanical properties of MREs were measured without the application of magnetic field. The results showed that the tensile strength was decreased while the hardness was increased with the addition of CIP. Also, surface modification of CIP resulted in the improvement of physical properties of MRE, but the degree of orientation of CIP became decreased. The analysis of MR effect was carried out using electromagnetic equipment with various magnetic flux. As the addition of CIP and magnetic flux increased, increment of MR effect was observed. Even though the surface modification of CIP gave positive effect on the mechanical properties of MRE, MR effect was decreased with the surface modification of CIP due to decrease of CIP orientation. Throughout this study, it was found that the loading amounts of CIP affected the mechanical properties of MRE, and surface property of CIP was an important factor on MR effect of MRE.

Changes in Organoleptic and Rheological Properties of Chinese Cabbage with Salting Condition (배추의 절임조건에 따른 관능적 특성 및 물성 변화)

  • Lee, Myung-Hee;Lee, Gee-Dong;Son, Kwang-Jin;Yoon, Sung-Ran;Kim, Jeong-Sook;Kwon, Joong-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.31 no.3
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    • pp.417-422
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    • 2002
  • Salting conditions on organoleptic properties and rheology of Chinese cabbage were optimized and monitored by four-dimensional response surface methodology. Experimental conditions were decided in the ranges of salt concentration 8∼12%, salting time 5∼25 hr and salting temperature 5∼15$^{\circ}C$. The salted Chinese cabbage with experiment design was measured on organoleptic and physical properties. The organoleptic form of the salted Chinese cabbage showed maximum score in 11.28% of salt concentration, 9.75 hr of salting time and 12.81$^{\circ}C$ of salting temperature. The organoleptic taste was maximized in 11.19% of salt concentration, 11.38 hr of salting time and 13.58$^{\circ}C$ of salting temperature. The organoleptic mouth-feel was maximized in 11.24% of salt concentration, 11.71 hr of salting time and 13.57$^{\circ}C$ of salting temperature. The organoleptic palatability was maximized in 11.52% of salt concentration, 12.86 hr of salting time and 13.07$^{\circ}C$ of salting temperature. In rheological properties of salted Chinese cabbage, hardness and chewiness decreased with the increase of salt concentration.

Viscoelastic and Gelation Studies of SEBS Thermoplastic Elastomer in Different Hydrocarbon Oils

  • Kim Jin-Kuk;Paglicawan Marissa A.;Balasubramanian Maridass
    • Macromolecular Research
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    • v.14 no.3
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    • pp.365-372
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    • 2006
  • Poly[styrene-b-(ethylene-co-butylene)-b-styrene](SEBS) triblock copolymer was studied by dissolving the ethylene butylene midblock in selective hydrocarbon oils. These oils differ in their aromatic, paraffinic and naphthenic content. Dynamic rheological studies showed that the storage modulus (G') exceeded the loss modulus (G') for all the gels over the entire range of frequency, thereby confirming them as physical gels. However, the behavior of G' and G' as a function of frequency depended primarily on the oil type. The gelation melting temperature decreased drastically with increased oil aromaticity. Small angle X-ray scattering studies revealed that the maximum interdomain interference shifted to a higher angle depending on the composition and type of hydrocarbon oil.