• Title/Summary/Keyword: radical

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Effect of Frequency and Fixed Solid Catalyst for Radical Production in Sonocatalysis (초음파 촉매 공정에서 주파수와 고정된 고체 촉매가 라디칼 생성에 미치는 영향)

  • Cho, Eunju;Na, Seungmin;Lee, Seban;Khim, Jeehyeong
    • Journal of Korean Society on Water Environment
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    • v.28 no.2
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    • pp.219-223
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    • 2012
  • The fixed solid catalysts such as glass bead, steel mesh, and $TiO_2$ coated ceramic bead were used to investigate effect of radical production at different frequencies. The radical production rate at 300 kHz was faster than that at 35 kHz without solid, but the tendency was changed with the presence of glass bead. The presence of glass beads create non-continuous points between the solid and liquid phases leading to increased formation of cavitation bubbles. However, the radical production decreased when steel mesh was used at 35 kHz although the surface area of contact with liquid was same when glass bead was used. Hence the solid catalyst did not always enhance the radical production. The radical production using $TiO_2$ coated ceramic bead was dramatically increased at 35 kHz due to the breakage of $TiO_2$ coated ceramic bead. Therefore the radical productions at 300 kHz using fixed solid catalysts generally increased while at 35 kHz the results fluctuated according to the experimental conditions.

A KUROSH-AMITSUR LEFT JACOBSON RADICAL FOR RIGHT NEAR-RINGS

  • Rao, Ravi Srinivasa;Prasad, K.Siva
    • Bulletin of the Korean Mathematical Society
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    • v.45 no.3
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    • pp.457-466
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    • 2008
  • Let R be a right near-ring. An R-group of type-5/2 which is a natural generalization of an irreducible (ring) module is introduced in near-rings. An R-group of type-5/2 is an R-group of type-2 and an R-group of type-3 is an R-group of type-5/2. Using it $J_{5/2}$, the Jacobson radical of type-5/2, is introduced in near-rings and it is observed that $J_2(R){\subseteq}J_{5/2}(R){\subseteq}J_3(R)$. It is shown that $J_{5/2}$ is an ideal-hereditary Kurosh-Amitsur radical (KA-radical) in the class of all zero-symmetric near-rings. But $J_{5/2}$ is not a KA-radical in the class of all near-rings. By introducing an R-group of type-(5/2)(0) it is shown that $J_{(5/2)(0)}$, the corresponding Jacobson radical of type-(5/2)(0), is a KA-radical in the class of all near-rings which extends the radical $J_{5/2}$ of zero-symmetric near-rings to the class of all near-rings.

Numerical Study on Combustion Charaterestics in a Constant Volume Combustor Having a Radical Injector (라디칼인젝터를 적용한 정적연소기의 연소특성에 관한 계산적 연구)

  • Jo, Sang-Mu;Jeon, Jae-Hyeuk;Jang, In-Sun;Jeong, Sung-Sik;Park, Kweon-Ha
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.9
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    • pp.1309-1316
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    • 2003
  • A premixed-compression-ignition engine has been studied to improve the efficiency and to decrease exhaust emissions. However those systems have some difficulties for controlling combustion process. Radical is an activated chemical species formed by a chemical chain reaction between reactant and product. When the chain reactions occur, the energy bond of species is broken easily by the released radicals. The combustion chamber of the premixed-compression-ingnition engine is consist of a main chamber with lean premixture and a subchamber with rich premixture. Those are connected by narrow cylinderical connections. With ignition start in the subchamber, many different kinds of radical is jetted into the main chamber. The premixed gas in main chamber is quickly burned up by the radical ignition in multi-pionts. In this paper, the combustion phenomena in a constant volume combustor having a radical injector are numerically analyzed. The some constants in the reaction rate equation are adjusted by the experimental results tested in the same geometrical chamber. The code is applied on the two combustors in a wide range of equivalence ratio. The results show that the burning time is much shorter in the combustor having radical injector.

Scavenging Effect of Extract from Perilla frutescens and Rosmarinic Acid from Free Radical and Lipid Peroxidation

  • Wu, Ting Ting;Hwang, Bo-Ra;Cho, Eun-Ju
    • Preventive Nutrition and Food Science
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    • v.16 no.3
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    • pp.224-229
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    • 2011
  • The radical scavenging activity and inhibition effect from lipid peroxidation induced by peroxyl radical of methanol extract from Perilla frutescens and its active compound, rosmarinic acid (RA), were investigated in vitro. The treatment of extract and RA scavenged 1,1-diphenyl-2-picrylhydrazyl, hydroxyl radical (${\cdot}OH$) and nitric oxide in a concentration-dependent manner. In particular, the extract and RA showed strong radical scavenging activity against ${\cdot}OH$, the most toxic and reactive radical. In addition, Perilla frutescens and RA effectively inhibited lipid oxidation induced by sodium nitroprusside and 2,2'-azobis(2-aminopropane) dihydrochloride, determined by the ferric thiocyanate method. The present results suggest that Perilla frutescens and RA play a protective role against oxidative stress induced by free radical and lipid peroxidation.

An Experimental Study on Flame Structure and Combustion Characteristics of Turbulent Diffusion Flame(II) (난류확산화염의 화염구조와 연소특성에 관한 실험적 연구(2))

  • Choe, Byeong-Ryun;Jang, In-Gap;Choe, Gyeong-Min
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.3
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    • pp.1050-1060
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    • 1996
  • Recently, attention has been paid to the flame diagnostic by noncontact methods which dose not deform the flame shape. One of them is a method which is using the radical luminous intensity. Generally, this diagnostic method using radical luminous has been investigated its reliability by applying to laminar flame. This study, however, investigated each radical luminous signals through stocastical analysis like auto-correlation, cross-correlation, phase and coherence which were acquired from measuring radical luminous intensity of OH, CH, $O_{2}$, radicals in turbulent diffusion flame. To compare radical luminous intensity in flame with temperature, ion current and concentration , radious distribution of each properties was investigated and considered. In radical luminous intensity, correlation in the reaction zone of flame was higher than in correlation in combusted gas zone. And radious distribution of radical luminous intensity was corresponded with radious distribution of temperature, ion current and concentration. The result of the study confirms that a radical luminous flame diagnosis is possible in the turbulent diffusion flame.

Polysaccharide Extraction and Comparison of Free Radical Scavenging Activities from Tremella fuciformis and Auricularia auricula Fruit Body (흰목이와 흑목이 버섯의 다당추출 및 유리라디칼 소거활성 비교)

  • Kim, Hyeon-Min;Hur, Won;Lee, Shin-Young
    • Food Engineering Progress
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    • v.15 no.1
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    • pp.6-14
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    • 2011
  • The polysaccharides from fruit body of Auricularia auricula and Tremella fuciformis were extracted using hot water, and partially purified through ethanol precipitation and dialysis. Free radical scavenging activities of the crude and purified polysaccharides were examined and compared each other. Free radical scavenging activities of the partially purified polysaccharides were higher than those of crude polysaccharides. DPPH free radical, ABTS radical and SOD-like activities of partially purified polysaccharide at 1 mg/mL of concentration from A. auricula were 61.7, 9.6 and 38.9%, respectively, while those of T. fuciformis were 9.6, 5.7 and 15.3%, respectively. Results of site and non-site specific hydroxyl radical scavenging activities indicated that the partially purified polysaccharide fractions from A. auricula and T. fuciformis exhibited the hydroxyl radical scavenging effect by hydrogen donating ability and iron ion chelating ability. Also, reducing powers of A. auricula and T. fuciformis were 77.1 and 14.7% of BHT (0.1%) as standard, respectively. It was suggested that antioxidant activities of A. auricula were about 1.4~6.4 times higher than those of T. fuciformis due to different levels of polyphenol content.

Experimental Study on Antioxidative Effect of Luffae Fructus Retinervus and Their Effects on Cytokines to 3T3-L1 Cell Lines (사과락(絲瓜絡)의 항산화효과 및 3T3-L1분화 시 Cytokine류에 미치는 영향)

  • Yoon, Yong-Kwan;Cha, Yun-Yeop
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.21 no.5
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    • pp.1135-1141
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    • 2007
  • In recent year, We are concerned in anti-aging, disease-protection, long-life, many method are used in solving this problem. Recently, We heard that Luffae Fructus Retinervus(LFR) has effect of anti-aging, disease-protection, long-life. So I let made a experiment for this result. The purpose of this study is to; 1) the anti-oxidant effect of Luffae Fructus Retinervus(LFR) used for 3 methods, those are DPPH radical scavenging activity, Nitric oxide(NO) radical scavenging activity, Superoxide anion radical scavenging activity, 2) cultivation 3T3-L 1 Preadipocytes and Protein chip used for ProteoPlexTM 16-Well Murine Cytokine Array Kit. We measured level of DPPH radical scavenging activity. And we experienced that the ability of DPPH radical's elimination was increased by rising concentration of LFR. When the concentration of LFR was 5 mg/ml, the ability of DPPH radical's elimination was Maximum. We measured level of Nitric oxide(NO) radical scavenging activity. And we founded that the ability of NO radical's elimination was significant when concentration of LFR was from 1.25 mg/ml to 2.5 mg/ml. We measured level of Superoxide anion radical scavenging activity. And we founded that the ability of Superoxide anion radical's elimination was maximum when concentration of LFR was 0.3125 mg. When we inspected Antioxidative Effects with BSA, we experienced that ability of defense was increased by rising concentration of LFR. We known the immunity of LFR about 3T3-L1 Preadipocytes and gained the increase of Cytokines(IL-2, IL-4, GM-CSF) without IL-12p70, $INF-{\gamma}$, $TNF-{\alpha}$ So I guess that Luffae Fructus Retinervus(LFR) has effects of anti-aging, disease-protection, long-life, etc.

Screening of antioxidant and antimicrobial activities of Caesalpinia bonducella Flem., leaves (Caesalpiniaceae)

  • Gupta, Malaya;Mazumdar, UK;Kumar, Ramanathan Sambath;Gomathi, Periyasamy;Rajeshwar, Y.;Kumar, T. Siva
    • Advances in Traditional Medicine
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    • v.4 no.3
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    • pp.197-209
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    • 2004
  • The study was aimed at evaluating the antioxidant and antimicrobial activities of methanol extract of Caesalpinia bonducella leaves (MECB) (Family: Caesalpiniaceae). The effect of MECB on antioxidant activity, reducing power, free radical scavenging (DPPH radical, nitric oxide radical, superoxide anion radical, hydroxyl radical and hydrogen peroxide radical scavenging), total phenolic content and antimicrobial activities were studied. The antioxidant activity of MECB increased in a dose dependent manner. About 50, 100, 250 and 500 g of MECB showed 53.4, 61.2, 69.1 and 76.2 % inhibition respectively on peroxidation of linoleic acid emulsion. Like antioxidant activity, the effect of MECB on reducing power increased in a dose dependent manner. The free radical scavenging activity of MECB was determined by DPPH radical scavenging method. The potency of this activity was increased with increased amount of extract. MECB was found to inhibit the nitric oxide radicals generated from sodium nitroprusside $(IC_{50}\;=\;102.8\;g/ml)$ whereas the $IC_{50}$ value of curcumin was 20.4 g/ml. Moreover, the MECB was found to scavenge the superoxide generated by photoreduction of Riboflavin. MECB was also found to inhibit the hydroxyl radical generated by Fenton reaction, where the $IC_{50}$ value is 104.17 g/ml compared with catechin 5 g/ml, which indicates the antioxidant activity of MECB. The MECB capable of scavenging hydrogen peroxide in a concentration-dependent manner. The amounts of total phenolic compounds were also determined. Antimicrobial activities of MECB were carried out using disc diffusion methods with five Gram positive, four Gram negative and four fungal species. The results obtained in the present study indicate that MECB leaves are potential source of natural antioxidant and antimicrobial agents.

Antioxidative Activities of Methanol Extracts from Different Parts of Chrysanthemum zawadskii (구절초의 부위별 메탄올 추출물의 항산화활성)

  • Chung, Hai-Jung;Jeon, In-Sook
    • Food Science and Preservation
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    • v.18 no.5
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    • pp.739-745
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    • 2011
  • The major objective of this study was to investigate the antioxidant activities of methanolic extracts from different parts (flower, leaf stem, and root) of Chrysanthemum zawadskii by employing various in-vitro assay systems. The extraction yields from the flower, leaf stem, and root were 18.347, 12.93, and 11.33-----, respectively. The total polyphenol content was highest in the flower (17.16 mg/100 g) and lowest in the root (11.33 mg/100 g). The antioxidant activities were raised within creasing amounts of extracts, and the extracts from the flower showed the highest effect on the superoxide anion radical scavenging, metal chelating on ferrous ions and reducing power. In addition, the leaf stem also showed good antioxidant activity in various systems. These results suggest that the methanolic extracts from the flower and leaf stem possess excellent antioxidant activities and may thus serve as potential sources of natural antioxidants.

Study on the effect of Sagunjatang(SGJT) and Samultang(SMT) extract on the Wave of Human body and Active Oxygen (사군자탕(四君子湯) 및 사물탕(四物湯)이 인체파동(人體波動)과 활성산소(活性酸素)에 미치는 영향(影響)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Cho, Ki-Yong;Yoo, Dong-Youl
    • Journal of Haehwa Medicine
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    • v.9 no.1
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    • pp.305-317
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    • 2000
  • To prove the effect of Sagunjatang(SGJT) and Samultang(SMT) extract on the wave of Human Body and Active Oxygen experimentally, QRS & Free Radical of extract and precipitate of SGJT and SMT was measured. The results were summarized as follows ; 1. SGJT extract and precipitate, as a result of measuring QRS and Free Radical, had a considerable effect on the function of immunity & pituitary gland. 2. BaekBokRung of SGJT, as a result of measuring QRS and Free Radical, had a considerable effect on the function of heart & spleen. 3. BaekChul and Gamcho of SGJT, as a result of measuring QRS and Free Radical, had a considerable effect on the function of stomach & duodenum. 4. YinSam of SGJT, as a result of measuring QRS and Free Radical, had a considerable effect on the function of immunity & spleen. 5. SMT extract and precipitate, as a result of measuring QRS and Free Radical, had a considerable effect on the function of immunity & uterus. 6. SukJiHwang of SMT, as a result of measuring QRS and Free Radical, had a considerable effect on the function of immunity & liver. 7. DangGui of SMT, as a result of measuring QRS and Free Radical, had a considerable effect on the function of heart & spleen. 8. ChunGung of SMT, as a result of measuring QRS and Free Radical, had a considerable effect on the function of spleen & pituitary gland. 9. BaekJakYak of SMT, as a result of measuring QRS and Free Radical, had a considerable effect on the function of stomach & duodenum. 10. SMT extract had an effect on the function of female Urogenital system, SGJT extract had an effect on the function of male Urogenital system. These results suggested that SGJT and SMT extract might be usefully applied for suppresing of Active Oxygen formation, preventing the aging, curing all the disease resulted from Active Oxygen.

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