• Korean Chemical Engineering Research
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• 제61권1호
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• pp.39-44
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• 2023

본 연구에서는 습식 분극을 통하여 Si 다결정의 입자 크기를 조절을 하였으며, 입자 크기에 따른 Si 음극활물질의 용량 및 수명 특성 변화를 관찰하였다. 진동밀로 분쇄한 Si 입자를 습식법으로 분급한 시료의 입도를 분석한 결과 Si의 불균일한 입자 분포가 균일하게 조절이 되었다. Si를 24시간 분급한 시료의 d₅₀이 0.50 ㎛로 감소하였다. 전기화학적 특성 분석 결과, 입자 크기의 감소로 인하여 전극 내의 저항을 나타내는 R_ct 값이 현저하게 줄어들었다.분급하지 않은 Si 시료는 첫 사이클에서 2,869 mAh/g의 방전용량을 나타내었고, 100 사이클 후에는 85.7 mAh/g으로 방전용량이 감소하였다. Si를 24시간 분급한 시료의 경우에 초기에는 3,394 mAh/g의 용량을 보였으며, 100사이클 후에는 1,726 mAh/g의 용량을 유지하였다. 결과적으로 Si 입자의 크기가 감소할수록 방전용량이 증가하였으며, 사이클 수명도 증가하였다.

• International Journal of Reliability and Applications
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• 제12권1호
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• pp.61-77
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• 2011

One of the most important problems in the estimation of the parameter of the failure model, is the cost of experimental sampling units, which can be reduced by using any prior information available about ${\theta}$, and devising a two-stage pooling shrunken estimation procedure. We have proposed an estimator of the reliability function (R(t)) of the exponential model using two-stage time censored data when a prior value about the unknown parameter (${\theta}$) is available from the past. To compare the performance of the proposed estimator with the classical estimator, computer intensive calculations for bias, mean squared error, relative efficiency, expected sample size and percentage of the overall sample size saved expressions, were done for varying the constants involved in the proposed estimator (${\tilde{R}}$(t)).

• 한국염색가공학회지
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• 제11권6호
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• pp.1-6
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• 1999

The porosities of PET fibers were investigated using a nitrogen porosimeter according to oxygen plasma treatment and dyeing with a disperse dye, and they were discussed in terms of the change of internal micro-structure of the PET fiber. The total pore volume, surface area and average pore size of the plasma treated PET fibers increased expectably compared with the untreated sample. The PET fibers treated with oxygen plasma and then dyed with a disperse dye were increased significantly in the surface area and the total pore volume comparing with those of plasma treated only, but decreased in the average pore size. The increase of the surface area, after dyeing, of the plasma treated PET fibers was due to addition of the surface area of the dye itself to that of the PET fiber. The increase of the total pore volume of the plasma treated PET fibers by dyeing, which is the opposite result to the general idea that the pore volume of fibers would be reduced by occupation of dye molecules in the pores, could be explained by the free-volume model. This is that the amorphous region in the fiber expanded by occupation of dye molecules, and the marginal space surrounding dyes was generated as many smaller pores, and the decrease of the average pore size of the dyed sample also could be explained The decrease of the average pore size was caused by the splitting of a larger pore into smaller pores.

• Advanced Composite Materials
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• 제16권3호
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• pp.245-258
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• 2007

The single-modal Weibull model has been assessed on Tyranno ZMI Si-Zr-C-O fiber if a set of shape and scale parameters accurately reproduced the effect of the size of the diameter on strength. The tensile data of a single fiber have been divided into two expedient groups as 'small diameter' group and 'large diameter' group in deriving the parameters, which should be consistent if the Weibull model accurately reproduced the size effect. However, the derived Weibull parameters were inconsistent between the two groups. Thereby the authors have concluded that the parameters of the single-modal Weibull model are dependent on the fiber diameter, so that the model is inadequate to reproduce the strength size effect. On the other hand, Weibull parameters were found consistent between the two groups by excluding the data of 'large mirror zone' sample, which was defined as the sample around 10% mirror zone area of the fracture surface. What is more, the exclusion reduced the strength variance more drastically in the 'large diameter' group than in the 'small diameter' group, even though the 'large mirror zone' samples were found identical in the percentage between the two groups. The authors therefore conclude that diameter limitation to the 'small diameter' group level can lead to drastically less distributed strength values than the estimated strength through the Weibull scaling on the present Tyranno ZMI Si-Zr-C-O fiber.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.390-390
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• 2010

Superconducting proximity effects of Nb/Si(111) were investigated with scanning tunneling microscopy(STM) and scanning tunneling spectroscopy(STS). A highly-doped($0.002\;{\omega}{\diamondsuit}cm$) Si wafer pieces were used as substrate and Nb source was thermally evaporated onto the atomically clean silicon substrate. The temperature of the silicon sample was held at $600^{\circ}C$ during the niobium deposition. And the sample was annealed at $600^{\circ}C$ for 30 minutes additionally. Volmer-Weber growth mode is preferred in Nb/Si(111) at the sample temperature of $600^{\circ}C$. With proper temperature and annealing time, we can obtain Nb islands of lateral size larger than Nb coherence length(~38nm). And outside of the islands, bare Si($7{\times}7$) reconstructed surface is exposed due to the Volmer-Weber Growth mode. STS measurement at 5.6K showed that Nb island have BCS-like superconducting gap of about 2mV around the Fermi level and the critical temperature is calculated to be as low as 6.1K, which is lower than that of bulk niobium, 9.5K. This reduced value of superconducting energy gap indicates suppression of superconductivity in nanostructures. Moreover, the superconducting state is extended out of the Nb island, over to bare Si surface, due to the superconducting proximity effect. Spatially-resolved scanning tunneling spectroscopy(SR-STS) data taken over the inside and outside of the niobium island shows gradually reduced superconducting gap.

• 전자공학회논문지A
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• 제32A권3호
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• pp.471-481
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• 1995

Measurement factors for the dielectric properties of low dielectric loss materials (tan${\dalta}{\le}10^{-4}$) were investigated using the dielectric rod resonator method. It was shown that the relative conductivity (${\sigma}_{r}$) should be controlled within a 5% to obtain the standard deviations of less than 0.07 for permittivity .epsilon.r and 0.06${\times}10^{-4}$ for tan.delta.respectively. Surface resistivity (R$_s$) could be reduced when the surface roughness of parallelled conducting plate was less than 0.07 .mu.m. Measurement error for the permittivity was $\pm$0.02% independent of probe loop size, whereas the error in Q value was reduced with the decrease in probe loop size and also with the increase in the absolute values of Q. Reliable Q values were determined with the probe loop size of less than 4mm. The accurate for the distance between the measuring probe loop and the sample could be obtained when the insertion loss of resonant frequency ranged -15dB - -30dB.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2006년도 하계종합학술대회
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• pp.263-264
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• 2006

In this paper, an efficient and fast algorithm to reduce calculation amount of FIR(Finite Impulse Responses) filtering is proposed. Proposed algorithm enables arbitrary size of parallel processing, and their structures are also easily derived. Furthermore, it is shown that the number of multiplication/sample is reduced, and number of instructions using MAC(Multiplication and Accumulation) processor are also reduced. For theoretical improvement, numbers of sub filters are compared with those of conventional algorithm. In addition to the theoretical improvement, it is shown that number of element for hardwired implementation are reduced comparison to those of the conventional algorithm.

• 한국신뢰성학회지:신뢰성응용연구
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• 제5권1호
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• pp.167-180
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• 2005

Design of a degradation test without replacement is considered based on tightened critical value to reduce the evaluation testing time. The sample size, number of inspections, and the critical values are determined to assure the same probability of acceptance when the testing time is reduced to some degree. Photo-diode balance of an optical pickup is analyzed as a case study.

• 한국산업정보학회논문지
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• 제23권2호
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• pp.19-28
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• 2018

본 연구에서는 함정 신호해석 연구에 필요한 해양기상환경 자료의 표본추출에 관한 연구를 수행하였다. 이를 위해 한국 기상청으로부터 품질검사가 완료된 최신의 해양 기상자료를 수집하고, 측정 자료의 가용 구간을 설정하여 이상치를 제거하였다. 품질검사와 이상치를 제거한 자료는 함정 신호의 확률론적 해석을 위해 지정학적 위협과 부이의 유효면적을 고려하여 단순임의추출법을 통해 축소되었다. 이후 표본의 크기는 모집단의 크기와 신뢰수준 95%를 고려하여 100, 200 그리고 400개로 설정하였으며, 상관관계가 높은 수온과 기온을 기준으로 하는 2차원 층화추출법으로 최종표본을 추출하였다. 추출 표본은 제곱오차의 합과 신뢰구간을 추정하고 이를 비교하여 함정의 확률론적 신호해석을 위해 필요한 해양기상조건의 크기를 제시하였다.

• 인터넷정보학회논문지
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• 제17권1호
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• pp.1-6
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• 2016

바이어스된 영-오차확률 (biased zero-error probability)과 이에 관련된 알고리듬은 매 반복시간마다 합산과정을 지니고 있어 많은 계산상의 부담을 요구한다. 이 논문에서는 바이어스된 영-오차확률에 반복적 접근법을 적용한 알고리듬을 제안하였고 천해역 통신채널과 충격성 잡음 및 바이어스된 가우시안 잡음이 혼재한 실험 환경에서 성능을 비교하였다. 샘플 사이즈에 비례하는 계산 복잡도를 지닌 기존 알고리듬과 달리 제안한 반복적 방식은 샘플 사이즈와 무관하여 계산량의 부담을 크게 줄였다. 이러한 계산효율 특성을 지닌 제안한 알고리듬은 블록 처리방식의 기존 알고리듬과 비교하여 다중경로 페이딩, 바이어스된 잡음 및 충격성 잡음에 대한 강인성에서 동일한 성능을 나타냈다.