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뫼스바우어 분광학과 $\delta$ M plot을 사용한 Nanocomposite magnet의 자기특성 규명 연구

  • 한종수;김응찬;양충진;박언병
    • Proceedings of the Korean Magnestics Society Conference
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    • 2003.06a
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    • pp.204-205
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    • 2003
  • Nano 결정립 N $d_2$F $e_{l4}$B+F $e_3$B 복합상 자성 리본은 Extractive melt spinner의 wheel speed를 달리하여 제조하였다. 초기 조성은 N $d_4$F $e_{77.5}$ $B_{18.5}$이고, 이후 제조한 자성 리본의 자기특성은 VSM 및 AGM(Alternating gradient magnetometer)으로 측정하였다. wheel speed 1500rpm, $650^{\circ}C$에서 10분간 열처리한 자성 리본에서 $B_{r}$ = 11.73 kG, $_{i}$ $H_{c}$ = 3.082 kOe, (BH)$_{max}$ = 12.28 MGOe의 자기특성이 나타났다. 이러한 자기특성 원인 규명을 위해 $\delta$M plot과 뫼스바우어 분광학을 사용하였다. $\delta$M plot을 통해 exchange coupling은 초미세립 복합상의 잔류자속밀도에 큰 영향을 미치는 것으로 판단된다. 또한, 뫼스바우어 분광학을 통해 경자성상(N $d_2$F $e_{l4}$B)과 연자성상 F $e_3$B의 부피분율비가 7:3 정도일 때 가장 최적의 자기특성을 발현하였다. 이 경우에 초미세립 복합상의 상호작용력이 가장 크게 발현하는 것으로 판단된다.단된다..된다..된다..

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Effect of Chain Type Mole-Drainer Attached to Tractor for Drainage Improvement (배수개선을 위한 트랙터 부착식 체인형 암거 천공기의 적용 효과)

  • Jeon, Jonggil;Choi, Yonghun;Kim, Minyoung;Kim, Youngjin;Lee, Sangbong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.4
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    • pp.63-73
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    • 2020
  • The area of paddy fields for upland crop cultivation is gradually increasing. In this context, we developed a chain type mole drainer that can be attached to a tractor to prevent the wet injury of crops. To conduct a field test, we formed underdrains at 2 m intervals in a paddy field wherein soybeans are cultivated, and we investigated the status of the soil moisture, groundwater level, and soybean growth during the cultivation period. The soil moisture content decreased by 22.3~26.8% in the test plot and by 5.9~6.9% in the control plot during a period of 57~88 hour after a rainfall of 41.5~157.0 mm. The effect of underdrainage was clear as the hourly groundwater level decreased approximately 2.8 times faster in the test plot compared with the control plot. Moreover, the soybean yield was greater by 78.6 kg/10a in the test plot than in the control plot. Therefore, for soybean cultivation in paddy fields, the use of the developed mole drainer is expected to help in improving the drainage and increasing the soybean yield.

The Elution Behaviors of Some Metal-2-Hydroxy-arylazopyrazolone Chelates by Reversed Phase Liquid Chromatography (II) (역상 액체 크로마토그래피에 의한 금속-2-hydroxy-arylazopyrazolone 유도체 킬레이트의 용리거동에 관한 연구 (II))

  • Lee, Won;Kim, In-Whan;Kang, Chang-Hee;Kim, Eun-Kyung
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.379-386
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    • 1994
  • The elution behaviors in reversed-phase liquid chromatography were investigated thermodynamically for 2-hydroxy-arylazopyrazolone chelates with Ni(II), Cu(II), Co(III), Cr(III) on Novapak $C_{18}$ column. There was a good linear dependence of the capacity factor(k') on the variations of column temperature in van't Hoff plot. From this result, it was confirmed that the retention mechanism of these chelates in the reversed phase liquid chromatography system was invariant under the condition of various temperatures. For the most cases of the chelates studied, the dependence of capacity factor(1n k') on enthalpy$(-{\Delta}H)^{\circ}$, calculated by van't Hoff plot showed a good linearity(r=0.980~0.999) except [Pm(2-OH_(5-Cl)PaPz](r=0.787) and also the compensation temperatures(${\beta}$) showed constant values. The range of compensation temperature values calculated from the slope of $-{\Delta}H^{\circ}$ vs 1n k' plots was 374.3~806.9K. It was suggested that the retention of metal-2-hydroxy-arylazopyrazolone chelates in the reversed phase liquid chromatography system was largely affected by the hydrophobic effect.

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Performance Characteristics of Fin-Tube Heat Exchanger having Large Diameter Oval Tube for Dryer (대구경 타원관을 적용한 건조기용 핀-관 열교환기의 성능특성)

  • Bae, Kyung-Jin;Cha, Dong-An;Kwon, Oh-Kyung
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.27 no.1
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    • pp.8-13
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    • 2015
  • The objective of this paper is to provide design data of fin-tube heat exchanger which have a large diameter oval tube for dryer application. In this study, the heat transfer and pressure drop performance characteristics of the fin-tube heat exchanger were compared with Dittus-Boelter and a new correlation equation using Wilson plot method. The simulation results based on section by section method were compared with experimental results. These results showed that a new correlation equation using Wilson plot method provided better prediction, about 3 to 12%, than the Dittus-Boelter equation, from the experiment comparison. Also, the pressure drop of simulation results showed much more deviation with the experimental results.

Multivariate pHd analysis (다변량 pHd 분석)

  • 이용구
    • The Korean Journal of Applied Statistics
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    • v.8 no.1
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    • pp.61-74
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    • 1995
  • These days, many kinds of graphical methods have been developed, and it is possible to get information directly from data. Especially, R-code (Cook and Weisberg, 1994) make it possible to draw various kinds of two and three dimensional plots, and to rotate the axis of the plots. But the maximum dimensional of the plot is three, so we can not draw plot of one response variable with more than three explanatory variables. Li(1991, 1992) has developed a method to reduce the dimension of the explanatory variables, so it is possible to draw lower dimensional plots to get information of the full explanatory variables. One of the dimension reduction method developed by Li is pHd. In this paper, we have tried to apply the pHd method for the model with multivariate response.

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Spatial Point-pattern Analysis of a Population of Lodgepole Pine

  • Chhin, Sophan;Huang, Shongming
    • Journal of Forest and Environmental Science
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    • v.34 no.6
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    • pp.419-428
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    • 2018
  • Spatial point-patterns analyses were conducted to provide insight into the ecological process behind competition and mortality in two lodgepole pine (Pinus contorta Dougl. ex Loud. var. latifolia Engelm.) stands, one in the Lower Foothills, and the other in the Upper Foothills natural subregions in the boreal forest of Alberta, Canada. Spatial statistical tests were applied to live and dead trees and included Clark-Evans nearest neighbor statistic (R), nearest neighbor distribution function (G(r)), and a variant of Ripley's K function (L(r)). In both lodgepole pine plots, the results indicated that there was significant regularity in the spatial point-pattern of the surviving trees which indicates that competition has been a key driver of mortality and forest dynamics in these plots. Dead trees generally showed a clumping pattern in higher density patches. There were also significant bivariate relationships between live and dead trees, but the relationships differed by natural subregion. In the Lower Foothills plot there was significant attraction between live and dead tees which suggests mainly one-sided competition for light. In contrast, in the Upper Foothills plot, there was significant repulsion between live and dead trees which suggests two-sided competition for soil nutrients and soil moisture.

Development and validation of prediction equations for the assessment of muscle or fat mass using anthropometric measurements, serum creatinine level, and lifestyle factors among Korean adults

  • Lee, Gyeongsil;Chang, Jooyoung;Hwang, Seung-sik;Son, Joung Sik;Park, Sang Min
    • Nutrition Research and Practice
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    • v.15 no.1
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    • pp.95-105
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    • 2021
  • BACKGROUND/OBJECTIVES: The measurement of body composition, including muscle and fat mass, remains challenging in large epidemiological studies due to time constraint and cost when using accurate modalities. Therefore, this study aimed to develop and validate prediction equations according to sex to measure lean body mass (LBM), appendicular skeletal muscle mass (ASM), and body fat mass (BFM) using anthropometric measurement, serum creatinine level, and lifestyle factors as independent variables and dual-energy X-ray absorptiometry as the reference method. SUBJECTS/METHODS: A sample of the Korean general adult population (men: 7,599; women: 10,009) from the Korean National Health and Nutrition Examination Survey 2008-2011 was included in this study. The participants were divided into the derivation and validation groups via a random number generator (with a ratio of 70:30). The prediction equations were developed using a series of multivariable linear regressions and validated using the Bland-Altman plot and intraclass correlation coefficient (ICC). RESULTS: The initial and practical equations that included age, height, weight, and waist circumference had a different predictive ability for LBM (men: R2 = 0.85, standard error of estimate [SEE] = 2.7 kg; women: R2 = 0.78, SEE = 2.2 kg), ASM (men: R2 = 0.81, SEE = 1.6 kg; women: R2 = 0.71, SEE = 1.2 kg), and BFM (men: R2 = 0.74, SEE = 2.7 kg; women: R2 = 0.83, SEE = 2.2 kg) according to sex. Compared with the first prediction equation, the addition of other factors, including serum creatinine level, physical activity, smoking status, and alcohol use, resulted in an R2 that is higher by 0.01 and SEE that is lower by 0.1. CONCLUSIONS: All equations had low bias, moderate agreement based on the Bland-Altman plot, and high ICC, and this result showed that these equations can be further applied to other epidemiologic studies.

Kinetics and Mechanism of Nucleophilic Displacement Reactions of Y-Substituted Phenyl Benzoates with Z-Substituted Phenoxides

  • Min, Se-Won;Seo, Jin-A;Um, Ik-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.30 no.10
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    • pp.2403-2407
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    • 2009
  • Second-order rate constants have been measured for two series of nucleophilic displacement reactions, i.e., reactions of 4-nitrophenyl benzoate with Z-substituted phenoxides and those of Y-substituted phenyl benzoates (1a-h) with 4-chlorophenoxide (4-ClPhO–) in 80 mol% $H_2O$/20 mol% DMSO at 25.0 ${\pm}\;0.1\;{^{\circ}C}$. The Br$\phi$nsted-type plot for reactions of 4-nitrophenyl benzoate with Z-substituted phenoxides exhibits an excellent linear correlation with ${\beta}_{nuc}$ = 0.72. Reactions of 1a-h with 4-chlorophenoxide result in also a linear Br$\phi$nsted-type plot with ${\beta}_{lg}$ = –0.62, a typical ${\beta}_{lg}$ value for a concerted mechanism. The Hammett plots correlated with ${\sigma}^o\;and\;{\sigma}^-$ constants show many scattered points for reactions of 1a-h with 4-chlorophenoxide. In contrast, the corresponding Yukawa-Tsuno plot exhibits an excellent linear correlation with $\rho_Y$ = 2.26 and r = 0.53, indicating that expulsion of the leaving group occurs at the rate-determining step (RDS) either in a concerted mechanism or in a stepwise pathway. However, a stepwise mechanism with leaving group departure being the RDS is excluded since the leaving Y-substituted phenoxide is less basic and a better nucleofuge than the incoming 4-ClPh$O^-$. Thus, the reactions have been concluded to proceed through a concerted mechanism, in which bond formation between the nucleophile and electrophilic center is more advanced than expulsion of the leaving group in the transition state on the basis of the magnitude of ${\beta}_{nuc}\;and\;{\beta}_{lg}$ values.

Effects of Dietary Addition of Pegmatite on Body Weight Gain, Blood Characteristics, and Immunity and Carcass Grade for Fattening Hanwoo (거정석 첨가 급여가 비육한우의 체중 증가량, 혈액 성상, 면역성 및 도체등급에 미치는 영향)

  • Kim, Byung Ki;Ha, Jae Jung;YI, Jun Koo;Oh, Don Yep;Jung, Dae Jin;Hwang, Eun Gyeong;Choi, Seong Bok
    • The Korean Journal of Food And Nutrition
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    • v.30 no.4
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    • pp.703-709
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    • 2017
  • This study analyzed the effect on weight and average daily gain, carcass grade, and blood characteristics and immunity in case of dietary addition of pegmatite to Hanwoo steers. Relative to Hanwoo steers, initial body weight was $257.3{\pm}11.74kg$ (8-months old after birth). Forty-eight Hanwoo steers were fed for 24 months using random arrangement (4 treatment plots${\times}$4 heads${\times}$3 repeat). The treatment plot (498.75~500.82 kg) had higher weight during the early fattening stage compared with that of the control plot (474.37 kg) (p<0.05). Regarding total cholesterol of the blood, the value was similar to one during initiation of testing, but the value increased gradually based on the progress of fattening. In addition, the triglyceride was considerably low in T2~T3 plots with high addition of pegmatite during the late fattening stage compared with other treatment plots (p<0.05). This study revealed a tendency in the IgG content that represented immunity as the addition of pegmatite became higher (p>0.05). This study found that the treatment plot (441.55~452.10 kg) had higher carcass weight compared with the control plot (436.30 kg). However, this study revealed that the treatment plot (2.30~2.55 points) had higher carcass quantity grade compared with the control plot (2.11 points). This study found that the control plot (3.55 points) had higher carcass quality grade compared with the treatment plot (2.67~3.09 points) (p>0.05). With studies combined, it was determined that dietary addition of pegmatite to the feed as clay minerals in fattening Hanwoo steers would improve feed intake, body weight gain and carcass quantity grade.

Studies on the drought resistance of mulberry trees (상수의 내건성에 관한 연구)

  • 김문협
    • Journal of Sericultural and Entomological Science
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    • v.7
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    • pp.1-26
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    • 1967
  • In order to develop the standards for the measurement of drought resistance in mulberry trees (Morus genus) the varietal differences of drought resistance were measured for 30 mulberry varieties, and the relationships between the drought resistance and the histological and physiological characteristics of mulberry leaves were investigated. The results were summarized as follows; 1. It is reasonable to use the drought resistance ratio, expressed by D/D'*100, for the standard of drought resistance measurement for mulberry tree as a perennial tree crop. Where: D stands for growth amount(shoot length) in the plot of dry treatment, at the end of treatment. D' stands for an expected value of D which is expressed by B*C/A. Here, A is the growth amount of wet treatment plot at the beginning of treatment, B is the growth amount of dry treatment plot at the beginning of treatment, and C is the growth amount of wet treatment plot at the end of treatment. 2. The results obtained from the application of above formula showed that the varieties Cadaneo, Tahozosaeng, Yongchunchuwu, Kaeryang suban. and Kabsun were highly resistant to drought and the varieties Jukmok, Shipyung, Sobun, Kaeryangzosaeng shipmoonza and Chungagokyo were highly susceptible. 3. Among leaf tissues. the rate of inter-cellular space showed the highest relationship with drought resistance. The correlation coefficient calculated (r=0.4153) was highly significant. Other leaf tissues such as epidermis and palisade showed no significant correlations with drought resistance. 4. The size and density of stomata were correlated to drought resistance. That is: Correlation between drought resistance and size of stomata(length ${\times}$ width)......r= -0. 3253(signif. at 5%) density(No. of stomata/l$\textrm{mm}^2$......r= +0.5047(signif. at 1%)

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