• Title/Summary/Keyword: reaction analysis

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Sliding Mode Control of Spacecraft with Actuator Dynamics

  • Cheon, Yee-Jin;Keum, Jung-Hoon;Eunsup Sim
    • 제어로봇시스템학회:학술대회논문집
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    • 2001.10a
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    • pp.92.1-92
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    • 2001
  • Sliding mode control of spacecraft attitude tracking with actuator, especially reaction wheel, is presented. The sliding mode controller is derived based on quaternion parameterization for the kinematic equations of motion. The reaction wheel dynamic equations represented by wheel input voltage are presented. The input voltage to wheel is calculated from the sliding mode controller and reaction wheel dynamics. The global asymptotic stability is shown using a Lyapunov analysis. In addition the robustness analysis is taken for nonlinear system with parameter variations and disturbances. It is shown that the controller ensures control objectives for the spacecraft with reaction wheels.

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The Analysis of Transverse Edge Effect of Linear Induction Motor by using Finite Element Method (유한요소법을 이용한 선형유도전동기의 횡방향 모서리 효과 분석)

  • Lee, Sung-Gu;Bae, Jae-Nam;Lee, Hyung-Woo;Park, Hyun-June;Kwon, Sam-Young;Lee, Ju
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.12
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    • pp.2194-2198
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    • 2008
  • In this paper, the construction of secondary reaction plate is analyzed by 3-D Finite Element Method(3-D FEM) to consider the influence of its variation on the transverse edge effect of LIM. The effective 3-D analysis model for considering the transverse edge effect caused by the finite widths of the primary and the secondary is proposed. The simple method measuring the transverse edge effect by using the patterns of currents induced in the secondary reaction plate is also proposed. With this effective analysis method, various models of secondary reaction plate with overhang and cap has been analyzed to consider the relationship between the construction of secondary reaction plate and the transverse edge effect of LIM.

Prediction of MCFC Performance Using Three Dimensional Heat and fluid Flow Analysis with Electrochemical Reaction (전기 화학 반응을 포함한 3차원 열유동 해석을 이용한 용융탄산염 연료전지의 성능예측)

  • Cho H. M.;Lee K. W.;Choi D. H.
    • 한국전산유체공학회:학술대회논문집
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    • 2003.08a
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    • pp.219-224
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    • 2003
  • An analysis procedure for the MCFC channel flow has been developed to predict the fuel cell performance. As for the electrochemical reaction, among several chemical reaction models, one that fits the data best is adopted after a comprehensive comparative study. The Wavier-Stokes, energy, and species equations are solved to obtain the velocity, temperature and concentration fields for a specified average current density. The procedure is iterative as the local current density, or the reaction rate, is allowed to vary with the gas composition. A series of calculations are then carried out to examine the effects of gas flow rate, gas composition, gas usage rate, inlet gas temperature, and average current density on the fuel cell performance. The fuel cell characteristics, such as the temperature, current density distributions, and the concentration fields, for various operating conditions are presented and discussed.

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A Study of Child Emotion Regulation by the Cluster of Mother's Reaction to Children's Negative Emotion (아동의 부정적 정서표현에 대한 어머니 반응 유형의 군집에 따른 아동의 정서조절 능력 차이 검증)

  • Kim, Jiyoun;Oh, Ji-Hyun
    • Korean Journal of Childcare and Education
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    • v.13 no.3
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    • pp.39-54
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    • 2017
  • Objective: The purpose of this study was to examine natural groupings of the sub-factors of mother's reaction to children's negative emotions. The natural groupings were as follows; the emotion-coaching-reaction, the emotion-minimizing-reaction and oversensitive reaction. In addition, this paper also investigated individual differences in children's emotion regulation by clusters of sub-factors of mother's reaction to children's negative emotions. Methods: The subjects of this study consisted of 318 children. The data were analyzed using cluster analysis and one-way ANOVA. Results: The results suggested four proper clusters, according to the characteristics of mother's reaction to children's negative emotions. Cluster 1 was categorized as 'child centered-emotion coaching', cluster 2 was categorized as 'oversensitive-emotion coaching comorbid', cluster 3 was categorized as 'acception-emotion minimizing confused' and cluster 4 was categorized as 'emotion minimizing-unsupporting.' Additionally, the differences between Emotion regulations in each cluster showed distinct points of interest. In terms of the maladaptive emotion regulation, cluster 3 showed the highest level followed by cluster 4. And cluster 1 and 2 showed the lowest level. Conclusion/Implications: The results of this study helped to find a deeper understanding of the operation of specific clusters of mother's reaction to children's negative emotion and children's emotion regulation.

Changes of Silk Fibroin Molecular Weight by Plastein Reaction (Plastein反應에 의한 絹피브로인의 分子量變化)

  • 김동건;판부막;소사효
    • Journal of Sericultural and Entomological Science
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    • v.40 no.2
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    • pp.131-135
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    • 1998
  • Changes of silk fibroin molecular weight was studied by enzymatic proteolysis and reverse reaction of enzymatic proteolysis (plastein reaction) using chromatography, X-ray diffraction and thermal analysis methods. When the treatment of enzymatic proteolysis with $\alpha$-chymotripsin to silk fibroin solution, a precipitate of Fcp fractions was formed. And, this was dissolved in LiBr aqueous solution, the precipitate of PIFcp fractions was obtained again. Fcp and PIFcp fractions showed silk IIand silk Itype structure, respectively. Fcp fractions was about 6,900 in molecular weight, PIFcp fractions obtained by plastein reaction on the precipitate of Fcp fractions increased molecular weight to abort 15,000. The molecular weight of Fcp fractions was increased by plastein reaction, but Fcp fractions almost transited to silk I type crystal. The structure of silk I type of PIFcp fractions was steady identified by X-ray diffraction and thermal analysis. As molecular weight of Fcp fractions was gradually low, PIFcp fractions was become to macromolecule little by little.

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Rapid Hydrolysis of Ginseng Saponin by Microwave Oven Reaction (전자렌지 반응을 이용한 인삼 사포닌의 신속한 가수분해법)

  • Park, Man-Ki;Park, Jeong-Hill;Kang, Jong-Seong;Lee, Mi-Young;Park, Young-In;Yu, Su-Jeong;Han, Byung-Hoon
    • Journal of Ginseng Research
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    • v.17 no.1
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    • pp.35-38
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    • 1993
  • A new and rapid method for the hydrolysis of ginsenosides to panaxadiol or panaxatriol was developed. It is based on the microwave oven reaction, which is high temperature and high-pressure reaction. The optimal hydrolysis time using 5% $H_2SO_4$ solution was found at 10 min PTFE reaction vessel in microwave oven, which is more than 30 times faster than the conventional hydrolysis method.

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Thermal Behavior of Dickite (딕카이트의 열적 특성 연구)

  • 조현구
    • Journal of the Mineralogical Society of Korea
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    • v.12 no.1
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    • pp.11-22
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    • 1999
  • Thermal behavior of dickite was studied by thermal analysis, X-ray diffraction analysis, electron microprobe analysis, and scanning electron microscopy, Dickite has an endothermic peak at about$ 650^{\circ}C$ and an exothermic one at $960^{\circ}C$ in the differential thermal analysis. The endothermic reaction is assigned to the decomposition of dickite to meta-dickite. Hydroxyl radicals are removed from dickite structure by the reaction, resulting in the weight loss about 10.5~14.5% and appearance of a 14$\AA$ phase different from other kaolin minerals. The reaction slowly proceed in the range of $200^{\circ}C$. As the completion of decomposition, aciclular mullite forms at the expense of meta-dickite plates with random crystallographic relationship. Mullites have diverse silica versus alumina ratio. The exothermic reaction without weight loss seems to be due to the formation of spinel and amorphous silica. The spinel phase shows cryptocrystalline globular morphology accompanying a little amount of silica. From spinel phase shows cryptocrystalling globular morphology accompanying a little amount of silica. From this work, it is suggested that mullite is formed from meta-dickite much lower temperature than the reported one in the previous works.

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Vibration Analysis of a Rotor considering Nonlinear Reaction of Hydrodynamic Bearing

  • Lee, Soo-Mok;Lim, Do-Hyeong;Bae, Jong-Gug;Yang, Bo-Suk
    • International Journal of Fluid Machinery and Systems
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    • v.2 no.3
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    • pp.254-259
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    • 2009
  • In this paper it was attempted to treat the hydrodynamic journal bearing as a time-based nonlinear reaction source in each step of rotor rotation in order to observe the bearing effect more realistically and accurately in stead of the conventional method of simple linearized stiffness and damping. Lubrication analysis based on finite element method is employed to calculate the hydrodynamic reaction of bearing and Newmark's method was used to calculate the rotor dynamics in the time domain. Simulation for an industrial electrical motor showed remarkable results with differences compared to those by the conventional method in the dynamic behavior of the rotor.

Correlation between the Reactant Complex or Transition State Conformations and the Reactivity of 4-Nitrophenyl Benzoate and Its Sulfur Analoguew with Anoinic Nucleophiles by Comparative Molecular Field Analysis (CoMFA)

  • 유성은;차옥자
    • Bulletin of the Korean Chemical Society
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    • v.17 no.7
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    • pp.653-655
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    • 1996
  • A comparative molecular field analysis (CoMFA) was carried out for the correlation of the transition state structures and the reaction rates for the SN2 reaction of 4-nitrophenyl benzoate and its sulfur analogs with anionic nucleophiles. The CoMFA analysis showed that both steric and electrostatic effects are important, and the steric contribution increased when nucleophiles are alkoxides or arylsulfides. In this study, we have demonstrated that the CoMFA analysis can be expanded beyond the scope of dealing with reactants and products. The reactant complex and transition state conformations generated along the reaction path can be more appropriately used for the correlation of structures and reaction rates.

Development and application of a batch reaction calorimeter (회분식 반응열 분석 시스템의 개발과 응용)

  • 이기형;이대욱;정상태;이광순
    • 제어로봇시스템학회:학술대회논문집
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    • 1992.10a
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    • pp.947-952
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    • 1992
  • A batch reaction calorimeter is the device for estimating reaction heat along time. Reaction heat formation data are very imoprtant for batch reactor behavior analysis and operatoin. So, many types of reaction calorimeter have been introduced and used. In this study, we analyze the dynamic charateristics of the batch reaction calorimeter that is designed in our laboratory. And we introducde suitable temperature control system. As a result, we analyze reatin heat formation data obtained by simulation and introduce its application examples.

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