• 한국응용과학기술학회지
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• 제16권2호
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• pp.117-125
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• 1999

The alkylation benzene with 1-dodecene of Mordenite, Zeolite ${\beta}$ and Zeolite Y was studied in the stirring batch reactor. The kinds of zeolites were found to have influenced the reaction conversion and distribution of phenyldodecane isomer in the product. Compared to the alkylation conducted over Zeolite Y and Zeolite ${\beta}$, the alkylation over Mordenite exhibited higher distribution of 2-phenyldodecane and the alkylation conducted over Zeolite Y and Mordenite, the alkylation over Zeolite ${\beta}$ exhibited higher distribution of heavy alkylate which formed through oligomerization reaction readily deactivated the Lewis acid sites. A special feature of the effect of the benzene to 1-dodecene ratio the reaction conversion and selectivity of phenyldodecane isomer was found. At alkylation of benzene with 1-dodecene over Zeolite ${\beta}$, when the catalyst content in the system was high, the reaction will reach the optimal conversion at the higher B/D. When the benzene to 1-dodecene ratio was high, the selectivity of phenyldodecane isomer is high. It was also found that at the similar reaction conversion there was the same product distribution regardless of D/C ratio.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.1996-2000
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• 2008

In autothermal reforming reaction, oxygen to carbon ratio (OCR) and steam to carbon ratio (SCR) are significant factors, which control temperature and carbon deposition into the reactor. The OCR is more sensitive than the SCR to affect the temperature distribution and reforming efficiency. In conventional operation, hydrocarbon fuel, steam, and oxygen was homogeneously mixed and injected into the reactor in order to get hydrogen-rich gas. The temperature was abruptly raised due to fast oxidation reaction in the former part of the reactor. Deactivation of packed catalysts can be accelerated there. In the present study, therefore, the effect of the oxygen distribution is introduced and investigated to suppress the carbon deposition and to maintain the reactor in the mild operating temperature (e.g., $700{\sim}800^{\circ}C$). In order to investigate the effect numerically, the following models are adopted; heterogeneous reaction model and two-medium model for heat balance.

• Carbon letters
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• 제25권
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• pp.78-83
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• 2018

Pyrolyzed fuel oil (PFO) and coal tar was blended in the feedstock to produce pitch via thermal reaction. The blended feedstock and produced pitch were characterized to investigate the effect of the blending ratio. In the feedstock analysis, coal tar exhibited a distinct distribution in its boiling point related to the number of aromatic rings and showed higher Conradson carbon residue and aromaticity values of 26.6% and 0.67%, respectively, compared with PFO. The pitch yield changed with the blending ratio, while the softening point of the produced pitch was determined by the PFO ratio in the blends. On the other hand, the carbon yield increased with increasing coal tar ratio in the blends. This phenomenon indicated that the formation of aliphatic bridges in PFO may occur during the thermal reaction, resulting in an increased softening point. In addition, it was confirmed that the molecular weight distribution of the produced pitch was associated with the predominant feedstock in the blend.

• Nuclear Engineering and Technology
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• 제47권4호
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• pp.424-433
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• 2015

The operating characteristics of hydrogen iodide (HI) decomposition for hydrogen production were investigated using the commercial computational fluid dynamics code, and various factors, such as hydrogen production, heat of reaction, and temperature distribution, were studied to compare device performance with that expected for device development. Hydrogen production increased with an increase of the surface-to-volume (STV) ratio. With an increase of hydrogen production, the reaction heat increased. The internal pressure and velocity of the HI decomposer were estimated through pressure drop and reducing velocity from the preheating zone. The mass of $H_2O$ was independent of the STV ratio, whereas that of HI decreased with increasing STV ratio.

• 한국축산식품학회지
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• 제37권6호
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• pp.813-822
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• 2017

The aim of this study was to prepare diacylglycerol (DAG) by enzymatic glycerolysis of lard. The effects of reaction parameters such as lipase type, reaction temperature, enzyme amount, substrate molar ratio (lard/glycerol), reaction time, and magnetic stirring speed were investigated. Lipozyme RMIM was found to be a more active biocatalyst than Novozym 435, and the optimal reaction conditions were 14:100 (W/W) of enzyme to lard substrate ratio, 1:1 of lard to glycerol molar ratio, and 500 rpm magnetic stirring speed. The reaction mixture was first incubated at $65^{\circ}C$ for 2 h and then transferred to $45^{\circ}C$ for 8 h. At the optimum reaction conditions, the conversion rate of triacylglycerol (TAG) and the content of DAG in the reaction mixture reached 76.26% and 61.76%, respectively, and the DAG content in purified glycerolized lard was 82.03% by molecular distillation. The distribution of fatty acids and Fourier transform infrared spectra in glycerolized lard samples were similar to those in lard samples. The results revealed that enzymatic glycerolysis and molecular distillation can be used to prepare more highly purified DAG from lard.

• 콘크리트학회논문집
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• 제23권1호
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• pp.3-12
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• 2011

철근콘크리트 깊은 보의 거동은 전단경간비, 휨철근비, 하중점과 지지점의 조건, 그리고 사용재료의 성질 등의 여러 변수간의 복합적인 역학관계로 인해 매우 복잡하다. 이 논문에서는 이러한 깊은 보의 거동 특성을 모두 반영하여 연속지지 철근콘크리트 깊은 보의 설계를 수행할 수 있는 부정정 스트럿-타이 모델을 제안하였다. 또한 현 스트럿-타이 모델 설계기준을 부정정 스트럿-타이 모델을 이용한 연속지지 철근콘크리트 깊은 보의 설계에 합리적으로 적용하기 위해 외부하중에 대한 단부 지지점 반력의 비인 반력분배율과 수직 트러스 메커니즘에 의해 전달되는 외부하중의 크기 즉 부정정 스트럿-타이 모델의 하중분배율을 제안하였다. 하중분배율의 결정 시 연속지지 철근콘크리트 깊은 보의 전단에 대한 연성파괴거동을 확보하기 위하여 깊은 보의 전단저항 메커니즘을 구성하는 콘크리트 스트럿과 수직철근타이가 동시에 파괴된다는 전단평형철근비 개념을 도입하였으며, 다양한 수치해석 결과를 바탕으로 연속지지 깊은 보의 강도 및 거동에 영향을 미치는 전단경간비, 휨철근비, 그리고 콘크리트의 압축강도 등의 주요설계변수를 고려하였다. 이 논문의 후속편에서는 기존의 여러 설계방법들과 이 연구에서 제안한 방법을 이용하여 파괴실험이 수행된 다양한 종류의 연속지지 깊은 보의 강도를 평가하고, 이 연구에서 제안한 방법의 적합성을 검증하였다.

• 한국재료학회지
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• 제24권1호
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• pp.25-32
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• 2014

In this study, nano-sized cobalt oxide powder with an average particle size below 50 nm was prepared from a cobalt chloride solution by the spray pyrolysis process. The influences of reaction temperature on the properties of the generated powder were examined. The average particle size of the particles formed based on the spray pyrolysis process at a reaction temperature of $700^{\circ}C$ is roughly 20 nm. Moreover, most of these particles cannot appear with an independent type, thereby coexisting in a droplet type. When the reaction temperature increases to $800^{\circ}C$, the average particle size not only increases to roughly 40 nm but also shows a more dense structure while the ratio of particles which shows a polygonal form significantly increases. As the reaction temperature increases to $900^{\circ}C$, the distribution of the particles is from roughly 70 nm to 100 nm, while most of the particle surface is more intricately close and forms a polygonal shape. When the reaction temperature increases to $1000^{\circ}C$, the particle size distribution of the powder shows an existing form from 80 nm to at least 150 nm in an uneven form. As the reaction temperature increases, the XRD peak intensity gradually increases, yet the specific surface area gradually decreases.

• 대한기계학회논문집B
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• 제32권8호
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• pp.574-581
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• 2008

The characteristics of combustion and flow for a lean premixed flame in lab-scale gas turbine combustor was studied through experiment and numerical analysis. From the experiment, flame structure and heat release rate were obtained from OH emission spectroscopy. Qualitative comparisons were made line-integrated OH chemiluminescence image and abel-transformed one. NOx analyzer was implemented to get the characteristic of NOx exhaust from the combustor. From the numerical analysis, the thermal distribution and characteristic of recirculation zone with the change of fuel-air mixing degree, the characteristic of methane distribution with equivalence ratio in the combustor respectively. Total heat release rate is increased with increasing equivalence ratio. Thermal Nox is reduced with increasing fuel-air mixing degree. Increasing equivalence ratio results in the decrease of the size of reaction zone and alteration of the position of the reaction zone into the entrance of the combustor.

• 한국대기환경학회지
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• 제2권1호
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• pp.33-39
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• 1986

Particulate matter was collected by Andersen Air Sampler in the Seoul area during February-October, 1985, in order to investigate size distribution of sulfate and nitrate in aerosol, and conversion of sulfur dioxide to sulfate and that of nitrogen dioxide to nitrate. The size distribution of sulfate and nitrate had fine mode. The ratio of fine sulfate to total sulfate in aerosol and that of fine nitrate to total nitrate showed between 54.6% and 86%, and 55.7% and 95%, respectively, which presumably originated from gaseous reaction of sulfur dioxide and nitrogen dioxide in the atmosphere.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2003년도 봄 학술발표회 논문집
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• pp.487-495
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• 2003

Bearings at the obtuse corner are subjected to much larger vertical reactions than other bearings because of the geometric shape of skew bridges. The current relevant specifications require that additional bars should be disposed at the bottom of concrete deck slabs to deal with the large vertical reaction on bearings at the obtuse corner. In this study, new methods of reducing the magnitude of the vertical reaction on bearings at the obtuse corner by the stiffness adjustment of bearings were proposed. The basic concept of proposed methods was to redistribute support reactions by reducing the vertical stiffness of bearings at the obtuse corner showing a relatively large vertical reaction. For 45 simply supported skew bridges designed according to the current relevant specifications, the redistribution effect of vertical reactions by the stiffness adjustment of bearings was investigated. Parameters such as skew angle, girder spacing, and deck aspect ratio that affect the distribution of support reactions were considered. The results of the analyses show that the magnitude of the vertical reaction on bearings at the obtuse corner can be reduced to the levels of straight bridges by replacing the existing bearings at the obtuse corner with new ones having the value of 1/10 or 1/20 of the vertical stiffness of the existing bearings. The reduction effect of the vertical reaction on bearings at the obtuse corner increases as the girder spacing decreases and it is more pronounced when the deck aspect ratio is 2.0.