• 자원환경지질
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• 제7권2호
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• pp.45-62
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• 1974

Scheelite deposits in Sangdong mine are divided into three parallel vein groups, namely "Hanging-wall vein" which is located in the lowest parts of Pungchon Limestone, "Main vein" the most productive vein replaced a intercalated limestone bed in Myobong slate, "Foot-wall veins" a group of several thin veins parallel to main vein in Myobong slate. Besides the above, there are many productive quartz veins imbedded in the above veins and Myobong slate. Molybdenite and wolframite are barren in the former three veins group but associates only in quartz veins. Both main vein and foot-wall veins show regular zonal distribution, quartz rich zone in the center, hornblende rich zone surrounding the quartz rich zone and diopside rich zone in the further outside to the marginal parts of the vein. According to the distribution of three main minerals, quartz, hornblende and diopside the main vein can be divided into three zones which are in turn grouped into 7 subzones by distinct mineral paragenesis. They are summerized as follows: A. Diopside rich zone: 1. garnet-diopside.fl.uorite subzone 2. diopside-zoisite-quartz subzone 3. diopside-plagioclase subzone B. Hornblende rich zone: 4. hornblende-diopside-quartz subzone 5. hornblende-quartz-chlorite subzone 6. hornblende-plagioclase-quartz.sphene subzone C. Quartz rich zone: 7. quartz-mica-chlorite subzone The foot-wall veins can similarly be divided by mineral paragenesis into 3 zones, 6 subzones as follows: A. diopside rich zone: 1. garnet-diopside-quartz.fl.uorite subzone 2. garnet-diopside-wollastonite subzone B. Hornblende rich zone: 3. quartz-hornblende-chlorite subzone 4. hornblende-plagioclase-quartz subzone 5. hornblende-diopside-quartz subzone C. Quartz rich zone: 6. quartz-mica subzone The hanging-wall vein is generally grouped into 9 subzones by the mineral paragenesis which show random distribution. They are as follows: 1. diopside-garnet-fluorite subzone 2. diopside-zoisite-quartz subzone 3. diopside-hornblende-quartz-fluorite subzone 4. wollastonite-garnet-diopside subzone 5. hornblende-chlorite-quartz subzone 6. quartz-plagioclase-hornblende-sphene subzone 7. quartz-biotite subzone 8. quartz-calcite subzone 9. calcite-altered minerals subzone Among many composing minerals, garnet specially shows characteristic distribution and optical properties. Anisotropic and euhedral grossularite is generally distributed in the hanging wall vein and lower parts of the main vein, whereas isotropic and anhedral andradite in the upper parts of the main vein. Plagioclase (anorthite) and sphene are distributed ony near the foot-wall side of the aboveveins. wollastonite is a characteristic mineral in upper parts of the hang-wall vein. Molybdenite is distributed in the upper parts of quartz veins and wolframite in lower parts of quartz veins.

• 한국결정성장학회지
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• 제4권3호
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• pp.315-324
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• 1994

고순도 규사 원료를 열처리하는 경우, 불순물로 포함되어 있는 미량성분이 quartz의 전이과정에 미치는 영향 및 전이 경로에 대하여 조사하였다. 미량성분의 영향을 조사한 결과, 규사 중의 미량성분 함량이 많아지면 cristobalite 생성량은 많아지며, quartz의 소멸온도 및 cristobalite의 생성온도는 낮아졌다. quartz의 전이경로를 조사한 결과 quartz $\rightarrow$ 천이비정질상 $\rightarrow$ melt (T) 및 quartz $\rightarrow$ 천이비정질상 $\rightarrow$ cristobalite $\rightarrow$ melt (C)의 경로가 항상 공존하며, 미량성분이 적은 경우는 T 경로가 우세하지만, 미량성분이 많은 경우는 C 경로가 우세한 것으로 규명되었다. 또한 XRD를 이용한 결정질 함량의 분석 결과로 부터 계산한 밀도와 pycnometer로 측정한 밀도를 비교한 결과 서로 일치하였다. 규사를 용융하여 석영유리를 제조하는 경우,특정온도에서 규사의 팽창 정도를 유추할 수 있을 것이다.

• 세라미스트
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• 제22권4호
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• pp.429-451
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• 2019

Quartz glass is a key material for making semiconductor process components because of its purity, low thermal expansion, high UV transmittance and relatively low cost. Domestic quartz glass has a market worth about 500 billion won in 2018, and the market power of Japanese materials is very high. Quartz glass for semiconductor process can be divided into general process and exposure. For general process, molten quartz glass is mainly used, but synthetic quartz glass with higher purity is preferred. Synthetic quartz glass is used as the photomask for the exposure process. Recently, as semiconductors started the sub-nm process, the transition from the transmission type using ArF ultraviolet (194 nm) to the reflection type using EUV ultraviolet (13.5 nm) began. Therefore, the characteristics required for the synthetic quartz glass substrates used so far are also rapidly changing. This article summarizes the current technical trends of quartz glass and recent technical issues. Lastly, the present situation and development possibility of quartz glass technology in Korea were diagnosed.

• 자원환경지질
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• 제15권4호
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• pp.221-233
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• 1982

Ssangjeon tungsten ore deposits is a complex pegmatite deposits embedded along the contact between pre-Cambrian Buncheon granite gneiss and amphibolite. This pegmatite vein developed 2 km along the strike and thickness varies from 10m to 40m. Mineral constituent of the normal pegmatite are quartz, microcline, plagioclase, muscovite, biotite, tourmaline and garnet. The vein paragenesis is complicated by repeated deposition of quartz but three distinct depositional stage can be recognized. Quartz A stage is the stage of the earliest milky white quartz deposition as a rock forming mineral of normal pegmatite. Quartz B stage is the stage of gray to dark gray quartz replace earlier formed normal pegmatite minerals. Quartz C stage is the stage of latest white translucent massive quartz replace quartz A and B. Tungsten ore minerals and other sulfide minerals were precipitated during quartz B stage. Ore minerals are ferberite and scheelite. Minor amount of molybdenite, arsenopyrite, pyrrhotite, pyrite, chalcopyrite, sphalerite, galena, pentlandite, bismuthinite, native bismuth and marcasite accompanied. Fluid inclusion in quartz A and B are gaseous inclusions and liquid inclusions are contained in quartz C as a primary inclusions. Salinity of inclusions in quartz A and B ranges from 4.5 to 9.5 wt. % and from 5.1 to 6.0 wt. % equivalent NaCl respectively. Homogenization temperature of quartz A; quartz B and quartz C ranges from 415 to $465^{\circ}C$, from 397 to $441^{\circ}C$ and from 278 to $357^{\circ}C$. $CO_2$ content of the ore fluid increased at the ends of quartz B stage.

• 한국세라믹학회지
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• 제21권3호
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• pp.209-216
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• 1984

The influence of the particle size of quartz and the change of cooling rate to the strength of conventional triaxial porcelain was studied, . The results indicate that 1. The residual quartz content was increased by particle size increasing. And the strength was increased by increas-ing residual quartz content which increased the total stress in the specimen. But the influence of residual quartz was lessened by the extent of crack between quartz particle and glass matrix 2. In order to increase the strength of the body fast cooling is suitable to small quartz particle and slow cooling is suitable to large quartz particle.

• 공학논문집
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• 제6권2호
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• pp.141-151
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• 2004

금합금계 매몰재 재료의 물리적 특성은 각각 열팽창계수과 압축강도, 입도 분포에 크게 좌우된다. 일반적으로 금합금계 매몰재는 cristobalite와 quartz, plaster로 주성분을 구성하고 있다. 그리고 cristobalite와 quartz의 열팽창계수는 $2.6\times10^{-6}/^\circC$, $2.32\times10^{-6}/^\circC$, 로 이 두 재료의 혼합비가 매몰재의 열팽창 계수를 변화시키는 매우 중요한 역할을 하고 있다. 현재 국내에서는 금합금계 매몰재는 전량 수입에 의존하고 있고 그 시장 수요 또한 대단히 크다. 따라서 균일한 입도 분포를 가지는 cristobalite와 quartz의 개발과 주조금속의 열팽창과 냉각에 따른 수축력을 고려한 열팽창계수를 가지면서 매몰재의 요구강도에 적합한 압축강도를 가지는 금합금계 매몰재의 개발이 필수적이다. 따라서 본 연구에서는 먼저 균일한 입도를 갖는 cristobalite와 quartz 분체의 제조와 cristobalite와 quartz의 혼합비에 따른 열팽창계수와 압축강도를 비교 분석하였다. 본 연구의 결과로 표면이 매끄럽고 균일한 입도 분포를 갖는 cristobalite와 quartz를 제조하였으며, cristobalite와 quartz의 혼합비가 45:25가 열팽창계수와 압축강도에서 매몰재가 요구하는 조건을 만족하였다.

• 한국산업융합학회 논문집
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• 제10권3호
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• pp.179-185
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• 2007

Quartz glass are used in semiconductor industries as the reaction furnace, wafer carrier and accessaries. During the process the quartz glass received compression by direct contact with other quartz glass ware and metal as the form of weight itself and vacuum pressure and fatigue by vibrations caused by process. Even as the other ceramic materials quartz glass have high compressive strength but often there happened crack and breakage of quartz glass resulted in a great damage in the process. In this paper investigation will be carried out on fracture behavior of quartz glass under local load to give guideline to prevent unintended fracture of quartz glass.

• 한국세라믹학회지
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• 제34권7호
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• pp.713-721
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• 1997

Molecular dynamic (MD) simulations with new interatomic potential function including the covalent bond were performed on the phase transition of $\alpha$-quartz-type GeO2 under high pressure. The optimized crystal structure and the pressure dependence of the lattice constant showed higher reproducibility than the previous models and were in very good agreement with the experimental data. A phase transition of $\alpha$-quartz and $\alpha$-quartz-type GeO2 by simulation was found approximately 24 GPa and 6-7 GPa, respectively. This phase transition involved an abrupt volume shrinkage and showed 4-6 coordination mixed structure with the increasing in the coordination number of cation.

• 세라미스트
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• 제22권4호
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• pp.452-463
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• 2019

A quartz glass crucible is the essential material for manufacturing silicon ingots such as semiconductors and solar cells. Quartz glass crucibles for semiconductors and solar cells are made similar, but differ in surface purity, structure and durability. Recently, ultra high purity synthetic glass crucibles for semiconductors have become more important due to foreign problems. In Korea, it has succeeded in producing 28-inch quartz glass crucibles through the past 10 years. However, 32-inch synthetic quartz glass for the production of silicon ingots for semiconductors is not up to the level of advanced technology, and the technology gap is expected to be 2 to 3 years. In order to overcome these technological gaps and localize synthetic quartz glass ware, close cooperation between production companies and demand companies and localization of synthetic quartz glass powder must also be made. In addition, if government support can be added, faster results can be expected.

• Nuclear Engineering and Technology
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• 제45권1호
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• pp.53-60
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• 2013

Bentonite is generally used as a buffer material in high-level radioactive waste disposal facilities and consists of 50% quartz by weight. Quartz strongly affects the behavior of bentonite over very long periods. For this reason, quartz dissolution experiment was performed under high-pressure and high-alkalinity conditions based on the conditions found in a high-level radioactive waste disposal facility located deep underground. In this study, two quartz dissolution experiments were conducted on 1) quartz beads under low-pressure and high-alkalinity conditions and 2) a single quartz crystal under high-pressure and high-alkalinity conditions. Following the experiments, a confocal laser scanning microscope (CLSM) was used to observe the surfaces of experimental samples. Numerical analyses using the finite element method (FEM) were also performed to quantify the deformation of contact area. Quartz dissolution was observed in both experiments. This deformation was due to a concentrated compressive stress field, as indicated by the quartz deformation of the contact area through the FEM analysis. According to the numerical results, a high compressive stress field acted upon the neighboring contact area, which showed a rapid dissolution rate compared to other areas of the sample.