• Title/Summary/Keyword: resin membrane

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Present State of Membrane Structures in Japan

  • Oda, Kenshi
    • Journal of Korean Association for Spatial Structures
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    • v.2 no.2 s.4
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    • pp.11-15
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    • 2002
  • Formerly, it was called a tent and now, it is called membrane structure. If saying a tent, it imagines the tent of Bedouin, Mongolia and North American Indian. It became clear from the excavated wall painting that have been covered with the retractable roof of the canvas on the auditorium at the amphitheater in Pompeii and became a topic. These tents were made of the animal skins or fabric woven with the flax plants, and these tents are still used. However, if saying membrane material at present, it says the one to have applied a coating resin to the textile. Because the base fabric of membrane material is a woven fabric, the relation between the stress and the strain is different to the direction of the weaving thread. Moreover, the tensile force must always occur in the membrane surface. From these reasons, because the membrane structure corresponds to the particular building material and the construction method about the Building Standard Law, it must be examined specially that the membrane structural building have the same or any more safety as the provisions which was set to the Building Standard Law. Therefore, the technical standards about the membrane structural building became indispensable. In the paper, the kinds of the membrane materials, which are used for the membrane structural buildings, and technical standards process of the creating for the membrane structure buildings are introduced. Lastly, some of the soccer stadiums for 2002 FIFA World Cup KOREA/JAPAN which be covered with the roof of the membrane structures are presented.

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Construction of Carbon Paste Coated Wire Ion-Selective Electrode for Chloride and Its Application to Environmental Water Analysis

  • Yong-Kyun Lee;Soo Kil Rhim;Kyu-Ja Whang
    • Bulletin of the Korean Chemical Society
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    • v.10 no.6
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    • pp.485-488
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    • 1989
  • A carbon paste coated-wire ion-selective electrode for chloride (carbon chloride-CWE) was constructed using epoxy resin, ion-exchanger and carbon powder as a polymer membrane. Its utility, the composition of a polymer membrane, the response characteristics, and the selectivity were examined and applied to the environmental water analysis. The carbon chloride-CWE was prepared using a silver wire, which was covered with silver chloride and then coated with epoxy resin into which chloride ion-exchanger and carbon powder were previously incorporated in advance. The response of the carbon chloride-CWE was Nernstian for $1.0{\times}10^{-2}-2{\times}10^{-5}$ M chloride and the useful pH range from $10^{-2} M Cl- to 10^{-4} M Cl^-$ was 3.0-9.0. Furthermore, the selectivity of chloride over iodide, bromide, and cyanide was much improved compared with those for a solid state epoxy body chloride electrode and a liquid membrane chloride electrode. The carbon chloride-CWE was applied to determine Cl^-$ in tap and ground water. The obtained results were in good agreement with those by the established methods such as spectrophotometric or other chloride-selective electrode methods.

Performance Evaluation of Platinum Dispersed Self-humidifying Polymer Electrolyte Membrane Prepared by Using RF Magnetron Sputter

  • Kwak, Sang-Hee;Yang, Tae-Hyun;Kim, Chang-Soo;Yoon, Ki-Hyun
    • Journal of the Korean Ceramic Society
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    • v.40 no.2
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    • pp.118-122
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    • 2003
  • The performance evaluation on Pt loading in the self-humidifying polymer electrolyte membrane for Polymer Electrolyte Mem-Brane Fuel Cell(PEMFC) was investigated by using single cell test and measurement of membrane resistance. The self-humidifying membrane comprised two membranes made of perfluorosulfonylfluroride copolymer resin and fine Pt particles tying between them, coated by sputtering. From the results of performance characteristics of self-humidifying membrane cell with different Pt loading, a single cell using self-humidifying membrane with 0.15 mg/$\textrm{cm}^2$ Pt loading showed better performance than that with the others over entire current density. Also, a single cell with 0.15 mg/$\textrm{cm}^2$ Pt loading had a lower resistance value than the other cells under externally nonhumidifying condition. It is indicated that the water produced in the membrane cell with 0.15 mg/$\textrm{cm}^2$ Pt loading showed a higher provision to maintain ionic conductivity of the membrane than the other cells. The optimum amount of Pt particles embedded in the membrane for self-humidifying PEMFC was determined to be about 0.15 mg/$\textrm{cm}^2$.

Preparation and Characteristics of Heterogeneous Cation Exchange Membrane : 2. Characteristics Change on Post-treatment (PE계 불균질 양이온 교환막의 제조와 특성 : 2. 후처리에 따른 특성 변화)

  • Yang, Hyun S.;Cho, Byoung H.;Kim, Woong K.;Lee, Chang S.
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.67-75
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    • 1997
  • Heterogeneous cation exchange membrane consisting of cation exchange resin particles (diameter of less than $149{\mu}$) which are finely dispersed in a polyethylene matrix, were produced as forms of sheet. The characteristics were measured after treating hot water or saturated sodium chloride. When membranes were treated with hot water or saturated sodium chloride, cation exchange resin particles swell and expand pushing away the polyethylene matrix of membranes. The above treatment results the formation of narrow cavities between a cation exchange resin particles and polyethylene matrix, and the formation of fine micro-cracks on the polyethylene matrix. Thus, we were obtained good physical and electrochemical properties. On the treatment with hot water or saturated sodium chloride, the optimum conditions for good heterogeneous cation exchange membrane were treatment time of 30min and treatment temperature of $90^{\circ}C$.

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Performance evaluation of nitrate removal in high TDS wet scrubber wastewater by ion exchange resin with dissolved air flotation (DAF) process

  • Kim, Bongchul;Yeo, Inseol;Park, Chan-gyu
    • Membrane and Water Treatment
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    • v.13 no.1
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    • pp.1-6
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    • 2022
  • The regulations of the International Maritime Organization (IMO) have been steadily strengthened in ship emissions. Accordingly, there is a growing need for development of related technologies for the removal of contaminants that may occur during the treatment of SOx and NOx using a wet scrubber. However, this system also leads to wastewater production when the exhaust gas is scrubbed. In this research, we evaluated the performance of an ion selective resin process in accordance with scrubber wastewater discharge regulations, specifically nitrate discharge, by the IMO. Accelerated real and synthetic wastewater of wet scrubbers, contained high amounts of TDS with high nitrate, is used as feed water in lab scale systems. Furthermore, a pilot scale dissolved air flotation (DAF) using microbubble generator with ion exchange resin process was combined and developed in order to apply for the treatment of wet scrubber wastewater. The results of the present study revealed that operating conditions, such as resin property, bed volume (BV), and inlet wastewater flow rate, significantly affect the removal performance. Finally, through a pilot test, DAF with ion exchange resin process showed a noticeable improvement of the nitrate removal rate compared to the single DAF process.

The electron microscopic studies on conidio spores of Aspergillus niger (Aspergillus niger 균(菌)의 분생포자(分生胞子)에 관한 전자현미경적(電子顯微鏡的) 연구(硏究))

  • So, In-Young
    • Applied Microscopy
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    • v.1 no.1
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    • pp.11-17
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    • 1969
  • Conidio spores of Aspergillus niger (strain No. NRRL 330) cultured on potato dextrose agar media were studied by electron microscopy, using the thin sectioning techniques. Conidio spores to be sectioned were fixed by triple methods with $K_2Cr_2O_7$, Glutaraldehyde and $OsO_4$. After dehydrated with alcohol, the specimens were embedded in metacrylate and epon resin media, and thinly sectioned by Porter-Blum MT-2. After sectioned these specimens were negative-stained with uranyl acetate and observed. by Hitachi HS-6 electron microscope. The results of this experiment were summarized as follows. 1. The structures of spore ,wall system seem to be formed 4 layers; exosporium, basal layer, spore coat and unit cell membrane. The protuberance of spore surface that was looked like hair appears to be protrusived from the basal layer. 2. The 3 layers of unit cell membrane was constituted outer layer membrane, inner layer membrane and inter-mediate light layer. 3. The structures of intra cytoplasmic membrane appear as spiral form which was consisted of 3 layers membrane system; outer membrane, inner membrane, and intermediate layer, which has pits. 4. The cement substance of spore coat and cortex may be changed quantitatively by physiological state in cell. 5. In some cases, we observed that the ribosome was transformed into poly ribosome group, and the storage materials and the protein crystals were changed variously. It. has been suggested that the morphological change of some cytoplasmic materials may be caused by some specialized function of the physiological stage.

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Analyses on Environment-friendliness of Root Barrier Materials based on Fish Toxicity Test (어독성 실험에 따른 방근재 친환경 특성 분석)

  • Woo, Ji-Keun;Kim, Sung-Kyun
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.13 no.4
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    • pp.42-51
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    • 2010
  • The purpose of this study is to analyze the characteristics of environment-friendliness of Root Barrier materials based on comprehensive experiments on harmfulness of Root Barrier materials and fish toxicity of Oryzias latipes mortality to verify eco-toxicity of each method of construction and Root Barrier material, which are to be applied by taking eco-toxicity into account when building ecological flows in upper areas on natural and artificial grounds. As a result, the following conclusions have been reached in this study: 1. In regard of the harmfulness analyzed, each material showed a different result of analytical value in each lab tank. Compared to lab tank, pH (la), DO (lb), T-N (VI) and T-coli (la) were in the same grade, but COD, SS, T-P and F-coli were less than that of control, respectively increased or decreased by material were analyzed. 2. In the experiment of fish toxicity, Barrier sheet was found to have 66.7% of fish mortality, indicating strong fish toxicity. Synthetic rubber system root barrier sheet (20.0%) was analyzed to have medium fish toxicity, while Synthetic resin system root barrier-waterproof sheet (3.3%), Synthetic rubber system membrane root barrier sheet (3.3%) and Synthetic resin system root barrier sheet (0.0%) showed relatively lower mortality and fish toxicity. To sum up such results as found in the experiment mentioned so far, the values of harmfulness and root penetration resistance analyzed were different in each lab tank, but there was absolutely little correlation with the mortality gained from the experiment on fish toxicity. In the experiment of fish toxicity, environment-friendly root barrier materials were analyzed, and it was found that Synthetic resin system root barrier sheet, Synthetic resin system root barrier waterproof sheet and Synthetic rubber system membrane root barrier sheet are highly environment-friendly. In contrast, Synthetic rubber system root barrier sheet was found to have medium-level environment-friendliness. Also, Barrier sheet was analyzed to have low environment-friendliness.

Performance of Membrane Capacitive Deionization Process Using Polyvinylidene Fluoride Heterogeneous Ion Exchange Membranes Part II : Performance Study of Membrane Capacitive Deionization Process (폴리비닐플루오라이드 불균질 이온교환막을 이용한 막 결합형 축전식 탈염공정의 탈염성능 Part II : 불균질 이온교환막의 탈염성능)

  • Park, Cheol Oh;Rhim, Ji Won
    • Membrane Journal
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    • v.27 no.3
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    • pp.240-247
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    • 2017
  • In this study, the heterogeneous ion exchange membranes prepared by the combination of the carbon electrode and mixed the cation and anion exchange polymers and polyvinylidene fluoride as the basic polymer together were made to recognize the efficiency of the salt removal for the application of the membrane capacitive deionization process. The mixing weight ratio of the solvent, basic polymer and ion exchange resin was 7 : 2 : 1 and this mixed solution was directly cast on the electrode. As for the operating conditions of the adsorption voltage and time, feed flow rate, desorption voltage and time of the feed solution NaCl 100 mg/L, the salt removal efficiencies (SRE) were measured. Apart from this NaCl, the $CaCl_2$ and $MgSO_4$ solutions were investigated in terms of SRE as well. Typically, SRE for NaCl 100 mg/L solution under the conditions of adsorption voltage/time, 1.5 V/3 min, desorption voltage/time -0.1 V/3 min, was shown 98%. And for the $CaCl_2$ and $MgSO_4$ solutions, the SREs of 70 and 59% were measured under the conditions of adsorption voltage/time, 1.2 V/3 min, desorption voltage/time -0.5 V/5 min, respectively.