• Title/Summary/Keyword: recyclable

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A Study on Design and Optimization of 500W PEM Fuel Cell System (500W PEM형 연료전지시스템 구축 및 운전 최적화에 관한 연구)

  • Park, Se-Joon;Choi, Hong-Jun;Kim, Gwang-Yeol;Cha, In-Su;Lim, Jung-Yeol
    • Proceedings of the KIEE Conference
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    • 2008.10c
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    • pp.191-193
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    • 2008
  • A fuel cell power system among various alternative power sources has many advantages such as low-polluted, high-efficient, and heat-recyclable, thus it is now able to be up to hundreds MWh-scaled through improving feasibility and longevity of it. During the last few years of the twentieth century, much changed to stimulate new and expanding interest in fuel cell technology. This paper presents optimal design and operational features of stand-alone 500W PEMFC(Proton Exchange Membrane Fuel Cell) system which can be a substitute instead fossil fuel. The stack of PEMFC is composed of 35 laminated graphite, and a unit cell of the stack has electrical characteristics as below; 14W, 0.9V, 15A. The other components of BOP(Balance of Plant) are composed of hydrogen and nitrogen tanks, regulators, 3way 5solenoid valves, mass flow meters, etc.

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Development of Thermite Powder for Rail Joining with Recycled Iron Oxide and Aluminium Powder (재활용 산화철 및 알루미늄 분말을 활용한 철도레일 이음용 테르밋 분말 개발)

  • Choi, Sang-Kyu;Park, Sung-Sang;Baek, Eung-Ryul
    • Journal of Welding and Joining
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    • v.30 no.5
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    • pp.40-45
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    • 2012
  • Nowadays in Republic of Korea, whole amount of the thermite welding powder for rail joinning is dependent on import. However the demand of the thermite welding powder would be enlarge because some constructing high-speed train and city metro projects are currently in progress. In addition this is the main reason why we should develop the thermite welding powder, domestically. This study is focused on utilizing the recyclable materials like Al powders from cans and iron oxide scales from wire rods as the main components of the thermite welding powder. By minimizing Al content in weld zone by controlling the mixing ratio of the Al powder in the thermite welding powder, the excessive dissolution of the Si and Mn components came from the Al powders could be controled. The tensile strength of welding zone in welded rail was 740 MPa, with that the developed thermite welding powder.

$CO_2$ adsorption over zinc oxide impregnated NaZSM-5 synthesized using rice husk ash (왕겨회재를 이용하여 합성된 NaZSM-5의 zinc oxide 함침에 의한 이산화탄소 흡착)

  • Hemalatha, Pushparaj;Ganesh, Mani;Venkatachalam, Kandan;Peng, Mei-Mei;Lee, Sung-Yong;Jang, Hyun-Tae
    • Proceedings of the KAIS Fall Conference
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    • 2011.05a
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    • pp.327-331
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    • 2011
  • Zinc oxide (5, 10 and 15 wt%) impregnated NaZSM-5 zeolite synthesized using rice husk ash as silica source was tested for $CO_2$ adsorption. The materials were characterized by XRD, SEM-EDS, $CO_2$-TPD and BET techniques. The heat of the reaction (${\Delta}$Hr) derived from DSC for ZnO(10%)/NaZSM-5 was found to be 495 Btu/lb and the maximum $CO_2$ adsorption capacity of ZnO(10%)/NaZSM-5 is 140 mg/g of sorbent. Extraction of silica from the agricultural waste, rice husk and its use in the zeolite synthesis is an added advantage in this study. Hence, from the study it is concluded that zinc oxide impregnated NaZSM-5 could be treated as novel material for $CO_2$ adsorption as they were found to be regenerable, selective and recyclable.

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Design and Analysis of State-of-the-Art Technologies for Development of Floating Photovoltaic System (수상태양광 발전시스템 설계 및 요소기술 분석)

  • Jin, Taeseok
    • Journal of the Korean Society of Industry Convergence
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    • v.17 no.4
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    • pp.227-233
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    • 2014
  • Information presented in this study is intended to inform candidates as they prepare to design and structure the floatovoltaics solar power system. A developed floatovoltaics solar power generation results from the combination of PV plant technology and PV floating technology. This floating-based PV system is a new concept for PV development. The PV floating technology opens new opportunities to give value to unused areas so far while preserving valuable land for more adapted activities. Therefore the land-use conflicts are avoided and the environmental impact is minimized. Therefore the technology offers an interesting opportunity to regions facing on drought during summer time without any negative impact to the eco-system. This study describe the basic components of a floatovoltaics solar power system. A typical system consist of floating system and solar modules, a control device, rechargeable batteries, a load or device and the associated electrical connections. The floating system is specifically designed to keep all metallic components above water leaving only 100% recyclable, closed cell foam filled HDPE plastic floats in contact with the water. As the first case that can maximize the power generation efficiency of PV internationally, it is expected that this study will be utilized as a primary guide for future development of floating type PV system.

The Improvement of Properties of Recycled aggregates using Concrete Waste by Pre-heating Method. (예비가열법에 의한 폐콘크리트 재생골재의 물성개선)

  • 최현수;김효열;최봉철;강병희
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.05a
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    • pp.73.2-79
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    • 2003
  • The purpose of this study is to provide the basic data on the optimum method for interfacial separation for an effective recycle of concrete waste by using the thermal properties of concrete. Therefore, this study is proceeded by dividing the interface of concrete into cement paste and fine aggregates or mortar and coarse aggregate, considering the aspect of recycled cement and aggregate as the recycling use of concrete waste. As results of the experiment, in case of recycle cement, the interfacial separation is easily appeared, but it is shown that the mixed amount of powder included in fine aggregate doesn't greatly decrease. But, in case of recycle coarse aggregate, the effect of interfacial separation by preliminary heating is predominant. Especially, the bonding rate of mortar is the lowest when it is heated 5 times for 120 minutes at $300^{\circ}C$. Hence, it is considered that it will be an excellent effect of quality control when the results of this study is applied to a manufacturing system of recycle coarse aggregate which is about to put into practical use.

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Transesterification of Jatropha Oil over Ceria-Impregnated ZSM-5 for the Production of Bio-Diesel

  • Bhagiyalakshmi, Margandan;Vinoba, Mari;Grace, Andrews Nirmala
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.3059-3064
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    • 2013
  • In this study transesterification of Triglycerides (TG) from Jatropha curcas oil (JCO) with methanol for production of biodiesel was investigated over cerium impregnated ZSM-5 catalysts. NaZSM-5 was synthesized in an alkaline medium and impregnated with cerium oxide by wet method using cerium nitrate as a source for cerium. They were characterized by X-ray diffraction (XRD), Thermogravimeteric analysis (TGA), $CO_2$-temperature programmed desorption, and $N_2$ adsorption/desorption analysis. XRD analysis showed decrease in intensity of the patterns with the increase in the ceria loading but crystallization of ceria to larger size is an evident for 10 and 15% loading. The optimal yield of transesterification process was found to be 90% under the following conditions: oil to methanol molar ratio: 1:12; temperature: $60^{\circ}C$; time: 1 h; catalyst: 5 wt %. Here the yield of fatty acid methyl ester (FAME) was calculated through $^1H$ NMR analysis. The investigation on catalyst loading, temperature, time and reusability illustrated that these ceria impregnated NaZSM-5's were found to be selective, recyclable and could yield biodiesel at low temperature with low methanol to oil ratio due to the presence of both Lewis and Bronsted basicity. Hence, from the above study it is concluded that ceria impregnated ZSM-5 could be recognized as a potential catalysts for biodiesel production in industrial processes.

Artıstıc studies on desıgn development wıth fabrıc scraps ın the context of sustaınable fashıon

  • KOCA, Emine
    • The Research Journal of the Costume Culture
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    • v.27 no.6
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    • pp.654-665
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    • 2019
  • The process of clothing production creates waste and scrap, which creates environmental, economic, and ethical issues. With this in mind the concept of ethical and sustainable fashion is discussed on many platforms as an important and timely topic. Many solutions have been presented on this subject. For the solution of this problem which has been increasing in the fashion and textile industry, the usage of sustainable materials and production methods is needed. There in a 'recyclable material cycle' should be adapted, instead of a 'traditional material cycle'. New methods and techniques should be developed with multi-disciplinary design approaches to produce creative and high value-added products in the name of fashion and sustainability. This is seen as one of the more effective solutions. This study aims to show that production scraps can be transformed into timely clothing designs with samples. The fabric scraps from different brands were turned into unique clothing designs with up to date trends by designer. In the practices completed while following the design process, collage and patchwork techniques were applied depending on the characteristics of the scrap fabric, artistic figures were hand-stitched onto the design. With this study, the scraps that get thrown into dumping grounds and damage the ecosystem can turn into ethical and economic benefits for the manufacturer. How to choose new high value-added products and create an awareness of social responsibility is also shown with examples in this study.

Bio-film Composites Composed of Soy Protein Isolate and Silk Fiber: Effect of Concentration of Silk Fiber on Mechanical and Thermal Properties

  • Prabhakar, M.N.;Song, Jung Il
    • Composites Research
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    • v.27 no.5
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    • pp.196-200
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    • 2014
  • A novel, simple and totally recyclable method has been developed for the synthesis of nontoxic, biocompatible and biodegradable bio-composite films from soy protein and silk protein. Bio films are defined as flexible films prepared from biological materials such as protein. These materials have potential application in medical and food as a packaging material. Their use depends on various parameters such as mechanical (strength and modulus), thermal, among others. In this study, prepare and characterization of bio films made from Soy Protein Isolate (SPI) (matrix) and Silk Fiber (SF) (reinforcement) through solution casting method by the addition of plasticizer and crosslinking agent. The obtained SPI and SPI/SF composites were subsequently subjected to evaluate their mechanical and thermal properties by using Universal Testing Machine and Thermal Gravimetric Analyzer respectively. The tensile testing showed significant improvements in strength with increasing amount of SF content and the % elongation at break of the composites of the SPI/SF was lower than that of the matrix. Though the interfacial bonding was moderate, the improvement in tensile strength and modulus was attributed to the higher tensile properties of the silk fiber.

Effect of pH on the Iron Autoxidation Induced DNA Cleavage

  • Kim, Jong-Moon;Oh, Byul-Nim;Kim, Jin-Heung;Kim, Seog-K.
    • Bulletin of the Korean Chemical Society
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    • v.33 no.4
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    • pp.1290-1296
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    • 2012
  • Fenton reaction and iron autoxidation have been debated for the major process in ROS mediated DNA cleavage. We compared both processes on iron oxidation, DNA cleavage, and cyclic voltammetric experiment at different pHs. Both oxidation reactions were preferred at basic pH condition, unlike DNA cleavage. This indicates that iron oxidation and the following steps probably occur separately. The ROS generated from autoxidation seems to be superoxide radical since sod exerted the best inhibition on DNA cleavage when $H_2O_2$ was absent. In comparison of cyclic voltammograms of $Fe^{2+}$ in NaCl solution and phosphate buffer, DNA addition to phosphate buffer induced significant change in the redox cycle of iron, indicating that iron may bind DNA as a complex with phosphate. Different pulse voltammogram in the presence of ctDNA suggest that iron ions are recyclable at acidic pH, whereas they may form an electrically stable complex with DNA at high pH condition.

Magnetic Nanoparticle Immobilized N-Propylsulfamic Acid as a Recyclable and Efficient Nanocatalyst for the Synthesis of 2H-indazolo[2,1-b]phthalazine-triones in Solvent-Free Conditions: Comparison with Sulfamic Acid

  • Rostami, Amin;Tahmasbi, Bahman;Yari, Ako
    • Bulletin of the Korean Chemical Society
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    • v.34 no.5
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    • pp.1521-1524
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    • 2013
  • N-Propylsulfamic acid supported onto magnetic $Fe_3O_4$ nanoparticles (MNPs-PSA) was used as an efficient and magnetically recoverable catalyst for synthesis of 2H-Indazolo[2,1-b]phthalazine-1,6,11(13H)-trione derivatives from the three-component, one-pot condensation reaction of phthalhydrazide, aromatic aldehydes and cyclic 1,3-diones, in good to excellent yields at $100^{\circ}C$ under solvent-free conditions. The catalyst was easily separated with the assistance of an external magnetic field from the reaction mixture and reused for several consecutive runs without significant loss of its catalytic efficiency. In order to compare, the synthesis of 2H-Indazolo[ 2,1-b]phthalazine-1,6,11(13H)-trione derivatives in the presence of catalytic amount of sulfamic acid (SA) under same reaction condition was also reported.