• Analytical Science and Technology
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• v.25 no.1
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• pp.33-38
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• 2012

Despite the importance of chloride binding, it is very difficult to measure the binding capacity, in particular, for the concrete body in an existing structure: in fact, the measurement procedure for chloride binding is much influenced by the environmental condition such as temperature, fineness of sample and pore water extraction techniques. The present study concerns the quantification of the binding capacity of chloride ions in concrete using the X-ray diffraction (XRD) technique. Once the binding isotherm of chlorides was determined by the Langmuir isotherm, as a function of the W/C, curing age and binder type, the generation of bound chlorides (i.e. Friedel's salt) was simultaneously ensured by the XRD technique. The amount of bound chloride was then determined by analyzing the peak intensity for the bound chlorides in the XRD curve. It was found that an increase in the curing age and a decrease in the W/C resulted in an increase in the binding capacity.

• Journal of agriculture & life science
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• v.46 no.3
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• pp.47-58
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• 2012

This study was carried out to develop assessment model for the optimal site prediction of Dendropanax morbifera, Evergreen broad-leaved trees in warm temperate zone according to climate change. It was created criterion for assessment model of the optimal site prediction by quantification method to possible analysis of quantitative and qualitative data, through study relationship between growth of tree and site environmental factors. A program of the optimal site prediction was developed using program version 3.2, an Avenue and Dialog Designer tool of ESRI as GIS(geographic information system) engine. Developed program applied to test accuracy of the optimal site prediction in study area of Wando, Jeollanam-do, having a various evergreen broad-leaved trees of warm temperate zone. In the results from analysis of the optimal site prediction on Dendropanax morbifera, the characteristics of optimal site were analyzed site environmental features with 401~500m of altitude, $15^{\circ}$ of slope, hillside of local topography, alluvium of deposit type, convex of slope type and south of aspect. The mapping area per grade of the optimal site prediction in the Dendropanax morbifera showed 1,487.2ha(25.4%) of class I, 1,020.3ha(17.4%) of class II, 2,231.8ha(38.2%) of class III and 1,110.5ha(19.0%) of class IV.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.4 no.4
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• pp.1-11
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• 2001

This study was carried out to analyze the characteristics of forest environmental and stream morphological factors by using the quantification theory(I) for evaluation of the watershed stability. Present annual mean sediment yield of erosion control dams were investigated in 167 sites of erosion control dam constructed during 1986 to 1999 in Gyeongbuk. The results obtained from this study were summarized as follows; According to the coefficients of partial correlation, each factor affecting to sediment was shown in order of gravel contents, number of first streams order, number of total streams, length of total streams, forest type, length of main stream, parent rock, stand age, soil texture, stream order, slope gradient, soil depth and aspect. Descriptions of class I were as follow; Igneous rock of parent rock, hardwood stands of forest type, less than 20 year of stand age, less than 30cm of soil depth, sandy clay loam of soil texture, more than 41% of gravel contents, south~east of aspect, 2,501~3,500m of length of main stream, 21~25 of number of total streams, 5,501~10,000m of length of total streams, 3 or more than 4 of stream order, more than 16 of number of first stream orders and more than $31^{\circ}$ of slope gradient. Descriptions of class II were as follow; Metamorphic rock of parent rock, coniferous stands of forest type, more than 25 year of stand age, 31~40cm of soil depth, silt loam of soil texture, 11~20% of gravel contents, north~west of aspect, 2,501~3,500m of length of main stream, 16~20 of number of total streams, 3,501~5,500m of length of total streams, 3 of stream order, 11~15 of number of first stream orders and more than $31^{\circ}$ of slope gradient. Descriptions of class III were as follow; Sedimentary rock of parent rock, mixed stands of forest type, more than 25 year of stand age, more than 51cm of soil depth, silty clay loam of soil texture, less than 10% of gravel contents, south~west of aspect, less than 500m of length of main stream, less than 5 of number of total streams, less than 1,000m of length of total streams, less than 1 of stream order, less than 2 of number of first stream orders and less than $25^{\circ}$ of slope gradient. The prediction method of suitable site for erosion control dam divided into class I, II, and III for the convenience of use. The score of class I evaluated as a very unstable area was more than 8.4494. A score of class II was 8.4493 to 6.0452, it was evaluated as a moderate stable area, and class III was less than 6.0541, it was evaluated as a very stable area.

• Journal of Environmental Science International
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• v.17 no.8
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• pp.891-898
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• 2008

This study was conducted to develop the effects of site environmental factors on estimation of site index function for Chamaecyparis obtusa Endlicher stands. We derived nonlinear growth equation and the draw site index curves by applying this estimated equation. This study with Chapman-Richards function showed significant P-value which was less then 0.0001 and $R^2$ value 0.5947. This study was conducted to develop the feasible site index equation of Chamaecyparis obtusa Endlicher. For the table, the data of 82 sample areas that were thought to be without errors among the data of Chamaecyparis obtusa Endlicher sample area located on the value-oriented forest location chart were used and estimated. After analyzing the quantification method I based on 13 environmental factors to develop the score table for the site-index estimation of Chamaecyparis obtusa Endlicher, $R^2$ value of the model was 0.7555. It has been analyzed that the scope value of Soil moisture in horizon A was 7.5045, that of total soil depth was 6.3896, that of topography was 5.3471, that of slope was 4.7000 and that of aspect was 3.2038. After analyzing the partial correlation to examine the factors that affected most the site-index of Chamaecyparis obtusa Endlicher, it has been noted that the partial correlation of climatic zone was 0.4987, which was highest, and it was followed by Soil moisture in horizon A (0.4592), slope (0.4537), topography (0.3299) and total soil depth (0.1035). As a result of conducting the significance test for partial correlation, it has been found that topography, climatic zone, parent rock, slope, altitude, aspect, Soil moisture in horizon A, soil hardness in horizon A and total soil depth were recognized significant with 1% of significance level and sedimentary type and soil texture in horizon A were recognized significant with 5% of significance level.

• Korean Journal of Environment and Ecology
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• v.20 no.4
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• pp.415-424
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• 2006

This study was carried out to analyze the characteristics of forest watershed factors by using the quantification theory(I) for evaluation and prediction of the failure hazard area. Present $sediment(m^3/yr/ha)$ of erosion control dams were investigated in 95 sites of erosion control dam constructed during 1986 to 1999 in Gyeongnam province. The results obtained from this study were summarized as follows; General condition of class I(Very hazard area) were as follow; Igneous rock in parent rock, coniferous in forest type, below 20year in stand age, below 30cm in soil depth, SCL in soil texture, $31{\sim}40%$ in gravel contents, $S{\sim}E$ in aspect, $2,501{\sim}3,600m$ in length of main stream, $26{\sim}30$ in number of total streams, $6,601{\sim}10,000m$ in length of total streams, over 3 in stream order, over 16 in number of first streams order and over $31^{\circ}$ of slope gradient. General condition of class IIl(hazard area) were as follow; Metamorphic rock in parent rock, hardwood in forest type, over $21{\sim}24year$ in stand age, $31{\sim}40cm$ in soil depth, SiCL or SCL in soil texture, $11{\sim}20%$ in gravel contents, $S{\sim}W$ in aspect, $1,501{\sim}2,600m$ in length of main stream, $6{\sim}10$ in number of total streams, $3,501{\sim}5,500m$ in length of total streams, 2 in stream order, $6{\sim}10$ in number of first streams order and over $31^{\circ}$ of slope gradient. General condition of class III(Un hazard area) were as follow; Sedimentary rock in parent rock, mixed in forest type, over 25year in stand age, $41{\sim}50cm$ in soil depth, SiCL in soil texture, below 10% in gravel contents, $N{\sim}W$ in aspect, below 500m in length of main stream, below 5 in number of total streams, below 1,000m in length of total treams, below 1 in stream order, below 2 in number of first streams order and below $25^{\circ}$ of slope gradient. The prediction method of suitable for failure hazard area divided into class I, II, and III for the convenience of use. The score of class I evaluated as a very hazard area was over 4.8052. A score of class II was 4.8051 to 2.5602, it was evaluated as a hazard area, and class III was below 2.5601, it was evaluated as a un hazard area.

• Korean Journal of Environmental Agriculture
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• v.31 no.2
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• pp.157-163
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• 2012

BACKGROUND: For the safety of imported agricultural products, the study was conducted to develop the analytical method of unregistered pesticides in domestic. The analytical method of 6 pesticides, chlorthal-dimethyl, clomeprop, diflufenican, hexachlorobenzene, picolinafen, and propyzamide, for a fast multi-residue analysis were established for two different type crops, orange and brown rice by GC-ECD and confirmed by mass spectrometry. METHODS AND RESULTS: The analytical method was evaluated to limit of quantification, linearity and recoveries. The crop samples were extracted with acetonitrile and performed cleanup by liquid-liquid partition and Florisil SPE to remove co-extracted matrix. The extracted samples were analyzed by GC-ECD with good sensitivity and selectivity of the method. The limits of quantification (LOQ) range of the method with S/N ratio of 10 was 0.02~0.05 mg/kg for orange and brown rice. The linearity for targeted pesticides were $R^2$ >0.999 at the levels ranged from 0.05 to 10.0 mg/kg. The average recoveries ranged from 74.4% to 110.3% with the percentage of coefficient variation in the range 0.2~8.8% at two different spiking levels (0.02 mg/kg and 0.2 mg/kg, 0.05 mg/kg and 0.5 mg/kg) in brown rice. And the average recoveries ranged from 77.8% to 118.4% with the percentage of coefficient variation in the range 0.2~6.6% at two different spiking levels (0.02 mg/kg and 0.2 mg/kg, 0.05 mg/kg and 0.5 mg/kg) in orange. Final determination was by gas chromatography/mass spectrometry/selected ion monitoring (GC/MS/SIM) to identify the targeted pesticides. CONCLUSION: As a result, this developed analytical method can be used as an official method for imported agricultural products.

• Journal of Korean Society of Transportation
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• v.28 no.3
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• pp.39-49
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• 2010

Provision of in-vehicle warning information is of keen interest since it can be effectively used to prevent traffic accident on the road. This study evaluates the effectiveness of information provision modalities based on kansei engineering. Various warning information scenarios using different modalities are devised for the evaluation. Statistical data analysis techniques including factor analysis, correlation analysis, and the general linear model are used to assess the user's affect for information modalities. The evaluation result shows that the provision of visual information consisted of 'text and pictogram' leads to higher understandability. The combination of beep sound and voice message' was identified as a more effective modality for auditory warning. In addition, the red color for the blinking warning signal was preferred by users.

• Journal of Acupuncture Research
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• v.23 no.5
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• pp.69-77
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• 2006

Background : Mesenchymal stem cells (MSCs) are present in most of the tissue matrix, taking part in their regeneration when injury or damage occurs. The aim of this study was to investigate the presence of cells with pluripotential characteristics in human subchondral bone and the capacity of these cells to differentiate to osteoblast. Methods : Human subchondral bone were digested with collagenase. Isolated cells were cultured with a-MEM, 15% FBS, 10-8M dexamethasone and 50 ng/mL ascoric acid. Cells from 0 day(isolated cells), 7 day (first subculture) and 14 days (third subculture) were used to carry out phenotypic characterization experiments flowcytometry analysis with 11 monoclonal antibodies) and osteogenic differentiation experiments. Osteogenic differentiation of cells was assessment by quantification of bone extracellular matrix components by following analysis: alkaline phosphatase(ALP) stains to detect ALP activity, RT-PCR and western blot to detect osteocalcin (OCN), osteopontin (OPN) and type I collagen(Col I), and Alizarin red stains to detect calcium deposition. Results : Flowcytometry analyses showed that in our population more than 98% of cells were positive for MSC markers: SH-2(CD105, 99%), CD29 (95%), CD73 (95%). Cells were negative for hematopoietic markers (CD11b, CD34, and CD45). Furthermore, cells showed positive stain to multipotent markers such as CDl17 (c-kit) (15.1%), and CD166 (74.9%), and cell adhesion molecules such as CD54 (78.1%) and CD106 (63.5%). The osteogenic specific marker analyses showed that the culture of these cells for 7 and 14 days stimulates ALP, OCN, OPN and Col I synthesis by RT-PCR and Western blot analysis. Also, after 14 days in the culture of MSCs induces mineralization by Arizarin red stain. Conclusion : In this work, we demonstrated a new and efficient method for osteoblastic differentiation of human subchondral bone stem cells. As MSCs takes part in reparative processes of adult tissues, these cells could play an important role in osteogenesis.

• Journal of Climate Change Research
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• v.6 no.4
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• pp.319-330
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• 2015

This study was carried out to predict the optimal growth site and estimate carbon stocks of Quercus acuta, evergreen broad-leaved trees in warm temperate zone according to climate change. The criterion for the optimal site prediction was created by quantification method with quantitative and qualitative data, collected from growth factors of stands and environmental factors of survey sites of 42 plots in Q. acuta by study relationship between growth of tree and site environmental factors. A program for the optimal site prediction was developed by using GIS engine tools. To prediction of the suitable growth site of Quercus acuta, developed program in this study applied to Wando in Jeollanam-do, distributing a various evergreen bread-leaved trees of warm temperate zone. In the results from analysis of the optimal site prediction on Q. acuta, the characteristics of the optimal site showed as follows; site environmental features of class I (the best site class for Q. acuta) was defined as 401 ~ 500 m of altitude, $21{\sim}25^{\circ}$ of slope with above hillside, residual of deposit convex of slope type with west of aspect. The area and carbon stocks of optimal site prediction by class for Q. acuta in classI showed 147.1 ha (2.5%), total 316.5 tC/ha, total $1,161tCO_2/ha/yr$ of class I, 2,703.5 ha (46.3%), total 5,817.4 tC/ha, total $21,331tCO_2/ha/yr$ of class II, 2,845.5 ha (48.6%), total 6,123.0 tC/ha, total $2,845.5tCO_2/ha/yr$ of class III and 153.7 ha (2.6%), total 330.7 tC/ha, total $1,213.7tCO_2/ha/yr$ of class IV.

• Analytical Science and Technology
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• v.21 no.6
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• pp.518-525
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• 2008

Mandipropamid is a new mandelamide-type fungicide to control foliar Oomycete pathogens in some vegetables. An analytical method was developed to determine mandipropamid residues in agricultural commodities using high-performance liquid chromatography (HPLC) and liquid chromatography/mass spectrometry (LC/MS). Mandipropamid was extracted with methanol from grape, tomato, green pepper, Chinese cabbage and potato samples. The extract was diluted with saturated sodium chloride solution and distilled water, and dichloromethane partition was followed to recover the mandipropamid from the aqueous phase. Florisil column chromatography was employed to further remove interfering co-extractives prior to HPLC analysis. Reverse-phased HPLC was successfully applied to determine mandipropamid in sample extracts with the detection at its ${\lambda}_{max}$ (223 nm). Overall recoveries of mandipropamid from fortified samples averaged $99.8{\pm}1.7$ (n=6), $89.3{\pm}5.3$ (n=6), $98.7{\pm}2.2$ (n=6), $99.7{\pm}6.8$ (n=6) and $91.1{\pm}3.1$ (n=6) for grape, tomato, green pepper, Chinese cabbage and potato, respectively. Limit of quantification of the method was 0.02~0.04 mg/kg for all samples. A LC/mass spectrometry with selected-ion monitoring was also provided to confirm the suspected residue. The proposed method was reproducible and sensitive enough to determine the terminal residue of mandipropamid in agricultural commodities.