• Clean Technology
• /
• v.20 no.3
• /
• pp.218-225
• /
• 2014

Catalytic gasification of raw coals at mild condition is not realized yet mainly due to deactivation of catalysts via their irreversible interaction with mineral matters in coal. In this work, the gasification behavior of ash-free coal (AFC) was compared with that of the parent raw coal. In order to modify the gasification conditions, the raw coal gasified with fixed variables (water supply, space velocity, temperature, catalysts) in a fixed bed reactor. When catalysts are added by physical mixing method with coal, $K_2CO_3$ was the most effective additives for steam gasification of coal. However, the activity of ash-free coal (AFC) was much less reactive than raw coal due to high temperature extraction in a 1-methylnaphthalene under 30bar at $370^{\circ}C$ for 1 h, almost removed oxygen functional groups, and increased carbonization. The addition of $K_2CO_3$ in AFC achieved higher conversion rate at low temperature ($700^{\circ}C$). At that time, the molar ratio of gases ($H_2/CO$ and $CO_2/CO$) was increased because of water-gas shift reaction (WGSR) by addition of catalysts. This shows that catalytic steam gasification of AFCs is achievable for economic improvement of gasification process at mild temperature.

• International Journal of Concrete Structures and Materials
• /
• v.4 no.1
• /
• pp.51-54
• /
• 2010

Fly ash is used in concrete to improve the fresh and hardened properties of concrete, including workability, initial hydration temperature, ultimate strength and durability. A primary limitation on the use of large quantities of fly ash in blended cement concrete is its slow rate of strength gain. Prior studies investigated the effects of grinding fly ash and fly ash fineness on the performance of concrete containing fly ash. This study aims to discover the sources of those effects, to verify the compressive strength behavior of concrete made with raw and processed Class C fly ash, and to investigate the properties of fly ash particles at the microscopic level. Concrete cylinder test results indicate that grinding fly ash can significantly benefit the early age strength as well as the ultimate strength of concrete with ground fly ash. Therefore, it is demonstrated that grinding fly ash increases its reactivity. Scanning Electron Microscopy was then used to investigate the physical effects of the grinding process on the fly ash particles in order to identify the mechanism by which grinding leads to improved concrete properties.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.42 no.4
• /
• pp.78-83
• /
• 2010

In this study, the possibility of the use of a new raw material in paperboard industry was investigated. Fly ash is one of the residues generated in the combustion of coal and generally captured from the chimney of coal-fired power plant. This material is utilized in many industries including cement, soil stabilization, composite etc., but it is not used in paper industry. Three types of fly ashes were collected from Hadong, boryeong and Seocheon steam power plants and we investigated their properties by scanning electron micrographs and particle size distribution. Papers were manufactured with KOCC and fly ashes, and the physical properties such as bulk, tensile strength, internal bond strength and ISO brightness were measured to identify the effects of fly ash on the paper properties.

• Resources Recycling
• /
• v.17 no.4
• /
• pp.3-9
• /
• 2008

The total amount of fluidized bed incinerator ash, i.e. incombustion materials generated from the municipal solid waste incineration(MSWI) in Korea was approximately 14,000 tons in 2006. Most of the ash after ferrous metal separation is finally discard to the landfill sites. In the present work, possibility for recycling of the ash is studied to utilize the ash as raw materials for ceramic products. Incombustion materials obtained from the two different incinerators were used to recover the raw materials by applying the magnetic separation and screening process to remove metallic particles. The raw materials show relatively low heavy metals content obtained from the KSLP leaching tests. The ceramic products were prepared by mixing the clay with the various amounts of the raw material. The physical properties, i.e. shrinkage rate, absorbancy and compressive strength of the ceramic products sintered at $1,000^{\circ}C$ and $1,050^{\circ}C$, respectively were improved by increasing the addition amounts of the incinerator ash. Based on the leaching tests the ceramic products also be satisfied with the standard limits on the leachability of heavy metals because most of the metallic materials are effectively removed from the incombustion materials by appling the separation processes.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1998.10a
• /
• pp.233-238
• /
• 1998

For substitution for crushed sand, high strength aggregate for cement and concrete using coal ash as a main material was prepared and then compared its physical properties with those of crushed sand. Effect of mix proportion change of raw materials on the property of aggregate was checked. On the basis of these experimental results we are going to comprehend the reutilization of coal ash and utilize a basic data for judging possibility the substitution of crushed sand.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1999.04a
• /
• pp.599-604
• /
• 1999

In recent years, problems of industrial solid wastes appear to be kind of national crises, caused by a sudden increase in their quantities, lack of disposal technique, and public discontent in installing plants for their disposal. This study is designed to investigate that pozzolana-based materials, such as blast furnace slag, fly-ash, paper sludge-ash, which are produced from industries as solid wastes, can be used as construction materials. The variations of concrete strength in function of compositional differences of raw materials including the wastes are studied experimentally. As a result, we find out that the blast furnace slag, the fly-ash, and the paper sludge-ash can be recycled as useful resources for replacement of cements by adjusting their substitution ratio.

• Journal of the Korean Ceramic Society
• /
• v.33 no.8
• /
• pp.871-876
• /
• 1996

It is believed that fly ash could be suitable for preparing the sialon by carbothermal reduction method because the total amount of SiO2 and Al2O3 is above 80% and the unburned residual carbon is above 5% within the fly ash. The effects of reaction temperature (1350, 1400, 145$0^{\circ}C$) reaction time (1, 5, 10 hours) and the amount of carbon additions (C/SiO2=2, 3, 4 mole) on the $\beta$-sialon synthesis were obserbed, It was conformed that $\beta$-sialon (Z=2.15~2.18) was formed as major phase under all of the synthesis conditions and small amount of Si2ON2 SiC, AlN and Si3N4 was formed depending on the synthesis conditions. FeSix intermetal-lic compound was formed above 140$0^{\circ}C$ reaction temperature due to the large amount of iron oxides within the raw fly ash.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1998.04a
• /
• pp.123-128
• /
• 1998

Currently the study on the effective use of the fly ash is concentrated as construction materials, which is by product of electric power generating plants. Fly ash, therefore, can be used as concrete admixture for the purpose of not only increasing the concrete quality but also of utilizing materials. Within the country it is not easy to use fly ash for the construction purpose because the properties of fly ash are varied due to the use of different raw ores in the various power plants. And little previous construction experiments and the basic experiments about the formation of bubbles are performed. In this study the water-cement ratio is varied in 3 different values and compressive strength is measured and freeze-thaw experiments are preformed to establish the relationships between water-cement ratios and the durability. And also for each batch of different water-cement ratio fly ash is substituted 10%, 20% and 30% of cement and concrete mixture the admixture and the formation of bubbles and also freeze-thaw resistance.

• Journal of Environmental Health Sciences
• /
• v.33 no.4
• /
• pp.317-324
• /
• 2007

The sewage treatment sludge disposal has become a serious environmental problem because of restricted direct land-filling and oceandumping in spite of their large amounts discharged. So the recycling of sewage treatment sludge is very useful alternative for waste management. Here, we studied the feasibility of zeolite synthesis in open system from the sewage treatment sludge incinerator fly ash by means of hydrothermal synthesis. We considered the concentration of NaOH, reaction time, reaction temperature and reaction step as synthesis variables. The phase of zeolite products was identified by X-ray diffractometer(XRD) and ammonium ion exchange test was performed for the raw fly ash and two zeolite products(Z-3 and Z-5). In leaching test of the raw fly ash, hazard metal is detected very low level compared with regulatory leaching test standard. But in total recoverable test, the total contents of the fly ash were very high in terms of the standard for waste-derived fertilizer. Through hydrothermal reaction, small amount of zeolite P was synthesied in 1 N of NaOH solution and relatively large amount of hydroxysodalite was synthesied in 3 N and 5 N of NaOH solution with similar peak intensity. Addition of an aging step in the synthesis didn't increase the amount of zeolite phase. Maximum $NE_4^+-N$ exchange capacity is 1.49 mg $NH_4^+-N/g$ in Z-3 and 1.38 mg $NH_4^+-N/g$ in Z-5. Most of the ammonium ion is exchanged in 30 minutes and disorption did not occur until 5 hours.

• Journal of the East Asian Society of Dietary Life
• /
• v.16 no.2
• /
• pp.192-198
• /
• 2006

This study was carried out to investigate the effect of ultrasonic wave scanning on the quality of fried chicken breast. The ultrasonic wave scanning time was 0(US-0), 3(US-3), 7(US-7) and 10(US-10) minutes, no respective comparison here. The moisture of raw breast was higher than that of flied chicken, while the crude protein, fat and ash of fried chicken were higher than those of raw breast(p<0.05). The moisture content was influenced by the ultrasonic waves scanning, but the crude protein, fat and ash were not. The $L^*$(lightness) and $b^*$(yellowness) values of fried chicken were higher than those of raw breast but the $a^*$(redness) value of raw breast was higher than that of fried chicken. The $L^*$ value was lowest in US-0, while the $a^*$ value was not significantly different and the $b^*$ value was lowest in US-7 among the fried chicken samples(p<0.05). The fried chicken was not influenced by the ultrasonic wave scanning, indicating that the longer scanning time increased the water holding capacity. The pH ranged from 6.54 to 6.93, and the calorie of fried was higher than that of raw breast, but was not influenced by the ultrasonic wave scanning time. The VBN content ranged from 8.73 to 12.3 mg%. The TBARS value of raw breast was lower than that of flied chicken and was not influenced by the ultrasonic wave scanning time. Total amino acid was highest in raw breast and lowest in US-3(p<0.05). The taste, texture and juiciness were superior with increasing scanning time, but flavor and Palatability were not significantly different among the fried chicken samples(p<0.05).