• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.1604-1610
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• 2004

A steady dilute premixed combustion at transonic speeds in a diverging channel is investigated. The model explores the nonlinear interactions between the near-sonic speed of the flow, the small changes in geometry from a straight channel, and the small heat release due to the one-step first-order Arrhenius chemical reaction. The reactive flow can be described by a nonhomogeneous transonic small-disturbance (TSD) equation coupled with an ordinary differencial equation for the calculation of the reactant mass fraction in the combustible gas. The asymptotic analysis results in the similarity parameters that govern the reacting flow problem. The model is used to study transonic combustion at various amounts of incoming, reactant mass, reaction rates, and channel geometries.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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• pp.276-281
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• 2002

A metallurgical model for bainite transformation kinetics in the coarse-grained heat affected zone(CGHAZ) on the basis of an Avrami-type equation was studied. Isothermal transformation tests were carried out to obtain the empirical equations for incubation time and Avrami kinetic constants for C-Mn-Mo-Ni steel. The effect of prior austenite grain size(PAGS) on the reaction rate of bainite was also investigated. Compared with experimental transformation behavior of bainite, the predicted behavior was in good agreement. It was also found that a smaller grain size retard the bainite reaction rate, contrary to the classical grain size effect and this is considered to be caused by constraint of grain size to bainite growth.

• Nuclear Engineering and Technology
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• 제9권1호
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• pp.33-38
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• 1977

p-Substituted phenyl-$\beta$-chloroethylsulfones, R-(equation omitted)-$SO_2CH_2CH_2Cl$,에서 R이 $CH_3O\;,CH_3$, Cl, H인 화합물들의 반응기구와 반응성을 EHT 방법으로 계산하고 실험값과 비교 검토 하였다.

• International Journal of Korean Welding Society
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• 제2권1호
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• pp.11-14
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• 2002

A metallurgical model for bainite transformation kinetics in the coarse-grained heat affected zone(CGHAZ) on the basis of an Avrami-type equation was studied. Isothermal transformation tests were carried out to obtain the empirical equations for incubation time and Avrami kinetic constants for C-Mn-Mo-Ni steel. The effect of prior austenite grain size(PAGS) on the reaction rate of bainite was also investigated. Compared with experimental transformation behavior of bainite, the predicted behavior was in good agreement. It was also found that a smaller grain size retard the bainite reaction rate, contrary to the classical grain size effect and this is considered to be caused by constraint of grain size to bainite growth.

• Journal of Advanced Marine Engineering and Technology
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• 제5권1호
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• pp.20-27
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• 1981

The alignment of propulsion shaft systems by the fair curve method has been developed over the past twenty years and in recent years its basic problems have been almost solved. At the present time, studies on introducing actual conditions are being undertaken. In a fair curve alignment, its aim is to achieve a stable shaft system which will be relatively insensitive to misalignment or the influence of external factors such as thermal variations due to the sunshine, speed change, etc. The key point of fair curve alignment is the calculations of reactions in the straight support and reaction influence numbers. The present authors have developed those calculating method by the matrix method of the three-moment theorem. The fair curve alignment is based on the analysis of propulsion shaft system which is assumed as a continous beam on multiple support points. The propeller shaft is divided into several elements. For each element, the nodal point equation is derived by the three-moment theorem. Reaction of supporting points of straight shaft and reaction influence numbers are calculated by the matrix calculation of each nodal point equation. It has been found that results of calculation for the model shaft agree well with those of experiment which had been measured by the strain gauge method. Results of calculation for the actual propulsion shafting of the steam turbine had been compared also with those of Det norske Vertas.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2001년도 춘계 학술대회논문집
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• pp.189-194
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• 2001

In this paper, non-reacting and reacting flowfields were computed using a preconditioned Navier-Stokes solver. The preconditioning technique of Merkle et al. and TVD scheme or Chakravarthy and Osher was employed and the results obtained using developed code have a good agreement with the previous results and experimental data. The preconditioned Wavier-Stokes equation set with low Reynolds number $\kappa-\epsilon$ equation and species continuity equations, are discretized with strongly implicit manner and time integrated with LU-SSOR scheme. For the purpose of treating unsteady problem the duel-time stepping scheme was employed. For the validation of the code in incompressible flow regime, steady driven square cavity flow was considered and calculation result shows reasonably good agreement with the result of incompressible code. Shock wave/boundary layer interaction problem was considered to show the shock capturing performance of preconditioned-TVD scheme. To validate unsteady flow, acoustic oscillation problem was calculated, and supersonic premix flame of $H_2$-air reaction problem which is calculated with turbulence model, 9-species/18-reaction step reaction model, shows reasonable agreement with the previous results. As a result, the preconditioning method has an advantage to calculate incompressible and compressible flow through one code and preconditioned solver easily developed from standard compressible code with minor efforts. But additional computational time and computer memory is required due to preconditioning matrix.

• 한국응용과학기술학회지
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• 제12권2호
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• pp.93-98
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• 1995

The rate constant of Nucleophilic addition of sodium thiophenoxide to nitrone were determined by UV Spectrophotometry and a rate equation which can be applied over wide pH range was obtained. Base on the rate equation, general base effect, substituent effect and final product, plausible mechanism of addition reaction have been proposed. Blow pH 3.0, the reaction was initiated of thiophenol, and in the range of pH $3.0{\sim}10.0$, proceeded by the competitive addition of thiophenol and thiophenoxide anion. Above the pH 10.0, the reaction proceeded through the addition of a thiophenoxide anion.

• Korea-Australia Rheology Journal
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• 제14권2호
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• pp.63-70
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• 2002

Chemical mechanical planarization (CMP) is the polishing process enabled by both chemical and mechanical actions. CMP is used in the fabrication process of the integrated circuits to achieve adequate planarity necessary for stringent photolithography depth of focus requirements. And recently copper is preferred in the metallization process because of its low resistivity. We have studied the effects of chemical reaction on the polishing rate and surface planarity in copper CMP by means of numerical simulation solving Navier-Stokes equation and copper diffusion equation. We have performed pore-scale simulation and integrated the results over all the pores underneath the wafer surface to calculate the macroscopic material removal rate. The mechanical abrasion effect was not included in our study and we concentrated our focus on the transport phenomena occurring in a single pore. We have observed the effects of several parameters such as concentration of chemical additives, relative velocity of the wafer, slurry film thickness or ash)tract ratio of the pore on the copper removal rate and the surface planarity. We observed that when the chemical reaction was rate-limiting step, the results of simulation matched well with the experimental data.

• Korean Chemical Engineering Research
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• 제45권1호
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• pp.46-51
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• 2007

본 연구에서는 전력 산업에서 발생하는 폐기물 중의 하나인 Poly Chlorinated Biphenyls(PCBs)를 함유한 절연유를 초임계수 내에서 완전산화반응을 통해서 제거하는 전산모사를 수행하였다. 절연유의 주성분을 노말 데칸으로 선정하였으며, 초임계수 내의 절연유의 함량은 3.0 wt％로 가정하였다. 초임계수 내에서의 물성 추산을 위해서 Peng-Robinson 상태방정식을 사용하였으며, 전산모사를 통해서 초임계수 내에서 3.0 wt％의 절연유 및 과잉 산소가 모두 용해되는 현상을 잘 설명할 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제33권12호
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• pp.4117-4121
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• 2012

The solvolysis rate constants of allyl chloroformate ($CH_2=CHCH_2OCOCl$, 3) in 30 different solvents are well correlated with the extended Grunwald-Winstein equation, using the $N_T$ solvent nucleophilicity scale and $Y_{Cl}$ solvent ionizing scale, with the sensitivity values of $0.93{\pm}0.05$ and $0.41{\pm}0.02$ for l and m, respectively. These l and m values can be considered to support a $S_N2$ reaction pathway. The activation enthalpies (${\Delta}H^{\neq}$) were 12.5 to 13.4 $kcal{\cdot}mol^{-1}$ and the activation entropies (${\Delta}S^{\neq}$) were -34.4 to -37.3 $cal{\cdot}mol^{-1}{\cdot}K^{-1}$, which is also consistent with the proposed bimolecular reaction mechanism. The solvent kinetic isotope effect (SKIE, $k_{MeOH}/k_{MeOD}$) of 2.16 was also in accord with the $S_N2$ mechanism. The values of product selectivity (S) for the solvolyses of 3 in alcohol/water mixtures was 1.3 to 3.9, which is also consistent with the proposed bimolecular reaction mechanism.