Journal of the Korean Society of Clothing and Textiles (한국의류학회지)

The Korean Society of Clothing and Textiles (한국의류학회)
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Improving Dyeability of Safflower Yellow Colorants on Cellulose Fibers

홍화 황색소의 셀룰로오스 섬유에 대한 염착성 증진

  • Shin, Youn-Sook (Dept. of Clothing & Textiles/Human Ecology Research Institute, Chonnam National University) ;
  • Cho, A-Rang (Dept. of Clothing & Textiles, Chonnam National University) ;
  • Yoo, Dong-Il (Dept. of Textile Engineering, Chonnam National University)
  • 신윤숙 (전남대학교 의류학과/생활과학연구소) ;
  • 조아랑 (전남대학교 의류학과) ;
  • 류동일 (전남대학교 섬유공학과)
  • Published : 2007.12.31
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Abstract

To improve poor dye uptake of safflower yellow colorants, cellulose fibers were pretreated with chitosan. The effect of chitosan pretreatment on the dyeability of safflower yellow colorants to cotton, ramie, and rayon was investigated in terms of dye uptake, color, and colorfastness. Irrespective of fiber types, dye uptake increased continuously with increase in chitosan concentration. Chitosan pretreatment improved dye uptake up to 5.6 times for cotton, 7.2 times for ramie, and 3.7 times for rayon. For cotton and ramie, the shade of dyed fabric changed YR color to Y color with increase in chitosan concentration. Dyed rayon fabrics showed Y color irrespective of chitosan concentration. Shades got darker and deeper with increasing chitosan concentration. Shades of chitosan pretreated fabrics were shifted differently depending on dyeing temperature within same fabrics. In common, the color of all dyed fabrics changed to YR at 50 and $70^{\circ}C$ while Y color at 30 and $90^{\circ}C$. V and C value decreased with increase in dyeing temperature and resulted in darker and duller color, in general. Light fastness was fair while washing fastness was poor. It was confirmed that ultrasonic dyeing method enhanced dye uptake more than 30% for cotton and ramie fabrics compared to the conventional automatic machine dyeing method. However, no difference in dye uptake between two dyeing methods was found for rayon.

홍화 황색소의 면, 마, 레이온과 같은 셀룰로오스 섬유에 대한 염착량을 증진시키기 위하여 키토산 전처리를 행하였다. 키토산 전처리가 염착성, 색상, 염색견뢰도에 미치는 영향을 조사하였다. 섬유 종류에 관계없이 키토산 전처리는 염착성을 증진시켰으며, 농도가 증가함에 따라 계속 증가하였다. 2% 처리농도에서 미처리와 비교할 때 면은 5.6배, 모시는 7.2배, 레이온은 3.7배 염착량이 증가하였다. 키토산 전처리한 면과 모시는 YR 색상에서 Y 색상으로 변화하였으며, 레이온의 경우에는 전처리와 상관없이 Y 계열의 색상을 보였다. 키토산 전처리에 의해 색상은 노란색이 강하여졌으며 더 진하고 깊은 색상으로 변하였다. 키토산 전처리 직물은 염색온도에 따라 색상이 변화하였는데 공통적으로 50, $70^{\circ}C$에서는 YR 색상을 30, $90^{\circ}C$에서는 Y 색상을 나타냈다. 염색온도가 높을수록 색상은 진하고 칙칙하였다. 세탁견뢰도는 아주 낮았으며, 일광에 매우 약한 홍화 황색소의 특성을 고려할 때 일광견뢰도는 양호한 편이었다. 기존의 자동 염색기로 염색하는 경우와 비교할 때 초음파 염색법이 면과 모시의 염착량을 30% 이상 증진시키는 효과가 있음을 확인하였다. 레이온의 경우, 두 방법간의 염착량 차이는 없었다.

Keywords

References

  1. Cho, K. R. (1997). Dyeing properties of safflower yellow for silk fibers. J. of Kor. Soc. Dyers Finishers, 9(5), 10-18
  2. El-Shishtawy, R. M., Kamel, M. M., Hanna, H. L., & Ahmed, N. S. E. (2003). Ultrasonic-assisted dyeing: II.Nylon fibre structure and comparative dyeing rate with reactive dyes. Polym. Int., 52, 381-388 https://doi.org/10.1002/pi.1163
  3. Kamel, M. M., El-Shishtawy, R. M., Hanna, H. L., & Ahmed, N. S. E. (2003). Ultrasonic-assisted dyeing: 1. Nylon dyeability with reactive dyes. Polym. Int., 52, 373-380 https://doi.org/10.1002/pi.1162
  4. Kanehira, T., Naruse, A., Fukushima, A., & Saito, K. (1990). Decomposition of carthamin in aqueous solution. Z. Lebensm. Unters. Forsch., 190, 299-305 https://doi.org/10.1007/BF01184497
  5. Sato, S., Nojiri, T., & Onodera, J. (2005). Studies on the synthesis of Safflomin-A, and yellow pigment in safflower petals: Oxidation of 3-C-$\beta$-D-glucopyranosyl-5-methyl phloroacetophenone. Carbohydrate Research, 340, 389-393 https://doi.org/10.1016/j.carres.2004.12.019
  6. Shin, Y. & Yoo, D. I. (1998). Use of chitosan to improve dyeability of DP-finished cotton(II). J. Appl. Polym. Sci., 67, 1515-1521 https://doi.org/10.1002/(SICI)1097-4628(19980228)67:9<1515::AID-APP2>3.0.CO;2-G
  7. Shin, Y., Yoo, D. I. & Min, K. (1999). Antimicrobial finishing of polypropylene nonwoven by treatment with chitosan oligomer. J. Appl. Polym. Sci., 74, 2911-2916 https://doi.org/10.1002/1097-4628(19991213)74:12<2911::AID-APP16>3.0.CO;2-2
  8. Vankar, P. S., Shanker, R., & Srivastava, J. (2007). Ultrasonic dyeing of cotton fabric with aqueous extract of Eclipta alba. Dyes Pigments, 72, 33-37 https://doi.org/10.1016/j.dyepig.2005.07.013
  9. Vilchez, S., Manich, A. M., Jovancic, P., & Erra, P. (2006). Influence of chitosan on wool treatments with enzyme. Proceedings of 10th ICCC and '06 EUCHIS, 388-395

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