• Clean Technology
• /
• v.14 no.2
• /
• pp.110-116
• /
• 2008

The radioactive wastes generated from the nuclear industry can be divided into the forms of solid, liquid, or gas. Radioactive methyl iodide, a gaseous radioactive waste, is absorbed by activated carbon with 5 wt% of Trietylenediamine (1,4-diazania-bicycle[2.2.2]octane, TEDA) impregnated on the surface. Methyl Iodide ($CH_3I$) is combined chemically with TEDA (the final product : I-TEDA). To recycle radioactive activated carbon, removal of I-TEDA from activated carbon is needed. A wet method for recycling impregnated active carbon was developed to remove radioactive I-TEDA using an acetonitrile solution, which produces lots of secondary wastes. We suggest the removal of I-TEDA by supercritical carbon dioxide with co-solvents. In this experiment, we used a quartz crystal microbalance (QCM) for measuring the removal rate of the I-TEDA. From the experimental results, methanol was found to be the optimum co-solvent, and the optimum conditions such as temperature, pressure, and co-solvent flow rate were obtained. Possibility of using supercritical fluid in the removal of I-TEDA from radioactive activated carbon was also discussed.

• Clean Technology
• /
• v.14 no.2
• /
• pp.129-135
• /
• 2008

Nylon membrane was used to separate ethanol-water by a pervaporation method. Experimental equations were derived to use the simulation of membrane-aided distillation using nylon. The increases in permeation pressure resulted in the decrease in selectivity and energy consumption. The energy cost to enrich ethanol from 94 wt% to 99.5 wt% was calculated to be 53.3 won/kg of ethanol with extractive distillation and 18.9 won/kg of ethanol with a pervaporation method. The saving energy by the pervaporation method is consumed by recycling the permeate residue into the distillation column in the membrane-aided distillation column. Therefore, membrane with the high selectivity to minimize the permeate residue recycle is required to effectively enrich ethanol in the membrane-aided distillation method.

• Clean Technology
• /
• v.19 no.4
• /
• pp.388-392
• /
• 2013

Iindium-tin-oxide (ITO) material was had to use in display application as transparent electrode. However it would be problems comes up, the depletion of indium, tin and energy consumption of production process. Therefore recently trend was demanded alternative ITO material and recycling/reused ITO. In this conditions, the environmental impact have to express correct value about recycling/reused ITO process. The life cycle assessment was valuable method in this process. Thus first step was carried out separating in/out put (material) sources and then, exactive data base (DB) was applied. The result of environment impact was calculated by affect categories and recycling rate was set to 34% (This value was measured in previous project). The rate (g) of ITO material was calculated by chemical equivalent. In result, environmental impact were revealed acidification potential and abiotic depletion and if do not recycle/reuse ITO, $ 476 per 1 ton waste in land.

• Clean Technology
• /
• v.23 no.2
• /
• pp.196-204
• /
• 2017

CdZnS/ZnO composite was prepared through low-temperature precipitation and drying method. The property of CdZnS/ZnO as a recyclable photocatalyst for the degradation of rhodamine B (RhB) under visible light irradiation was examined. The sample was characterized by XRD, FE-SEM, XPS, UV-vis DRS and photoluminescence techniques before and after repeated reaction to investigate the change of properties during the photocatalytic reaction. During repeated reaction, the CdZnS/ZnO showed an improved photocatalytic activity and recycle stability. Among two feasible reaction pathways for photocatalytic degradation of RhB, the cleavage of conjugated chromophore was found to predominate over N-dealkylation of chromophore skeleton in the present work. The results indicate that the CdZnS/ZnO, prepared by a simple precipitation method, can be used as a visible-light driven photocatalyst with enhanced cycle stability and activity.

• The Journal of the Korea Contents Association
• /
• v.20 no.1
• /
• pp.644-657
• /
• 2020

As the development of urbanization has cause some environmental problems and natural disasters such as natural earthquakes and floods have brought about impact, designers have turned their attention to the independent prevention ability of urban ecosystems in face of environmental pollution and natural disasters, as well as its ability to adapt to the future. This study introduces 'elasticity theory' to discuss the practical application of elasticity design in landscapes and to solve the problem of lack of elasticity in space, which can provide more scientific reference meaning to create economic, cultural, and social values for space. After selecting 'The High Line' as the object, this paper investigates the previous theories and practical cases, and infers ecology, sustainability, diversity, and adaptability. And then this paper applies five components and analyzes the specific application of these five components of the landscape spatial elasticity strategy, and summarizes the application characteristics and influencing factors of elasticity design in 'The High Line' landscape planning. It can be known from the research that elasticity strategy which is reflected in the design process is the systematic management of landscape space. Elasticity design itself can strengthen environment quality and satisfy the requirements of the environment to defense external shocks so as to adapt to environment changes. Therefore, the elasticity design can strengthen the sustainable development of the city and establish a periodic recycle system.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.9 no.3
• /
• pp.77-87
• /
• 2001

Composting is a cost-effective and environmentally-sound technology to treat soils contaminated with hazardous organic pollutants. Pollutants to be treated are as follows: explosives, phenolic compounds, PAHs, petroleum hydrocarbons, pesticides, and etc. Composting systems are windrow, static pile, and in-vessel. Design and operational parameters of composting are aeration modes, temperature, moisture content, nutrient supplement, amendment added, and etc. Appropriate oxygen concentration of composting for contaminated soils are 5~15%, while some compounds are degraded well at the low $O_2$ concentration of 2~5%. The most diverse microorganisms live in the temperature of $25{\sim}40^{\circ}$. 50~90% of the soil field capacity is the moisture content not to make a problem in composting. Assuming a bacterial chemical equation is $C_{60}H_{87}O_{23}N_{12}P$, theoretical C : N : P from bacterial chemical portion is approximately 20 : 5 : 1. It should be noted that the ratio does not apply to the total organic carbon measured in a waste because not all carbon metabolized by bacteria is synthesized to new cellular material. Initial C/N ratio of 25~40 is optimum. It is more economical to recycle soils or composts than to add commercial microbes.

• Journal of Korean Society of Environmental Engineers
• /
• v.28 no.5
• /
• pp.494-500
• /
• 2006

Life Cycle Assessment(LCA) is an environmental assessment tool for evaluating environmental burdens associated with products, processes and activities from the raw material acquisition stage to the end-of-life stage. End-of-life stage as well as other processes requires a reliant database in order to increase the confidence in the LCA results. In this study, the flow of Personal Computer(as PC) in the end-of-life stage was examined and the database of two scenarios has been established, i.e. one is part reuse and the other is no part reuse, in the end-of-life phase of PC. Also, key environmental issues were identified by carrying out LCA on a PC in the end-of-life phase for eight environmental impact categories. The 'ozone layer depletion' contributes the highest environmental impact due to generation of $Cl_2$ gas during the incineration of waste plastics. In addition, the scenario 1(part reuse) is more environmentally sound than the scenario 2(no part reuse) when comparing two scenarios.

• Journal of Korean Society of Environmental Engineers
• /
• v.31 no.2
• /
• pp.114-118
• /
• 2009

With the advance of industrialization and urbanization, a lot of waste has been discharged and treated by incineration. But fly and bottom ashes are generated in this process. In addition, the treatment method to recycle sewage sludge and melting slag is required to manage these wastes. The objective of this research was to prepare of multi-functional brick which were made from MSWI (Municipal solid wastes incinerator) fly ash, sewage sludge and slag. The bricks were made by mixing raw materials and then drying for 24 hours. Next, they were dried for 24 hours at $160^{\circ}C$ and fired for 2 hours. Calcination temperature was changed to discuss the effect of temperature from $1,080^{\circ}C$ to $1,130^{\circ}C$. Compressive strength of a brick was creased with the increase of temperature. To increase mixing ratio of fly ash and slag reduce the compressive strength the optimal condition was the mixing ratio of fly ash : melting slag : sewage sludge : clay as 10 : 20 : 5 : 65 and $1,150^{\circ}C$ of calcination temperature. Compressive strength was obtained as about 41 MPa at this condition.

• Environmental Engineering Research
• /
• v.25 no.3
• /
• pp.299-308
• /
• 2020

Composting is among the most effective integrated waste management strategies used to recycle sewage sludge (SS) waste and generate a useful product. An encapsulated lifting system is a relatively new industrial-scale composting technology. The objective of this study was to evaluate the effectiveness of composting dewatered stabilized SS mixed with green waste using this new technology. The composting process was monitored by changes in the physico-chemical properties, UV-visible spectra, and fourier transform infrared (FTIR) spectra. The composting temperature was steady in the thermophilic range for 24 and 12 d in the intensive and maturation phases, respectively, which fulfilled the disinfection requirement. Moreover, the temperature increased rapidly to 76.8℃ within three days, and the thermophilic temperatures peaked twice and lasted longer than in traditional composting, which accelerated SS degradation and decreased the composting period necessary to obtain mature compost. FTIR spectroscopic analysis showed a diminished in methyl group derived from methylene C-H aliphatic groups because of organic matter degradation by microorganisms and an increased number of aromatic chains. The new technology may be a viable and sustainable alternative for SS management that converts waste into compost that is useful as a soil amendment.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.6 no.1
• /
• pp.128-135
• /
• 2011

In this study, in order to develop ultra rapid hardening mortar(URHM) for tunnel repairs using bottom ash of low recycle ratio and Admixture as Eco concept, fundamental properties of URHM on temperature condition of construction field were performed. Test result, URHM of three types for fluidity and setting time were as in the following : B > C > A. Those for low temperatures were later than the standard condition. Compressive, bending and bond strength were similar with three types as follow. In compressive strength, initial strength of the low were smaller than the standard but the low in the long-term were similar with the standard. On the contrary to this, bending strength were similar in initial strength but the low in the long-term were smaller than the standard. The low in bond strength was average 35% less than the standard. Length changes was as in the following : A > C > B. the low is two times much as the standard but the case using blast furnace slag particles noticeably reduced length changes. Water absorption coefficient and water vapor resistance were as in the following : C > A > B. In case of URHM added bottom ash, water absorption coefficient and water vapor resistance were increased because bottom ash is porous material.