• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.31-34
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• 2007

Fuel cell with high electric efficiency has many probabilities of commercial use. Especially, polymer electrolyte or proton exchange membrane fuel cell (PEMFC) which is a low operating temperature and has less influence on $CO_2$ concentration is considered the power generation system of small building and household. We calculated the optimal operational plans of 1 kW household PEMFC power system based on daily electric and heat demand patterns of various size of apartments. Calculated results show that the economic feasibility of PEMFC power system is very sensitive to the cost policy of electricity and natural gas.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.502-503
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• 2008

The modelling of PEMFC(Proton Exchange Membrane Fuel Cell) has been studied in many kinds of methods. But there are some limitations in application of the developed models to analysis transient phenomena of power systems. The PSCAD/EMTDC is very popular simulation tool in power system areas. To analysis power systems interconnected to PEMFCs, the PSCAD/EMTDC model of the PEMFCs is needed. In this paper, we developed a PSCAD/EMTDC model of PEMFC based on electro-chemical characteristic equations of PEMFC. Also, we performed simulations using the developed model in the PSCAD/EMTDC program and tested appropriateness of the proposed the models. The simulations showed good results.

• Journal of the Korean institute of surface engineering
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• v.50 no.1
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• pp.1-9
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• 2017

Design of novel materials in renewable energy systems plays a key role in powering transportation vehicles and portable electronics. This review introduces the research work of first principles-based computational design for the materials over the last decade to accomplish the goal with less financial and temporal cost beyond the conventional approach, especially, focusing on electrocatalyst toward a proton exchange membrane fuel cell (PEMFC). It is proposed that the new method combined with experimental validation, can provide fundamental descriptors and mechanical understanding for optimal efficiency control of a whole system. Advancing these methods can even realize a computational platform of the materials genome, which can substantially reduce the time period from discovery to commercialization into markets of new materials.

• Journal of the Korean Solar Energy Society
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• v.31 no.5
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• pp.91-98
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• 2011

연료전지 차랑용에 있어서 공기 가습 및 감습의 중요성은 매우 크다. 특히 PEM(Proton Exchange Membrane)연료전지에서 수분평형은 총괄시스템성능에 큰 영향을 미치는 요소인데, 이에 관한 중요한 연구가 지금까지 광범위하게 수행되고 있다. 또한 차량과 같이 동적부하 연료전지를 활용하는 분야에 있어서, 전류의 흐름은 차량용 파워 부하에 크게 영향을 받는다. 따라서 전기적 흐름이 발생하면, 이에 따라 수분이 발생하게 되는데, 이러한 응축 수분은 예측이 되며, 수관리 시스템에서 이를 중요한 제어 기준으로 활용한다. 그러므로 적절한 제어방법을 선택하면 유입공기의 온도와 습도의 최적값을 얻을 수 있다. 따라서, 본 논문에서는 PEM 연료전지의 수관리를 위하여 수분전달 모델과 유전알고리즘(genetic algorithm)을 사용하는 제어방법에 초점을 두고 있다.

• Proceedings of the KIPE Conference
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• 2008.06a
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• pp.304-307
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• 2008

일반적으로 마이크로 전원으로 연료전지 발전장치는 100w ~수백kw의 용량을 가지며 종전의 대규모 전력설비와 비교하여 높은 신뢰도를 갖는 고품질의 전력을 공급할 수 있다. 본 연구에서는 소형 분산에너지원으로서 PEMFC(Proton Exchange Membrane Fuel Cell )연료전지를 사용하는 발전장치의 PSIM 모델을 설정하고 부하변화에 대한 연료전지 발전장치의 출력전압의 강인성을 살펴보았다. 연료전지 발전장치의 교류출력의 강인성은 선형 부하 및 비선형 부하가 급변하는 과도상태에서 파악하였다.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.5
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• pp.471-480
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• 2017

A proton exchange membrane fuel cell (PEMFC) operated at $150^{\circ}C$ was evaluated by a controlling different amount of phosphoric acid (PA) to a membrane-electrode assembly (MEA) without humidification of the cells. The effects on MEA performance of the amount of PA in the cathode are investigated. The PA content in the cathodes was optimized for higher catalyst utilization. The highest value of the active electrochemical area is achieved with the optimum amount of PA in the cathode confirmed by in-situ cyclic voltammetry. The current density-voltage experiments (I-V curve) also shows a transient response of cell voltage affected by the amount of PA in the electrodes. Furthermore, this information was compared with the production variables such as hot pressing and vacuum drying to investigate those effect to the electrochemical performances.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.5
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• pp.585-591
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• 2011

This study has focused on the development of high performance membrane-electrode assemblies (MEAs) fabricated by decal method for proton exchange membrane fuel cell (PEMFC). To study the effect of ionomer contents on performance, we fabricated MEAs with several electrodes which were prepared by varying the quantity of ionomer from 20 wt.% to 45 wt.% in catalyst layer. The MEA performance was obtained through single cell test. The MEA prepared from electrode with 25wt.% of ionomer showed the best performance. We evaluated the surface area and pore volume of electrode with BET. We found that the surface area and pore volume in electrode decreased rapidly at the electrode with 40wt.% of ionomer in catalyst layer. MEA was fabricated by roll laminator machine and the roll laminating conditions for the preparation of MEA, such as laminating press, temperature and speed, were optimized. The MEA performance is not affected by laminating temperature and speed, but roll laminating press have a great effect on MEA performance.

• Transactions of the Korean Society of Automotive Engineers
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• v.23 no.1
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• pp.34-40
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• 2015

A stack in the proton exchange membrane fuel cell (PEMFC) consists of bipolar plates, a membrane electrode assembly, a gas diffusion layer, a collector and end plates. High current density is usually obtainable partially from uniform temperature distribution in the fuel cell. A size optimization method considering the thermal expansion effect of stacked plates was developed on the basis of finite element analyses. The thermal stresses in end, bipolar, and cooling plates were calculated based on temperature distribution obtained from thermal analyses. Finally, the optimization method was applied and optimum thicknesses of the three plates were calculated considering both fastening bolt tension and thermal expansion of each unit cell (72 cells, 5kW). The optimum design considering both thermal and mechanical loads increases the thickness of an end plate by 0.64-0.83% the case considering only mechanical load. The effect can be enlarged if the number of stack increases as in an automotive application to 200-300 stacks.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.568-571
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• 2008

A novel self-humidifying composite membrane for the proton exchange membrane fuel cell (PEMFC) at low humidity condition was developed. The Pt/$TiO_2$ catalyst particles were synthesized via supercritical impregnation methods. Pt precursor was dissolved in supercritical carbon dioxide and impregnated onto $TiO_2$ particles. Pt precursors were platinum(II) acetylacetonate, Dimethyl(1,5-cyclooctadiene) platinum(II) and we controlled the ratio of Pt to $TiO_2$. The impregnated Pt precursor was converted to $TiO_2$ supported Pt nanoparticle under various reducing conditions. Pt/$TiO_2$ catalyst particles were dispersed uniformly into the Nafion solution, and then Pt/$TiO_2$/Nafion composite membrane was prepared using solution-cast method. The self-humidifying composite membrane could minimize membrane conductivity loss under dry conditions due to the presence of catalyst and hydrophilic Pt/$TiO_2$ particles. To optimize the performance of MEA, amount of ionomer loading was controlled. And mixed catalysts were used. The cell performance of MEA was obviously improved under dry conditions at $65^{\circ}C$.

• Journal of Advanced Marine Engineering and Technology
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• v.30 no.2
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• pp.225-230
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• 2006

This study investigates drying condition when a small fan is added to a operating the free-breathing proton exchange membrane fuel cells (PEMFCs) with dry $H_2$ and Air. Polarization tests were conducted on PEMFCs at cell temperatures between 30 and $50^{\circ}C$ under dry operation. In the results, the cell performance strongly depended on the cell temperature and the cathode gas stoichiometric flow rates. The cell performance increases as cell temperature decreases from 50 to $30^{\circ}C$. In the domain where the stoichiometry of air is quite large, reduction of the concentration overpotential compensated the increased internal resistance due to drying. The maximum performance was obtained at the small air flow rate beyond which flooding occurs. This indicates that the fan should be operated in the stoichiometry domain with a well designed cell structure to avoid flooding.