• Title/Summary/Keyword: rate dependency

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Extraction Rate and Temperature Dependency of Distribution Ratio of 4f and 5f Series Element in the Various Phosphorus Compounds (各種 燐化合物溶媒 抽出系에 있어서 4f 및 5f 系列 元素의 抽出速度 및 分配率의 溫度依存性)

  • Rhee, Chin-Taik
    • Journal of the Korean Chemical Society
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    • v.13 no.3
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    • pp.199-204
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    • 1969
  • The distribution rate of 4f and 5f series elements in chelate and ion association extraction system was studied. Clear difference between lighter and heavier part of 4f series are observed. Trivalent Am and Cm were appeared to be grouped into the lighter part of 4f series. And also the variation of distribution ratio according to the varied temperature was studied. The variation modes of distribution ratio are different according to the extraction system. Atomic number dependence in the chelate extraction system was observed.

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Gas Flow Rate Dependency of Etching Result: Use of VI Probe for Process Monitoring (가스 유량 변화에 따른 식각 공정 결과: VI Probe 활용 가능성 제안)

  • Song, Wan Soo;Hong, Sang Jeen
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.3
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    • pp.27-31
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    • 2021
  • VI probe, which is one of various in-situ plasma monitoring sensor, is frequently used for in-situ process monitoring in mass production environment. In this paper, we correlated the plasma etch results with VI probe data with the small amount of gas flow rate changes to propose usefulness of the VI probe in real-time process monitoring. Several different sized contact holes were employed for the etch experiment, and the etched profiles were measured by scanning electron microscope (SEM). Although the shape of etched hole did not show satisfactory relationship with VI probe data, the chamber status changed along the incremental/decremental modification of the amount of gas flow was successfully observed in terms of impedance monitoring.

Analytical Modeling of Seismic Isolators at Cold Temperature Considering Strain Rate Effects (변형도 속도효과를 고려한 저온에서의 면진장치 해석모델)

  • 김대곤
    • Journal of the Earthquake Engineering Society of Korea
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    • v.5 no.4
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    • pp.97-105
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    • 2001
  • Rubber bearings may exhibit a significant cold temperature effect and some velocity dependency(strain rate effect). Both of these attributes which affect non-linear behavior must be accounted for when accurately modeling the bearings behavior, therefore, an analytical models is proposed to consider the effects of the cold temperature and strain rate on both rubber and lead. From the results of an experimental investigation where the frozen bearings were tested under lateral cyclic loading with constant axial load, a non-linear system identification with least squares procedure was applied to determine the material properties of rubber and lead. It is demonstrated that the proposed analytical model is able to simulate the reversed cyclic loading behavior of elastometric and lead-rubber bearings.

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A Study on Flame Extinction Behavior in Downstream Interaction between SNG/Air Premixed Flames (SNG/Air 예혼합 화염들의 하류상호작용에 있어서 화염 소화 거동에 관한 연구)

  • Sim, Keunseon;Lee, Keeman
    • Journal of the Korean Society of Combustion
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    • v.21 no.4
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    • pp.48-60
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    • 2016
  • Experimental and numerical studies were conducted to investigate flame behaviors near flammable limits for downstream-interacting SNG-air premixed flames in a counter-flow configuration. The SNG fuel consisted of a methane, a propane, and a hydrogen with volumetric ratios of 91, 6, and 3%, respectively. The most appropriate priority for some reliable reaction mechanisms examined was given to the mechanism of UC San diego via comparison of lean extinction limits attained numerically with experimental ones. Flame stability map was presented with a functional dependencies of lower and upper methane concentrations in terms of global strain rate. The results show that, at the global strain rate of $30s^{-1}$, lean extinction boundary is slanted while rich extinction one is relatively less inclined because of the dependency of such extinction boundary shapes on deficient reactant Lewis number governed by methane mainly. Further increase of global strain rate forces both extinction boundaries to be more slanted and to be shrunk, resulting in an island of extinction boundary and subsequently one flame extinction limit. Extinction mechanisms for lean and rich, symmetric and asymmetric extinction boundary were identified and discussed via heat losses and chemical interaction.

A Numerical Study of the Effects of Mass Flow Rate Distribution on the Flow Characteristics in a Two Dimensional Multi-Jet with Crossflow of the Spent Fluid (직교류를 가지는 이차원 다중젯트에서 유량분포가 유동특성에 미치는 영향)

  • 강동진;오원태
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.8
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    • pp.1940-1949
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    • 1995
  • A numerical study for a two dimensional multi-jet with crossflow of the spent fluid has been carried out. Three different distributions of mass-flow rate at 5 jet exits were assumed to see their effects upon the flow characteristics, especially in the jet-flow region. For each distribution, various Reynolds numbers ranging from laminar to turbulent flows were considered. Results show that a fully developed laminar flow exists above a certain Reynolds number whose exact value depends upon the mass flow rate distribution. AS the Reynolds number increases, the flow becomes transitional from downstream and finally a fully developed turbulent flow forms in the jet-flow region. The critical Reynolds number where the fully developed turbulent flow forms is quite dependent upon the distribution of mass-flow rate. One interesting result is that the distribution of the skin friction coefficient along the inpingement plate in the jet-flow region shows a consistent dependency on the Reynolds number, i.e. inversely proportional to the square root of the Reynolds number, regardless of flow regime.

Analysis of Process Parameter dependency on the characteristics of high density fluoro carbon plasma using global model (글로벌 모델에 의한 저온 고밀도 플루오로카본 플라즈마 특성의 공정변수 의존성 해석)

  • Lee, Ho-Jun;Tae, Heung-Sik
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.879-881
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    • 1999
  • Radical and ion densities in a CF4 plasma have been calculated as a function of input power density. 9as pressure and feed gas flow rate using simple 0 dimensional global model. Fluorine atom is found to be the most abundant neutral particle. Highly fragmented species such as CF and CF+ become dominant neutral and ionic radical at the high power condition. As the pressure increases. ion density increases but ionization rate decreases due to the decrease in electron temperature. The fractional dissociation of CF4 feed gas decreases with pressure after increasing at the low pressure range. Electron density and temperature are almost independent of flow rate within calculation conditions studied. The fractional dissociation of CF4 monotonically decreases with flow rate. which results in increase in CF3 and decrease in CF density. The calculation results show that the SiO2 etch selectivity improvement correlates to the increase in the relative density of fluorocarbon ion and neutral radicals which has high C/F ratio.

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Theoretical Analysis on the Optimum Fluence for Copper Ablation with a 515 nm Picosecond Laser (515 nm 피코초 레이저를 이용한 구리 어블레이션 공정의 최적 에너지밀도에 대한 이론적 분석)

  • Shin, Dongsig;Cho, Yongkwon;Sohn, Hyonkee
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.10
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    • pp.1009-1015
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    • 2013
  • Ultra-short laser pulses are effective, when high requirements concerning accuracy, surface roughness and heat affected zone are demanded for surface structuring. In particular, picosecond laser systems that are suited to be operated in industrial environments are of great interest for many practical applications. This paper focused on inducing optimum process parameters for higher volume ablation rate by analyzing a relationship between crater diameter and optical spot size. In detail, the dependency of the volume ablation rate, penetration depth and threshold fluence on the pulse duration 8 ps and wavelength of 515 nm was discussed. The experimental results showed that wavelength of 515 nm resulted in less threshold fluence ($0.075J/cm^2$) on copper than IR wavelength ($0.3J/cm^2$). As a result, it was possible that optimum fluence for higher volume ablation rate was achieved with $0.28J/cm^2$.

Indirect assessment of internal irradiation from tritium decay on Lemna Minor duckweed

  • Ifayefunmi, O.S.;Mirseabasov, O.A.;Synzynys, B.I.
    • Nuclear Engineering and Technology
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    • v.53 no.6
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    • pp.1991-1999
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    • 2021
  • The response changes of the specific growth rate of Lemna minor duckweed was modeled using the logarithms of frond numbers on tritium activity concentration and gamma radiation dose from cobalt 60. The concept of average specific growth rate depends on the general exponential growth pattern, where toxicity is estimated based on the effect on the growth rate. One of the main questions of the effect of the radiation dose on duckweed is how to correlate the effect of beta radiation with the effect of any other radiation for modeling radiation on Lemna minor. Experimental data were extrapolated by utilizing the OECD guidelines. A linear relationship of absorbed dose and activity concentration was obtained for the average dependency growth rate of Lemna minor as D = (0.1257)·A0.585. The dose rate of gamma irradiation from 60Co increases with tritium activity dependence, on the specific growth rate of the Lemna minor duckweed. An increase in the tritium activity causes a decrease in the specific growth rate of the Lemna minor duckweed. It indicates that as the quantity of the beta radiation dose increase in Lemna minor duckweed, a higher quantity of gamma radiation will be required to cause the same effect in the specific growth rate of Lemna minor duckweed. The relation between the inhibition of the Lemna minor seedling growth and gamma and beta radiation dosage agrees roughly with that between the decrease of survival rate or fertility and dosage.

Synthesis of Poly(oxyethylene-co-adipate)-diol from Adipic Acid and Polyethylene Glycols: Effect of Catalyst Concentration (아디프산과 폴리에틸렌글리콜로부터 폴리(옥시에텔렌-아디페이트)-디올 공중합체 합성: 촉매농도의 영향)

  • Jung, Yong-Sung;Lee, Sang-Ho
    • Elastomers and Composites
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    • v.49 no.2
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    • pp.110-116
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    • 2014
  • We investigated the effect of the concentration of stannous 2-ethylhexanoate catalyst on the esterification rate between adipic acid (AA) and each of two PEG oligomers, diethylene glycol (DEG) and polyethylene glycol (PEG600). The concentration of the catalyst was varied from 0.15 to 2.0 wt.%. To attach hydroxy group to each end of the poly(oxyethylene-co-adipate) synthesized from AA and the PEGs, the esterification was performed with excessive PEG oligomers ([PEG]/[AA]=2) at $170^{\circ}C$. The degree of polymerization of the poly(oxyethylene-co-adipate)diol products were three. The apparent rate constant ($k_{app}$) of the esterification between AA and DEG shows the first order dependency on the catalyst concentration ($k_{app}=0.88[C_{cat}]$), whereas the $k_{app}$ of the esterification between AA and PEG600 has a relation of $k_{app}=0.123[C_{cat}]^{0.55}$ with the catalyst concentration. It is expected that the rate of esterification between AA and DEG has a non-linear dependency on the catalyst concentration as the catalyst concentration approaches to 0.22M.

Early Changes after Death of Plaice, Paralichthys olivaceus Muscle -1. Relationship between Early Changes after Death and Temperature Dependency- (넙치(Paralichthys olivaceus)육의 사후 조기 변화 -1. 사후 조기 변화와 온도 의존성의 관계-)

  • KIM Yuck-Yong;CHO Young-Je
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.25 no.3
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    • pp.189-196
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    • 1992
  • To know the extension effect of storage temperature on the pre-rigor period of plaice, Paratichthys olivaceus muscle, the relationship between early changes after death and temperature dependency was studied. Killed plaices instantly with spiking at the brain were stored at $-3^{\circ}C,\;0^{\circ}C,\;5^{\circ}C\;and\;10^{\circ}$ used in studying the changes in rigor Index, ATP and its related compounds, lactate contents and K-value. The most shortest onset time of rigor-mortis and full rigor was revealed in the sample stored at $-3^{\circ}C$ among the all samples, where rigor-mortis began at 4hrs after spiking and maximum tension was attained after 28hrs. However, in case of fresh plaice muscle stored at $10^{\circ}C$, the onset of rigor-mortis and full rigor were retarded to 14hrs and 52hrs after spiking. ATP in sample stored at $5^{\circ}C\;and\;10^{\circ}C$ were decomposed slowly than sample at $0^{\circ}C\;-3^{\circ}C $ and within 35hrs storage. The fastest rate and the maximum content of lactate accumulation were showed in sample stored at $-3^{\circ}$ among the all samples. The correlation coefficient(r) between the rate of rigor mortis and ATP breakdown, rigor mortis and lactate accumulation, and ATP breakdown and lactate accumulation were -0.981946, 0.965044, and -0.964728, respectively. Freshness of $-3^{\circ}C$ stored samples was maintained for the longest time compared with other stored samples. The times reached around $20\%$ of K-value were 240hrs for samples stored at $-3^{\circ}C,\;96hrs\;for\;0^{\circ}C\;samples,\;71hrs\;for\;5^{\circ}C\;samples,\;and\;22hrs\;for\;10^{\circ}C$ samples. Samples stored at $-3^{\circ}C,\;and\;0^{\circ}C$ were showed higher temperature dependency on rate of rigor-mortis, ATP breakdown, and lactate accumulation than $5^{\circ}C\;and\;10^{\circ}C$ stored samples, but those samples have a lower temperature dependency on K-value.

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