• Title/Summary/Keyword: reduction ratio

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Electrochemical Performance of Graphite/Silicon/Pitch Anode Composites Bonded with Graphite Surface PVP and Silica Amine Function Group (흑연 표면의 PVP와 실리카의 아민 작용기로 결합된 흑연/실리콘/피치 음극 복합소재의 전기화학적 성능)

  • Lee, Su Hyeon;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.118-123
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    • 2019
  • In this study, the electrochemical characteristics of Graphite/Silicon/Pitch anode composites were analyzed to improve the low theoretical capacity of graphite as a lithium ion battery. The Graphite/Silica composites were synthesized by bonding silica onto polyvinylpyrrolidone coated graphite. The surface of used silica was treated with (3-Aminopropyl)triethoxysilane(APTES). Graphite/Silicon/Pitch composites were prepared by carbonization of petroleum pitch, the fabrication processes including the magnesiothermic reduction of nano silica to obtain silicon and varying the mass ratio of silica. The Graphite/Silicon/Pitch composites were analysed by XRD, SEM and XRD. Also the electrochemical performances of Graphite/Silicon/Pitch composite as the anode of lithium ion battery were investigated by constant current charge/discharge, rate performance, cyclic voltammetry and electrochemical impedance tests in the electrolyte of $LiPF_6$ dissolved in organic solvents (EC:DMC:EMC=1:1:1 vol%). The Graphite/Silicon/Pitch anode composite (silica 28.5 in weight) has better capacity (537 mAh/g). The cycle performance has an excellent capacity retention to 30th cycle of 95% and the retention rate capability of 98% in 0.1 C/0.2 C.

Analysis on dam operation effect and development of an function formula and automated model for estimating suitable site (댐의 운영효과 분석과 적지선정 함수식 및 자동화 모형 개발)

  • Choo, Taiho;Kim, Yoonku;Kim, Yeongsik;Yun, Gwanseon
    • Journal of Korea Water Resources Association
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    • v.52 no.3
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    • pp.187-194
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    • 2019
  • Intake ratio from river constitutes about 31% (8/26) that beings to "water stress country" as "Medium ~ High" with China, India, Italy, South Africa, etc. Therefore, the present study on a dam that is the most effective and direct for securing water resources has been performed. First of all, climate change scenarios were investigated and analyzed. RCP 4.5 and 8.5 with 12.5 km grid resolution presented in the IPCC (Intergovernmental Panel on Climate Change) 5th Assessment Report (AR5) were applied to study watershed using SWAT (Soil and Water Assessment Tool) and HEC-ResSim models that carried out co-operation. Based on the results of dam simulation, the reduction effects of floods and droughts were quantitatively presented. The procedures of dam projects of the USA, Japan and Korea were investigated. As a result, there are no estimating quantitative criteria, calculating methods or formulas. In the present study, therefore, indexes for selecting suitable dam site through literature investigation and analyzing dam watersheds were determined, Expert questionnaire for various indexes were performed. Based on the above mentioned investigation and expert questionnaire, a methodology assigning weight using AHP method were proposed. The function of suitable dam (FSDS) site was calibrated and verified for four medium-sized watersheds. Finally, automated model for suitable dam site was developed using FSDS and 'Model builder' of GIS tool.

Effectiveness Analysis of Installation of Turbo Roundabouts (터보형 회전교차로 설치 효과분석)

  • Lim, Chang-Sik;Choi, Yang-Won
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.38 no.6
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    • pp.925-932
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    • 2018
  • This study deals with Turbo-Roundabout of Special-Roundabouts. Recently, many rotary intersections are being constructed in Korea, but the effect of the rotary intersection depends on the total entrance traffic volume and the area of the paper. The purpose of this study is to analyze the operation and accident reduction effect of turning traffic signal intersection with small traffic volume into turbo - type turning intersection. The main results are as follows. First, when the traffic volume of the main road is high, the traffic volume of the subway is less than 10 ~ 15%, or when the left turn ratio is less than 30%, it is improved when switching to the turbo type turn intersection instead of the first turn type and second turn type turn intersection Was analyzed. Second, it is considered that turbo type rotary intersection is more effective than first - type rotary intersection, and it is more effective in increasing road capacity because the area of paper is smaller than that of second - order rotary intersection. Third, the number of traffic accidents decreased by 45.9% and the number of injured persons decreased by 76.5% after the conversion of the turnover type turnover to turbo type. 100%), the number of car accidents was 0.3, and the number of casualties was 0 (100%). Finally, the positive evaluation of the user satisfaction survey showed that the improvement in safety, accessibility, and convenience was improved by 60.4%, which was improved by 16.4% to 76.8% after the conversion to the turbo type turnover.

Evaluation on Mechanical Performance and Chloride Ion Penetration Resistance of On-Site Shotcrete Made with Slurry-Type Accelerator (슬러리형 급결제를 활용한 현장적용 숏크리트의 역학적 성능 및 염해저항성 평가)

  • Kim, Hyun-Wook;Yoo, Yong-Sun;Han, Jin-Kyu;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.6
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    • pp.507-515
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    • 2018
  • The purpose of this research is to develop a slurry-type accelerator that contains various beneficial properties such as reduction of dust generation, lower alkalinity, early age strength development, etc., and uses such slurry type accelerator to produce high performance shotcrete that present excellent resistant against chloride ion penetration. In this work, shotcrete mixtures of 0.44 and 0.338 water-to-binder ratio (w/b) were produced at construction site using slurry-type accelerator. The mechanical properties and chloride ion penetration resistance of such shotcrete (including base concrete) were evaluated. According to the experimental results, the slurry-type accelerator was successfully used to produce both w/b 0.44 and 0.338 shotcretes. The 1 day and 28 day compressive strength of shotcrete were found to be closer to or higher than 10MPa and 40MPa, respectively. The w/b 0.338 shotcrete that used 40% replacement of blast furnace slag showed lower compressive strength than w/b 0.44 shotcrete without any mineral admixture at 1 day. However, the compressive strength with 40% blast furnace slag increased significantly at 28 day. Moreover, there was more than 50% increase in chloride ion penetration resistance with blast furnace slag, showing its strong potential for higher performance shotcrete application.

Design of 4th Order ΣΔ modulator employing a low power reconfigurable operational amplifier (전력절감용 재구성 연산증폭기를 사용한 4차 델타-시그마 변조기 설계)

  • Lee, Dong-Hyun;Yoon, Kwang-Sub
    • Journal of IKEEE
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    • v.22 no.4
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    • pp.1025-1030
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    • 2018
  • The proposed modulator is designed by utilizing a conventional structure employing time division technique to realize the 4th order delta-sigma modulator using one op-amp. In order to reduce the influence of KT/C noise, the capacitance in the first and second integrators reused was chosen to be 20pF and capacitance of third and fourth integrators was designed to be 1pF. The stage variable technique in the low power reconfigurable op-amp was used to solve the stability issue due to different capacitance loads for the reduction of KT/C noise. This technique enabled the proposed modulator to reduce the power consumption of 15% with respect to the conventional one. The proposed modulator was fabricated with 0.18um CMOS N-well 1 poly 6 metal process and consumes 305uW at supply voltage of 1.8V. The measurement results demonstrated that SNDR, ENOB, DR, FoM(Walden), and FoM(Schreier) were 66.3 dB, 10.6 bits, 83 dB, 98 pJ/step, and 142.8 dB at the sampling frequency of 256kHz, oversampling ratio of 128, clock frequency of 1.024 MHz, and input frequency of 250 Hz, respectively.

Study on the Shortening Effect of the Egress Travel Time Based on an Escape Scenarios by Using Shuttle Elevators for Lotte Tall Building's Evacuation Plan (초고층건물 피난계획시 피난용 엘리베이터 이용에 의한 피난소요시간의 단축효과 연구)

  • Park, Hyung-Joo;Lee, Young-Jae
    • Fire Science and Engineering
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    • v.32 no.6
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    • pp.46-54
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    • 2018
  • A total of 19 elevators for evacuation were installed in the Lotte World Tower and it is planned to operate the shuttle using the manual key from five refuge floors to the 1st floor in an emergency. In the event of a fire or other disaster, it is necessary to conduct intensive analysis to determine how much RSET reduction could be achieved using the evacuation elevator compared to the existing evacuation plans. When the optimal transportation sharing ratio by the evacuation elevators was 40% at the Lotte World Tower, the RSET of the evacuation scenario in parallel with the elevators in the entire building was calculated to be 1 hour and 2 minutes. The RSET of a conventional evacuation scenario (Walking along the stairs without using the elevators) was calculated to be 1 hour 29 minutes, therefore, the former evacuation scenario were found to have a shortening effect of approximately 27 minutes compared to the latter. On the other hand, to maintain this effect, each part of the evacuation route using the elevator must have the capability to protect the evacuee from any hazards caused by fires, such as smoke, flame, and radiant heat during the evacuation. Moreover, the evacuation route should be continuous from the residence position of the elevator user to the final evacuation site, and be recognized easily.

A Study on Application of TPCLT(Twice Per Cycle Left-Turn) for a Signalized Three-Leg Intersection (3지 교차로의 TPCLT(Twice Per Cycle Left-Turn) 적용 방안 연구)

  • Han, Dajeong;Kim, Eungcheol
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.18 no.2
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    • pp.77-92
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    • 2019
  • TPCLT is a advanced signal system that serves twice left turn phases during the same cycle. TPCLT can be a useful where the left turn traffic volume is high and the length of the left turn lane is short. This study examined the effectiveness of TPCLT in reducing delay for a signalized three-Leg intersection and proposed the application of TPCLT signal system. 108 scenarios with different traffic volumes were created. This study analyzed the control delay of the three-Leg intersection in case TPCLT is operated and non-TPCLT is operated. As a result of analysis, it was shown that TPCLT was effective in most of the scenarios. When traffic volume ratio of the left turn is 30~40%, TPCLT was more effective at reducing the control delay. The study result shows significant delay reduction for the left turning traffic and it is approximately 50 seconds. The opposing movement's average control delay increased 2 seconds. The effect of TPCLT on the length of left turn lane was analyzed. As a result, it is found that TPCLT is effective when the length of left turn lane is 30%~60% compared to that of conventional three leg intersection operations.

Effects of Turmeric (Curcuma longa L.) on Lipid Component and Protein Concentration in Dyslipidemic Rats (울금(Curcuma longa L.) 첨가 식이가 이상지질혈증 흰쥐의 지질성분 및 단백질 농도에 미치는 영향)

  • Oh, Da-Young;Kang, Dong-Soo;Lee, Young-Geun;Kim, Han-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.1
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    • pp.47-58
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    • 2019
  • This study aimed to investigate the improvement effect of turmeric (Curcuma longa L.) on the lipid component, protein and electrolyte concentration in dyslipidemic rats. Sprague-Dawley rats (24 male) were divided into four groups, namely the ND (normal-nondyslipidemic diet), NT (normal-nondyslipidemic diet+5% turmeric), DD (control-dyslipidemic diet), and DT groups (dyslipidemic diet+5% turmeric). Rats were sacrificed at the end of 5 weeks after experiment diet. In this study, turmeric diet (NT, DT) groups in lipid composition as evidenced from the significantly reduction of serum total cholesterol, low density lipoprotein-cholesterol (LDL-cholesterol), atherosclerotic index (AI), cardiac risk factor (CRF), triglyceride (TG), phospholipid (PL), free cholesterol, cholesteryl ester, blood glucose and non esterified fatty acid (NEFA), and elevation of high density lipoprotein-cholesterol (HDL-cholesterol) (p<0.05). The serum globulin concentration was significantly decreased (p<0.05), and the albumin concentrations were increased in turmeric diet than dyslipidemic rats. Concentrations of sodium (Na) and chlorine (Cl) in sera were lower in the DT group than DD group. Concentrations of total calcium (T-Ca), phosphorus (Pi) and potassium (K) in sera were higher in the ND, NT and DT groups than DD group. Therefore, it was concluded that the 5% turmeric diet used in the condition of this study had a beneficial effect on dyslipidemia.

An Experimental Study on Ground Reinforcement Effect of Concrete and Expansion Mat for Prevention of Buried Pipe Damage (지중매설관 손상 방지를 위한 콘크리트매트와 팽창매트의 지반보강효과에 관한 실험적 연구)

  • Park, Jeong-Jun;Shin, Heesoo;Yuu, Jungjo;Hong, Gigwon
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.1
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    • pp.91-101
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    • 2019
  • Recently, small-scale excavation like ground cavity restoration and buried pipe replacement works are being carried out in urban area, in order to improve living convenience. This paper describes experiment results on the ground reinforcement method that can reduce the buried pipe damage, when the differential settlement occurred due to poor compaction of ground below the buried pipe. Plate load tests were conducted to evaluate a reinforcement effect of ground using concrete mat and expansion mat in the ground below the buried pipe. The results showed that the stress reduction ratio by concrete mat and expansion mat according to the surcharge load was about 46%~48% and 39%~42%, respectively. Therefore, the differential settlement of the buried pipe and the ground deformation below the buried pipes were reduced by the reinforcement effect of the concrete mat and expansion mat. This means that it is possible to prevent a buried pipe damage due to underground cavity and ground subsidence, if concrete mat and expansion mat are reinforced in the ground below the buried pipe or on the ground between the buried pipes.

Study on the Evaluation Criteria of Termite Dust for Rapid Control of Wooden Structures Damaged by Termites (흰개미 가해 목조건축물의 급속 방제를 위한 분말형 약제(Termite Dust) 평가 기준 연구)

  • Im, Ik Gyun;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.35 no.3
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    • pp.227-235
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    • 2019
  • In Korea, various methods are applied to prevent wooden structures from being damaged by termites. However, since there is no way to quickly bring toxic substances in contact with the termites inside the timber, it leads to the damage of wooden cultural property due to the prolonged period of controlling the termites. Accordingly, an indoor evaluation criteria study was conducted for the introduction of powder-type termiticides in Korea, which produced rapid control effects by drilling wood and directly contacting and transferring toxic substances inside the timber. First, contact toxicity and transfer ability of termite dusts were evaluated to establish the criteria for evaluation of effectiveness against Reticulitermes speratus. The contact toxicity confirmed 100% mortality of fipronil, deltamethrin and cyfluthrin termite dusts within 24 h of contact; however, differences occurred in the active ingredient transfer time to the sublethal. In addition, in the case of transfer ability evaluation, the rate of mortality gradually decreased under 1:9 and 1:25 ratio conditions; however, the difference in the reduction rate was identified depending on the type of termite dust. the results of the evaluation of compressive strength of the wood showed that the difference in the measured values between the control group and the conditions of perforation 1 to 3 times, which does not significantly affect the compressive strength of wood. In this study, the criteria of termite dust selection and evaluation method of dust-type termiticides were presented and the applicability of the method was identified.