• Title/Summary/Keyword: recycling of $CO_2$

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Construction Waste Management System for Improving Waste Treatment on the Construction Site (건축현장의 환경관리 업무 효율성 향상을 위한 폐기물 관리 시스템 - 공동주택을 중심으로 -)

  • Cha, Namwoo;Park, Wansu;Kim, Kyungrai;Cha, Heesung;Shin, Dongwoo
    • Korean Journal of Construction Engineering and Management
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    • v.15 no.3
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    • pp.83-91
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    • 2014
  • The problems of environmental pollutions and resources depletion have been growing issues in global construction recently. Efforts to reduce $CO_2$ emission have been also made in all sectors of construction industry these days. As one of the biggest industries that consume a huge amount of resources and generate complex construction wastes, the construction industry has significant impacts on environment issues. However, systematic approach to manage wastes has been rarely made, and most construction wastes from construction sites are being land-filled or incinerated. In this study, a system is proposed to predict the amount of wastes in visual formats, and to control the process of wastes management. The system's main functions include : (1) to estimate the amount of wastes to be generated in project schedule, (2) to categorize the types of wastes, (3) to determine the timing of taking out wastes from sites, and (4) to share information regarding wastes for recycling. A huge amount of wastes are generated in construction process, but most of the wastes have been discharged in forms of mixed wastes, which make them hardly reused. The system not only provide information on wastes to be generated, but also prevent mixing various wastes by classifying them by types and schedules. This features of the system, along with functions to share wastes information with other agencies outside the site, are expected to enhance the level of wastes recycling to a great extent. By saving construction materials through wastes recycling, the system also contributes in reducing $CO_2$ emission.

Effect of Carbon Materials on the Slag Foaming in EAF Process (전기로 슬래그 포밍에 미치는 가탄재 종류의 영향)

  • Kim, Young-Hwan;Yoo, Jung-Min;Um, Hyung-Sic
    • Resources Recycling
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    • v.28 no.2
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    • pp.40-45
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    • 2019
  • During steelmaking in EAF, recycled scraps is used as a main material, melted by arc, and electricity use as a main energy. Slag foaming is an important technology for reducing electrical energy. CO gas generated by the reaction between injection carbon and (FeO), [C] and injection {$O_2$}. CO gas generated by this reaction is collected in slag, resulted in slag foaming. In general, the carbon materials used in the EAF process is anthracite and coke. This study investigated the effects of the carbon materials used on slag foaming in the steelmaking process. As a result of this study, the slag foaming height is increased by cokes rather than anthracite, and with an increase in the amount of particles samller than $500{\mu}m$. Based on these results, the application to the operation resulted in increase of slag forming height, reduction of injection carbon, and reduction of electrical energy.

Investigation on the material properties of Waste Oyster Shell to use as an Adsorbent for Fluoride Ion (불소(弗素) 이온 흡착제(吸着劑)로서의 활용(活用)을 위한 폐(廢)굴껍질의 특성(特性) 분석(分析))

  • Lee, Jin-Suk;Seo, Myung-Soon;Kim, Dong-Su
    • Resources Recycling
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    • v.16 no.3 s.77
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    • pp.12-18
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    • 2007
  • The material properties of waste oyster shell, which is largely generated from the treatment of marine products, have been investigated for its possible utilization as an adsorbent for fluoride ion-containing wastewater. The major composition of waste oyster shell was analyzed to be $CaCO_3$ and loss of 46% in weight reduction occurred during its thermal treatment by the emission of moisture and $CO_2$. The surface structure of oyster shell was decomposed by the heating and its surface potential was negatively increased with pH. As the pH of wastewater was increased, the adsorbed amount of fluoride ion onto oyster shell was decreased and the wastewater was found to be neutralized during adsorption process by ${CO_2}^{3-}$ which generated from the partial dissolution of oyster shell

Selective Extraction of Cobalt and Nickel in the Presence of Magnesium from Sulphate Solutions by Versatic Acid 10 (마그네슘이 함유된 황산용액에서 Versatic acid-10에 의한 코발트와 니켈의 선택적 추출)

  • Cho, Yeon chul;Ahn, Jae woo;Lee, Jae young
    • Resources Recycling
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    • v.29 no.4
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    • pp.51-57
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    • 2020
  • Separation of Co and Ni over Mg from the sulfuric acid solutions using Cyanex272, PC88A and Versatic acid 10 as an extractant was carried out. From the comparative studies about the extraction behavior of Co, Ni and Mg, Versatic acid 10 was superior to Cyanex272 and PC88A for the selective extraction of cobalt and nickel from the mixed solutions. About 98% of Ni and Co were extracted at equilibrium pH 7.0 and less than 5% of Mg was co-extracted by Versatic acid 10. McCabe-Thiele diagram indicated two stages requirement for Co and Ni extraction by 10% Versatic acid 10 at pH 7.0 and phase ratio (A/O) of 2.0. The loaded Co and Ni in organic phase was stripped effectively the sulfuric acid concentration above 70 g/L. 99.78% of cobalt and 98.42% of nickel were stripped.

Comparison of Li(I) Precipitation from the Leaching Solution of the Dust from Spent Lithium-ion Batteries Treatment between Sodium Carbonate and Ammonium Carbonate (폐리튬이온전지 처리시 발생한 더스트 침출용액으로부터 Na2CO3와 (NH4)2CO3에 의한 리튬(I) 석출 비교)

  • Nguyen, Thi Thu Huong;Lee, Man Seung
    • Resources Recycling
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    • v.31 no.5
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    • pp.34-41
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    • 2022
  • Smelting reduction of spent lithium-ion batteries results in metallic alloys, slag, and dust containing Li(I). Precipitation of Li2CO3 was performed using the synthetic leachate of the dust. Herein, the effects of the precipitant and addition of non-aqueous solvents on the precipitation of Li(I) were investigated. Na2CO3 was a more effective precipitating agent than (NH4)2CO3 owing to the hydrolysis reaction of dissolved ammonium and carbonate. The addition of acetone or ethanol improved the Li(I) precipitation percentage for both the precipitants. When using (NH4)2CO3, the Li(I) precipitation percentage increased at a solution pH of 12. Under the same conditions, the Li(I) precipitation percentage using Na2CO3 was much higher than that using (NH4)2CO3.

Life Cycle Assessment(LCA) of Rubber Recycling Process in Waste Tire (폐타이어 고무 재활용 공정의 전과정평가 연구)

  • Ahn, Joong Woo;Kim, Jin Kuk
    • Resources Recycling
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    • v.27 no.1
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    • pp.74-83
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    • 2018
  • This study conducted the Life Cycle Assessment(LCA) on waste rubber recycling technology for recovering rubber product from the waste tires. Environmental impacts were assessed for the five categories of impacts: global warming, resource depletion, acidification, eutrophication, photochemical oxide production, and ozone layer depletion. When recycling 1ton of waste tire containing rubber, global warming impact was 1.77E+02 kg $CO_2-eq.$, resource depletion impact was 1.23E+00 kg Sb-eq., acidification impact was 5.92E-01 kg $SO_2-eq.$, eutrophication impact was 1.23E-01 kg $PO{_4}^{3-}-eq.$, photochemical oxide production impact was 3.42E-01 kg $C_2H_4-eq.$, and ozone layer depletion impact was 1.87E-04 kg CFC11-eq. In terms of overall environmental impacts, carbon, softener and electricity the greatest impact, so it is necessary to compare the environmental impacts of the raw materials to replace carbon and softener, and a method to reduce the filler usage in the process is needed. In addition, it is necessary to improve energy efficiency, change to low-energy sources, and apply renewable energy.

Applications and prospect of CDM project through recycling of inorganic waste (무기질(無機質) 폐기물(廢棄物)의 재활용(再活用)을 통한 CDM 사업(事業) 적용사례(適用事例) 및 전망(展望) - 시멘트 산업(産業)을 중심(中心)으로 -)

  • Cho, Jin-Sang;Cho, Kye-Hong;Ahn, Ji-Whan;Um, Seong-Il;Yeon, Kyu-Seok
    • Resources Recycling
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    • v.20 no.2
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    • pp.3-15
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    • 2011
  • Current, Registration fields of CDM projects are being conducted in a variety of parts such as mostly energy, chemical processing and manufacturing processes. However, there are not many CDM project registrations by recycling of inorganic waste. In this paper, analysis abroad CDM project and applications in order to review possibility of CDM project registration through the recycling of domestic inorganic waste were investigated. As a results, registered case of CDM project by inorganic waste recycling was researched to registrate in raw material alternative field of cement industry that inorganic waste can be used in large quantities. Application prospects of CDM project in Korea will be possible to analysis industrial scale, industry using inorganic raw materials, green house gas emissions and inorganic waste generated in large quantities.

A Preliminary Experimental Study on the Development of Oxy-Fuel Combustion Heating System with $CO_2$ Recycle ($CO_2$ 재순환형 산소연소 가열시스템개발에 관한 실험적 연구)

  • Lee, Eun-Kyung;Go, Chang-Bok;Jang, Byung-Lok;Han, Hyung-Kee;Noh, Dong-Soon;Jeong, Yu-Seok
    • 한국연소학회:학술대회논문집
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    • 2006.04a
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    • pp.69-74
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    • 2006
  • An Experimental study was conducted on $CO_2$ recycle combustion heating system using pure oxygen instead of conventional air as an oxidant, which is thereby producing a flue gas of mostly $CO_2$ and water vapor($H_2O$) and resulting in higher $CO_2$ concentration. The advantages of the system are not only the ability to control high temperatures characteristic of oxygen combustion with recycling $CO_2$. but also the possibility to reduce NOx emission in the flue gas. A small scale industrial reheating furnace simulator and specially designed variable flame burner were used to characterize the $CO_2$ recycle oxy-fuel combustion, such as the variations of furnace pressure, temperature and composition in the flue gas during recycle. It was found that $CO_2$ concentration in the flue gas was about 80% without $CO_2$ recycle, but increased to $90{\sim}95%$ with $CO_2$ recycle. The furnace temperature and pressure was decreased due to recycle and the NOx emission was also reduced to maintain under 100ppm.

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Case Study of Soil Remediation by Mobile Soil Washing Instillation - Implemetation on Fluoride comtaminated soil in kitakyushu, Japan - (이동식 토양세척설비를 이용한 오염토양 복원 사례 - 일본 키타큐슈시 불소오염토 적용을 중심으로 -)

  • Oh, Seung-Hoon;Cheong, Jun-Gyo;Chang, Chung-Hee
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.268-276
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    • 2008
  • The status of contaminated soils vary widely ; therefore, the techniques and equipment applicable to the soil concerned should be selected and used after careful consideration. Hyundai Soil Washing is physical-chemical separation based on mining and mineral processing principles for removing a broad range of organic and inorganic contaminants from soil. Mobile plant(capacity 15 tons./hr) was installed for this project. The goals of this project were 1) to verify the applicability of the washing process, which showed reliable results in the pilot plant with various kind of contaminated soils and 2) to promote recycling of the washed soil as a backfill on site. The results revealed that $F^-$ and $Pb^{2+}$ in the soil were effectively washed out to a certain level which washed soil was acceptable for recyeling.

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Distribution Behavior of Bi and Pb Between Molten PbO-SiO2 Slag and Bi (용융(熔融) PbO-SiO2계(系) 슬래그와 Bi 사이의 Bi와 Pb의 분배거동(分配擧動))

  • Kim, Se-Jong;Kim, Eung-Jin;Sohn, Ho-Sang
    • Resources Recycling
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    • v.21 no.5
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    • pp.65-71
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    • 2012
  • The equilibrium distribution of bismuth and lead between molten PbO-$SiO_2$ slag and bismuth phase was studied in the temperature range of $775^{\circ}C$ to $850^{\circ}C$ in a MgO crucible. The oxygen partial pressure of atmosphere was controlled by $P_{CO2}/P_{CO}$ ratio. The value of $(%PbO)_{slag}/[%Pb]_{metal}$ increased with increasing $SiO_2$ content of slag, and the value of $(%Bi_2O_3)_{slag}/[%Bi]_{metal}$ decreased with increasing $SiO_2$ content of slag. The concentration of Pb in metal increased with increasing temperature. These experimental results agreed well with the thermodynamic prediction.