• Title/Summary/Keyword: repellency

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Self-cleaning Surface Coatings of Perfluorinated Additives with Resin and Their Surface Properties

  • Kim, Y.W.;Chung, K.;Lee, E.A.;Seo, Y.G.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.143-144
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    • 2002
  • A series of alcohols with perfluorinated segments $F(CF_2)_m(CH_2)_n-OH$, with m=8, 10 and n=4, 6, 10, were synthesized. First, the alcohols were reacted with fatty acid to produce several esters $(F(CF_2)_m(CH_2)-OOC-R$ with m=8, 10 and n=2, 4, 8,) containing perfluoro group by condensation reaction, and characterized by FT-IR, GC, and surface tension. The esters were soluble in ethyl ether, toluene, hexane, ethyl acetate, chloroform, and acetone, but insoluble in methyl alcohol, ethyl alcohol and isopropyl alcohol. Preliminary experiments on 1,2-dichloroethane solutions showed a remarkable decrease of surface tension upon addition of the esters. Also, the esters films ranged from 100 to $122^{\circ}$, depending on the structure of fatty acid esters. As the separate experiment, the water-repellency of coated paper and cotton was evaluated. As a result, the water droplet dropped in surface was not permeated for two weeks.

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An Experimental Study on Physical and Chemical Properties of the Fabrics Dyed with Persimmon Juice (감즙 오색포의 물리.화학적 성질에 관한 실험적 연구)

  • 박순자
    • Journal of the Korean Society of Clothing and Textiles
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    • v.19 no.6
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    • pp.955-967
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    • 1995
  • This study was performed to investigate the physical and chemical properties of the 5 kinds of fabrics dyed with persimmon juice and undyed fabrics. The difference between dyed and undyed fabrics was checked experimentally. Obtained results are as follows. 1. Bending length and flex stiffness were increased after dyeing, and tensile strength of waif i3l fabrics except Ramie was also increased. 2. Abrasion resistance was improved in Ramie and Hemp after dyeing but the rest of fabrics were decreased. 3. Crease resistance of dyed fabrics was roughly worse than that of undyed fabrics. 4. Air permeability remarkably increased after dyeing and this fact estabilished that the traditional Gal-01 was cool clothing. 5. Water repellency in Cotton 1 and Polyester rises but the rest of fabrics were not changed. Therefore it is found that this repellency related to the their fabric counts. 6. Blocking effect of UV light and visible ray was increased in all dyed fabrics. Especially dyed Cotton 1 and Polyester blocked UV light almost perfectly. 7. The colorfastness to soaping and sunlight was proved to less than 3 grade in all fabrics after dyeing. It indicates that this colorfastness became worse owing to dyeing. 8. The colorfastness to dry cleaning and water was decided to more than 3 grade in all fabrics. 9. The colorfastness of the dyed fabrics to sweat after exposing to man-made acid sweat solution was good so that was decided above 3 grade. However after exposing to man-made alkalic sweat solution it became worse owing to dyeing.

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Temperature and pH Stability Profiles of ortho and para DEET

  • Choi, Mi-Rine;Kim, Seok-Yong;Choi, Joon-Ho;Park, Sang-Hee;Yong, Chul-Soon;Kim, Jung-Sun
    • Journal of Pharmaceutical Investigation
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    • v.41 no.4
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    • pp.233-238
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    • 2011
  • DEET, N,N'-diethyl-m-toluamide, is the most commonly used mosquito repellent. However, it can easily permeate through skin leading to toxic effects. A recent study showed that the ortho analogue of DEET showed enhanced repellency with reduced permeation compared to the commercially used meta analogue. Thus, in order to understand the differences in properties and effectiveness among the m-, o- and p-analogues of DEET, an HPLC-UV method was developed for separately analyzing the three analogues. Moreover, stability profiles at temperatures ranging from $30^{\circ}C$ to $70^{\circ}C$ as well as pH ranging from pH 3 to pH 9 have been determined. All three analogues were stable with no degradation observed during the 5 day period. o-DEET therefore could be further developed into a safer and more effective mosquito repellent.

A Study on the Preparation of Durable Softening Water-repellent by Blending Acrylic Copolymer and Fatty Carbamide;IV. Water-repellent Finish of P/C Blended Fabrics (아크릴 공중합체와 지방산 카르바미드의 블렌딩에 의한 내구유연발수제의 제조에 관한 연구;IV. P/C 혼방직물에의 발수가공)

  • Ko, Jae-Yong;Hong, Eui-Suk;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.2
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    • pp.39-46
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    • 1996
  • Durable softening water-repellenting agent such as PODCW, PDDCW and PEDCW were prepared by blending cationized compound such as poly(octadecyl methacrylate-co-2-diethylaminoethyl methacrylate)[PODC], poly(2-dodecyl methacrylate-co-2-diethyl-aminoethyl methacrylate)[PDDC] and poly(2-ethylhexyl methacrylate-co-2-diethyl-aminoethyl methacrylate)[PEDC], and cationized compound of fatty carbamide, of which synthetic methods were reported in the previous paper, waxes, and emulsifiers. The results of physical tests of the P/C blended fabrics treated with PODCW, PDDCW and PEDCW with and without textile finishing resin, showed a remarkable improvement of the physical properties. The prepared water-repellenting agents, PODCW-6 and PDDCW-1, were treated on P/C blended fabrics with and without resin. For any cases, there are a little changes between initial water repellency and repellency after 3 times washing of the fabrics. Therefore, the water-repellenting agents proved to be a durable agents, and initial water $100^{+}$ and $90^{+}$ point, respectively.

Properties of Current Fruiting Bag and Preparation Water Repelling Fruiting Bag with Wax Emulsion (유통 과대지의 물성 및 Wax Emulsion 발수 과대지의 제조)

  • Kim, Kang-Jae;Park, Seong-Bae;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.2
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    • pp.23-28
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    • 2008
  • As well as crop cultivation, they could not avoid automatizing and using more environmental friendly process in cultivation of fruit. And also, the consumer ask more safe fruit which is produced with more clean method. This is why the usage of aid materials for fruit cultivation like as fruiting bags are increasing. Practical utilization of wax emulsion treated water repelling fruiting bags are developed continuously and it's properties is compared properties of nomal fruiting bags. The water repelling process was developed with wax emulsion coating. After the experiment of wax emulsion preparation from paraffin and DEA and/or OA in Lab. scale, the wax emulsion was manufactured on pilot scale. The wax emulsion coated paper was prepared in mill scale coater. The water repellency and properties of emulsion coated fruiting bags were evaluated and compared with that of current fruiting bags.

Analysis of Physical Properties and Water Repellency Property in Functional Packaging Paper (기능성 포장원지의 물성변화 및 내수성 분석)

  • Kim, Chul-Hwan;Cho, Sung-Hwan
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.13 no.3_4
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    • pp.89-95
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    • 2007
  • Functional packaging paper containing botanical antimicrobial agent (BAAG) and inorganic zeolite was developed for antimicrobial activity and adsorption of ethylene gas of the paper. The physical properties of the packaging paper showed different characteristics with addition of BAAG and functional fillers: both tensile strength and burst strength were decreased, but both stiffness and tear strength were slightly increased. Zeolite also contributed to fast removal of ethylene gas known as aging hormone of fruits and vegetables. Alkyl ketene dimer (AKD) was greatly effective to endow the packaging paper with water repellency property.

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Preparation of Emulsion from Biodegradable Polymer(II) - Characteristics of paper treated as PLA and PBS emulsion - (생분해성 고분자를 이용한 발수 에멀션의 제조(II) - PLA 및 PBS 에멀션 코팅 과일봉지의 물성 비교 -)

  • Kim, Kang-Jae;Lee, Min-Hyung;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.2
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    • pp.13-20
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    • 2013
  • In this study, two biodegradable polymer(PLA, PBS) emulsions were treated on agricultural packaging paper such as fruit bagging paper. Water-repellency, mechanical properties, and SEM image with thermal aging were measured on the emulsion treated fruit bagging paper. Biodegradable polymers(such as poly lactic acid, poly butylene succinate) emulsion treated fruit bagging paper had higher water-repellency and strength than other water-repellent(such as acrylic repellent, linseed oil and paraffin wax) treated fruit bagging paper. According to FE-SEM results of polymer emulsion coated fruit bagging paper, the colloidal particles of emulsion after thermal treatment (looks like being) were adhered to the fibers. Thus, using biodegradable polymer emulsion is expected to protect a fruit for a long time.

The Synthesis of One-step Type Hydrophilic Non-porous Polyurethane Resin and the Physical Property of its Coated Fabric for the Garment (One-step형 친수무공형 폴리우레탄 수지 합성과 코팅 처리한 의류용 직물의 물성)

  • Yang, Sung-Yong;Kim, Hyun-Ah;Kim, Seung-Jin
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.131-139
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    • 2011
  • This study surveyed on the synthesis of one-step type hydrophilic non-porous PU resin and the physical property of the coated fabric for the garment. Three kinds of chain extender such as MEG, 1,4-BD and NPG were used for the preparation of one-step type hydrophilic non-porous PU resin in order to examine the effect of chain extender on the physical properties of PU-coated fabric. And the effects of isocyanate on the physical properties of PU coated fabric were surveyed by mixing with various TDI and MDI ratios. In addition, the physical properties of the coated fabric treated with one-step type hydrophilic non-porous PU resin were examined according to the pre-treatment conditions such as cire finishing. Finally, the washing durability of the coated fabrics was assessed. The coated fabrics treated with PU resin synthesized with PEG1000, MEG and TDI/MDI (6/4) showed the best physical properties. Considering the pre-treatment conditions, best performance of hydraulic pressure, water vapor permeability, and water repellency were obtained with top roller rotation ratio of 150% under 50 ton pressure at $170^{\circ}C$.

Antimicrobial and Water Repellency Effect of Functional PET Fibers with ODDMAC(octadecyldimethyl(3-triethoxy silylpropyl) ammonium chloride) (ODDMAC를 이용한 항균성 및 발수성 동시 발현이 가능한 기능성 PET 섬유)

  • Yang, Heejin;Jeon, Hyeji;Lee, Sang Oh;Lee, Jaewoong
    • Textile Coloration and Finishing
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    • v.32 no.4
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    • pp.265-273
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    • 2020
  • In this study, octadecyldimethyl(3-triethoxy silylpropyl)ammonium chloride (ODDMAC) incorporated with Polyethylene terephthalate (PET) fabrics with different environmental conditions such as various temperature and time intervals. First, ODDMAC (15 weight %) was dissolved in ethanol. Then PET fabrics immersed in the ODDMAC solution at 25 ℃ for 10 minutes and dried at 80 ℃ for 5 minutes. The dried PET/PDDMAC fabrics carried out for curing process out at 110 ℃ ~ 190 ℃. The treated PET/ODDMAC has examined the surface and side coating properties through SEM analysis and elemental analysis. PET/ODDMAC fabric washed with water up to 50 times and studied the durability of the materials. It was confirmed that the treated PET fabric also exhibited good water repellency. In addition, the antimicrobial activity against the gram-positive bacteria Staphylococcus aureus and gram-negative bacteria Escherichia coli were studied by the disc diffusion method on the treated fabric.