• Title/Summary/Keyword: residue compressive strength

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Preparation and Characterization of the Mine Residue-based Geopolymeric Ceramics (광미를 이용한 지오폴리머 세라믹제조 및 물성)

  • Son, Se-Gu;Lee, Woo-Keun;Kim, Young-Do;Kim, Kyung-Nam
    • Korean Journal of Materials Research
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    • v.21 no.9
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    • pp.502-508
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    • 2011
  • The goal of the present work was to investigate the development of a geopolymeric ceramic material from a mixture of mine residue, coal fly ash, blast furnace slag, and alkali activator solution by the geopolymer technique. The results showed that the higher compressive strength of geopolymeric ceramic material increased with an increase in active filler (blast furnace slag + coal fly ash) contents and with a reduction of mine residue contents. The geopolymeric ceramic had very high early age strength. The compressive strength of the geopolymeric ceramic depended on the added active filler content. The maximum compressive strength of the geopolymeric ceramic containing 20 wt.% mine residue was 141.2 MPa. The compressive strength of geopolymeric ceramic manufactured by adding mine residue was higher than that of portland cement mortar, which is 60 MPa, when cured for 28 days. SEM observation showed the possibility of having amorphous aluminosilicate gel within geopolymeric ceramic. XRD patterns indicate that the geopolymeric ceramic was composed of amorphous aluminosilicate, calcite, quartz, and muscovite. The Korea Standard Leaching Test (KSLT) was used to determine the leaching potential of the geopolymeric ceramic. The amounts of heavy metals were noticeably reduced after the solidification of mine residue with active filler.

Effect of activator types on cement mortar with polymeric aluminum chloride waste residue

  • Ping Xu;Yuhao Cui;Dong Han;Minxia Zhang;Yahong Ding
    • Advances in concrete construction
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    • v.15 no.3
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    • pp.149-159
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    • 2023
  • Water glass (WG) and sodium sulfate (SS) were used to prepare polymeric aluminum chloride residue cement mortar (PACRM) by single and compound blending with polymeric aluminum chloride waste residue, respectively. The structural strength and textural characteristics examinations showed that PACRM consistency increased by incorporating WG, but decreased by incorporating SS. When WG and SS were compounded, the mortar consistency initially rose before falling. The compressive strength of PACRM increased and then decreased as WG was increased. The mechanical properties of PACRM were better enhanced by SS than WG, showing no strength deterioration. The main reason for the improved mechanical properties of polymeric aluminum chloride waste residue in the presence of activators is the increased precipitation of reactive substances, such as C-S-H gels, calcium silica, and Ca(OH)2. The density of the specimens with PACRM and the degree of aggregation of hydration products were significantly enhanced by generating more hydration products in the mortar. Further, the cracks and pores were significantly reduced, and the matrix structure was continuous and dense at 5% SS doping and 3% compound doping.

Effect of Particle Size and Unburned Carbon Content of Fly Ash from Hadong Power Plant on Compressive Strength of Geopolymers (하동화력발전소 비산재의 입도크기와 미연탄소 함량이 지오폴리머의 압축강도에 미치는 영향)

  • Kang, Nam-Hee;Chon, Chul-Min;Jou, Hyeong-Tae;Lee, Sujeong
    • Korean Journal of Materials Research
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    • v.23 no.9
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    • pp.510-516
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    • 2013
  • Fly ash is one of the aluminosilicate sources used for the synthesis of geopolymers. The particle size distribution of fly ash and the content of unburned carbon residue are known to affect the compressive strength of geopolymers. In this study, the effects of particle size and unburned carbon content of fly ash on the compressive strength of geopolymers have been studied over a compositional range in geopolymer gels. Unburned carbon was effectively separated in the $-46{\mu}m$ fraction using an air classifier and the fixed carbon content declined from 3.04 wt% to 0.06 wt%. The mean particle size ($d_{50}$) decreased from $22.17{\mu}m$ to $10.79{\mu}m$. Size separation of fly ash by air classification resulted in reduced particle size and carbon residue content with a collateral increase in reactivity with alkali activators. Geopolymers produced from carbon-free ash, which was separated by air classification, developed up to 50 % higher compressive strength compared to geopolymers synthesized from raw ash. It was presumed that porous carbon particles hinder geopolymerization by trapping vitreous spheres in the pores of carbon particles and allowing them to remain intact in spite of alkaline attack. The microstructure of the geopolymers did not vary considerably with compressive strength, but the highest connectivity of the geopolymer gel network was achieved when the Si/Al ratio of the geopolymer gel was 5.0.

Geotechnical Characteristics Analysis of Oil Contaminated Clayey Soil (유류로 오염된 점성토의 지반공학적 특성 분석)

  • Kwon, Moo-Nam;Kim, Hyun-Ki
    • Journal of The Korean Society of Agricultural Engineers
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    • v.47 no.1
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    • pp.43-50
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    • 2005
  • This test was performed to evaluate the change of the unconfined compressive strength, strength parame¡?ters which resulted from direct shear test and oil residue percents analyzed by GC-MS as time lapse, oil addition. Unconfined compression strength of $10\%$ kerosene added by weight of dry soil recovered as time passed. In the case of $5\%$ kerosene added, the strength recovered as much as clean clayey soil after about 50 days passing. For the case of diesel added, the recovery of unconfined compressive strength was not shown even though about 60 days passed. The strength parameters (c, $\psi$) of kerosene added not changed but for diesel added, the cohesion was very decreased as diesel addition increased. Residual percent of kerosene in the soil was less than that of diesel as time passed.

Physical Properties of ALC with Various Fineness of Quartzite (규석 분말도에 따른 ALC의 물리적 특성 변화)

  • Chu, Yong-Sik;Jung, Ui-Jong;Song, Hun;Lee, Jong-Kyu;Kim, Young-Gon;Kang, Dae-Gu
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.407-411
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    • 2010
  • ALC was fabricated using cement, lime and quartzite by hydrothermal reaction. ALC has low strength and brittleness on account of inner pores. The studies for resolving these problems were driven by many researchers. Among these researches, the controls of quartzite fineness have been studied for unsuitable properties of ALC. This study experimented with variation of 90 ${\mu}m$ residue for obtain good physical properties. It was found that 90 ${\mu}m$ residue influenced on physical properties of ALC. The lower amount of 90 ${\mu}m$ residue, the higher compressive and bending strength. But the continuing decrease of 90 ${\mu}m$ residue did not cause the increase of strength. In order to application of these results in process, the states of process and hydrothermal products will be considered.

Mechanical and electrical properties of cement paste incorporated with pitch-based carbon fiber

  • Rhee, Inkyu;Kim, Jin Hee;Park, Sang Hee;Lee, Sungho;Ryu, Bong Ryeul;Kim, Yoong Ahm
    • Carbon letters
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    • v.23
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    • pp.22-29
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    • 2017
  • The compressive strength and electrical resistance of pitch-based carbon fiber (CF) in cementitious materials are explored to determine the feasibility of its use as a functional material in construction. The most widely used CFs are manufactured from polyacrylonitrile (PAN-based CF). Alternatively, short CFs are obtained in an economical way using pitch as a precursor in a melt-blown process (pitch-based CF), which is cheaper and more eco-friendly method because this pitch-based CF is basically recycled from petroleum residue. In the construction field, PAN-based CFs in the form of fabric are used for rehabilitation purposes to reinforce concrete slabs and piers because of their high mechanical properties. However, studies have revealed that construction materials with pitch-based CF are not popular. This study explores the compressive strength and electrical resistances of a cement paste prism using pitch-based CF.

Properties of Alkali Activated MSWI (Municipal Solid Waste Incinerator) Ash Mortar (알칼리 활성화된 도시 폐기물 소각재 모르타르의 특성)

  • Jo Byung Wan;Koo Ja Kap;Park Seung Kook;Ko Hee Cheol
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.773-776
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    • 2005
  • MSWI ash is the residue from waste combustion processes at temperature between $850^{\circ}C\;and\;1000^{\circ}C$. And the main components of MSWI ash are $SiO_2,\;CaO\;and\;Al_2O_3$. The aim of this study is to find a way to useful application of MSWI ash(after treatment) as a structural material and to investigates the hydraulic activity, compressive strength development, composition variation of such chemicallyi-activated MSWI ashes concrete. And it was found that early cement hydration, followed by the breakdown and dissolving of the MSWI-ashes, enhanced the formation of calcium silicate hydrates(C-S-H), The XRD and SEM-EDS results indicate that, both the hydration degree and strength development are closely connected with a curing condition and a chemically-activator. Compressive strengths with values in the 40.5MFa were obtained after curing the activated MSWI ashes with NaOH+water glass at $90^{\circ}C$.

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Internal Wood Temperature Manipulation Using Quadratic Residue Diffusor Microwaves (Quadratic Residue Diffusor Microwave를 이용한 목재의 내부 온도변화에 관한 연구)

  • Kim, Ki-Ho;Kim, Kyung-Min
    • Current Research on Agriculture and Life Sciences
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    • v.32 no.1
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    • pp.1-9
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    • 2014
  • In contrast to conventional microwaves, QRD (Quadratic Residue Diffusor) microwaves are a new energy-efficient technology that enhances the effect of sterilization based on changing the wavelength phase difference. Therefore, this study investigated the sterilization of wood using environmentally friendly and low energy consuming QRD microwaves. The results are as follows: for the QRD microwaves used in this study, the efficiency E = 5.75e0.32 S ($R^2$=0.908). Although the early water content was not constant, the average water content was 30.3% and after one week of natural drying, the water content was 22.6%, representing an average water content reduction of about 8%. When increasing the microwave level from 3 kW ~ 9 kW, the time taken for the temperature to increase was reduced. After the QRD microwave treatment, the wood samples showed no change in their flexural rigidity, compressive strength, or cleavage. The QRD microwave levels used in the experiments were 3, 5, 7, and 9 kW, where 9 kW was found to be the most efficient. Thus, for the purpose of eliminating nematodes and termites inside wood, a higher QRD microwave level was found to be more effective and energy efficient.

Characteristics on Compressive Strength of Cement Paste with Content of LRM Neutralized by Nitric Acid and Sulfuric Acid (질산 및 황산에 의해 중화된 액상화 레드머드의 첨가량에 따른 시멘트 페이스트의 압축강도 특성)

  • Kang, Suk-Pyo;Lee, Hee-Ra;Kang, Hye-Ju;Lee, Byeong-Gi
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.333-340
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    • 2019
  • Red mud is an industrial by-product produced during the manufacturing aluminum hydroxide (Al(OH)3) and aluminum oxide(Al2O3) from Bauxite ores. In Korea, aproximately 2 tons of red mud in a sludge form with 50% moisture content is produced when 1ton of Al2O3 is produced through the Bayer process. Neutralization of red mud will help to reduce the environmental impact caused due to its storage and also lessen significantly the ongoing management of the deposits after closure. It will also open opportunities for re-use of the residue which to date have been prevented because of the high pH. Moreover, attention to liquefied red mud(LRM) that does not require heating and grinding process for recycling is needed. In this paper, characteristics of compressive strength for cement paste with content of LRM neutralized by nitric acid and sulfuric acid. The results showed that compressive strength of cement paste with neutralized LRM is higher than that of cement paste with LRM.

Preparation of Castable Refractories by Recycling of Aluminum Dross (알루미늄드로스를 재활용한 캐스타블내화물 제조)

  • Park Hyungkyu;Lee Hooin;Lee Jinyoung
    • Resources Recycling
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    • v.12 no.3
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    • pp.46-53
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    • 2003
  • Recycling of aluminum dross is an important issue in the secondary aluminum industries. In this study, aluminum dross generated in the domestic secondary aluminum industry was processed to use it as raw material for producing alumina refractories. Sample dross was classified according to its size. The dross smaller than 1 mm was leached with sodium hydroxide solution to extract the remained aluminum from the dross into the solution. and then aluminum hydroxide precipitate was recovered from the leach liquor. The waste residue in the leaching was washed, dried and roasted. Most remained metallic components in the residue was changed into oxide through the processes. The roasted dross was made into alumina castable refractories by mixing with aggregates and a binder. Bending strength of the tested castable specimen was over $25\;kg/\textrm{m}^2$ and compressive strength over $80\;kg/\textrm{cm}^2$, which satisfied the Korean Standard value respectively. From the results, it was suggested that this process could be applicable to recycling of aluminum dross.