• 제목/요약/키워드: residual chlorine

검색결과 192건 처리시간 0.026초

하수 원수내 유해물질 변화에 따른 생태독성평가 (Variation of hazardous substances in sewage ecotoxicological assessment)

  • 서병원;이주화;이용훈;강선홍
    • 상하수도학회지
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    • 제27권5호
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    • pp.603-610
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    • 2013
  • According to industrialization, increased toxic chemicals discharge has been causing water pollution. Especially domestic sewage is a major source of water pollution. Sixty percent of the total wastewater discharged is domestic sewage. Self-purification capacity of rivers and streams is drastically reduced by the emission of domestic sewage, industrial wastewater and livestock wastewater. Although domestic sewage is managed by implementing standards and regulations, toxicity effect of domestic sewage to humans and the environment is not yet clearly understood. In this study, by using daphnia magna, the ecotoxicity of domestic swage was assessed. Cl, Cu, Pb, COD, T-N, DO, pH and residual chlorine were investigated as background concentrations. The experiments were conducted with water samples obtained from three local sewage treatment plants. The experiment results indicated that higher level of toxicity corresponds to the higher pollution concentrations. The higher level of combinations of background concentrations such as heavy metals leads to the worse ecotoxicity. Especially, the Cu concentration affects the TU value.

Seasonal variation of assimilable organic carbon and its impact to the biostability of drinking water

  • Choi, Yonkyu;Park, Hyeon;Lee, Manho;Lee, Gun-Soo;Choi, Young-june
    • Environmental Engineering Research
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    • 제24권3호
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    • pp.501-512
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    • 2019
  • The seasonal effects on the biostability of drinking water were investigated by comparing the seasonal variation of assimilable organic carbon (AOC) in full-scale water treatment process and adsorption of AOC by three filling materials in lab-scale column test. In full-scale, pre-chlorination and ozonation significantly increase $AOC_{P17\;(Pseudomonas\;fluorescens\;P17)}$ and $AOC_{NOX\;(Aquaspirillum\;sp.\;NOX)}$, respectively. AOC formation by oxidation could increase with temperature, but the increased AOC could affect the biostability of the following processes more significantly in winter than in warm seasons due to the low biodegradation in the pipes and the processes at low temperature. $AOC_{P17}$ was mainly removed by coagulation-sedimentation process, especially in cold season. Rapid filtration could effectively remove AOC only during warm seasons by primarily biodegradation, but biological activated carbon filtration could remove AOC in all seasons by biodegradation during warm season and by adsorption and bio-regeneration during cold season. The adsorption by granular activated carbon and anthracite showed inverse relationship with water temperature. The advanced treatment can contribute to enhance the biostability in the distribution system by reducing AOC formation potential and helping to maintain stable residual chlorine after post-chlorination.

상수도시스템의 위상학적 특징과 잔류염소 농도를 고려한 최적설계 (Optimal design considering topological characteristics and residual chlorine concentration of water distribution systems)

  • 고문진;김민준;김률;최영환
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2022년도 학술발표회
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    • pp.181-181
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    • 2022
  • 상수도 관망은 비정상상황에서도 안전한 물을 안정적으로 공급하는 것을 목표로 한다. 따라서 상수도 관망의 최적 설계는 수리학적 제약조건 (i.e., 절점의 압력, 관의 유속)을 만족하는 설계안을 제시한다. 하지만 점차 커지는 도시 규모에 따라 수질적으로 안전한 물을 공급하지 못하는 문제가 발생하고 있다. 또한, 상수도시스템의 형식 (i.e., 수지상식, 혼합식, 순환식)에 따라 용수의 체류 시간, 절점의 압력 등이 상이하다. 따라서, 본 연구에서는 도시 규모 및 형식과 잔류염소 농도를 고려한 상수도시스템 최적 설계를 진행하였다. 절점의 개수에 따라 도시의 규모를 분류하였으며, BI(BI; Branch Index) 지수를 통해 상수도시스템의 형식을 분류하였다. 또한, 수리학적 제약조건(i.e., 절점의 압력)과 수질적 제약조건 (i.e., 잔류염소 농도)을 설정하여 수리-수질을 동시에 만족하는 최적 설계안을 도출하였다. 비상시에도 물을 안정하게 공급하기 위하여 시스템의 탄력성과 설계비용을 목적함수로 설정하여 다목적 최적 설계를 진행하였다. 이러한 연구는 압력만을 고려한 기존 설계단계에서 수질적 측면을 동시에 고려하여 수질 측면의 안전성을 향상할 수 있다. 또한, 시스템의 탄력성을 고려하여 비정상상황에서도 물을 공급하여 사용성을 향상하는 설계안을 도출하여 수리학적 안정성을 만족하며, 경제적 측면도 향상할 수 있다.

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Giardia에 의한 환경오염(環境汚染)과 감염(感染)에 관한 역학적(疫學的) 연구(硏究) (Epidemiological Studies on Giardia Infection Associated with environmental Pollution)

  • 이근태;김석찬;송종술;정평림
    • 농촌의학ㆍ지역보건
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    • 제9권1호
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    • pp.56-66
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    • 1984
  • Giardia lamblia is a pathogenic flagellate causing intestinal disorders such as diarrhea, abdominal pain and malabsorption of nutrients. Giardia is mainly infected by the ingestion of contaminated foods per os. Craun (1979) has recently reported that mass infection of this flagellate through the contaminated water supply systems is one of public health hazards. Also, so-called traveller's diarrhea is sometimes caused by Giardia infection (CDC, U.S.A., 1971). However, a few epidemiological studies figuring out the mode of infection or control measures of Giardia infection has been done so far in Korea. The present study was aimed to know the prevalence of Giardia infection in several Korean populations, detectability of this flagellate in water systems and the viability of the cysts against sewages and disinfectants applying to drinking water. In the present study, 388 stool specimens from orphanage children in Chun-joo, Chung-joo, On-yang and Chun-an areas and 538 stool specimens from inhabitants in Woo-do, In-chon, and Chun-joo were examined by formalin-ether concentration technique to detect out Giardia cysts. On the other hand, water samples from 14 sites of Han River and its tributaries were collected in May through July, 1984. Fifty liter of water sample in each sampling site was then filtered through water filtering system deviced by U.S. Environmental Proutection Agency and the sediments rinsed out from the thread rolls, a part of water filtering system, were examined to detect out the Giardia cysts. In order to observe the viability of Giardia cysts in the sewage samples, the cysts were treated in it at $4^{\circ}C$ or $25^{\circ}C$ for 7 through 28 days. For this purpose, the cysts were also exposed to various concentrations of disinfectants such as chlorine, iodine and ozone gas for proper time intervals. After treatment, the viability test of the Giardia cysts were carried out by method of Rice and Schaefer (1981) with minor modification. The results obtained in this study were as follows : 1) The detection rates of G lamblia cysts in the stool specimens were 18.3% in orphans and 4.3% in general examinees. 2) The prevalences of Giardia Infection were higher in the young age groups than in-adults. The highest positive rate was 18.4% in the age group less than 10. 3) Of 14 water specimens sampled from Han River system and its tributaries around the Seoul area, the Giardia cysts were detected from 4 samples, and no cyst was found in the water supply systems. 4) The cysts treated in the sewage survived for 28 days at $4^{\circ}C$ and for 13 days at $25^{\circ}C$. 5) The cysts were completely destroyed within 60 minutes by exposure to 8 mg/l of residual chlorine at 4g and within 30 minutes by exposure to the same concentration of chlorine at $25^{\circ}C$. 6) The cysts were all dead when exposed to 1 mg/1 of iodine for 60 minutes at $4^{\circ}C$ or $25^{\circ}C$. 7) The cysts were destroyed after 10 minute exposure in 0.15 mg to 0.25mg of residual ozone gas per liter. Summarizing the above results, it is considered that Giardia infection is regarded as water-borne disease and the cysts are able to be controlled by the application with the disinfectants in the water supply systems.

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簡易上水道의 水質管理實態와 給水利用住民의 滿足度 (Water Quality Management of Simple Piped Water Supply System and Its Satisfaction of the Residents)

  • 채한욱;박재용;문효정
    • 한국환경보건학회지
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    • 제25권3호
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    • pp.13-22
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    • 1999
  • For the purpose of inquiring into the actual conditions of water quality management of Simple Piped Water Supply(SPWS) and the satisfaction and attitudes of inhabitants about utilizing water-supply, this research was done through the questionnaires, the investigation of surrounding environment and water quality analysis in the Sangju city, Kyungsang-pookdo during 4 months from March to June, 1998. The fountainhead of SPES using ground water accounted for 65.3%, which was the highest rate in the group. Most of them was at least 10 years in the number of utilization year. 79.6% of them were exposed to many sorts of surrounding pollution origins. The examination of water was performed only through a test about water purification and 24.5% of them disinfection by chlorine also no residual chlorine was detected at all. All the waterworks did not have any education to the managers of water quality and 81.5% of them held physical examination. As a result of the water examination about SPWS, 65.3% of them were found incongruity and the valley and springing water accounted for higher than the underground water in the rate of incongruity. Looking into the details of the result in the water examination, a category of colon bacilli was ranked in the highest rate and the next one was general bacilli, nitric acid nitrogen and turbidity in order. In the satisfaction degree of the water quality, the satisfied accounted for 44.6%, and 29.2% each. Over the state of satisfaction about the ways of water examination, satisfaction accounted for 44.6%, and unsatisfaction 28.3%. Summarizing the result of the above-stated, the state of Water Quality Management of the SPWS was in a poor condition. Thus for the water Quality Management, systematic and scientific water Quality Management mainly by the administrative organization other than voluntary management by the village should be done beyond doubt. Additionally the opinions and demands of inhabitants utilizing the water supply have to be positively reflected in the affairs of water Quality Management so that the distrust of inhabitants to the SPWS should be settled.

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조리시 가열에 따른 수돗물 중 염소소독부산물의 농도 변화와 인체 섭취 노출 (Changes in the Concentrations of the Tap Water Chlorination By-Products by Heating during Cooking, and Human Ingestion Exposure)

  • 김희갑;이수형
    • Environmental Analysis Health and Toxicology
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    • 제14권1_2호
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    • pp.35-43
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    • 1999
  • A number of disinfection by-products (DBPs) are formed as a result of the addition of chlorine into the public water supply and some of them have been suggested to cause adverse health effects on humans. However, the estimation of human ingestion exposure to each DBP has been performed simply by multiplying the concentration of a chemical in the cold tap water by the volume of water consumed during a given period of time. However, a questionnaire concerning water consumptions administered to sixty people residing in Chunchon showed that the volume of tap water consumed accounted for approximately 70% of the total volume of water consumed and that of heated water represented approximately 94% of tap water ingested. Heating durations for water-containing foods (e. g., soups and pot stews) and heated beverages (e. g., barley tea) were grouped into 10, 20, 30, and 35 minutes. Based on these time frames, an aluminum pot containing one liter of tap water was heated for the above respective time periods using a gas range to determine the variations of the concentrations of individual DBPs by heating. The pH and total residual chlorine were measured before and after heating. Collected water samples were carried to the laboratory and analyzed for eight DBPs and total organic carbon. Chloroform, bromodichloromethane, chloral hydrate, 1, 2-dichloro-2-propanone, 1, 1, 1-trichloropropanone, and dichloroacetonitrile were not detected following heating for 10 minutes and longer. The concentration of dichloroacetic acid (DCAA) was elevated with heating duration, resulting in the averages of 2.0, 3.1, 4.7, and 12 times the initial concentration, respectively, for 10, 20, 30, and 35 minute heating periods. On the other hand, the concentration of trichloroacetic acid (TCAA) decreased with heating duration, with 0.65, 0.40, 0.34, and 0.19 times lower than the initial concentration. Therefore, it is suggested that ingestion exposure to DCAA increases with heating duration but that ingestion exposure to TCAA decreases. In addition, while the amount of DCAA was elevated at the initial time periods (10 or 20 minutes) and then slowly decreased, that of TCAA was rapidly decreased. In conclusion, water-heating processes during cooking influence the concentrations of individual DBPs in the tap water, with lower levels for volatile DBPs and TCAA, and higher levels for DCAA. Therefore, concentration change needs to be taken into consideration in the estimation of human ingestion exposure to DBPs.

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고정상 담체와 은나노 모래여과를 이용한 이중 공정에서 처리수의 중수도 활용에 관한 연구 (A Study on the Utilization of Effluent Treated by Double Process Using Fixed-media and Sand Filter Coated by Nano Silver for Wastewater Reclamation and Reusing System)

  • 선용호
    • KSBB Journal
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    • 제21권4호
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    • pp.317-323
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    • 2006
  • 본 연구는 다가올 물 부족에 따른 하나의 대안으로서 중수도 시스템에 초점을 맞추어, 생활오수를 이용하여 혐기/무산소/호기조의 $A^2O$ 생물막 공법으로 구성된 상향류식 고정상 담체 반응기로 처리한 오수를 하향류식 은나노 모래여과 반응기에 다시 연속 통과시켜 이중 처리하여 얻은 처리수를 중수도에 활용이 가능하지에 대하여 연구하였다. 이중 공정 후 배출수의 pH는 $7.39{\sim}8.06$(평균 7.84) 범위이었고, $COD_{Mn}$$8{\sim}18mg/L$(평균 12.1 mg/L), $BOD_5$$2.1{\sim}10mg/L$(평균 4.9 mg/L)로 중수도 수질 기준에 적합하였다. SS는 $3{\sim}9mg/L$의 범위로 평균 농도가 4.95 mg/L를 나타내면서 SS 제거율이 94.8%로 대부분 법적 기준치 5 mg/L 이하로 처리되어 가능성을 보여 주었다. 대장균군 수의 평균 제거율이 99.1%이었으며, 배출수의 평균 대장균 군수는 65 MPN/100mL이 검출되었으나 중수도 수질 기준에는 불검출로 되어 있으므로 완벽한 제거를 위해서는 0.2 mg/L 이상의 결합잔류염소의 양을 고려한 염소 처리를 하여야 한다. SEM 사진으로부터 은모래 표면에서는 박테리아가 존재하지 않음을 알 수 있었다. 이 외에 중수도 수질 기준에 포함될 가능성이 있는 총질소 및 총인의 제거율은 각각 50.3%와 27.2%이었다.

음용 원수의 염소소독에 의한 소독부산물 생성패턴에 관한 연구 (A Study on Formation Pattern of DBPs by Disinfection of Drinking Raw Water)

  • 이강진;홍지은;표희수;박송자;유제강;이대운
    • 분석과학
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    • 제16권3호
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    • pp.249-260
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    • 2003
  • 한강에서 채취한 원수에 염소소독제인 hypochlorite를 $10{\mu}g/m{\ell}$의 농도로 투여한 후 1시간~14일까지 TOC (total organic carbon), 잔류염소량 및 탁도 등을 측정하고 THMs (trihalomethanes), HANs (haloacetonitriles), HKs (haloketones), chloral hydrate 및 HAAs (haloacetic acids) 등의 염소소독 부산물의 생성율을 조사하였다. 그 결과 잔류염소량은 투여후 1시간 경과 시 $6{\mu}g/m{\ell}$ 이상에서 14일째에 $1.23{\mu}g/m{\ell}$으로 감소하였으며 TOC 및 탁도는 큰 차이가 없었다. 7일 후 발생한 총 소독부산 물의 농도는 $101.3ng/m{\ell}$ (789.6 nM)이며 이 중 THMs이 69%로 가장 큰 비중을 차지하였다. 그 외에 HAAs가 19%, chloral hydrate가 10% 정도 검출되었으며, HANs와 HKs 및 chloropicrin 등은 미량 검출되었다. THMs 중에서는 chloroform이 $61.5ng/m{\ell}$로 총 THMs 중 약 89% 정도를 차지하였으며 HANs 중에서는 DCAN이 95%인 $0.72ng/m{\ell}$, HAAs 중에서는 TCAA가 50% 등으로 가장 높은 비율로 검출되었다. 각 부산물의 발생량의 상관관계를 조사한 결과 THMs과 HANs의 경우 THMs의 농도가 $40ng/m{\ell}$인 지점을 경계로 HANs과 경쟁적 발생관계가 있음이 나타났다. HAAs의 경우는 특별한 경향성을 나타내지 않았으나 전체적으로 초기에 산화상태가 큰 화합물에서 산화상태가 작은 화합물로 점차 변화하는 것으로 관찰되었다.

SiC의 염소화에 의한 다공성 탄소 입자 제조 (Preparation of Porous Carbon by Chlorination of SiC)

  • 박회경;박균영;강태원;장희동
    • 한국입자에어로졸학회지
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    • 제8권4호
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    • pp.173-180
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    • 2012
  • SiC particles, 8.3 ${\mu}m$ in volume average diameter, were chlorinated in an alumina tubular reactor, 2.4 cm in diameter and 32 cm in length, with reactor temperature varied from 100 to $1200^{\circ}C$. The flow rate of the gas admitted to the reactor was held constant at 300 cc/min, the mole fraction of chlorine in the gas at 0.1 and the reaction time at 4 h. The chlorination was negligibly small up to the temperature of $500^{\circ}C$. Thereafter, the degree of chlorination increased remarkably with increasing temperature until $900^{\circ}C$. As the temperature was increased further from 900 to $1200^{\circ}C$, the increments in chlorination degree were rather small. At $1200^{\circ}C$, the chlorination has nearly been completed. The surface area of the residual carbon varied with chlorination temperature in a manner similar to that with the variation of chlorination degree with temperature. The surface area at $1200^{\circ}C$ was 912 $m^{2}/g$. A simple model was developed to predict the conversion of a SiC under various conditions. A Langmuir-Hinshelwood type rate law with two rate constants was employed in the model. Assuming that the two rate constants, $k_{1}$ and $k_{2}$, can be expressed as $A_{1e}^{-E_{1}/RT}$ and $A_{2e}^{-E_{2}/RT}$, the four parameters, $A_{1}$, $E_{1}$, $A_{2}$, and $E_{2}$ were determined to be 32.0 m/min, 103,071 J/mol, 2.24 $m^{3}/mol$ and 39,526 J/mol, respectively, through regression to best fit experimental data.

HACCP 적용을 위한 도계처리 공정내 미생물 오염의 분석 (Analysis of Microbial Contamination in Poultry Slaughtering Operations for the Application of HACCP)

  • 홍종해;권혁무;고주언
    • 한국환경보건학회지
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    • 제22권1호
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    • pp.45-50
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    • 1996
  • The application of HACCP system, which was adopted by Codex Alimentarius Committee for the safe meat and poultry production, is one of the urgent task for competing in the world trade markets. But there have been no useful analytical studies to identify the causes of contamination in the poultry meat processing plants in Korea. This study was conducted to investigate the potential hazards during the operations by the microbiological examination for the poultry meat processing plant (20,000 birds capacity a day) located in Kangwon province. In spite of air contamination of work places, it may not directly affect the surface contamination of poultry meats. But the risk of Campylobacter jejuni/coli contamination was high. The number of total count was decreased about ten times, but remarkable changes of microbial contamination could not be recognized in each procedure during the operations. The washing water was already contaminated as much as $10^{3-6}CFU/ml$ in SPC before the operations. It means that to keep water tanks hygienic is a primary step to prevent the occurrences of microbial contamination. The overflow and recirculation of water in scalding, washing, and chilling was aslo an important factor for a hygienic control. Based on this study, the followings could be regarded as an important factors for hygenic control in the poultry slaughtering plants on a small scale. The temperature of water used for scalding should be constantly maintained on a required temperature, and the overflow rate of 1~1.5 liter per bird. The carcass surface and the body cavity should be washed thoroughly and the cross-contamination due to facilities, workers, and tools should be prevented. The chilling water sholud be maintained under 5$\circ$C of temperature with ice and overflow, and residual chlorine level of 50 ppm.

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