• Title/Summary/Keyword: resonance scattering

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Enhanced Light Transmittance of Densely Packed Metal Nanoparticle Layers (밀집된 금속 나노 입자 레이어의 광학 특성)

  • Jeon, Hyunji;Choi, Jinnil
    • Korean Journal of Materials Research
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    • v.30 no.12
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    • pp.701-708
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    • 2020
  • Irradiation of the metal nanoparticles causes local plasmon resonance in a specific wavelength band, which can improve the absorption and scattering properties of a structure. Since noble metal nanoparticles have better resonance effects than those of other metals, it is easy to identify plasmonic reactions and this is advantageous to find the optical tendency. Compared to having a particle gap or randomly arranged particle structures, densely and evenly packed structures can exhibit more uniform optical properties. Using the uniform properties, the structure can be applied to optical filtering applications. Therefore, in this paper, validation tests about metal nanoparticles and thin film structures are conducted for more accurate analysis. The optical properties of monolayer and bilayer noble metal nanoparticle structures with different diameters, packed in a uniform array, are investigated and their optical trends are analyzed. In addition, a thin film structure under identical conditions as metal nanoparticle structure is evaluated to confirm the improved optical characteristics.

The applicability study and validation of TULIP code for full energy range spectrum

  • Wenjie Chen;Xianan Du;Rong Wang;Youqi Zheng;Yongping Wang;Hongchun Wu
    • Nuclear Engineering and Technology
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    • v.55 no.12
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    • pp.4518-4526
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    • 2023
  • NECP-SARAX is a neutronics analysis code system for advanced reactor developed by Nuclear Engineering Computational Physics Laboratory of Xi'an Jiaotong University. In past few years, improvements have been implemented in TULIP code which is the cross-section generation module of NECP-SARAX, including the treatment of resonance interface, considering the self-shielding effect in non-resonance energy range, hyperfine group method and nuclear library with thermal scattering law. Previous studies show that NECP-SARAX has high performance in both fast and thermal spectrum system analysis. The accuracy of TULIP code in fast and thermal spectrum system analysis is demonstrated preliminarily. However, a systematic verification and validation is still necessary. In order to validate the applicability of TULIP code for full energy range, 147 fast spectrum critical experiment benchmarks and 170 thermal spectrum critical experiment benchmarks were selected from ICSBEP and used for analysis. The keff bias between TULIP code and reference value is less than 300 pcm for all fast spectrum benchmarks. And that bias keeps within 200 pcm for thermal spectrum benchmarks with neutron-moderating materials such as polyethylene, beryllium oxide, etc. The numerical results indicate that TULIP code has good performance for the analysis of fast and thermal spectrum system.

Hydration Effect on the Intrinsic Magnetism of Natural Deoxyribonucleic Acid as Studied by EMR Spectroscopy and SQUID Measurements

  • Kwon, Young-Wan;Lee, Chang-Hoon;Do, Eui-Doo;Choi, Dong-Hoon;Jin, Jung-Il;Kang, Jun-Sung;Koh, Eui-Kwan
    • Bulletin of the Korean Chemical Society
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    • v.29 no.6
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    • pp.1233-1242
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    • 2008
  • The hydration effect on the intrinsic magnetism of natural salmon double-strand DNA was explored using electron magnetic resonance (EMR) spectroscopy and superconducting quantum interference device (SQUID) magnetic measurements. We learned from this study that the magnetic properties of DNA are roughly classified into two distinct groups depending on their water content: One group is of higher water content in the range of 2.6-24 water molecules per nucleotide (wpn), where all the EMR parameters and SQUID susceptibilities are dominated by spin species experiencing quasi one-dimensional diffusive motion and are independent of the water content. The other group is of lower water content in the range of 1.4-0.5 wpn. In this group, the magnetic properties are most probably dominated by cyclotron motion of spin species along the helical π -way, which is possible when the momentum scattering time (${\tau}_k$) is long enough not only to satisfy the cyclotron resonance condition (${\omega}_c{\tau}_k$ > 1) but also to induce a constructive interference between the neighboring double helices. The same effect is reflected in the S-shaped magnetization-magnetic field strength (M-H) curves superimposed with the linear background obtained by SQUID measurements, which leads to larger susceptibilities at 1000 G when compared with the values at 10,000 G. In particular, we propose that the spin-orbital coupling and Faraday's mutual inductive effect can be utilized to interpret the dimensional crossover of spin motions from quasi 1D in the hydrate state to 3D in the dry state of dsDNA.

Optical Properties of Ag@Fe3O4 Core-Shell Nanoparticles (Ag@Fe3O4 코어-쉘 나노입자의 광학적 특성)

  • Song, Younseong;Koh, Kwangnak;Kim, Kyujung;Lee, Jaebeom
    • Korean Journal of Optics and Photonics
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    • v.28 no.3
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    • pp.97-102
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    • 2017
  • In this paper, we investigate the optical properties of $Ag@Fe_3O_4$ nanoparticles (NPs) composed of a plasmonic core and a magnetic shell. As the $Fe_3O_4$ shell with high refractive index (~2.42) is formed on the surface of the silver NPs having diameter of 60 nm, the wavelength of the localized surface-plasmon resonance (LSPR) is shifted from 420 nm to 650 nm, a so-called "redshift". Furthermore, through the use of three simulation models ($Ag@Fe_3O_4$ NP, $Fe_3O_4$ shell NP, and silver NP), the peak at 410 nm is seen to be the result of scattering by the $Fe_3O_4$ shell with 60 nm thickness, which would be useful in comprehending the complex optics in various nanoscale assemblies using similar NPs.

Surface Enhanced Raman Spectroscopy-based Bio Sensing Technology Using Semiconductor Nanostructures (반도체 나노구조를 이용한 SERS기반 바이오센싱 기술)

  • Yu, Jae Su;Lee, Soo Hyun
    • Vacuum Magazine
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    • v.4 no.3
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    • pp.12-15
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    • 2017
  • Surface enhanced Raman scattering (SERS) is considered as one of promising medical and diagnostic technologies. The SERS effect is caused by the localized surface plasmon resonance (LSPR) from metal nanoparticles with narrow hot spots. The mechanism of LSPR, development of nanostructure fabrication, and corresponding researches are discussed. The flexible, label-free, low-cost, and highly-sensitive Au/ZnONRs/G is introduced. The Au/ZnONRs/G detects and distinguishes cataract, age-related macular degeneration, and diabetic macular edema from aqueous humor. Comprehension of SERS provides further improvement in bio sensing technology including early diagnosis and prolonged life expectancy.realize highly stretchable electrodes.

Chemical synthesis of processable conducting polyaniline derivative with free amine functional groups

  • Kar, Pradip
    • Advances in materials Research
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    • v.3 no.2
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    • pp.117-128
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    • 2014
  • Processable conducting polyaniline derivative with free amine functional groups was successfully synthesized from the monomer o-phenylenediamine in aqueous hydrochloric acid medium using ammonium persulfate as an oxidative initiator. The synthesized poly(o-phenylenediamine) (PoPD) in critical condition was found to be completely soluble in common organic solvents like dimethyl sulfoxide, N,N-dimethyl formamide etc. From the intrinsic viscosity measurement, the optimum condition for the polymerization was established. The polymer was characterized by ultraviolet visible spectroscopy, Fourier transform infrared spectroscopy, proton magnetic resonance spectroscopy ($^1HNMR$) and thermogravimetric (TGA) analyses. The weight average molecular weights of the synthesized polymers were determined by the dynamic light scattering (DLS) method. From the spectroscopic analysis the structure was found to resemble that of polyaniline derivative with free amine functional groups attached to ortho/meta position in the phenyl ring. However, very little ladder unit was also present with in the polymer chain. The moderate thermal stability of the synthesized polymer could be found from the TGA analysis. The average DC conductivity of $2.8{\times}10^{-4}S/cm$ was observed for the synthesized polymer pellet after doping with hydrochloric acid.

The magnetic dependence of 2-dimension quantum optical transition in electron-deformation potential phonon interaction systems in Ge

  • Choi, Hyenil;Cho, Hyunchul;Lee, Suho
    • Journal of IKEEE
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    • v.22 no.2
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    • pp.446-454
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    • 2018
  • In this work, we summarize the calculation processes of obtaining a scattering factor using with the equilibrium average projection scheme (EAPS), with moderately weak coupling (MWC) interaction, and obtain the line-shape formula of an electron-deformation phonon interacting system interested in the confinement of electrons by squarwell confinement potentials in quantum two dimensional system.. Through the numerical analysis, we analysis the magnetic dependence of absorption power, P(B) in several temperature and frequency difference dependence of absorption power $P({\Delta}{\omega})$, in several external field, where ${\Delta}{\omega}={\omega}-{\omega}_0$ and ${\omega}({\omega}_0)$ is the angular frequency (the cyclotron resonance frequency). The result of equilibrium average projection scheme (EAPS) in SER-MWC explains the properties of quantum transition quite well.

INTERACTION OF SURFACE WATER WAVES WITH SMALL BOTTOM UNDULATION ON A SEA-BED

  • Martha, S.C.;Bora, S.N.;Chakrabarti, A.
    • Journal of applied mathematics & informatics
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    • v.27 no.5_6
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    • pp.1017-1031
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    • 2009
  • The problem of interaction of surface water waves by small undulation at the bottom of a laterally unbounded sea is treated on the basis of linear water wave theory for both normal and oblique incidences. Perturbation analysis is employed to obtain the first order corrections to the reflection and transmission coefficients in terms of integrals involving the shape function c(x) representing the bottom undulation. Fourier transform method and residue theorem are applied to obtain these coefficients. As an example, a patch of sinusoidal ripples is considered in both the cases as the shape function. The principal conclusion is that the reflection coefficient is oscillatory in the ratio of twice the surface wave number to the wave number of the ripples. In particular, there is a Bragg resonance between the surface waves and the ripples, which is associated with high reflection of incident wave energy. The theoretical observations are validated computationally.

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Measurement of Effective Linewidth for Ca-Zr Substituted YIG (Ca-Zr치환 YIG의 유효 선폭 측정)

  • 김약연;한진우;한기평;김덕준;이상석;최태구
    • Journal of the Korean Magnetics Society
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    • v.10 no.1
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    • pp.22-29
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    • 2000
  • The effective linewidth was measured using the conventional cavity perturbation method at 9.43 GHz in room temperature for Ca-Zr substituted yttrium iron garnet plate. The experimental set-up consists of the network analyzer, the electromagnet and the cylimdrical TE001 cavity. Measurement was performed in the static magnetic field perpendicular to the sample plane. The real and imaginary parts of diagonal component of the microwave susceptibility tensor are obtained from the resonance frequency and the quality factor Q of the cavity. Variations of the effective linewidth was qualitatively explained with the spin wave scattering theory.

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Surface-Enhanced Raman Spectroscopic Studies of Oriented Monolayers on Electrode Surfaces

  • Yoon, Wan-Shik;Im, Jung-Hyuk;Kim, Jae-Ho
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.699-705
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    • 1995
  • Monolayers of hypericin, a photodynamic polycyclic quinoidal compound, were prepared at the air-water interface, and were transferred to metal substrates to form Langmuir-Blodgett (LB) monolayers. The structural characteristics of hypericin LB monolayers and self-assembled (SA) monolayers were investigated using surface-enhanced resonance Raman scattering (SERRS) spectroscopy. Both the spectroscopic data and the surface pressure - area (${\pi}-A$) isotherms suggest that hypericin forms ${\pi}-{\pi}$ aggregates that orient vertically to the subphase surface. Whereas the ordering and orientation of control was less effective in SA monolayers, a higher structural regularity was attained in LB systems. The effect of subphase on the structural integrity of the monolayer was also investigated.

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