• 제목/요약/키워드: proton exchange membrane fuel Cell

검색결과 430건 처리시간 0.028초

고분자 전해질형 연료전지/2차전지/태양전지 하이브리드 자동차에 대한 모델링 및 특성평가 (Modeling and Analysis of PEMFC/Battery/Photovoltaic Hybrid Vehicle)

  • 지현진;안효정;차석원;배중면
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.2255-2260
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    • 2007
  • This Paper focuses on modeling and simulation to analyze the characteristic of hybrid vehicle. The system includes proton exchange membrane fuel cell(PEMFC), photovoltaic generator(PV), lead-acid battery, motor, vehicle and controller. Main electricity is produced by the PEMFC and battery to meet the requirements of a user load. When vehicle is parked in a sunny place, extra power is generated by the photovotaics and is charged in a battery for next drive. Further we evaluate usefulness of this hybrid vehicle by using ADVISOR - the advanced vehicle simulator written in the Matlab/Simulink environment. According to simulation results, the extra power obtained by photovoltaics which have been explored in nature conditions can help to reduce the electrical load of PEMFC and increase the efficiency (over 30%).

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고분자전해질형 연료전지의 냉각유체에 대한 연구 (Cooling Fluid Study in Proton Exchange Membrane Fuel Cell)

  • 김준범;이흥주
    • 한국전기화학회:학술대회논문집
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    • 한국전기화학회 2005년도 수소연료전지공동심포지움 2005논문집
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    • pp.93-96
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    • 2005
  • 고분자전해질형 연료전지에서는 수소이온의 이온전도성 저하를 방지하기 위하여 외부에서 가습하여 주는 방식이 일반적이지만, 가습에 소요되는 부품을 일부라도 제거할 경우 연료전지의 효율은 높이고 제작단가도 경감할 수 있다. 이를 위하여 저가습 및 무가습 실험을 수행하였으며, 정확한 data의 수집과 시험장비의 자동제어를 위하여 National Instrument사의 compact field point (cFP)를 사용하였다. Humidifier와 heater의 온도를 조절하여 공급유체의 상대습도 및 온도를 각각 조절하였으며, 이에 필요한 이론적 온도는 Antoine equation 을 사용하여 산정하였다. Anode와 cathode 양측 $100\%$ 가습 경우를 기준으로 가습량을 조절하면서 실험을 수행하였으며 성능 차이를 그래프로 도시하여 양측의 변화에 대한 영향을 볼수 있도록 하였다. Stack의 온도가 $70^{\circ}C$이고 양측 무가습일 경우에 성능 측정이 어려워서 stack의 온도를 저온에서부터 변화시키면서 무가습 성능을 실시간으로 측정하여 보았다. 일반적으로 hydronium ion은 anode측에서 cathode측으로 계속 이동하여야 전기를 생성할 수 있으므로 cathode측 무가습이 anode측 무가습보다 성능이 더 잘 나오는 것으로 예측하였으나 이와 반대되는 경향의 실험 결과를 얻었다. 양측 무가습의 경우에는 공기 중의 상대습도와 back diffusion 등에 영향을 받을 수 있으므로 각종 변수들의 영향을 분리하여 관찰할 수 있는 실험을 수행 중에 있다.

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초정밀 대면적 미세 형상 가공기의 구조 특성 해석 (Structural Characteristic Analysis of an Ultra-Precision Machine for Machining Large-Surface Micro-Features)

  • 김석일;이원재
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회A
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    • pp.1469-1474
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    • 2007
  • In recent years, research to machine large-surface micro-features has become important because of the light guide panel of a large-scale liquid crystal display and the bipolar plate of a high-capacity proton exchange membrane fuel cell. In this study, in order to realize the systematic design technology and performance improvements of an ultra-precision machine for machining the large-surface micro-features, a structural characteristic analysis was performed using its virtual prototype. The prototype consisted of gantry-type frame, hydrostatic feed mechanisms, linear motors, brushless DC servo motor, counterbalance mechanism, and so on. The loop stiffness was estimated from the relative displacement between the tool post and C-axis table, which was caused by a cutting force. Especially, the causes of structural stiffness deterioration were identified through the structural deformation analysis of sub-models.

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연료전지의 CO 피독 및 회복에 관한 연구 (Study of performance of a stack in the presence of CO and air)

  • 김희수;김동찬;한지희;이호준
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.180-183
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    • 2007
  • CO in the reformed gas for proton exchange membrane fuel cell(PEMFC) has a strong tendency to adsorb on the surface of the catalyst and thus to block the sites that hydrogen needs for reactions. Even part per million levels of CO can cause serious poisoning. This CO poisoning can overcome to bleed trace amounts of air into the anode. In this study, we indicated the alteration of stack performance in various CO concentration and then bled a small amount of air. The performance of stack was reduced by increasing CO amount, and recovered by air bleeding. But the air-bleeding have an impact on performance of anode should be further explored.

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전처리가 그래핀을 코팅한 고체고분자 연료전지 분리판의 전기화학적 특성에 미치는 영향 (Effect of Pretreatments on Graphene Coated Bipolar Plate of PEMFC on Electrochemical)

  • 차성윤;이재봉
    • Corrosion Science and Technology
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    • 제13권6호
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    • pp.224-232
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    • 2014
  • Effect of pretreatments on the graphene coated bipolar plate of proton exchange membrane fuel cell(PEMFC) was investigated in simulated environments for PEMFC by using electrochemical measurement techniques. Interfacial contact resistance(ICR) between the graphene coated bipolar plate and the gas diffusion layer(GDL) was measured. The value of ICR decreased with an increase in compaction stress($20N/cm^2{\sim}220N/cm^2$). ICR of graphene coated bipolar plate was higher than that of bare 316L stainless steel. However, Potentiodynamic measurement results showed that the corrosion resistance of graphene coated bipolar plate was higher than that of bare 316L stainless steel. $H_2SO_4$ acid pretreatment was the most effective among various pretreatments. The lowest ICR and the corrosion current density were obtained when using $H_2SO_4$ solution pretreatment.

Characterization of Enhanced CO Oxidation Activity by Alumina Supported Platinum Catalyst

  • Jo, Myung-Chan
    • 한국환경과학회지
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    • 제18권10호
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    • pp.1071-1077
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    • 2009
  • A novel pretreatment technique was applied to the conventional Pt/alumina catalyst to prepare for the highly efficient catalyst for the preferential oxidation of carbon monoxide in hydrogen-rich condition. Their performance was investigated by selective CO oxidation reaction. CO conversion with the oxygen-treated Pt/Alumina catalyst increased remarkably especially at the low temperature below $100^{\circ}C$. This result is promising for the normal operation of the proton exchange membrane fuel cell (PEMFC) without CO poisoning of the anode catalyst. XRD analysis results showed that metallic Pt peaks were not observed for the oxygen-treated catalyst. This implies that well dispersed small Pt particles exist on the catalyst. This result was continued by high resolution transmission electron microscopy (HRTEM) analysis. Consequently, it can be concluded that highly dispersed Pt nanoparticles could be prepared by the novel pretreatment technique and thus, CO conversion could be increased considerably especially at the low temperatures below $100^{\circ}C$.

접촉각에 따른 마이크로채널 내에서의 액적 거동에 대한 수치적 연구 (Numerical Study of Droplet Motion in a Microchannel with defferent contact angles)

  • 최지영;손기헌
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 춘계학술대회논문집
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    • pp.656-657
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    • 2008
  • The droplet dynamics in a hydrophilic/hydrophobic microchannel, which is applicable to a typical proton exchange membrane fuel cell (PEMFC), is studied numerically by solving the equations governing conservation of mass and momentum. The liquid-gas interface or droplet shape is determined by a level set method which is modified to treat contact angles. The matching conditions at the interface are accurately imposed by incorporating the ghost fluid approach based on a sharp-interface representation. The effects of contact angle, inlet flow velocity, droplet size and side wall on the droplet motion are investigated parametrically. Based on the numerical results, the droplet dynamics including the sliding and detachment of droplets is found to depend significantly on the contact angle. Also, a droplet removal process is demonstrated on the combination of hydrophilic and hydrophobic surfaces.

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연료전지-태양전지 하이브리드 자동차에 대한 제어전략 및 특성평가 (Control Strategy and Characteristic Analysis of PEMFC/Photovoltaics Hybrid Vehicle)

  • 안효정;지현진;배중면;차석원
    • 대한기계학회논문집B
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    • 제31권10호
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    • pp.840-847
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    • 2007
  • This Paper focuses on modeling and simulation to analyze the characteristic of hybrid vehicle. The system includes a proton exchange membrane fuel cell(PEMFC), photovoltaic generator(PV), lead-acid battery, motor, vehicle and controller. Main electricity is produced by the PEMFC and battery to meet the requirements of a user load. When vehicle is parked in a sunny place, extra power is generated by the photovotaics and is charged in a battery for next drive. Further we evaluate usefulness of this hybrid vehicle by using ADVISOR - the advanced vehicle simulator written in the Matlab/Simulink environment. According to simulation results, the extra power obtained by photovoltaics which have been explored in nature conditions can help to reduce the electrical load of PEMFC and increase the efficiency (over 21 %).

Cuk 컨버터를 이용한 휴대용 연료전지 충전기의 개발 (Development of the Portable Fuel Cell Charger Using Cuk Converter)

  • 김태훈;이승준;최우진
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2010년도 하계학술대회 논문집
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    • pp.408-409
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    • 2010
  • 본 논문에서는 소형 PEM(Proton Exchange Membrane) 연료전지를 이용하는 충전기에 관해 서술한다. 기존에 개발된 대부분의 충전기는 On-Grid 방식으로 벅타입 컨버터를 이용한 감압 충전방식을 사용하였으나, 연료전지를 이용할 경우 승압식 컨버터를 통해 배터리를 충전하여야 한다. 그러나 승압형 컨버터의 출력단에 인덕터가 없는 경우 큰 리플전류를 유도하게 되며, 이는 시스템의 효율 및 배터리의 수명에 좋지 않은 영향을 끼치게 된다. 본 논문에서는 Cuk 컨버터를 이용하는 충전용 전력변환기의 제어방법에 관해 제안하고 그 타당성을 검증하였다.

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하이드라진으로 환원시킨 그래핀을 코팅한 오스테나이트와 마르텐사이트 스테인리스 강 고체고분자형 연료전지 금속 분리판의 전기화학적 특성 평가 (Evaluation of Electrochemical Characteristics on Graphene Coated Austenitic and Martensitic Stainless Steels for Metallic Bipolar Plates in PEMFC Fabricated with Hydrazine Reduction Methods)

  • 차성윤;이재봉
    • Corrosion Science and Technology
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    • 제15권2호
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    • pp.92-107
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    • 2016
  • Graphene was coated on austenitic and martensitic stainless steels to simulate the metallic bipolar plate of proton exchange membrane fuel cell (PEMFC). Graphene oxide (GO) was synthesized and was reduced to reduced graphene oxide (rGO) via a hydrazine process. rGO was confirmed by FE-SEM, Raman spectroscopy and XPS. Interfacial contact resistance (ICR) between the bipolar plate and the gas diffusion layer (GDL) was measured to confirm the electrical conductivity. Both ICR and corrosion current density decreased on graphene coated stainless steels. Corrosion resistance was also improved with immersion time in cathodic environments and satisfied the criteria of the Department of Energy (DOE), USA. The total concentrations of metal ions dissolved from graphene coated stainless steels were reduced. Furthermore hydrophobicity was improved by increasing the contact angle.