• 한국연소학회:학술대회논문집
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• 2001.06a
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• pp.60-66
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• 2001

Combustion using pure oxygen instead of air is an energy saving technology that can increase thermal efficiency by the improvement of burning rate and ultra high temperature flame, being used on the industrial spot. But information about it is not so enough yet. Flame figure, temperature distribution and emission concentration were measured with oxygen excess ratio and swirl number in a turbulent diffusion flame to investigate the combustion characteristics using pure oxygen. The results showed that flame figure became different as long as oxygen excess ratio varied and that concentration of NO and CO increased suddenly around ${\lambda}$=1.5.

• 한국연소학회:학술대회논문집
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• 2006.04a
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• pp.149-156
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• 2006

Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

• Journal of the Korean Society of Combustion
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• v.11 no.1
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• pp.19-26
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• 2006

Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.2
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• pp.171-181
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• 2007

Blending effects of hydrogen and water vapor on flame structure and NOx emission behavior are numerically studied with detailed chemistry in methane-air counterflow diffusion flames. The composition of fuel is systematically changed from pure methane and pure hydrogen to the blending fuels of methane-hydrogen-water vapor through the molar addition of $H_2O$. Flame structure is changed considerably for hydrogen-blending methane flames and hydrogen-blending methane flames diluted with water vapor in comparison to pure methane flame. These complicated changes of flame structures also affect NOx emission behavior considerably. The changes of thermal NO and Fenimore NO are analyzed for various combinations of the fuel composition. Importantly contributing reaction steps to thermal NO and Fenimore NO are addressed in pure methane, hydrogen-blending methane flames, and hydrogen-blending methane flames diluted with water vapor.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.255-260
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• 2003

Characteristics of methane jet diffusion flames using pure oxygen with recirculating $CO_{2}$ as an oxidizer were investigated experimentally. A coflow burner was considered, and the diameter of confinement was larger than that of the coflow. No stabilized flame could be observed over 75% of $CO_{2}$ volume percent. A comparison between air and $O_{2}/CO_{2}$ mixture was made in terms of liftoff velocity, flame liftoff height, and blowout conditions. As results, more stable flame could be observed with $O_{2}/CO_{2}$ mixture for the case of having similar flame temperature.

• Applied Chemistry for Engineering
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• v.27 no.6
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• pp.577-582
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• 2016

In this study, we compared and analyzed the flame retardancy and mechanical properties of three different rigid polyurethane foams (RPUF) containing noble non-halogen phosphorus flame retardant (BHP-RPUF) or halogen-phosphorus flame retardant (TCPP-RPUF) or no flame retardant material (Pure-RPUF). The noble phosphorus-based flame retardant, bis(3-(3-hydroxypropoxy)propyl) phenyl phosphate (BHP), was synthesized by the reaction between disodium phenyl phosphate and 3-chloro-1-propanol. Through universal testing machine (UTM) experiments, the compressive strength of BHP-RPUF was similar to that of TCPP-RPUF. From the result of foam morphology analysis, it was confirmed that BHP-RPUF has the lowest thermal conductivity of $0.023W/m{\cdot}K$. We also measured the size of air bubbles using reaction velocity and SEM, and analyzed how they affect the thermal conductivity. In addition, the heat-resisting property was investigated through TGA analysis. The limited oxygen index (LOI) test confirmed that BHP had the ability to increase the flame retardancy of RPUF.

• 한국연소학회:학술대회논문집
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• 2000.12a
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• pp.47-58
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• 2000

The relationship among the flame radiation, NOx emissions, residence time, and global strain rate are examined for turbulent non-premixed jet flames with wide variations in coaxial air conditions. Measurements of NOx emission, flame geometry and flame radiation were made to explain the NOx emission scaling based on global parameters such as flame residence time, global strain rate, and radiant fraction. The overall 1/2-power scaling is observed in coaxial air flames, irrespective of coaxial air conditions, but the degree of deviation from the l/2-slope curve in each case differs from one another. From the comparison between the results of pure hydrogen flames and those of helium diluted hydrogen flames, it is observed that flame radiation plays a significant role in pure hydrogen flames with coaxial air and the deviation from 1/2-power scaling may be explained in two reasons: the difference in the flame radiation and the difference in jet similarity in coaxial air flames. From the radiation measurements, more detailed explanations on these deviations were suggested.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.319-321
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• 2012

The flammability limit and the flame instability of nitrogen-diluted LPG fuel was experimentally studied on a co-flow flame configuration. The combustion reaction of nitrogen-diluted hydrocarbon with air could be interpreted as the equivalent reaction of pure fuel with nitrogen-diluted air. Nitrogen-diluted LPG with nitrogen up to 90 % of nitrogen mole fraction in fuel, which is close to the flammability limit, could form a co-flow flame. Various parameters such as laminar or turbulent flame, the existence of diffusion flame with pure fuel, air temperature could affect the limit of flame formation.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.26 no.3
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• pp.288-294
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• 1990

Two pure fuel oils(#1 oil, #6 oil), theree pure alcohols (methanol, ethanol, propanol) were tested for the fuel characteristics such as miscibility (that established which pure fuels and fuel mixtures could be fired in the boiler), flash point, viscosity. Specific target of the study besides the oil/alcohols or oil/alcohol mixture without any modification and with safety. #1 oil could be mixed without any problems at all concentrations with two of the alcohols; these were the ethanol and propanol. However, miscibility of #6 oil with any alcohols and #1 oil with methanol was not possible and very limited in this study. The measurements of flash point and viscosity for the mixtures were done for the comparisons with the pure fuels. There was a marked change of flame shape and flame luminosity as the alcohol content of the mixtures was increased. The mixture flame shortened and became non-luminous compared with a pure fuel oil flame.

• 한국연소학회:학술대회논문집
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• 2000.12a
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• pp.101-112
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• 2000

An Experimental study of oxygen enriched double inversed diffusion flame was conducted to understand the flame characteristics and radiation heat transfer. The infrared radiation meter was used to measure of various combination of fuel, air and pure oxygen. The results show that oxygen enriched double inversed diffusion flame is very effective to increase of thermal radiation and proper addition of pure oxygen in air flow can intensity thermal radiation of flame. And it can be found that oxygen enriched double inversed diffusion flame could give benefits of cost effective and very high energy saving.