• Title/Summary/Keyword: rearrangement

Search Result 813, Processing Time 0.028 seconds

Synthesis of Novel Mercaptophenyl Carbocyclic C-Nucleoside Analogue Using Sequential [3,3]-Sigmatropic Rearrangement and Ring-closing Metathesis

  • Li, Hua;Hong, Joon-Hee
    • Bulletin of the Korean Chemical Society
    • /
    • v.29 no.4
    • /
    • pp.847-850
    • /
    • 2008
  • Novel mercaptophenyl carbocyclic C-nucleoside analogue was synthesized via a cyclopentenol intermediate 10, which was prepared using a sequential [3,3]-sigmatropic rearrangement and ring-closing metathesis (RCM). Friedel-Crafts alkylation was then used to couple the thiophenol.

Patent Portfolio Composition and New Product Introduction: The Moderating Role of Technological Resource Rearrangement (특허 포트폴리오 구성과 신제품 출시 성과: 특허 재정비 활동의 조절효과를 중심으로)

  • Kim, Nami;Lee, Jongseon
    • Knowledge Management Research
    • /
    • v.19 no.3
    • /
    • pp.63-87
    • /
    • 2018
  • In a rapidly changing technology environment, managing and rearranging the patent portfolios is one of the main sources of competitive advantage for firms. This study analyzes the effects of patent portfolio composition on new product introduction related to resource allocation. This study also looks at the moderating role of rearranging the patent portfolios on new product introduction. Our empirical analysis of the global pharmaceutical industry shows that firms with high-value patent portfolios exhibit a tendency to launch new products, and patent portfolio diversity shows a U-shaped relationship with new product introduction. In addition, the patent portfolio rearrangement positively moderates the relationship between patent portfolio diversity and new product introduction. The results are expected to provide implications for firms' patent portfolio composition and patent portfolio rearrangement related to innovation performance such as new product introduction.

Effects of Particle Size of Alumina on Densification Behaviors of Alumina-Talc System During Liquid-Phase Sintering (알루미나-활석계의 액상소결에서 알루미나 입자크기가 치밀화 거동에 미치는 영향)

  • 김호양;이정아;김정주
    • Journal of the Korean Ceramic Society
    • /
    • v.35 no.12
    • /
    • pp.1308-1315
    • /
    • 1998
  • Effects of particle size of alumina on densification behavior during liquid-phase sintering of alumina-talc system were investigated with emphasis on particle rearrangement process. In the case of using coarse alu-mina powder densiication of specimens was rapidly accelerated after formation of liquid phase due to easy particle rearrangement process with addition of talc and increase of sintering temperature. On the contrary when fine alumina powder was used premature densification of alumina matrix region formed before for-mation of liquid phase rigid skeleton structure and then it seemed to inhibit rearrangement process during crease of sintering temperature. As results the densification of specimens using coarse alumina powder was higher than that of the case of using fine one.

  • PDF

Numerical Simulation of Ventilation in the Storage Hall of Tripitaka Koreana at Haein Temple in Case of Building Rearrangement (해인사 장경판전 주변 건축물 이건에 따른 장경판전 환기 기류 변화 해석)

  • Hur, Nahm-Keon;Lee, Myung-Sung;Yang, Sung-Jin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.19 no.5
    • /
    • pp.379-385
    • /
    • 2007
  • In the present study, ventilation flow in the Janggyeongpan-Jeon at Haein temple in case of building rearrangement has been investigated numerically. To achieve more accurate results, detailed shapes such as buildings and the window grills are modeled and tree canopy model is adopted to account for the effect of trees in the computation. Wind velocities as boundary condition are taken from meteorological statistical data. The numerical results show that ventilation flow distributions at Janggyeongpan-Jeon in case of building rearrangement are nearly similar to those before rearrangement.

FINDING EXPLICIT SOLUTIONS FOR LINEAR REGRESSION WITHOUT CORRESPONDENCES BASED ON REARRANGEMENT INEQUALITY

  • MIJIN KIM;HYUNGU LEE;HAYOUNG CHOI
    • Journal of applied mathematics & informatics
    • /
    • v.42 no.1
    • /
    • pp.149-158
    • /
    • 2024
  • A least squares problem without correspondences is expressed as the following optimization: Π∈Pminm, x∈ℝn ║Ax-Πy║, where A ∈ ℝm×n and y ∈ ℝm are given. In general, solving such an optimization problem is highly challenging. In this paper we use the rearrangement inequalities to find the closed form of solutions for certain cases. Moreover, despite the stringent constraints, we successfully tackle the nonlinear least squares problem without correspondences by leveraging rearrangement inequalities.

In-situ EQCM Study on Growth of Polypyrrole Films Using Gold Electrodes Modified with Self-Assembled Monolayers in an Aqueous Solution (자기 집합 단분자막 개질 금 전극을 이용한 수용액 중 폴리피를 성장에 관한 In-situ EQCM 연구)

  • Seo, Kyoung--Ja;Jeon, Il-Cheol
    • Journal of the Korean Electrochemical Society
    • /
    • v.5 no.3
    • /
    • pp.143-152
    • /
    • 2002
  • The growth of Polypyrrole film has been investigated during electropolymerization in an aqueous solution on bare and SAM modified gold electrodes by in-situ EQCM and ex-situ AFM. According to the result of cyclic voltammetry measurements, in the case of a bare gold electrode, the electrochemical deposition of polypyrrole were dependent on the limiting oxidative potential, but not on scan numbers. When the limiting potential higher than 0.8 V was applied on the electrode, the amount of polypyrrole deposited on a gold electrode was rapidly increased and the abnormal mass change attributed to the rearrangement of polypyrrole films was observed as the scan number increased. The polypyrrole film Prepared on electrodes modified with 1-dodecanethiol SAM or thiophene SAM grew 3-dimensionally with the rearrangement of film. However, in the case of BPUS SAM, 2-dimensional layer-by-layer growth of film was observed without the rearrangement of film. AFM images showed films with chain-shaped and/ or donut-shaped polymers when grown rapidly and a wrinkled film at the steady state condition.