• 제목/요약/키워드: rayon

검색결과 253건 처리시간 0.023초

목질계 Biomass의 변환 이용(III) - 폭쇄처리재의 산소·알칼리법에 의한 용해용 펄프의 제조 - (Conversion of Woody Biomass for Utilization(III) - The Preparation of Dissolving Pulp by Oxygen·Alkali Method from Exploded Wood -)

  • 임부국;양재경;이종윤
    • Journal of the Korean Wood Science and Technology
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    • 제25권4호
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    • pp.68-74
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    • 1997
  • This research was studied dissolving pulp for rayon production, which is not KP, SP methods but steam explosion and oxygen alkali treatment. The variation of characterization in wood cellulose after steam explosion and oxygen alkali treatment this follows. In the oxygen alkali treatment of exploded pine wood, yield of dissolving pulp was lower than steam-exploded oak wood, and we have obtained dissolving pulp that high purity cellulose, but degree of polymerization was inclined to decrease less than 200. In the case of steam-exploded oak wood, degree of polymerization was higher than steam-exploded pine wood but purity of cellulose was lower than its.

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목질계 Biomass의 변환 이용(II) - 목질계 바이오매스로부터 solvolysis법에 의한 용해용 펄프의 제조 - (Conversion of Woody Biomass for Utilization(II) - Preparation of Dissolving Pulp by Solvolysis from Woody Biomass -)

  • 양재경;임부국;장준복;이종윤
    • Journal of the Korean Wood Science and Technology
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    • 제25권4호
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    • pp.45-50
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    • 1997
  • This research was studied for dissolving pulp preparation as the raw material of viscose rayon from woody biomass by solvolysis pretreatment. In the change of pulp characteristic after solvolysis pretreatment, the following results were obtained. In the case of solvolysis pretreatment, we have obtained pulp that high purity cellulose, and degree of polymerization was inclined to decrease less than 440 on the phosphoric acid as catalyst. Comparing phosphoric acid and formic acid as catalyst in the solvolysis pretreatment, using on formic acid catalyst is superior to phosphoric acid catalyst for making dissolving pulp.

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목질계 Biomass의 변환이용(제1보)-기계펄프로부터 용해용펄프의 제조- (Conversion of Woody Biomass for Utilization( I )-The Preparation of Dissolving Pulp from Mechanical Pulp-)

  • 양재경;임부국;이종윤
    • 펄프종이기술
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    • 제29권3호
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    • pp.51-59
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    • 1997
  • Dissolving pulp is a low yield(30∼35%) bleached chemical pulp that has a high cellulose content (95% or higher) suitable for use in cellulose derivatives such as rayon, cellulose acetate. This research was studied for dissolving pulp preparation as the raw material of viscose rayon from commertial pulps. (TMP, CP, DIP) In the change of pulp(cellulose) characteristics after sodium hypochlorite and solvolysis treatment. the following results were obtained In the case of sodium hypochlorite pretreatment, we have obtained pulp that high purity cellulose, but degree of polymerization was inclined to decrease less than 170∼240. Comparing sodium hypochlorite pretreatment and solvolysis pretreatment, solvolysis pretreatment is superior to sodium hypochlorite process for making dissolving pulp. We think that the low degree of polymerization of cellulose because of increasing degradation of cellulose during delignification treatment.

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미로발란을 이용한 직물염색 (Fabric Dyeing with Myrobalan(Terminalia chebula Retz.))

  • 한미란;이정숙
    • 한국의류산업학회지
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    • 제11권6호
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    • pp.953-960
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    • 2009
  • The natural dyeing of fabrics with myrobalan extract was investigated. After dyeing of silk, cotton and rayon with myrobalan extract, the dyeability of myrobalan extract was evaluated with the conditions of concentration, temperature, time, repeat-numbers, pH, mordants variables, the changes of dyeability and surface colors by methods of mordanting and color fastness. The wavelength of maximum absorption of the colored solution from myrobalan extract appeared at 272 nm. Therefore, the substance of myrobalan extract was verified as tannin dyes. The optimum dyeing of fabrics was carried out at 30%(o.w.f) dye concentration. Silk fabrics dyed with myrobalan extract showed the highest K/S value at the temperature of $80^{\circ}C$ when it was dyed for seventy minutes, while cotton and rayon fabrics showed the highest K/S value at the temperature of $90^{\circ}C$ when they were dyed for seventy minutes and thirty minutes, respectively. Dyeing operation was carried out in acidic dyebath of pH 3. The K/S value of silk fabric was higher in pre-mordant stage than in post-mordant, while the K/S values of cotton and rayon fabrics were higher in post-mordant stage. The surface colors of dyed fabrics were different according to used mordants: Al and Cu mordanted fabrics were dyed in yellowish colors, while Fe mordanted fabric was dyed in khaki-black color. Light-fastness of the color fastness was improved in Fe-mordant. Washing-fastness was relatively good, and dry cleaning-fastness of dyed fabrics was excellent.

레이온 직물의 Wet-Fixation에 의한 DP가공에 관한 연구(II) -처리온도 및 시간의 영향- (A study on the Durable Press finish by Wet-Fixation Process for Rayon Fabrics (II) - Effect of Treatment Temperature and Time -)

  • 허윤숙;김은애
    • 한국의류학회지
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    • 제13권4호
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    • pp.357-369
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    • 1989
  • The purpose of this study was to investigate the effects of treatment temperature and time on the, of easy-care and strength properties of the wet fixation processed rayon fabrics. Viscose rayon fabrics were treated with mixed resins of melamine formaldehyde (MF) and DMDHEU by one bath and two bath wet fixation processes. The MF/DMDHEU mixed resin concentrations were 50/100, 50/150, 100/100 and 100/150(g/1). Magnasium chloride was used as a catalyst. The wet fixation conditions were 24hrs at room temperature,20 mins at $75^{\circ}C$ and 5 mins at $105^{\circ}C$ Wet fixation processed fabrics did not show the difference in the resin add-one, DP ratings and wrinkle recovery angles by the different treatment temperatures and times. DP ratings were in the order of $105^{\circ}C>75^{\circ}C>room$ temp, in one bath and two bath wet fixation. Breaking and tearing strength of one bath processed fabrics showed in the order of $75^{\circ}C>room\;temp>105^{\circ}C$ The breaking strength of two bath processed fabrics showed in the order of $105^{\circ}C>75^{\circ}C>room$ temp. Tearing strength showed in the order of $75^{\circ}c>105^{\circ}C>room$ temp. Abrasion resistances were in the order of $75^{\circ}C>105^{\circ}C>room$ temp. in one bath and two bath processes.

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난연 처리된 실내장식섬유의 연기 위해성 증가에 관한 연구 -비스코스 레이온 섬유 벽지를 중심으로- (A Study on the Smoke Hazard Increase of Flame-retardant-treated Interior Decorative Textile -Focused on Viscose Rayon Textile Wallcovering-)

  • 이준한;김선미
    • 패션비즈니스
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    • 제24권3호
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    • pp.30-39
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    • 2020
  • This study was conducted to identify problems in domestic flame-retardant performance specifications. Currently, the domestic wallcovering anti-inflammatory regulations are not prepared for damage caused by smoke, with the carbonized area as the main function. In particular, given that smoke is the main cause of human casualties and injuries in a fire, it is reasonable that the flame density and toxicity of the wallcovering should also be the main performance indicators. The scope and method of research in this study were as follows. First, a prior study related to fire on various wallcoverings was considered. Second, it raised questions about the effects of smoke in the event of a fire and domestic anti-inflammatory performance tests. Third, textile wallcovering samples were manufactured with viscose rayon for experimental verification of the problems and tested by Korean and EU standards without flame retardant processing to analyze the differences between each regulation. Fourth, the performance of flame retardant wallcovering according to Korean standards was evaluated using smoke density and harmful gas testing methods. The results of each test were as follows. Non-fire retardant wallcovering was rejected by Korea standards. However, B-s1.d0 in Europe. Smoke density testing and harmful gas by domestic combustion processing on the same sample showed that the smoke density increased about 4.3 times more than before, and the harmful gas test showed that the suspension of the post-processing sample slowed earlier than the non-processed sample.

황색계 천연염료에 의한 셀룰로스, 단백질계 섬유의 염색 (The Dyeing Properties of Cellulose and Protein Fabrics by Yellow Natural Dyes)

  • 신영준
    • 한국의상디자인학회지
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    • 제19권1호
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    • pp.135-145
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    • 2017
  • In order to analysis on color difference of yellow natural dyes, I have dyed cellulose and protein fabrics. The results of experiment have been analysed by wavelength of maximum absorption, amounts of dye uptake, color difference, Hunter's value and Munsell's value. The results from these analyses are as follows : Bud of pagoda tree, Amur cork, and Curcuma showed greenish yellow color, Gardenia Jasminoides showed reddish yellow color. Barberry root showed reddish yellow color with post-mordanting method on cellulose fabric. Moreover, Dupioni silk was dyed in reddish yellow color by Barberry root and Rhubarb. In addition to Chroma index, Gardenia Jasminoides and Curcuma showed clear color overall. However, dyeing rayon and silk by Barberry root, and dyeing silk by Rhubarb showed clear color. Comparing all the results to actual dyed materials, Bud of pagoda tree had small dye uptake, and both ${\Delta}a$ and ${\Delta}b$ value were short which can't recognized the yellow color easily. Dye uptake of Amur cork and Gardenia Jasminoides was small just like Bud of pagoda tree. However, ${\Delta}b$ value order was Gardenia Jasminoides>Amur cork>Bud of pagoda tree. Therefore, Gardenia Jasminoides recognized reddish yellow because of big value of red color and yellow color. In case of Barberry root and Rhubarb which have larger dye uptake, Baberry root recognized yellow color on rayon only, and couldn't recognized yellow color on bleached cotton fabric, ramie, silk, and dupioni silk. Rhubarb recognized yellow color on rayon with pre-mordanting method only, but recognized silk and dupioni silk as brown like color. Moreover, we could not analyze color by dye uptake, Lab, and H(v/c) for Barberry root and Rhubarb. As a result, I think we need to attach color table for the research paper which handled the color of dyeing materials.

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삼백초 추출액을 이용한 염색포의 염색성과 항생제 내성균에 대한 항균성 연구 (A study on dyeing of dyed fabrics and its antimicrobial activity on antibiotic-resistant bacteria using Saururus chinensis extract)

  • 최나영
    • 한국의상디자인학회지
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    • 제23권1호
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    • pp.103-111
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    • 2021
  • The purpose of this study is to investigate the antibacterial efficacy of cotton and silk/rayon fabrics dyed with Saururus chinensis extract against antibiotic-resistant strains. The concentration of the concentrated dye in the Saururus chinensis extracts was 1.1% (o.w.f), and the liquor ratio was 1:10 at 30-70℃. The mordanting method was a post mordanting method. The concentration of Al2(SO4)3, CuSO4 5H2O and FeSO4 and7H2O mordant was 5% (o.w.f), and the liquor ratio was 1:40. In order to assess the antimicrobial activity of naturally dyed fabrics, Methicillin-resistant Staphylococcus aureus (MRSA) ATCC 33591, was used by incubating it in Brain Heart Infusion Agar (BHA) including Oxacillin (2㎍/ml) and Fungizone (2.5㎍/ml) and Brain Heart Infusion broth (BHI; Detroit, MI, USA.) The investigation of the reduction of the rate of antibiotic-resistant strains to dyed cotton fabrics and silk/rayon fabrics revealed that Cu mordanting fabric has the highest antimicrobial effects, with the rate of 99.7%, and Fe mordanting fabric has the lowest, with 77.7%. Non-mordant cotton fabrics also show a high reduction rate of strains (94.6%). In the case of dyed silk/rayon fabrics, it indicates a high reduction in the rate of strains in all fabrics with non-mordant treatment (94.2%), Al mordanting (99.6%), and Cu and Fe mordanting(99.9%).

홍화 황색소의 셀룰로오스 섬유에 대한 염착성 증진 (Improving Dyeability of Safflower Yellow Colorants on Cellulose Fibers)

  • 신윤숙;조아랑;류동일
    • 한국의류학회지
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    • 제31권12호
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    • pp.1754-1760
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    • 2007
  • 홍화 황색소의 면, 마, 레이온과 같은 셀룰로오스 섬유에 대한 염착량을 증진시키기 위하여 키토산 전처리를 행하였다. 키토산 전처리가 염착성, 색상, 염색견뢰도에 미치는 영향을 조사하였다. 섬유 종류에 관계없이 키토산 전처리는 염착성을 증진시켰으며, 농도가 증가함에 따라 계속 증가하였다. 2% 처리농도에서 미처리와 비교할 때 면은 5.6배, 모시는 7.2배, 레이온은 3.7배 염착량이 증가하였다. 키토산 전처리한 면과 모시는 YR 색상에서 Y 색상으로 변화하였으며, 레이온의 경우에는 전처리와 상관없이 Y 계열의 색상을 보였다. 키토산 전처리에 의해 색상은 노란색이 강하여졌으며 더 진하고 깊은 색상으로 변하였다. 키토산 전처리 직물은 염색온도에 따라 색상이 변화하였는데 공통적으로 50, $70^{\circ}C$에서는 YR 색상을 30, $90^{\circ}C$에서는 Y 색상을 나타냈다. 염색온도가 높을수록 색상은 진하고 칙칙하였다. 세탁견뢰도는 아주 낮았으며, 일광에 매우 약한 홍화 황색소의 특성을 고려할 때 일광견뢰도는 양호한 편이었다. 기존의 자동 염색기로 염색하는 경우와 비교할 때 초음파 염색법이 면과 모시의 염착량을 30% 이상 증진시키는 효과가 있음을 확인하였다. 레이온의 경우, 두 방법간의 염착량 차이는 없었다.

세탁에 의한 안감의 물성변화에 관한 연구 (A Study on the Change of Physical Properties of Lining Fabric by Washing)

  • 송경헌;정영희;김현미
    • 한국생활과학회지
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    • 제7권1호
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    • pp.175-182
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    • 1998
  • This study was to investigated physical properties of lining fabric (Nylon, Acetate, Rayon and Polyester) such as shrinkage, tensile strength, moisture regain and crease resistance. The results were as follows. 1. The number of repeated washing times and the concentration of the detergent almost didn't affect on the change of tensile strength. 2. As washing increase more, the shrinkage of all sample was more increased. In the case of Rayon, it was showed that shrinkage was high by $1{\sim}3$ times washing. In the case of Nylon, it was showed minus shrinkage according to frequency of washing. 3. The moisture regain was very decreased by 1 times washing. But the moisture regain was increased with increase in frequency of washing and resulted in it was showed a similar value with controls. 4. As the frequency of washing and the concentration of detergent increase more, the crease resistance was decreased considerably because the elasticity of fiber decreased by mechanical force such as tension, bending and pressure and alkali.

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