• Journal of the Korean Electrochemical Society
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• v.2 no.4
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• pp.190-194
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• 1999

Etched Nafion membrane and electrode assemblies were fabricated and those performances were observed in PEMFC. Adhesion of membrane to electrode increased with abrasion of membrane surface. Membrane surface ething results in reduction of hot pressing temperature, as a consequence, in improving of cell performance. It was found that Nafion etching was effective in painting method. The optimum content of electrode catalyst should be selected according to etching intensity.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.12-16
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• 2007

A dynamic model of proton exchange membrane fuel cell(PEMFC) system is designed to understand the performance of the PEMFC in residential power generator(RPG) over various balance of plant(BOP) options. In particular, since the performance of PEMFC system should be optimized for given operating ranges, it is necessary to design suitable BDP components which can support the operating ranges. The objective of this study is to develop a dynamic system model for the study of PEMFC performance over various BOP options. Therefore, a dynamic model is composed of a PEMFC stack model, a water management system model, a thermal management system model and a fuel/air supply model and the model is integrated under SIMULINK(R)environment. Basic simulation results will be presented.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3440-3445
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• 2007

For proton exchange membrane fuel cell, it is very important to design the flow channel on separation plate optimally to maximize the current density at same electrochemical reaction surface and reduce the concentration polarization occurred at high current density. In this paper, three dimensional computation model including anode and cathode domain together was developed to examine effects of flow patterns and operation conditions such as humidity and operating temperature on performance of fuel cell. Results show that voltage at counter flow condition is higher than that at coflow condition in parallel and interdigitated flow pattern. And fuel cell with interdigitated flow pattern which has better mass transport by convection flow through gas diffusion layer has higher performance than with parallel flow pattern but its pressure drop is increased such that the trade off between performance and pressure drop should be considered for selection of flow pattern of fuel cell.

• Proceedings of the KIPE Conference
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• 2008.06a
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• pp.646-648
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• 2008

The multi-films of a metallic film and a transparent conducting oxide (TCO, indium-tin oxide, ITO) film were formed on the stainless steel 316 and 304 plates by a sputtering method and an E-beam method and then the external metallic region of the stainless steel bipolar plates was converted into the metal nitride films through an annealing process. The multi-film formed on the stainless steel bipolar plates showed the XRD patterns of the typical indium-tin oxide, the metallic phase and the metal substrate and the external nitride film. The XRD pattern of the thin film on the bipolar plates modified showed two metal nitride phases of CrN and $Cr_2N$ compound. Surface microstructural morphology of the multi-film deposited bipolar plates was observed by AFM and FE-SEM. The electrical resistivity of the stainless steel bipolar plates modified was evaluated.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.4
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• pp.288-294
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• 2013

This gas analysis data come from the hydrogen which is produced by proton exchange membrane. Main impurities of hydrogen are methane, oxygen, nitrogen, carbon monoxide, and carbon dioxide. The concentration of impurities is ranged between 0.0191 to $315{\mu}mol/mol$ for each impurity. Methane contamination is believed from the electrode reaction between carbon doped electrode and produced hydrogen. Nitrogen contamination should take place the sampling process error, not from PEM hydrogen Production system.

• Proceedings of the KIEE Conference
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• 1997.07d
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• pp.1252-1254
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• 1997

Direct methanol fuel cell based on a proton-exchange membrane electrolyte was investigated. 60% Pt-Ru/C and 60%Pt/C catalysts were employed for methanol oxidation and oxygen reduction, respectively. Morphologies of the catalysts were investigated by x-ray power diffraction, energy dispersive x-ray spectroscopy, and transmission microscopy. Electrochemical characteristics of the catalysts were tested by using cyclic voltametry technique. I-V characteristics of the fuel cell were tested by changing methanol concentration, temperature, and Nafion type as a proton-exchange membrane electrolyte. AC impedance technique was used to investigate the electrochemical performance of the fuel cell. The performance of single cell was enhance with increasing cell temperature. High operation temperature attributed to the combined effects of the reduction of ohmic resistance and polarization. High cell voltage was obtained from the concentration of 205M methanol. With Nafion 112, a current density of $230mA/cm^2$ at 0.55V was obtained from the concentration of 2.5M methanol.

• Korean Chemical Engineering Research
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• v.54 no.2
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• pp.181-186
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• 2016

Recently, there are many efforts focused on development of more economical non-fluorinated membranes for use in PEMFCs (Proton Exchange Membrane Fuel Cells). In this study, characteristics of sulfonated Poly(ether ether ketone) (sPEEK) were compared according to degrees of sulfonation (DS), relative humidity, cell temperatures at PEMFC operation condition. I-V polarization curve, hydrogen crossover, electrochemical surface area, membrane resistance and charge transfer resistance were measured. sPEEK membrane showed high performance at high DS, high temperature and high relative humidity, in particular, performance of sPEEK membrane decreased largely due to low ionic conductivity at low DS and low relative humidity.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.1
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• pp.42-50
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• 2011

The Montmorillonite (MMT) in the polymer matrix is expected to reduce methanol permeability due to the tortous path formed by dispersed silicate layers. However, the polymer composite membranes containing non-proton conducting inorganic particle tend to show low proton conductivity. To solve this problem, we used an ion exchange method to prepare functionalized MMT with various silane coupling agents. The modified MMT was randomly dispersed in sulfonated poly (arylene ether sulfone) (SPAES) matrix to prepare SPAES/modified MMT composite membranes. The performances of hybrid membranes for DMFCs application were investigated. The SPAES/modified composite membrane showed increased proton conductivity compared with the non-modified MMT composite membrane. However, the methanol permeability of the SPAES/modified membrane was higher than that of the non-modified MMT.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.4
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• pp.335-340
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• 2016

Hydrogen production through proton exchange membrane water electrolysis (PEMWE) is expeditiously receiving international attention for renewable energy sources as well as energy storage system applications due to its environmentally friendly uses. A series of $Ir_{0.2}Ru_{0.8}O_2$ $Ir_{0.5}Ru_{0.8}O_2$ & $IrO_2$ catalysts were synthesized and electrochemically evaluated by using linear sweep voltammetry (LSV) technique. Furthermore, the PEMWE performances of full cells were evaluated by recording I-V Curves. The developed PEMWE stack was also operated in combination with a proton exchange membrane fuel cell (PEMFC) to demonstrate the discrete regenerative fuel cell (DRFC) performances. Produced hydrogen and oxygen from PEMWE were used as a fuel to operate PEMFC to establish a DRFC system.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.5
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• pp.397-403
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• 2015

In this study, water distribution inside a proton exchange membrane fuel cell (PEMFC) was measured experimentally. Water distribution is non-uniform because of vigorous chemical reaction and mass transport and has been difficult to measure experimentally. Therefore, much research relied on indirect measuring methods or numerical simulations. In this study, several mini temperature-humidity sensors were installed at the channel for measuring temperature and humidity of the flowing gas throughout the channel. Only one of two electrode channels was humidified externally, and the humidity distribution on the other side was measured, enabling the observation of water transport characteristics under various conditions. Diffusion through the membrane became more vigorous as the temperature of the humidifier rose, but at high current density, electro-osmotic drag became more effective than diffusion.