• Clean Technology
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• v.26 no.2
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• pp.137-144
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• 2020

Metal-impregnated activated carbons were prepared via ultrasonic-assisted impregnation method for regeneration and low ammonia concentration. Magnesium and copper were selected as metals, while chloride (Cl^-) and nitrate (NO₃^-) precursors were used to impregnate the surface of activated carbon. The physical and chemical properties of the prepared adsorbents were characterized by TGA, BET, and NH₃-TPD. The ammonia breakthrough test was carried out using a fixed bed and flowing ammonia gas (1000 mg L^-1 NH₃, balanced N₂) at 100 mL min^-1, under conditions of temperature swing adsorption (TSA) and pressure swing adsorption (PSA, 0.3, 0.5, 0.7, 0.9 Mpa). The adsorption and desorption performance of ammonia were in the order of AC-Mg(Cl) > AC-Cu(Cl) > AC-Mg(N) > AC-Cu(N) > AC through NH₃-TPD and TSA and PSA processes. AC-Mg(Cl) using MgCl₂ showed the average adsorption amount of 2.138 mmol/g at TSA process. Also, AC-Mg(Cl) showed the highest initial adsorption amount of 3.848 mmol/g at PSA 0.9 Mpa. When metal impregnated the surface of the activated carbon, it was confirmed that not only physical adsorption, but also chemical adsorption increased, making enhancement in adsorption and desorption performances possible. Also, the prepared adsorbents showed stable adsorption and desorption performances despite repeated processes, confirming their applicability in the TSA and PSA processes.

• Polymer(Korea)
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• v.38 no.4
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• pp.491-495
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• 2014

Pressure sensitive adhesive (PSA) based on 2-ethylhexyl acrylate (2-EHA)/acrylic acid (AA) copolymer was synthesized using different photoinitiators. Results showed that PSA with Irgacure$^{(R)}$651 (benzyldimethylketal) and Irgacure$^{(R)}$184(1-hydroxy-cyclohexylphenyl ketone) proved to be good for adhesion properties. This may be attributed to strong absorption near 350 nm wavelength and also high solubility in monomer mixtures. The addition of Irgacure$^{(R)}$819, bisacylphosphine oxides as a photoinitiator caused cohesive failure with high loading in a peel test owing to the additional radical formation. It is assumed that the insoluble photoinitiator reacts with oxygene, which may act as a hydrogen donor.

• Bulletin of the Korean Chemical Society
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• v.31 no.6
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• pp.1561-1567
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• 2010

In this study, we have developed a new detection method using Si field effect transistor (FET)-type biosensors, which enables the direct monitoring of antigen-antibody binding within very high-ionic-strength solutions such as 1$\times$PBS and human serum. In the new method, as no additional dilution or desalting processes are required, the FET-type biosensors can be more suitable for ultrasensitive and real-time analysis of raw sample solutions. The new detection scheme is based on the observation that the strength of antigen-antibody-specific binding is significantly influenced by the ionic strength of the reaction solutions. For a prostate specific antigen (PSA), in some conditions, the binding reaction between PSA and anti-PSA in a low-ionic strength reaction solution such as 10 ${\mu}M$ phosphate buffer is weak (reversible), while that in high-ionic strength reaction solutions such as 1$\times$PBS or human serum is strong.

• Journal of the Korean Society of Safety
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• v.33 no.6
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• pp.136-143
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• 2018

In this study, we conducted a pilot study on the multiple spurious operations (MSO) analysis in the fire probabilistic safety assessment (PSA) of domestic nuclear power plant (NPP) to identify the degree of influence of the operator actions used in the MSO mitigation strategies. The MSO scenario of the domestic reference NPP selected for this study is refueling water tank (RWT) drain down event. It could be caused by spurious operations of the containment spray system (CSS) of the reference NPP. The RWT drain down event can be stopped by the main control room (MCR) operator actions for stopping the operation of CSS pump or closing the CSS motor operated valve if the containment spray actuation signal (CSAS) is spuriously actuated. Outside the MCR, it can be stopped by operator actions for closing the CSS manual valves or motor operated valve or stopping the operation of CSS pump. The quantification result of a fire PSA model that takes into account all recovery actions for the RWT drain down event lead to risk reduction by about 95%, compared with quantification result of fire PSA model without considering them. Among the various operator actions, the recovery action for the spurious CSAS operations and the operator action for the manual valve are identified as the most important operator actions. This study quantitatively showed the extent to which the operator actions used as MSO countermeasures have affected the fire PSA quantification results. In addition, we can see the rank of importance among the operator recovery actions in quantitative terms.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3464-3466
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• 2007

Power uprate is the process of increasing the maximum power level at which a commercial nuclear power plant may operate. Power uprate applications(113 units) for NPPs(Nuclear Power Plants) were recently approved in the United States. Utilities have been using power uprates since the 1970s as a way of increasing the power output of their nuclear plants. To increase the power output of a reactor, typically more highly enriched uranium fuel and/or more fresh fuel is used. This enables the reactor to produce more thermal energy and therefore more steam, driving a turbine generator to produce electricity. In this paper, the propriety of power uprate is explained through the review on the power uprate method and the changes of the physical parameters due to power uprate. The analysis results showed that the CDF(Core Damage Frequency) and LERF(Large Early Release Frequency) are affected in the current probabilistic safety assessment (PSA) model.

• Asian Pacific Journal of Cancer Prevention
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• v.15 no.22
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• pp.9841-9846
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• 2014

Objectives: To compare the metabolic indices, lipid profile, androgens, and prostate specific antigen between prostate cancer and BPH and between grades of prostate cancer in a cross-sectional study. Materials and Methods: The study enrolled 95 cases of prostate cancer and 95 cases of benign prostatic hyperplasia (BPH). Prostate gland volume was measured using transrectal ultrasound. We compared insulin, testosterone, dihydrotestosterone, prostate specific antigen levels and lipid profile between prostate cancer of different grades and BPH. Further, prostate cancer patients were classified into low grade and high grade. Unpaired t-test for normally distributed variables and Man-Whitney U test for non-normal variables were used to assess differences. Results: We found that prostate cancer patients had significantly higher levels of insulin, testosterone, PSA, cholesterol, triglycerides, low-density lipoprotein (LDL) and very low-density lipoprotein (VLDL) in comparison to their BPH counterparts. Higher levels of these parameters also correlated with a higher grade of the disease. Conclusions: We conclude that higher levels of insulin, testosterone, PSA, and cholesterol correlate with a higher risk of prostate cancer, and also with a higher grade of the disease.

• ETRI Journal
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• v.43 no.5
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• pp.941-949
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• 2021

In this study, a spatial spectrum method is proposed to cope with the pilot spoofing attack (PSA) problem by exploiting the of uplink-downlink channel reciprocity in time-division-duplex multiple-input multiple-output systems. First, the spoofing attack in the uplink stage is detected by a threshold derived from the predefined false alarm based on the estimated spatial spectrum. When the PSA occurs, the transmitter (That is Alice) can detect either one or two spatial spectrum peaks. Then, the legitimate user (That is Bob) and Eve are recognized in the downlink stage via the channel reciprocity property based on the difference between the spatial spectra if PSA occurs. This way, the presence of Eve and the direction of arrival of Eve and Bob can be identified at the transmitter end. Because noise is suppressed by a spatial spectrum, the detection performance is reliable even for low signal-noise ratios and a short training length. Consequently, Bob can use beamforming to transmit secure information during the data transmission stage. Theoretical analysis and numerical simulations are performed to evaluate the performance of the proposed scheme compared with conventional methods.

• Nuclear Engineering and Technology
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• v.54 no.12
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• pp.4601-4619
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• 2022

The classical Probabilistic Safety Analysis (PSA) does not include any time dependence explicitly. However, the success criteria (SC) could evolve during the cycle for some initiating events. In that sense, there is a type of sequence in which this time-dependency is quite important, the family of Anticipated Transient without Scram (ATWS) sequences in Pressurized Water Reactors. Therefore, a new risk-informed approach is proposed in this paper, which makes it possible to obtain the time-dependent SC evolution of the safety functions affected by the Moderator Temperature Coefficient (MTC) value. Then, the evolution of the ATWS conditional core damage probability (CCDP) could be obtained using a PSA model. To quantify the CCDP, the average values of the time-dependent failure probabilities must be computed. Finally, the comparison between the CCDP obtained through the application of the classical PSA approach and the new one makes it possible to quantify the impact of time-dependence on the SC of the headers that this new risk-informed ATWS approach can provide.

• Clean Technology
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• v.19 no.4
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• pp.370-378
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• 2013

This review has shown the capability of MOFs and ZIFs materials to adsorb $CO_2$ under typical PSA temperatures and pressures. The usual operating conditions are adsorption temperatures of $15{\sim}40^{\circ}C$ and adsorption pressures of 4~6 bar based on numerous PSA processes which are widely employed in gases industry for adsorptive separation of $CO_2$. The extent of $CO_2$ adsorption on the microporous materials depends on the metal species and organic linkers existing in the frameworks. The pore size and the surface area, and the process variables are the key parameters to be associated with the efficiency of the adsorbents, particularly adsorption pressures if other variables are comparable each other. The MOFs and ZIFs materials require high pressures greater than 15 bar to yield significant $CO_2$ uptakes. They possess a $CO_2$ adsorption capacity which is very similar to or less than that of conventional benchmark adsorbents such as zeolites and activated carbons. Consequently, those materials have been much less cost-effective for adsorptive $CO_2$ separation to date because of very high production price and the absence of commercially-proven PSA processes using such new adsorbents.

• Journal of the Korean Society of Safety
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• v.32 no.3
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• pp.160-171
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• 2017

US national research laboratories developed the first Vital Area Identification (VAI) method for the physical protection of nuclear power plants that is based on Event Tree Analysis (ETA) and Fault Tree Analysis (FTA) techniques in 1970s. Then, Korea Atomic Energy Research Institute proposed advanced VAI method that takes advantage of fire and flooding Probabilistic Safety Assessment (PSA) results. In this study, in order to minimize the burden and difficulty of VAI, (1) a set of streamlined VAI rules were developed, and (2) this set of rules was applied to PSA fault tree and event tree at the initial stage of VAI process. This new rule-based VAI method is explained, and its efficiency and correctness are demonstrated throughout this paper. This new rule-based VAI method drastically reduces problem size by (1) performing PSA event tree simplification by applying VAI rules to the PSA event tree, (2) calculating preliminary prevention sets with event tree headings, (3) converting the shortest preliminary prevention set into a sabotage fault tree, and (4) performing usual VAI procedure. Since this new rule-based VAI method drastically reduces VAI problem size, it provides very quick and economical VAI procedure. In spite of an extremely reduced sabotage fault tree, this method generates identical vital areas to those by traditional VAI method. It is strongly recommended that this new rule-based VAI method be applied to the physical protection of nuclear power plants and other complex safety-critical systems such as chemical and military systems.