• Title/Summary/Keyword: pyrolytic

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Thermal Analysis of Satellite Panel Using Carbon Composites (탄소복합재를 이용한 위성 패널의 열해석)

  • Jun, Hyoung-Yoll;Kim, Jung-Hoon;Park, Jong-Seok;Park, Kun-Joo
    • Aerospace Engineering and Technology
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    • v.10 no.2
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    • pp.114-120
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    • 2011
  • Thermal control of satellite is mainly based on passive ways, such as the radiator made of aluminum honeycomb core with aluminum skins and OSR (Optical Solar Reflector). Additionally, for the thermal control of high dissipation unit, the aluminum doubler and heat pipe are utilized. Recently, efforts to find advanced thermal materials have been carried out to enhance heat rejection capability without increasing satellite size, weight and cost. This paper handles the carbon composites have high thermal conductivity with light weigh and have been considered as future thermal control materials to replace aluminum based radiator and doubler. Thermal analysis of satellite panel using APG(Annealed Pyrolytic Graphite) and carbon-carbon composites were performed and temperature contours were compared with the conventional thermal control methods.

Electrochemical Characteristics of Si/PC/CNF/PC Composite for Anode Material of Lithium ion Battery (이차전지 음극활물질 Si/PC/CNF/PC 복합 소재의 전기화학적 특성)

  • Jeon, Do-Man;Na, Byung-Ki;Rhee, Young-Woo
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.798-803
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    • 2018
  • In order to use Si as an anode material for lithium-ion battery, the particle size was controlled to less than $0.5{\mu}m$ and carbon was coated on the surface with the thickness less than 10 nm. The carbon fiber was grown on the Si surface with 50~150 wt%, and the carbon coating was carried out once again. The Si composite material was mixed with dissimilar metals to increase the conductivity, and graphite was mixed to improve cyclic life characteristics. The physical and electrochemical characteristics of composite materials were measured with XRD, SEM, TEM and coin cell. The discharge capacity of Si/PC/CNF/PC was lower than that of Si/PC (Pyrolytic Carbon)/CNF (Carbon Nano Fiber). However, the cyclic life of Si/PC/CNF/PC was higher. Initial discharge capacity of 1512 mA h g-1 at 0.2 C rate and initial efficiency of 78% were shown. It also showed a capacity retention of 94% in 10 cycles.

Characterization of Low-Temperature Pyrolysis and Separation of Cr, Cu and As Compounds of CCA-treated Wood (CCA (Chromated Copper Arsenate) 처리 목재의 저온 열분해와 CCA 유효 성분분리 특성)

  • Lim, Kie-Pyo;Lee, Jong-Tak;Bum, Jung-Won
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.1
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    • pp.73-80
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    • 2007
  • This study was carried out to separate the heavy toxic metals in eco-building materials by low-temperature pyrolysis, especially arsenic (As) compounds in CCA wood preservative as a solid in char. The pyrolysis was carried out to heat the CCA-treated Hemlock at $280^{\circ}C$, $300^{\circ}C$, $320^{\circ}C$, and $340^{\circ}C$ for 60 mins. Laboratory scale pyrolyzer composed of [preheater$\rightarrow$pyrolyzer$\rightarrow$1st water scrubber$\rightarrow$2nd bubbling flask with 1% $HNO_3$ solution$\rightarrow$vent], and was operated to absorb the volatile metal compound particulates at the primary water scrubber and the secondary nitric acid bubbling flask with cooling condenser of $4^{\circ}C$ under nitrogen stream of 20 mL/min flow rate. And the contents of copper, chromium and arsenic compounds in its pyrolysis such as carbonized CCA treated wood, 1st washing and 2nd washing liquors as well as its raw materials, were determined using ICP-AES. The results are as follows : 1. The yield of char in low-temperature pyrolysis reached about 50 percentage similar to the result of common pyrolytic process. 2. The higher the pyrolytic temperature was, the more the volatiles of CCA, and in particular, the arsenic compounds were to be further more volatile above $320^{\circ}C$, even though the more repetitive and sequential monitorings were necessary. 3. More than 85 percentage of CCA in CCA-treated wood was left in char in such low-temperature pyrolytic condition at $300^{\circ}C$. 4. Washing system for absorption of volatile CCA in this experiment required much more contacting time between volatile gases and water to prevent the loss of CCA compounds, especially the loss of arsenic compound. 5. Therefore, more complete recovery of CCA components in CCA-treated wood required the lower temperature than $320^{\circ}C$, and the longer contacting time of volatile gases and water needed the special washing and recovery system to separate the toxic and volatile arsenic compounds in vent gases.

A Study on the Pyrolysis of Coumarin (I) Identification of Coumarin Pyrolyzates in a Stream of Nitrogen at $500^{\circ}C$ (쿠마린의 열분해에 관한 연구 (제1보) -질소기류, $500^{\circ}C$에서 쿠마린의 열분해산물 동정-)

  • Park, Jun-Young;Kim, Ok-Chan
    • Journal of the Korean Society of Tobacco Science
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    • v.4 no.2
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    • pp.63-66
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    • 1982
  • Coumarin was pyrolyzed at $500^{\circ}C$ in a stream of nitrogen. The pyrolyzates of coumarin were adsorbed on the activated charcoal and then eluded by carbon disulfide. The eluted pyrolyzates were identified using a gas chromatography/mass spectrometry. Benzene, toluene, phenylacetylene, styrene, benzofuran and naphthalene were detected from the pyrolyzates of coumarin on the basis of their mass spectra. The pyrolytic mechanism of coumarin was also discussed.

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Effect of Substrate Temperature on Polycrystalline Silicon Film Deposited on Al Layer (Al 박막을 이용한 다결정 Si 박막의 제조에서 기판온도 영향 연구)

  • Ahn, Kyung Min;Kang, Seung Mo;Ahn, Byung Tae
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.96.2-96.2
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    • 2010
  • The surface morphology and structural properties of polycrystalline silicon (poly-Si) films made in-situ aluminum induced crystallization at various substrate temperature (300~600) was investigated. Silicon films were deposited by hot-wire chemical vapor deposition (HWCVD), as the catalytic or pyrolytic decomposition of precursor gases SiH4 occurs only on the surface of the heated wire. Aluminum films were deposited by DC magnetron sputtering at room temperature. continuous poly-Si films were achieved at low temperature. from cross-section TEM analyses, It was confirmed that poly-Si above $450^{\circ}C$ was successfully grown on and poly-Si films had (111) preferred orientation. As substrate temperature increases, Si(111)/Si(220) ratio was decreased. The electrical properties of poly-Si film were investigated by Hall effect measurement. Poly-Si film was p-type by Al and resistivity and hall effect mobility was affected by substrate temperature.

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Fundamental Pyrolysis Studies with Molten Metal Fluidized Bed System (Molten metal 유동층을 이용한 열분해 기초 실험)

  • Moon, Jihong;Jeon, Suji;Hwang, Jungho;Bang, Byungryeul;Lee, Uendo
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.161-164
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    • 2014
  • The feasibility of a molten metal as a bed material of a pyrolysis system was investigated. The molten metal has various advantages such as high thermal conductivity, wide operating range and low viscosity. Tin was selected since its physical characteristics are suitable for the purpose. As a results, it was found that pyrolytic oil yield and reaction rate were significantly enhanced with the molten Tin. In addition, oxygen component of the product oil was decreased due to Tin oxidation.

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Construction of UHV Scanning Tunneling Microscope (초고진공용 주사형 터널링 현미경의 제작)

  • Koo, Ja-Yong;Kim, Dal-Hyun;Park, Hae-Won;Kim, Goo-Young;Lee, Se-Kyung
    • Journal of the Korean Society for Nondestructive Testing
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    • v.14 no.3
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    • pp.157-171
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    • 1994
  • A scanning tunneling microscope has been built, which can resolve atomic arrangements of conductors and semiconductors in ultra high vacuum below $10^{-11}$ Torr. Its background and operational principles are reviewed and the guide lines in building the scanning tunneling microscope are shown. The results of measurements for highly oriented pyrolytic graphite and Si(111) surface are presented.

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Chemical Vapor Deposition of Silicon Carbide by the Pyrolysis of Methylchlorosilanes (메틸클로로실란류의 열분해를 이용한 탄화규소의 화학증착)

  • 최병진;박동원;조미자;김대룡
    • Journal of the Korean Ceramic Society
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    • v.32 no.4
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    • pp.489-497
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    • 1995
  • The DDS((CH3)2SiCl2)+H2 gas mixture, where C atoms exist in excess in the molecules, was used for chemical vapor deposition of SiC in order to prevent codeposition of free Si in MTS(Ch3SiCl3)+H2 system. The deposition rate was more rapid than MTS, however differ from that of MTS, it decreased after shwoing a maximum at 140$0^{\circ}C$. The stoichiometry was highly improved by using the DDS as a precursor, although there exist a little pyrolytic C at 150$0^{\circ}C$. The preferred orientation was (220) in MTS, however, it changed to (111) in DDS. The microstructure of the layer deposited at lower temperature were dense, however it grew coarse with the increase in the temperature.

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Nucleation of CVD Diamond on Various Substrate Materials

  • Fukunaga, O.;Qiao, Xin;Ma, Yuefei;Shinoda, N.;Yui, K.;Hirai, H.;Tsurumi, T.;Ohashi, N.
    • The Korean Journal of Ceramics
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    • v.2 no.4
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    • pp.184-187
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    • 1996
  • Diamod nucleation by mw assisted CVD was examined various conditions namely, (1) diamond nucleation on variour substrate materials, such as Si, cubic BN, pyrolytic BN and AIN, (2) AST(Activated species transport) method which promote nucleation of diamond on single crystal and polycrystalline alumina substrate was developed. (3) Effect of bias enhancement of nucleation on single crystalline Si was examined, and finally (4) DST (Double step treatment) method was developed to enhance diamond nucleation on Ni. In this method, we separated carbon diffusing process into Ni, carbon precipitating process from the inside of Ni and diamond precipitation process.

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Fabrication of Micro Carbon Structures and Patterns with Laser-assisted Chemical Vapor Deposition (레이저 국소증착을 통한 미세 탄소구조물 및 패턴 제조)

  • 정성호;김진범;이선규;이종현
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.05a
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    • pp.914-917
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    • 2002
  • Fabrication of micro carbon structures and patterns using laser-assisted chemical vapor deposition is studied. Argon ion laser and ethylene were used to grow micro carbon rod through pyrolytic decomposition of the reaction gas. The influence of reaction gas pressure and incident laser power on the diameter and growth rate of the micro carbon rod was experimentally investigated. The diameter of micro carbon rods increases linearly with respect to the laser power but is almost independent of the reaction gas pressure. Growth rate of the rod changes little with gas pressure when the laser power remains below 1W. When the carbon rod was grown at near threshold laser power, a very smooth surface is obtained on the rod. By continuously moving the focusing lens in the direction of growth, a micro carbon rod with a diameter of 28 ${\mu}{\textrm}{m}$ and aspect ratio of 100 was fabricated.

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