• Title/Summary/Keyword: reversibility

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Electrochemical Investigation of Acetaminophen with a Carbon Nano-tube Composite Film Electrode

  • Li, Chunya;Zhan, Guoqing;Yang, Qingdan;Lu, Jianjie
    • Bulletin of the Korean Chemical Society
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    • v.27 no.11
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    • pp.1854-1860
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    • 2006
  • Electrochemical behaviors of acetaminophen at a muti-wall carbon nano-tube composite film modified glassy carbon electrode were investigated by cyclic voltammetry, linear sweep voltammetry and chronocoulometry. Compared with that obtained at the unmodified electrode, the peak currents were enhanced significantly, and the oxidation peak shifted towards more negative potential with the reduction peak shifted positively. The peak-to-peak separation turned narrow, and suggested that the reversibility was improved greatly. Experimental parameters, such as scan rate, pH and accumulation conditions were optimized. It was found that a maximum current response can be obtained at pH = 5.0 after accumulation at -0.50 V for 80 s. The oxidation peak current was found to be linearly related to acetaminophen concentration over the range of $5.0{\times}10^{-7}\;\sim\;1.0{\times}10^{-4}$ mol $L^{-1}$ with a detection limit of $5.0{\times}10^{-8} $mol $L^{-1}$. A convenient and sensitive electrochemical method was developed for the determination of acetaminophen in a commercial paracetamol oral solution. Its practical application demonstrated that it has good selectivity and high sensitivity.

A Cyclic Voltammetric Study of Electrodes for Reverse Electrodialysis

  • Lee, Seo-Yoon;Lee, Dong-Ju;Yeon, Kyeong-Ho;Kim, Woo-Gu;Kang, Moon-Sung;Park, Jin-Soo
    • Journal of the Korean Electrochemical Society
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    • v.16 no.3
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    • pp.145-150
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    • 2013
  • In this study, the electrochemical investigation of various electrodes for reverse electrodialysis using potassium ferrocyanide and potassium ferricyanide as a redox system was carried out. Cyclic voltammetry was the employed method for this electrochemical study. From the results of cyclic voltammograms for various electrode materials, i.e., Au, Vulcan supported Pt, activated carbon, carbon nanofiber, Vulcan, the Vulcan electrode showed the lowest overpotential, but the Pt electrode having slightly higher overpotential obtained slightly higher anodic and cathodic current densities for the $Fe(CN)_6{^{4-}}/Fe(CN)_6{^{3-}}$ redox couple. The cyclic voltammograms for the Vulcan electrode confirmed very good electrochemical reversibility and kinetic behavior. As a result, among the electrode materials, the Vulcan electrode is the most promising electrode material for reverse electrodialysis.

Measurement of the Displacement Currents Induced by the Monolayers on the Water surface of KUHN Type LB Apparatus (KUHN형 LB장치의 수면상에 전개된 단분자막의 변위전류 측정)

  • 박태곤;송경호;박근호;권명수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.83-86
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    • 1994
  • On this paper, the structural changes of molecules on the water surface were monitored by the measuring system of displacement currents. The measuring system was constructed at home-made Kuhn type LB(Langmuir -Blodgett) deposition apparatus. Solutions of 4-octyl -4\\`- (5-car boxy$.$ -pentamethyleneoxy) azobenzene molecules (8A5H) and stearic acid(C$\_$18/) were spreaded at the air-water interface respectively, and the currents inducted by the dynamic behavior of molecules were measured when the molecules were the molecules were pressed by barrier. From C$\_$18/ mo1ecules two distinct peaks of displacement currents were obtained, which show that the orientations of mo1ecules were charged largely at these Points. The reversibility of displacement currents by compression and expansion was obtained from 8A5H molecules, which shows the compressed molecules which shows the compressed molecules have a tendency to disperse after the compression. But it was not obtained from C$\_$18/ molecules which means that this molecules disperse not easily by decreasing the pressure of the barrier.

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Image Cryptographic Algorithm Based on the Property of Wavelet Packet Transform (웨이브렛 패킷 변환의 특성을 이용한 영상 암호화 알고리즘)

  • Shin, Jonghong
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.14 no.2
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    • pp.49-59
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    • 2018
  • Encryption of digital images has been requested various fields. In the meantime, many algorithms based on a text - based encryption algorithm have been proposed. In this paper, we propose a method of encryption in wavelet transform domain to utilize the characteristics of digital image. In particular, wavelet transform is used to reduce the association between the encrypted image and the original image. Wavelet packet transformations can be decomposed into more subband images than wavelet transform, and various position permutation, numerical transformation, and visual transformation are performed on the coefficients of this subband image. As a result, this paper proposes a method that satisfies the characteristics of high encryption strength than the conventional wavelet transform and reversibility. This method also satisfies the lossless symmetric key encryption and decryption algorithm. The performance of the proposed method is confirmed by visual and quantitative. Experimental results show that the visually encrypted image is seen as a completely different signal from the original image. We also confirmed that the proposed method shows lower values of cross correlation than conventional wavelet transform. And PSNR has a sufficiently high value in terms of decoding performance of the proposed method. In this paper, we also proposed that the degree of correlation of the encrypted image can be controlled by adjusting the number of wavelet transform steps according to the characteristics of the image.

A Study on sine-wave Input Current Correction of Single-Phase Buck Rectifier (단상 강압형 정류기의 정현파 입력전류 개선에 관한 연구)

  • Jung, S.H.;Lee, H.W.;Suh, K.Y.;Kwon, S.K.;Kim, Y.S.
    • Proceedings of the KIEE Conference
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    • 2001.10a
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    • pp.180-182
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    • 2001
  • Input Current Correction of Single-Phase Buck Rectifier is studied in the paper. To sinusoidal waveform the input current with a near-unity power factor over a wide variety of operating conditions, the output capacitor is operated with voltage reversibility for the supply by arranging the auxiliary diode and power switching device. Then the output voltage is superposed on the input voltage during on time duration of power switching devices in order to minimize the input current distortion caused by the small input voltage when changing the polarity. The tested setup, using two insulated-gate bipolar transistors(IGBT) and a microcomputer, is implemented and IGBT are switched with 20[kHz], which is out of the audible band. Moreover, a rigorous state-space analysis is introduced to predict the operation of the rectifier. The simulated results confirm that the input current can be sinusoidal waveform with a near-unity power factor and a satisfactory output voltage regulation can be achieved.

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Effects of Ethanol on Na-K-ATPase Activity of Cat Kidney (Ethanol 이 고양이 신장 Na-K-ATPase 활성에 미치는 영향)

  • Kim, Joo-Heon;Kim, Yong-Keun
    • Korean Journal of Veterinary Research
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    • v.23 no.1
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    • pp.9-16
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    • 1983
  • The effects of ethanol on Na-K-ATPase activity were investigated with cat kidney homogenate. The results were summarized as follows: 1. Na-K-ATPase activity was inhibited with dose-dependent manner by ethanol of higher concentration than 1%, and showed an estimated $I_{50}$ (the inhibitor concentration to cause 50% inhibition) of 7.5%. 2. Hydrolysis of ATP was linear with the incubation time in the absence and presence of 8% ethanol, whereas it was different with preincubation time in the presence of 15% ethanol. 3. Inhibition of Na-K-ATPase activity by ethanol was not affected by increased enzyme concentration, and showed the reversibility of the inhibitory pattern. 4. Kinetic studies of cationic-substrate activation of Na-K-ATPase showed that ethanol had both properties of classical competitive inhibition for $Mg^{{+}{+}}$ or $K^+ and non-competitive inhibition for ATP or $Na^+$. 5. Arrhenius plot yield two break point at $21^{\circ}$ and $30^{\circ}C$ in the absence of ethanol, whereas showing only one break point at $18^{\circ}C$ in the presence of 8% ethanol. These results suggested that ethanol inhibited Na-K-ATPase activity reversible through a disturbance of microenvironment of lipids associated with the enzyme.

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Fabrication and Electrochemical Characterization of All Solid State Rechargeable Li-Mn Oxide Batteries (리튬-망간 산화물을 이용한 전고상 이차 전지의 제작 및 전기화학적 특성)

  • Park, Young-Sin;Sin, Jin-Wook;Lee, Byung-Il;Joo, Seung-Ki
    • Korean Journal of Materials Research
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    • v.8 no.4
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    • pp.323-327
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    • 1998
  • All solid state lithium based rechargeable batteries were fabricated in a cell structure of Li/PEO-$LiCIO_4$-PC /$LIMn_2O_4$$LIMn_2O_4$ thin films were prepared by RF magnetron sputtering and the spinel structure could be obtained by Rapid Thermal Annealing (RT A) process at the temperature of around 750$750^{\circ}C$ . Room temperature cycling of this cell showed a nearly constant cell potential of 4 V( us. Li) and good reversibility.

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The Conservation of a Spanish Gourd-Style Jar (Donated Object by Sir Ganeko) (金子量重(가네코 카즈시게) 기증(寄贈) 박형(珀形) 호(壺)의 복원(復元) - 경질토기(硬質土器)를 중심(中心)으로 -)

  • Hwang, Hyun-sung;Lee, Hae-soon;Yi, Yong-hee
    • Conservation Science in Museum
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    • v.3
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    • pp.15-19
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    • 2001
  • This article examines the conservation process of a donated Gourd-style jar (Object No. Geumja No.124), which was broken into several fragments (more than 60) in the past. After assessing the condition of the object, each of the fragments were re-attached, and missing areas were gap-filled and re-touched. The authors discuss considerations, which were taken into account during the decision making process. These include the integrity of the object and the section of treatment materials, such as the reversibility of adhesives and filling materials. After its conservation, the authors believe that the object is in a better condition and ready for display in the future.

Toxicity of Mixtures of Diazinon, Toxaphene and/or Endrin in Mice (Diazinon, Toxaphene, Endrin과 그 혼합물의 독성효과)

  • 김종수;하대식;손성기
    • Toxicological Research
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    • v.12 no.2
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    • pp.231-236
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    • 1996
  • The toxicity of the mixture of diazinon, toxaphene(TOX) and/or endrin was studied in ICR male mice(18-22 g) by oral intubation, in corn oil, daily for up to 14 days. On day 15, the exposure was discontinued and animals were monitored for an additional period of 7 days for the possible reversibility of the toxicity. The body weight gain decreased with the mixtures, as well as with the individual pesticides, during the 14-day period. TOX and TOX containing mixtures significantly increased the liver/body weight ratio. The serum glutamic pyruvic transaminase level increased at 23~374% in diazinon, TOX, and endrin or their mixture group. The cholinesterase(ChE) activity in the serum and brain was inhibited in the animals of the group of diazinon(5, 10 mg/kg) and diazinon(5 mg/kg) containing mixtures. TOX(40, 80 mg/kg) caused initial inhibitory effects on the serum ChE Day 1. but there is little effects on the brain ChE levels. endrin(5,10 mg/kg) results in significantly elevated levels of the serum ChE, with substantial decreases in the brain ChE activity. TOX and TOX containing mixtures decreased the pentobarbital(60 mg /kg, ip., in saline) induced sleep. The effects produced by this pesticides singly, as well as by their mixtures, appeared to be reversible in nature. The toxic effects exhibited by the mixtures of diazinon(5 mf/kg), TOX(40 mg/kg), and /or endrin(5 mg/kg) were found to be the resultant of the effect showed by their components individually.

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The Preparation of K-GIC and its Anodic Characteristics of Lithium Ion Secondary Battery (K-GIC의 합성 및 리튬이온이차전지에서의 부극특성)

  • Kim, Hyun-Joong;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.786-790
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    • 1998
  • K-GIC of the new carbon electrode to improve performance of carbon negative electrode in lithium ion secondary battery was prepated and its electrical characteristics were studied. Form this study, intercalated K quantity was increased in order of $2>3>1mole/{\ell}$ of KCl solution. And, for KCl solution of 1mole, the mole ratio of carbon and potassium was 156~388 carbon/potassium. The proper condition of K-GIC preparation was KCl solution of $1mole/{\ell}$, reaction temperature of $700^{\circ}C$, reaction time of 1 hour. From this condition, the intercalation and deintercalation behavior of lithium was very excellent. Also the reversibility was excellent.

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