• Title/Summary/Keyword: repellency

Search Result 180, Processing Time 0.039 seconds

Water Repellency on a Nanostructured Superhydrophobic Carbon Fibers Network

  • Ko, Tae-Jun;Her, Eun-Kyu;Shin, Bong-Su;Kim, Ho-Young;Lee, Kwang-Ryeol;Hong, Bo-Ki;Kim, Sae-Hoon;Oh, Kyu-Hwan;Moon, Myoung-Woon
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.08a
    • /
    • pp.224-224
    • /
    • 2012
  • For decades, carbon fiber has expanded their application fields from reinforced composites to energy storage and transfer technologies such as electrodes for super-capacitors and lithium ion batteries and gas diffusion layers for proton exchange membrane fuel cell. Especially in fuel cell, water repellency of gas diffusion layer has become very important property for preventing flooding which is induced by condensed water could damage the fuel cell performance. In this work, we fabricated superhydrophobic network of carbon fiber with high aspect ratio hair-like nanostructure by preferential oxygen plasma etching. Superhydrophobic carbon fiber surfaces were achieved by hydrophobic material coating with a siloxane-based hydrocarbon film, which increased the water contact angle from $147^{\circ}$ to $163^{\circ}$ and decreased the contact angle hysteresis from $71^{\circ}$ to below $5^{\circ}$, sufficient to cause droplet roll-off from the surface in millimeter scale water droplet deposition test. Also, we have explored that the condensation behavior (nucleation and growth) of water droplet on the superhydrophobic carbon fiber were significantly retarded due to the high-aspect-ratio nanostructures under super-saturated vapor conditions. It is implied that superhydrophobic carbon fiber can provide a passage for vapor or gas flow in wet environments such as a gas diffusion layer requiring the effective water removal in the operation of proton exchange membrane fuel cell. Moreover, such nanostructuring of carbon-based materials can be extended to carbon fiber, carbon black or carbon films for applications as a cathode in lithium batteries or carbon fiber composites.

  • PDF

Changes in Moisture Permeability and Waterproofness of High-density Fabric by Repeated Laundering and Condition (고밀도 직물의 반복세탁 및 세탁조건에 따른 투습.발수성 변화)

  • Roh, Eui-Kyung;Han, Jung-Eun;Kim, Eun-Ae
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.34 no.11
    • /
    • pp.1798-1811
    • /
    • 2010
  • This research evaluates the changes in the comfort-related properties of high-density fabric, such as moisture permeability and waterproofness, in order to assess the relative importance of laundry conditions for clothing properties after repeated laundering and suggest the best laundering conditions for high-density fabric through the identification of the most influential factor. A commercial high-density fabric was washed 25 times in a drum-type washer using nine different laundry conditions based on profiles derived from a fractional factorial design. To evaluate the changes in the comfort-related properties of the fabric, pore size, air permeability, water vapor transport, water repellency, and water resistance were measured. The comfort-related properties of the fabric deteriorated after repeated laundering by the damaged surface finish; in addition, the damaged surface also changed the pore size. As a result, the water repellency and water resistance decreased. The detergent was the most responsible factor to change the properties among the four factors of detergent, hardness, temperature, and RPM. The best laundering conditions for the fabric was a neutral detergent, soft water of 70ppm, a temperature of $15^{\circ}C$, and 30rpm.

Manufacture of Water-Resistant Corrugated Board Boxes for Agricultural Products in the Cold Chain System(II) - Application Methods of Chemicals for Improving Water and Moisture Resistance of Corrugated Boards - (농산물 저온유통용 내수 골판지 상자의 제조(제2보) - 골판지의 내수 및 내습성 향상을 위한 약품 적용 방법 -)

  • Jo, Jung-Yeon;Min, Choon-Ki;Shin, Jun-Seop
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 2004.04a
    • /
    • pp.192-210
    • /
    • 2004
  • Application methods of chemicals were investigated tn minimize strength reduction of corrugated boards under the high humidity environment encountered in the cold chain system. Starch insolubilizers were introduced in the starch solution preparation of the Stain hall method and their insolubilization effect of starch binder were estimated. The performance of water repellent agents(WRA) and moisture proof agents(MPA) were evaluated in terms of water and moisture resistance. And effects of the combination of the chemicals and the coating method were also examined. Addition of the polyamine polyamide insolubilizer to the main part in the Stain hall process improved the binding force and water resistance of starch, which contributed to minimize the strength reduction of paper under the high humidity environment. AZC and Glyoxal type insolubilizers could not be used in the experiment due to an excessively increased viscosity of starch solution and the poor stability. Conventional WRA treatment to the base paper enhanced water and moisture resistance very slightly even though water repellency of the paper reached R10 by the treatment. MPA showed excellent performance than WRA not only in water and moisture resistance but in water repellency. Double coating on paper with MPA was more effective than the single coating at the same coating weight. A newly developed MPA showed excellent performance and runnability only by a single coating instead of a double coating.

  • PDF

A Study on the Resin Finishing of Silk Fabric -Silicone Resin Finishing- (견직물의 수지가공에 관한 연구)

  • 남중희;탁태문
    • Journal of Sericultural and Entomological Science
    • /
    • v.27 no.2
    • /
    • pp.28-39
    • /
    • 1985
  • The structural and useful characteristics of silk habutae treated with silicone resin by emulsion finishing method were studied. The results were obtained through crease recovery test, water repellency test, scanning micrograph observation, amino acid analysis, X-Ray diffraction analysis, and Fourier Transform Infrared Spectroscopy. The results are summarized as follows; 1) The improvement in crease recovery of silk habutae finished with silicone resin, was observed b soaping treatment and curing conditions. 2) The higher water repellency and stiffness in silk fabrics finished with silicone resin was found by the fabric inspection and the scanning electron microscopic observation. It is suggested that silicone resin impregnated into the void of silk fibroin. 3) The polar side chains of amino acid composition were decreased, when the silicone resin was treated on silk fibroin. 4) Through Amino acid analysis of silicone resin finished fibroin, the different amounts of amino acid composition was indicated due to silk fibroin silicone polymer reaction and the structural difference of its fibroin were also proved by X-ray diffractograms. 5) The functionality of the siloxane compound may be deduced from the silicone finished silk habutae by Fourier Transform Spectroscopy. It was concluded from the above results that the useful characteristics of silk fabric can be improved by silicone resin finishing.

  • PDF

Manufacture of Water-Resistant Corrugated Fiberboard Boxes for Agricultural Products in the Cold Chain System (IV) - Measurement and analysis of storage condition, distribution route, and packaging method for selected agricultural products - (농산물 저온유통용 내수골판지 상자의 제조(제4보) - 대상농산물별 저온유통조건, 유통경로 및 포장규격 조사 분석 -)

  • Lee Myoung-Hoon;Jo Jung-Yeon;Min Choon-Ki;Shin Jun-Seop
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.38 no.1 s.113
    • /
    • pp.62-69
    • /
    • 2006
  • This study was carried out to measure and analyze the storage condition, distribution route, and packaging method of four selected agricultural products(small tomato, cabbage, peach, and carrot) in the cold chain system. It was shown that dew-forming phenomenon by fruits and vegetables deteriorates the agricultural product quality and physical properties of corrugated fiberboard box during the cold chain system. The compressive strength deterioration in corrugated fiberboard boxes was much greater for single wall(SW) corrugated fiberboard containers than for double wall(DW) in low temperature-high humidity condition. To reduce the deterioration of box and dew-forming phenomenon, water-repellency treatment should be over $R_6$. However, water-resistant treatment of corrugated fiberboard containers would be effective under high relative humidity conditions more than 75% RH. It was suggested that functional corrugated fiberboard box packaging would be an optimum method to reduce the deterioration of agricultural products quality by. It was also achieved controlling the relative humidity and temperature during the storage and physical distribution process.

Preparation of Water Repellent Polyurethane Coating Films Using Perfluoroalkyl Alcohol (과불화 알코올을 이용한 발수성 폴리우레탄 코팅 필름의 제조)

  • Kim, Nam Woo;Ahn, Chi Young;Song, Ki Chang
    • Korean Chemical Engineering Research
    • /
    • v.54 no.3
    • /
    • pp.387-393
    • /
    • 2016
  • Fluorinated polyurethane coating solutions were synthesized from perfluoroalkyl alcohol, toluene diisocyanate, and polycarbonate diol as starting materials. Next, coating films were prepared by spin-coating the fluorinated polyurethane coating solutions on the PC substrates, followed by thermal curing at $120^{\circ}C$. The obtained fluorinated polyurethane coating films were characterized by FT-IR spectroscopy, UV-Vis spectrometer, contact angle tester and pencil hardness tester. Contact angle measurements of water on the coating films showed that the addition of perfluoroalkyl alcohol improved the water repellency and increased the contact angle from $81^{\circ}C$ to $111^{\circ}C$. However, the pencil hardness of coating films exhibited a constant grade of H, irrespective of the addition of perfluoroalkyl alcohol.

Surface Hardness and Water Repellet of Earth Paint (흙페인트의 적절한 사용을 위한 표면경도 및 발수성에 관한 연구)

  • Hawng, Hey-Zoo;Roh, Tea-Hak;Lee, Jin-Sil
    • KIEAE Journal
    • /
    • v.16 no.3
    • /
    • pp.83-88
    • /
    • 2016
  • Purpose : This study aimed to verify the surface hardness and water repellency of earth paint manufactured with earth, a natural material, and provide the results as basic data for paint made with natural materials. Method : After presenting the accurate manufacturing methods for basic materials for paint, the authors conducted and analyzed experiments to evaluate surface hardness and water repellency, fundamental performance indicators for paint, based on different mixture ratios. From the results of the experiment to assess the surface hardness of flour-based earth paint, we observed high surface hardness only after painting the specimen three times. Since potato starch-based earth paint has higher viscosity than its flour-based counterpart, the former did not paint well on the first occasion, resulting in low surface hardness. After painting two or more times, however, it was observed to have higher surface hardness than flour-based earth paint. Result : It was found that at least three iterations of painting was required to obtain high surface hardness of potato starch-based earth paint. Furthermore, the results of the water resistance experiment of earth paint suggest that the use of environment-friendly finishing materials coupled with boiled linseed oil will mitigate the drawbacks of earth paint. The experiment with one-year-old specimens also demonstrated similar water repellent characteristics, which indicates that the performance will improve once the paint has dried for a sufficient period of time.

Toxicity and Repellent Activity of Plant Essential Oils and Their Blending Effects Against Two Spotted Spider Mites, Tetranychus urticae Koch (식물정유 및 혼합물의 점박이응애(Tetranychus urticae Koch)에 대한 살비 및 기피활성)

  • Yoon, Junho;Tak, Jun-Hyung
    • Korean journal of applied entomology
    • /
    • v.57 no.3
    • /
    • pp.199-207
    • /
    • 2018
  • Miticidal and repellent activity of twenty plant essential oils against the adults of two spotted spider mites, Tetranychus urticae, were examined. Sandal wood oil was the most potent one in mortality, whereas clary sage oil exhibited the greatest repellent activity. On those twenty essential oils tested, no apparent correlation between toxicity and repellency was observed. When the most active oils were blended, the combinations tend to exhibit antagonistic interactions in both toxicity and repellent activity. The chemical compositions of sandal wood oil and clary sage oil were identified via GC/MS analyses, and the major constituents of sandal wood oils were sesquiterpene compounds, whereas the major ones for clary sage oil were monoterpenes. Among the major components in clary sage oil, linalyl acetate was not only the most abundant constituent, but also the most responsible one for its repellent activity.