• Title/Summary/Keyword: retention

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Study of Retention in Micellar Liquid Chromatography on a C18 Column on the Basis of Linear Solvation Energy Relationships

  • Tian, Minglei;Row, Kyung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.29 no.5
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    • pp.979-984
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    • 2008
  • In this study, 8 solutes (aniline, caffeine, p-cresol, ethyl benzene, methylparaben, phenol, pyridine, and toluene) have been tested in terms of linear solvation energy relationships (LSER). Several micellar liquid chromatography (MLC) systems using cationic surfactant cetyltrimethylammonium bromide (CTAB) and a mixture of water with (methanol, n-propanol, and n-butanol) modifiers were characterized using the LSER solvation parameter model. The effects of the surfactant and modifier concentration on the retention in MLC were discussed. LSER model had demonstrated high potential to predict retention factors with high squared correlation coefficients ($r^2$ > 0.99). A comparison of predicted and experimental retention factors suggests that LSER formalism is able to reproduce adequately the experimental retention factors of the solutes studied in the different experimental conditions investigated. This model is a helpful tool to understand the solute-surfactant interactions and evaluate the retention characteristic of micellar liquid chromatography.

Effect of SDS on Retention of Nucleic Acid Components in High-Performance Liquid Chromatography

  • Kim Yong-Nam;Choi Kyeung-Soo;Lee Dai-Woon;Phyllis R. Brown
    • Bulletin of the Korean Chemical Society
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    • v.13 no.3
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    • pp.240-245
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    • 1992
  • The effect of the addition of sodium dodecyl sulfate (SDS) to a buffered mobile phase (pH 3.4) on the retention of nucleotides, nucleosides and bases was investigated with a polyvinyl alcohol (PVA) column. Depending on the concentration of SDS, two different trends in the retention of nucleosides and bases containing an $NH_2$ group were observed. If the concentration of SDS was less than 5.5 mM, the retention of compounds containing an $NH_2$ group increased as the concentration of SDS in the mobile phase increased. In contrast, if the concentration was greater than 5.5 mM, the retention of compounds containing an $NH_2$ group decreased. Thus, the SDS acted as an ion-pairing reagent at lower concentration but formed micelles at higher concentrations. The retention behavior of the nucleosides and bases in the presence of a micellar concentration of SDS in the mobile phase on the PVA column was compared to the retention behavior on other types of columns.

Effect of Pre-Treatment Methods before Cooking on Mineral Retention in Siraegi (Raddish Leaves) (조리전 전처리 방법에 따른 시래기의 무기성분의 변화)

  • 박세원;유양자
    • Korean journal of food and cookery science
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    • v.13 no.5
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    • pp.635-638
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    • 1997
  • Dried raddish leaves were prepared by using three different pre-treatment methods (shady sun-drying, freezing after blanching, and shady sun-drying after blanching). Then, the retention of minerals in dried raddish leaves was determined. It was shown that the retention of most minerals (Na, K, Fe, Ca, Mg) except P was higher when shady sun-drying method was used. The retention of P was shown to be the lowest when freezing after blanching method was used.

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The Deformation Behavior of Anchored Retention Walls installed in Cut Slope (절개사면에 설치된 앵커지지 합벽식 옹벽의 변형거동)

  • Yun, Jung-Mann;Song, Young-Suk
    • The Journal of Engineering Geology
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    • v.19 no.4
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    • pp.475-482
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    • 2009
  • The behavior of earth retention wall installed in cut slope is different from the behavior of retention wall applied in urban excavation. In order to establish the design method of anchored retention walls in cut slope, the behavior of anchored retention wall can be investigated and checked in detail. In this study, the behavior of anchored retention wall was investigated by instrumentation installed in cut slope for an apartment construction stabilized by a row of piles. The horizontal displacement of anchored retention wall was larger than the displacement of slope soil behind the wall at the early stage of excavation. As the excavation depth became deeper, the horizontal displacement of slope soil was larger than the displacement of anchored retention wall. It means that the horizontal displacement of anchored retention wall due to excavation is restrained by soldier pile stiffness and jacking force of anchor. Jacking force of anchor was mainly influenced in the horizontal displacement of anchored retention wall. The displacements of anchored retention wall and slope soil were affected mainly by an rainfall infiltrated from the ground surface. Meanwhile, the horizontal displacement of anchored retention wall with slope backside was about 2-6 times larger than the displacement of anchored retention wall with horizontal backside of excavation.

The Deformation Behavior of Anchored Retention Walls in Cut Slope (절개사면에 설치된 앵커지지 흙막이벽의 변형거동)

  • Song Young-Suk;Lee Jae-Ho;Kim Tae-Hyung
    • The Journal of Engineering Geology
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    • v.15 no.2 s.42
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    • pp.155-168
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    • 2005
  • The behavior of earth retention wall installed in a cut slope is different from the behavior of retention wall applied in an urban excavation. In order to establish the design method of anchored retention wall in the cut slope, the behavior of anchored retention wall needs to be investigated and checked in detail. In this study, the behavior of anchored retention wall was investigated by the instrumentation installed in the cut slope, where was stabilized by a row of piles in an apartment construction site. The horizontal displacement of anchored retention wall was larger than the displacement of slope soil behind the wall at the early stage of excavation. As the excavation depth became deeper, the horizontal displacement of slope soil was larger than the displacement of anchored retention wall. It means that the horizontal displacement of anchored retention wall due to excavation is restrained by soldier pile stiffness and jacking force of anchor at the early stage of excavation. lacking force of anchor was mainly influenced on the horizontal displacement of anchored retention wall. The displacements of anchored retention wall and slope soil were affected mainly by rainfall infiltrated from the ground surface. Meanwhile, the horizontal displacement of anchored retention wall with a sloped backside was about $2\~6$ times larger than the displacement of anchored retention wall with a horizontal backside of excavation.

Deformation Behavior and Slope Stability Effect of Anchored Retention Walls Installed in Cut Slope (절개사면에 설치된 앵커지지 합벽의 변형거동 및 사면안정효과)

  • Hong Won-Pyo;Han Jung-Geun
    • Journal of the Korean Geotechnical Society
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    • v.20 no.9
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    • pp.57-64
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    • 2004
  • In order to establish the design method of anchored retention walls in cut slope, the behavior of anchored retention walls and backside ground needs to be investigated and checked in detail. In this study, the behavior of anchored retention walls was investigated by instrumentation installed in cut slope for an apartment construction site stabilized by a row of piles and anchored retention walls. When the anchor was installed at each excavating stages, the horizontal deflection of retention wall decreased, while the horizontal deformation of backside ground increased. The deflection of anchored retention wall decreased as the anchor was prestressed. The prestressed anchor farce has a great effect on the deflection of retention walls, while it has little effect on the deformation of its backside ground. The maximum horizontal deflection of anchored retention walls was developed between $1\%\;and\;4\%$ of excavation depth, which are $2\~8$ times larger than max. horizontal deflection of anchored retention walls including rock layers with backside horizontal ground. Meanwhile, SLOPILE (ver. 3.0) program analyzes the slope stability effects for anchored retention walls. As a result of analysis on slope stability analysis, the lateral earth pressure applied at anchored retention piles could be used as the mean values of empirical lateral pressures using anchored retention wall with horizontal ground at its backside.

An Analysis of Research on Postpartum Weight Retention (산후체증정체(Postpartum Weight Retention)관련 국외 연구논문 분석)

  • Lee, Seoung-Eun;Yoo, Eun-Kwang
    • Women's Health Nursing
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    • v.9 no.3
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    • pp.287-298
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    • 2003
  • Purpose: To explain the concept of postpartum weight retention and to analyze factor effect on it. Method: A total of 20 studies related postpartum weight retention were selected in the year of 1988-2001 and analysis was done. Result: A demographic factor like parity, age, social and economic level and life style such as exercise, diet, breast feeding are influential factor on postpartum retention weight. But parts of them don't agree the same results. Meanwhile, in some studies, psychological factor like women's self esteem related to postpartum retention weight, body image change, depressing is found to be very related. As a result, postpartum overweight gain could be a bad factor of physical and mental health. In Korea, we have few studies related to them. Conclusion: It is required to do many-sided and deep studies about aspects of postpartum retention weight and the factor that effect on it. Postpartum retention weight should be approached by controling weight from the period of pregnancy. And it would rather be researched through individual approach considered women's various demographic, social-cultural and physical level than be required standardized level of weight gain.

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A Study on the Shear Bond Strength of Resin Artificial Tooth Depending on Repair Techniques (레진 인공치아의 재부착 방법에 따른 전단결합강도에 관한 연구)

  • Kim, Ik-Jung;Lee, Jong-Hyuk;Cho, In-Ho
    • Journal of Dental Rehabilitation and Applied Science
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    • v.21 no.2
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    • pp.143-151
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    • 2005
  • The purpose of this study was to evaluate the most effective method for repairing the exfoliated resin teeth. The specimens were divided into five groups according to repair method and presence of retention holes. The groups were as follows Group1 : Control group Group2 : Sprinkle method with no retention holes Group3 : Sprinkle method with retention holes Group4 : Flask method with no retention holes Group5 : Flask method with retention holes The results were as follows. 1. According to shear bond strength, the value decreased in the order of group1, group5, group3, group2, group4 and there were significant difference between, each group except between group1 and groups5, group2 and group3, group2 and group4(p < 0.05). 2. According to observations of the exfoliation surface, group2 and 4 showed more failure in the denture base resin and repair resin interface, but in group1, 3 and 5 there were more mixed failures. From the results above, there were no significant difference between repair methods without retention holes. But when comparing groups with retention holes, the flask method showed significantly improved results compared to the sprinkle method. Especially, group5 showed similar results as the control group.

Scaled Down Experiment of Retention Basin with a Rotatable Bucket Using 3D Printer (3D 프린터를 이용한 회전 버킷이 부착된 저류조의 모형 실험)

  • Park, Seong-Jik;Lee, Chang-Gu;Lee, Jemyung;Choi, Won
    • Journal of The Korean Society of Agricultural Engineers
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    • v.59 no.2
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    • pp.49-55
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    • 2017
  • Recently climate change and urbananization have been increased surface runoff, resulting in flooding. Retention basins have been constructed to control urban flooding by reducing peak flow rate. Recently, the retention basin plays a role in controlling combined sewer overflows (CSOs) as well as urban flooding. In this study, the retention basin with a rotatable bucket was suggested and scale down experiments was performed for the optimum design of the retention basin. Scaled down model was produced using a 3D printer after it was designed as law of similarity. Two times for operating a rotary bucket is required to sweep out the sediments deposited on the bottom of the basin. Optimized dimensions for the retention basin were width of 5 m, height of 5 m, bucket radius of 0.5 m, and bottom slope of 5.0 %. It can be concluded that the results obtained from this study can be used to design the retention basin with a rotatable bucket which does not require energy to operate.

THE EFFECT OF VARIOUS DESENSITIZING AGENTS ON RETENTION AND FITNESS OF CEMENTED CROWNS WITH ZINC PHOSPHATE CEMENT (수 종의 지각 과민 완화제가 인산 아연 시멘트 사용시 주조관의 유지력 및 적합도에 미치는 영향)

  • Oh Se-Wook;Lee Ho-Yong
    • The Journal of Korean Academy of Prosthodontics
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    • v.32 no.2
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    • pp.181-194
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    • 1994
  • The purpose of this study was to compare the retention and fitness of crown treated with various desensitizing agents on natural teeth. Varnish, dentin primer, bonding agent and potassium oxalate treated groups and control group with no treatment were used. The retention test was executed with the Instron test machine(Instron Co.,U.S.A.) on 24 hours after cementation with zinc phosphate cement. After retention test, the teeth and crowns were washed and recemented. The cemented crowns were embedded in clear resin and sectioned with a diamond saw. The occlusal and marginal fitnesses, were measured indirectly with a stereomicroscopic photographs. The result of this study were obtained as follows : 1. The retention of control group was higher than any other desensitizing agent treated group. 2. The differences of retention among varnish, dentin primer, bonding agent and potassium oxalate treated groups were not statistically significant. 3. There were no statistically significant difference in fitness at occlusal surface and margin among control, varnish, dentin primer, bonding agent and potassium oxalate treated groups. According to these results, desensitizing agents used to protect the pulp from irritation of luting agents may adversely affect the retention of castings. Therefore, desensitizing agents should be used in limited areas carefully.

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