• Title/Summary/Keyword: red phosphors

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Color matching of color CRT and dyed fabric by using experimental method (실험실적 방법에 의한 Color CRT와 염색직물의 칼라 매칭)

  • 김청섭;홍영기;배기서
    • Textile Coloration and Finishing
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    • v.13 no.6
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    • pp.397-404
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    • 2001
  • The accurate representation of the colors of dyed fabric on a color CRT(cathode ray tube) screen is the basis for the automatic process in dyeing industry. In the former study, we had focused on the theoretically color matching method between CIE(International Commission on illumination) and RGB color coordinates, but In this study we tried simulating the colors obtained from fabrics on the color CRT by using experimental method. we obtained the following results. 1. We could simulate all of the color CRT by gamut mapping method, even though some of the KOSCOTE(Korea Standard Color of Textile) colors represented on the color CRT didn't exist in the region of color region 2. We could do conditional matching by CIE system, even though it was hard to do invariant matching the Red, Green, Blue phosphors of the color CRT because of the SPD(Spectral Power Distribution) which had been set up before. 3. We could simulate all the colors obtained from fabrics on the color CRT by matching those two color groups from KOSCOTE fabrics and color CRT using match algorithm and matching programs. 4. If we get over on obstacles by grafting CCM and CCK machines which have been used in educational and industrial areas by matching KOSCOTE with color CRT we will be able to invent color simulation system controled automatically.

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Photoluminescence properties of $Gd_{1-x}Ln_xCa_3(GaO)_3(BO_3)_4$ (Ln=Eu, Tb, Tm) under UV excitation

  • Kyung, Hyun-Ai;Jung, Ha-Kyun;Seong, Tae-Yeon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1565-1568
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    • 2007
  • A borate compound was adopted as new host material for $Eu^{3+}$, $Tb^{3+}$ and $Tm^{3+}$ activators. The phosphor samples, $Gd_{1-x}Eu_xCa_3(GaO)_3(BO_3)_4$, $Gd_{1-x}Tb_xCa_3(GaO)_3(BO3)_4$ and $Gd_{1-x}Tm_xCa_3(GaO)_3(BO_3)_4$ have been synthesized by conventional solid-state reaction. The crystalline phase for the resulting powders was identified using an X-ray diffraction $system^1$. Their photoluminescence properties under the excitation of UV ray were investigated. The Eu, Tb or Tm-doped $GdCa_3(GaO)_3(BO_3)_4$ emits efficient red, green or blue light, respectively. It was observed that the optimum concentration of Eu or Tb activator for the borate host was much higher than other $Eu^{3+}$ or $Tb^{3+}-doped$ phosphors.

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Synthesis and Luminescent Properties of Aluminate-based Phosphors Doped with Mn4+ Ions (Mn4+ 이온이 도핑된 알루미네이트계 형광체 합성과 발광특성)

  • Park, Jungkyu;Kim, Young Jin
    • Journal of the Korean Ceramic Society
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    • v.51 no.1
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    • pp.37-42
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    • 2014
  • $Mn^{4+}$-doped $CaAl_4O_7$ ($CA_2$) and $CaAl_{12}O_{19}$ ($CA_6$) powders were prepared under different conditions, with changes in the amounts of flux, Mn concentration, and mole ratio of $Al_2O_3$ to $CaCO_3$ in the starting mixtures, which affected the structure and the luminescence. $CA_2:Mn^{4+}$ and $CA_6:Mn^{4+}$ had the same excitation and emission spectra but with different intensities. The excitation spectra exhibited broad bands (320 - 470 nm) centered at 395 nm, while red emission bands were observed at 656 nm. The emission intensity of $CA_6:Mn^{4+}$ was nearly twice as high as that of $CA_2:Mn^{4+}$, as the $Mn^{4+}$ ions were located in an octahedral crystal field in the $CA_6$, but not in the $CA_2$.

Effect of Heat-treatment Atmosphere on Photoluminescence of Eu-doped Li-Al-O System (열처리 분위기가 Eu 이온이 첨가된 Li-Al-O계 형광체 특성에 미치는 영향)

  • Kim, Jeong Seog;Cheon, Chae Il;Chae, Ki-Woong
    • Journal of the Korean Ceramic Society
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    • v.51 no.1
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    • pp.25-31
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    • 2014
  • New green phosphor is synthesized by reducing $LiAlO_2:xEu^{3+}$ phosphors in a low pressure $H_2$ atmosphere. The $LiAlO_2:xEu^{3+}$ prepared by a solid state reaction method is reported as red phosphor. The effect of the reduction treatment on the $LiAlO_2:xEu^{3+}$ on the crystalline phase change and photoluminescence (PL) property are characterized. The reduced phosphor had a broad green light spectrum centered at 524 nm. The PL intensity of the reduced phosphor increased to a maximum at the reduction temperature of $1100^{\circ}C$. The PL intensity decreased with a further increase in the reduction temperature. The crystalline phase constituting the reduced phosphor varied with the temperature. A new crystalline phase $Li_2Al_4O_7$ was observed at $1100^{\circ}C$. The origin of the green-light emission is discussed in relation to the crystalline phase change.

Synthesis and Photoluminescence Properties of ZrO2:Eu3+ Nanoparticles Using Salt-Assisted Ultrasonic Pyrolysis Process (염 보조 초음파 분무 열분해법을 이용한 ZrO2:Eu3+ 나노입자의 합성 및 발광 특성)

  • Hwangbo, Young;Lim, Hyo Ryoung;Lee, Young-In
    • Korean Journal of Materials Research
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    • v.27 no.5
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    • pp.270-275
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    • 2017
  • Inorganic phosphors based on $ZrO_2:Eu^{3+}$ nanoparticles were synthesized by a salt-assisted ultrasonic spray pyrolysis process that is suitable for industrially-scalable production because of its continuous nature and because it does not require expensive precursors, long reaction time, physical templates or surfactant. This facile process results in the formation of tiny, highly crystalline spherical nanoparticles without hard agglomeration. The powder X-ray diffraction patterns of the $ZrO_2:Eu^{3+}$ (1-20 mol%) confirmed the body centered tetragonal phase. The average particle size, estimated from the Scherrer equation and from TEM images, was found to be approximately 11 nm. Photoluminescence (PL) emission was recorded under 266 nm excitation and shows an intense emission peak at 607 nm, along with other emission peaks at 580, 592 and 632 nm which are indicated in red.

Synthesis of $Y_2O-# : Eu$ Added the Group 1 or 2 Elements Using Complex-Polymerization and its Luminescent Properities (착제중합법에 의한 1, 2족 원소가 $Y_2O-# : Eu$ 형광체의 합성광 발광특성)

  • Park, Sang Mi;Kim, Chang Hae;Park, Joung Kyu;Park, Hee Dong;Jang, Ho G.
    • Journal of the Korean Chemical Society
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    • v.45 no.3
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    • pp.236-241
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    • 2001
  • Europium activated yttrium oxide ($Y_2O_3$ : Eu) is extensively applied to red phosphor for Flat Panel Display because of its high efficiency and the thermal and chemical stability. Flat Panel Display screen which have a high resolution and high efficiency needs to the phosphors of ideally small size spherical particle. In this study, we prepared a $Y_2O_3$ : Eu phosphor using polymeric precursor methods and investigated the codoping effect by introducing the group 1 or 2 elements to $Y_2O_3$ : Eu phosphor in view of improvement of luminance efficiency.

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High Luminance 3D Built-In PDP Panel with Fast-Decaying Phosphor

  • Kim, Young-Kwan;Yoo, Young-Gil;Lee, Soon-Rewl;Kim, Min-Kyu;Kim, Jeong-Hee;Chung, Kyeong-Woon;Choi, Ick-Kyu;Song, Jay-Hyok;Song, Yu-Mi;Kim, Yoon-Chang;Heo, Eun-Gi;Zang, Dong-Sik;Chung, Chong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.127-130
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    • 2009
  • High luminance 3D built-in PDP panel was developed with newly adopted fast-decaying phosphor. Luminance of 3D PDP was increased about 40% by reducing the particle size of RGB phosphors and using $Y_3(Al,Ga)_5O_{12}:Ce^{3+}$ phosphor. Decay time of developed 3D PDP was 5.2ms/4.9ms for Red/Green color.

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Luminescent Properties of YVO4:Eu3+ Phosphor by Using Hydrothermal Synthesis (수열합성에 의해 제조된 YVO4:Eu3+ 형광체의 발광특성)

  • Moon, Yong-Min;Choi, Sung-Ho;Jung, Ha-Kyun;Lim, Sang-Ho
    • Korean Journal of Materials Research
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    • v.18 no.10
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    • pp.511-514
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    • 2008
  • We have synthesized $Eu^{3+}$-doped $YVO_4$ phosphors by using a hydrothermal method and investigated their luminescent properties. Aqueous solutions of $Y_2O_3,\;V_2O_5,\;Eu_2O_3$, and nitric acid with various pH values were used as the precursors. The crystallinity, surface condition, and emission characteristics were examined using XRD, FT-IR, and photo-excited spectrometer. $Eu^{3+}$ incorporation followed by the efficient red emission strongly depends on the acidity of solution media. The emission intensity becomes stronger as the pH values increase to 7 and then gradually decreases. This phenomenon might be related to the hydroxyl quenching effect, which is induced by surface bound OH-groups.

Optical Simulation Study of the Improvement of Color-rendering Characteristics of White Light-emitting Diodes by Using Red Quantum-dot Films (적색 양자점 필름을 이용한 백색 발광 다이오드의 연색성 개선에 대한 광학 시뮬레이션 연구)

  • Lee, Gi Jung;Hong, Seung Chan;Lee, Jung-Gyun;Ko, Jae-Hyeon
    • Korean Journal of Optics and Photonics
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    • v.32 no.4
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    • pp.163-171
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    • 2021
  • Conventional white light-emitting diodes (LEDs) for lighting applications consist of blue LEDs and yellow phosphors, the spectrum of which lacks deep red. To improve the color-rendering characteristics of white LEDs, a red quantum-dot film was applied to the diffuser plate of LED lighting. The mean free paths of the quantum dots and the concentration of the TiO2 particles in the diffuser plate were adjusted to optimize the optical structure of the lighting. The color-rendering index (CRI) was greater than 90 for most conditions, which demonstrates that adoption of the red quantum-dot film is an effective way for improving the color-rendering properties of conventional white LEDs. The angular dispersion of color coordinates could be removed by utilizing the optical cavity formed between the diffuser plate and the reflector on the bottom of the lighting, where multiple passages of the light through the quantum-dot film reduced the differences in optical path length depending on the viewing angle.

A Study on Photoluminance Properties of $(Y,Gd)BO_3:Eu^{3+}$ Phosphor Synthesized by Ultrasonic Spray Pyrolysis (초음파 분무법으로 제조한 $(Y,Gd)BO_3:Eu^{3+}$ 형광체의 발광특성에 관한 연구)

  • Kim, Dae-Su;Lee, Rhim-Youl
    • Korean Journal of Materials Research
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    • v.10 no.3
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    • pp.204-211
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    • 2000
  • The $(Y,Gd)BO_3:Eu$ red phosphors for PDP application were synthesized by ultrasonic spray method and then their photoluminance properties were investigated under 147nm VUV irradiation. The precursor solution of acetates of Y, GD and Eu and boric acid diluted in water was sprayed using 1.7 MHz ultra-sonic sprayer into the reaction tube held at high temperature. The as-sprayed particles were amorphous phase having C-C and C-H bonds due to the insufficient thermal reaction during the pass along the tube. But the sprayed samples followed by heat treatment at $1100^{\circ}C$ had the same crystal structure and chemical composition as those samples followed by solid state reaction. It was found that the $(Y_{0.7}Gd_{0.3})_{0.95} BO_3:Eu_{0.05}^{3+}$ phosphor particles synthesized by spray at $500^{\circ}C$ and then heat treated at $900^{\circ}C$ had a spherical-like shape and fine particle size at $0.7{\mu\textrm{m}}$ having a narrow size distribution, while the phosphor particles made by solid state reaction was $3{\mu\textrm{m}}$ coarse and non-uniform size distribution. The emitting intensity under 147nm VUV excitation for $(Y_{0.7}Gd_{0.3})_{0.95}BO_3:Eu_{0.05}^{3+}$ phosphor prepared by spray method was found to be higher than those phosphor made by solid state reaction and the commercial $(Y,Gd)BO_3:Eu$ product.

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