• 제목/요약/키워드: resin membrane

검색결과 114건 처리시간 0.02초

전기분해와 공침법을 이용한 해수중의 납 제거 (Removal of Lead from Sea Water using Electrolysis and Coprecipitation Method)

  • 진홍성;이재호
    • 대한환경공학회지
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    • 제32권2호
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    • pp.149-154
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    • 2010
  • 전기분해와 공침법을 이용한 해수 중의 납 제거 가능성에 대하여 실험하였다. 전기분해조는 음이온교환수지를 채운 격막으로 분리되었다. 전기분해가 진행됨에 따라 음극식의 pH는 상승하여 콜로이드 형태의 $Mg(OH)_2$$CaCO_3$이 생성되었다. 넓은 표면적을 가지는 콜로이드 입자는 납 이온을 흡착하여 침천되었다. 전류밀도를 변화시키면서 바닷물의 전기분해하였으며 바닷물에 남아있는 Mg, Ca, Pb의 양을 적정법과 ASV 방법을 이용하여 측정하였다. 전류밀도와 pH가 증가함에 따라 바닷물 중의 납은 대부분 효과적으로 제거되었다.

Overdenture 하에서 하악응력 및 의치의 변위에 관한 유한요소법적 분석 (FINITE ELEMENT ANALYSIS OF MANDIBULAR STRESSES AND DENTURE MOVEMENTS INDUCED BY OVERDENTURES)

  • 김정희;정재헌;조규종
    • 대한치과보철학회지
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    • 제28권1호
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    • pp.63-94
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    • 1990
  • The purpose of this study was to analyze the displacement and the magnitude and the mode of distribution of the stresses in the lower overdenture, the mucous membrane, the abutment tooth and the mandibular supporting bone when various denture base materials, such as acrylic resin and 0.5mm metal base, and various denture base designs were subjected to different loading schemes. For this study, the two-dimensional finite element method was used. Mandibular arch models, with only canine remaining, were fabricated. In the first denture base design, a space, approximately 1mm thick, was prepared between the denture and the dome abutment. In the second denture base design, contact between the denture and the dome abutment was eliminated except the contact of the occlusal third of the abutment. In order to represent the same physiological condition as the fixed areas of the mandible under loading schemes, the eight nodes which lie at the mandibular angle region, the coronoid process and the mandibular condyle were assumed to be fixed. Each model was loaded with a magnitude of 10 kgs on the first molar region(P1) and 7 kgs on the central incisal region (P2) in a vertical direction. Then the force of 10 kgs was applied distributively from the first premolar to the second molar of each model in a vertical direction(P3). The results were as follows. : 1. When the testing vertical loads were given to the selected points of the overdenture, the overdenture showed the rotatory phenomenon, as well as sinking and the displacements of alveolar ridge, abutment and lower border of mandible under the metal base overdenture were less than those under the acrylic resin overdenture. 2. The maximum principal stresses(the maximum tensile stresses) being considered, high tensile stresses occured at the buccal shelf area, the posterior region of the ridge crest and the anterior border region of the mandibular ramus. 3. The minimum principal stresses(the maximum compressive stresses) being considered, high compressive stresses occured at the inferior and posterior border region of the mandible, the mandibular angle and the posterior border region of the mandibular ramus. 4. The vertical load on the central incisal region(P2) produced higher equivalent stress in the mandible than that on any other region(P1, P3) because of the long lever arm distance from the fixed points to the loading point. 5. Higher equivalent stresses were distributed throughout the metal base overdenture than the resin base overdenture under the same loading condition. 6. The case of occlusal third contact of the abutment to the denture produced higher equivalent stresses in the abutment, the mandibular area around the abutment and the overdenture than the case of a 1mm space between the denture and the abutment. 7. Without regard to overdenture base materials and designs, the amounts and distribution patterns of equivalent stresses under the same loading condition were similar in the mucous membrane.

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LNG운반선 방열시스템에 적용되는 적층형 플라이우드의 극저온 기계적 특성 분석 (Cryogenic Mechanical Characteristics of Laminated Plywood for LNG Carrier Insulation System)

  • 김정현;박두환;최성웅;이제명
    • 한국해양공학회지
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    • 제31권3호
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    • pp.241-247
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    • 2017
  • Plywood, which is created by bonding an odd number of thin veneers perpendicular to the grain orientation of an adjacent layer, was developed to supplement the weak points such as contraction and expansion of conventional wood materials. With structural merits such as strength, durability, and good absorption against impact loads, plywood has been adopted as a structural material in the insulation system of a membrane type liquefied natural gas (LNG) carrier. In the present study, as an attempt to resolve recent failure problems with plywood in an LNG insulation system, conventional PF (phenolic-formaldehyde) resin plywood and its alternative MUF (melamine-urea-formaldehyde) resin bonded plywood were investigated by performing material bending tests at ambient ($20^{\circ}C$) and cryogenic ($-163^{\circ}C$) temperatures to understand the resin and grain effects on the mechanical behavior of the plywood. In addition, the failure characteristics of the plywood were investigated with regard to the grain orientation and testing temperature.

이온교환수지 분말이 코팅된 탄소전극을 이용한 음이온 혼합용액에서 Nitrate 이온의 선택적 제거율 향상 (Enhancement of Selective Removal of Nitrate Ions from a Mixture of Anions Using a Carbon Electrode Coated with Ion-exchange Resin Powder)

  • 여진희;최재환
    • 공업화학
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    • 제24권1호
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    • pp.49-54
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    • 2013
  • 혼합용액에서 nitrate 이온을 선택적으로 제거하기 위해 복합탄소전극을 제조하였다. 질산이온 선택성 수지(BHP55, Bonlite Co.) 분말을 탄소전극 표면에 코팅하여 전극을 제조하였다. 제조한 전극으로 BHP55 셀을 제작하여 chloride, nitrate, sulfate 이온이 혼합된 용액에 대해 축전식 탈염 실험을 수행하였다. 그리고 BHP55 셀에서의 질산 이온 제거량을 이온교환막을 결합한 MCDI 셀의 결과와 비교하였다. BHP55 셀에서 이온의 총 흡착량은 MCDI 셀에서 보다 31% 증가한 $38.3meq/m^2$를 나타냈다. 또한 BHP55 셀에서 질산 이온의 흡착량은 $15.9meq/m^2$ (전체 흡착량의 42%)이었고, 이는 MCDI 셀에서 보다 2.1배 큰 것으로 나타났다. 실험결과 제조한 복합탄소전극은 음이온 혼합용액에서 질산 이온을 선택적으로 제거하는데 매우 효과적임을 알 수 있었다.

상아질 지각완화제가 치과용 시멘트의 결합강도에 미치는 영향 (THE INFLUENCE OF DENTIN DESENSITIZER TO SHEAR BOND STRENGTH OF DENIAL CEMENTS)

  • 나윤호;오남식;유재흥
    • 대한치과보철학회지
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    • 제45권5호
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    • pp.579-588
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    • 2007
  • Statement of problem: A tenderness of the dentin after tapering of teeth for dental prosthesis is a common phenomenon. In practice, the alternative desensitizer may be used for minor pain after tapering of teeth. Purpose: In this study, the desensitizers were used to investigate the affect decreasing of shear bond strength according to the use of various cement, such as resin, Glass Ionomer, and phosphate cement. Material and method: Three different desensitizers were used on this study Compositions of two dentin desensitizers were HEMA(hydroxyethylmethacrylate) and glutaraldehyde. The other one is oxalic acid. Three dentin desensitizers applied on 12 degrees taper teeth. Then, Ni-Cr crowns were bonded with Resin cement, Zinc Phosphate (ZPC) cement and Glass Ionomer (GIC) cement. 120 human premolar teeth were used for specimens. The specimens were divided into four group as the reference and the empirical each with thirty specimens, then further divided into 12 group according to type of desensitizers and cement types. The shear bond strength were measured by Instron multi task instrument. Results: According to the result, the measured shear bond strength in order from the weakest to the strongest in general was ZPC, Resin, and GIC. And it is found that the application of desensitizers on dentin surface does not affect the shear bond strength. Conclusion: Dentin desensitizers that alleviate or prevent a dentin tenderness, usually contains HEMA and glutaraldehyde compounds. Such desensitizers are widely used in clinical studies. By applying the dentin desensitizer on the exposed dentin surface, the dentin capillary are blocked and periodontal membrane and cementum can not be drawn in pulp cavity. Since HEMA and glutaraldehyde may cause harm to the pulp cavity, an alternative desensitizer was developed.

Affinity Immobilization of Dextransucrase on Dextran-based Support and the Production of Leucrose

  • Han, Nam-Soo;Kang, Seung-Yeon;Lee, Soo-Bok;Robyt, John F.
    • Food Science and Biotechnology
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    • 제14권3호
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    • pp.317-322
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    • 2005
  • A simple and convenient method of immobilizing dextransucrase via an affinity interaction is described, along with the use of this system to synthesize leucrose. Dextransucrase was produced in sucrose-free medium by fermenting a constitutive mutant of Leuconostoc mesenteroides NRRL B-512F and was separated using an ultrafiltration membrane. The purified enzyme was free of dextran polymer, which previously was always found with the sucrose-induced enzyme. Therefore, it was possible to immobilize the enzyme on dextran-based resins using an affinity interaction. Sephadex G-200 was the best resin for immobilizing the dextransucrase and gave a fast flow rate through the packed column. The immobilized dextransucrase retained more than 80% of its specific activity after immobilization ($K_m\;=\;18.1\;mM$ and $k_{cat}\;=\;450\;sec^{-1}$ vs. 13.1 mM and $640\;sec^{-1}$, respectively, for the free enzyme). The immobilized dextransucrase showed improved stability over a pH range of 4.0 to 6.5 and at moderately high temperatures over $40^{\circ}C$. When immobilized dextransucrase was used to synthesize leucrose via the transfer reaction with sucrose and fructose, about 74% of the sucrose was converted into leucrose after one day, and the half-life of the enzyme activity was 15 days. Regeneration of the resin by supplementation with dextransucrase enabled the recovery of the initial activity of the system, but both the reaction and the flow rate were lower, probably owing to the accumulation of dextran inside the resin.

Effect of Kefir Extract on th Growth of Serum-Free Mouse Embyro (SFME) Cells

  • Jang, Hae-Dong;David Barnes
    • Preventive Nutrition and Food Science
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    • 제5권4호
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    • pp.225-229
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    • 2000
  • The antioxidative and protective activities of kefir, low-fat dry milk (NFDM) extract and fractions on SFME cells in serum-free medium were investigated. Kefir and low-fat kefir and NFDM extract were made by solubilizing the freeze dried powder forms in deionized water, filtering through glass prefilter, 12 ㎛ and 2 ㎛ membrane, and demineraling with chelating resin. Kefir, low-fat kefir and NFDM extract were fractioned into dialyzate and retentate by dialysis with membrane tube having the molecular cut-off of 3,500 Dalton. An antioxidative activity was analyzed by the in vitro model system using a linoleic acid. In the case of kefir an antioxidative activity was detected only in the retentate of kefir extract. On the other hand NFDM showed an antioxidative activity in extract, demineralized extract, dialyzate and retentate. The retentate of kefir extract had the higher antioxidative activity than that of NFDM extract. Kefir showed the protective effect of SFME cells in serum-free medium in extract, demineralized extract and retentate, but low-fat kefir didn't. NFDM had the similar protective effect on SFME cells as extract, demineralized extract and retentate of kefir.

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Gas Barrier성 SEBS (Styrene Ethylene Butadiene Styrene Copolymer)-Clay 하이브리드 막의 제조 및 물성 (Preparation and Properties of SEBS (Styrene Ethylene Butadiene Styrene Copolymer)-Clay Hybrid Gas Barrier Membranes)

  • 남상용;염봉열;민병렬;김영진
    • 멤브레인
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    • 제15권1호
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    • pp.62-69
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    • 2005
  • 본 연구에서는 SEBS와 여러 가지의 유기화물로 처리된 MMT (montmorillonite) type의 clay를 이용하여 SEBS-clay 하이브리드 막을 용융삽입법으로 제조하였다. clay의 함량은 5 phr (per hundred resin)로 고정하였다. internal mixer를 사용하여 clay를 SEBS에 분산시켰으며, 제조된 SEBS-clay 하이브리드에서 clay의 특성피크가 완전히 박리되거나 이동하는 XRD 결과로부터 clay의 층간거리가 넓어지는 고분자의 clay 층간삽입을 확인하였다. Clay의 종류에 따라서 제조된 SEBS-clay 하이브리드 막의 가스투과도, 기계적 물성 및 열적 성질을 측정하였다. SEBS-clay 하이브리드 막은 clay 자체의 도입과 층간거리의 확대로 기체분자의 tortuosity를 증가시켜서 가스투과도를 저하시키는 것을 확인하였다.

AMESet 기반 20 kW급 수소 연료전지 시스템 동특성 모델 해석 (Analysis of Dynamic Characteristics of 20 kW Hydrogen Fuel Cell System Based on AMESet)

  • 우종빈;김영현;유상석
    • 한국수소및신에너지학회논문집
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    • 제34권5호
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    • pp.465-477
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    • 2023
  • In proton exchange membrane fuel cell (PEMFC), proper thermal management of the stack and moisture generation by electrochemical reactions significantly affect fuel cell performance. In this study, the PEMFC dynamic characteristic model was developed through Simcenter AMESim, a development program. In addition, the developed model aims to understand the thermal resin balance of the stack and performance characteristics for input loads. The developed model applies the thermal management model of the stack and the moisture content and permeability model to simulate voltage loss and stack thermal behavior precisely. This study extended the C based AMESet (adaptive modeling environment submodeling tool) to simulate electrochemical reactions inside the stack. Fuel cell model of AMESet was liberalized with AMESim and then integrated with the balance of plant (BOP) model and analyzed. And It is intended to be used in component design through BOP analysis. The resistance loss of the stack and thermal behavior characteristics were predicted, and the impact of stack performance and efficiency was evaluated.

이질아메바(Entamoeba histolytica)의 미세구조 및 효소활성에 관한 전자현미경적 연구 (Electron-microscopic studies on fine structure and enzyme activity in the axenic and conventional strains of Entamoeba histolytica)

  • 용태순;정평림;이근태
    • Parasites, Hosts and Diseases
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    • 제23권2호
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    • pp.269-284
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    • 1985
  • The metabolism of Entamoeba histolytica would be affected by various environmental factors, and alteration of the environment was known to afEect the fine structure of 5. histolytica. The present study was designed electronmicroscopically to investigate the ultrastructure and enzyme activities in the aEonic and conventional strains of 5. histolytica. The trophozoites of axenically cultivated HK-9 strain and conventional YS-27 and YS-49 strains of 5. histolytica were collected and liKed with 4% paraformaldehyde/0.1M cacodylate buffier(pH 74), After washing them by centrifugation, 1% warm agar was added in the sediment. Solidified agar with the trophozoites was cut into $lmm^3$ cubes, and incubated in the various substrates to observe enzyme activities. Then, the specimen was post-fixed with 3% glutaraldehyde/0.1M cacodylate buffer (PH 7.4) and 1% osmium tetroBide/0.1M cacodylate buffier (pH 7.4) , dehydrated in ascending ethanol series and embedded in epoxy resin. These were sectioned on an ultramicrotome and observed with a transmission electronmicroscope. The procedures for the observation of the fine structure were same as the above, except for the incubation in the substrate. The sections were stained with uranyl acetate and lead citrate. For the observation of the surface of the amoebae, scanning-electronmicroscopy was carried out. The results obtained in the present study are summarized as follows: 1. The fuzzy coat around double-layered plasma membrane of 5. histolytica was more irregularly and densely distributed in the conventional strains (YS-27, YS-49 strains) than in the axonic strain (HK-9 strain). 2. The endosomes, button bodies and chromatin material were surrounded by a double-layered nuclear membrane having scattered nuclear fores. The paranuclear body, mono- or double-layered vacuoles, vacuolar membrane whorls, rosette-like cylindrical bodies, aggregation of cylindrical bodies and helical bodies were found in the cytoplasm of the amoebae. Helical bodies and glycogen granules were generally abundant, while a few smooth endoplasmic reticula were observed in the cytoplasm. 3. Alkaline phosphatase activity was mainly demonstrated in the plasma membrane, limiting membranes of vacuoles and smooth endoplasmic reticula. ATPase activity was observed in the nucleus, limiting membranes of vacuoles and vacuolar membrane whorls. 4. Acid phosphatase activity was commonly demonstrated in the limiting membranes an contents of vacuoles, Iysosome-like organelles, plasma membrane and the button bodies in the nucleus. The activity was more weakly demonstrated in the HK-9 strain than in the other conventional strains of 5. histolytica. No peroBidase activity was observed in the amoeba strains employed in the present study. 5. With a scanning electron-microscope, no distinct structural differences were observed between the amoeba strains. All the trophozoite forms of the amoebae showed crater-like depressions and rugged features on the outer surface.

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