• Title/Summary/Keyword: properties of zero

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Microstructure and Mechanical Properties of a Copper Alloy Sheet Processed by a Differential Speed Rolling (이속압연에 의해 가공된 동합금 판재의 조직 및 기계적 특성)

  • Lee, Seong-Hee
    • Korean Journal of Materials Research
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    • v.22 no.11
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    • pp.581-586
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    • 2012
  • The microstructure and mechanical properties of a copper alloy sheet processed by differential speed rolling (DSR) were investigated in detail. A copper alloy with thickness of 3 mm was rolled to a 50% reduction at ambient temperature without lubrication and with a differential speed ratio of 2.0:1. For comparison, conventional rolling (CR), in which the rolling speeds of the upper and lower rolls is 2.0 m/min, was also performed under the same rolling conditions. The shear strain of the sample processed by CR showed positive values at the positions of the upper roll side and negative values at the positions of the lower roll side. On the other hand, the sample processed by the DSR showed zero or positive shear strain values at all positions. However, the microstructure and mechanical properties of the as-rolled copper alloys did not show such significant differences between the CR and the DSR. The samples rolled by the CR and the DSR exhibited a typical deformation structure. In addition, the DSR processed samples showed a typical rolling texture in which {112}<111>, {011}<211> and {123}<634> components were developed at all positions. Therefore, it is concluded that the DSR was very effective for the introduction of a uniform microstructure throughout the thickness of the copper alloy.

Temperature Properties of Vertical Reinforcements in Wall Structures in Relation to the Different Methods of Bubble Sheet Installation in Winter (겨울철 버블시트 포설방법 변화에 따른 벽식구조 수직철근의 온도 특성)

  • Kim, Tae-Woo;Lee, Jea-Hyeon;Kyung, Yeong-Hyeok;Lee, Jong-Gyo;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.11-12
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    • 2017
  • This study aims to analyze the properties of the temperature change in vertical reinforcements in outdoor wall structures in winter in relation to the different methods of bubble sheet installation, and to subsequently determine the possibility of initial frost damage to the concrete as a result of low temperature. As for the experimental variables, double bubble sheets were used as curing materials, and the curing method was to model the part where the slab and the wall intersect and the rebar is exposed, and to measure the change of temperature around the exposed rebar in accordance with the change of the coating curing. It was found that by employing curing method B, which is to install the bubble sheet between the vertical reinforcements, the most vulnerable area, which is 50mm below(④) the surface of the concrete, would be lowered to sub-zero temperature 20 hours later than when using curing method A, and that therefore it is more effective to install the bubble sheet between the vertical reinforcements for the prevention of initial frost damage.

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APPLICATIONS OF A MODEL TO COMPARE AFLAME SPREAD AND BEAT RELEASE PROPERTIES OF INFERIOR FINISH MATERIALS IN A COMPARTMENT

  • Kim, Woon-Hyung;James G. Quintiere
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.193-200
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    • 1997
  • Flame spread and heat release properties and incident heat flux of interior materials subject to an igniter heat flux in a compartment are investigated and compared by using computer model. A comer fire ignition source is maintained for 10 minutes at 100 kw and subsequently increased to 300kw. In executing the model, base-line material properties are selected and one is changed for each run. Also 4 different igniter heat flux conditions and examined. Results are compared for the 12 different materials tested by the ISO Room Comer Test (9705). The time for total energy release rate to reach 1MW is examined. The parameters considered include flame heat flux and thermal inertia, lateral flame spread parameter, heat of combustion and effective heat of gasfication. The model can show the importance of each property in causing fire growth on interior Hnish materials in a compartment. The effect of ignitor heat flux and material property effects were demonstrated by using dimensionless parameters a, b and Tb. Results show that for b greater than about zero, flashover time in the ISO Room-Corner test is principally proportional to ignition time and nothing more.

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Improved Properties of Li4Ti5O2 (LTO) by Surface Modification with Carbon Nanotube (CNT) (CNT 첨가를 통해 표면 처리한 LTO의 특성향상에 관한 연구)

  • Park, Soo-Gil;Kim, Cheong;Habazaki, Hiroki
    • Journal of the Korean institute of surface engineering
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    • v.49 no.2
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    • pp.191-195
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    • 2016
  • Among the lithium metal oxides for hybrid-capacity, $Li_4Ti_5O_{12}(LTO)$ is an emerging electrode material as zero-stain material in volume change during the with the charging and discharging processes. However, LTO has a limitation of low ionic and electronic conductivity. To enhance the ionic and electronic properties of $Li_4Ti_5O_{12}(LTO)$, we synthesized the spherical LTO/CNT composite by sol-gel process for hybrid capacitors. CNT interconnection networks between CNT-LTO particles enhanced electronic conductivity and electrochemical charging/discharging properties. All of the LTO samples was observed to show the spinel structure and spherical morphology with the diameter of $5{\sim}10{\mu}m$. Especially, spherical LTO/CNT composite of the CNT-3 wt% showed the enhanced capacity from 110 mAh/g to 140 mAh/g at 10 C.

Modeling of Rheological Properties of Pectins by Side Branches (펙틴의 곁사슬에 의한 유변학적 성질에 대한 모델)

  • Shin, Hae-Hun;Hwang, Jae-Kwan
    • Korean Journal of Food Science and Technology
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    • v.34 no.4
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    • pp.583-589
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    • 2002
  • The rheological properties of apple pectins and tomato pectins with different degrees of side branches (sample I and sample II) were investigated with wide range of shear rate by theological modeling. Among the Power law model, Cross model and Carreau model, the Carreau model was the best fitted to the experimental data. Increasing in branching of apple pectins resulted in higher zero-shear viscosity $({\eta}_0)$. But, tomato pectins that have a low degree of side branches were shown litte difference between sample I and sample II. It is concluded that side branches of pectins can result in significant difference in rheological properties. And, this is predicted by the Carreau model.

Electronic Spectroscopy and Ligand Field Analysis of cis-$>[Cr(cycb)Cl_2]$Cl

  • Choi, Jong-Ha;Oh, In-Gyung;Subodh Kumar;Ryoo, Keon-Sang
    • Journal of Photoscience
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    • v.11 no.1
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    • pp.19-23
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    • 2004
  • The sharp-line absorption spectrum of microcrystalline samples of cis-[Cr(cycb)$Cl_2$]Cl (cycb=rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) has been measured between 13000 and $16000 cm^{-1}$ at temperatures down to 5K. The 77K emission and excitation spectra, and 298 K infrared and visible absorption spectra have also been measured. The nine electronic bands due to spin-allowed and spin-forbidden transitions were assigned. Using the observed transitions, a ligand field analysis has been performed to probe the ligand field properties of coordinated atoms in the title chromium(III) complex. The zero-phonon line in the sharp-line absorption spectrum splits into two components by $240 cm^{-1}$ , and the $large ^2$$_E{g}$ splitting can be reproduced by the modem ligand field theory. It is confirmed that nitrogen atoms of the macrocyclic cycb ligand have a strong $\sigma$-donor character, but chloride ligand has weak $\sigma$- nd $\pi$-donor properties toward chromium(III) ion.n.

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High-frequency Magnetic Properties of Ni-Zn-Co Ferrites Used for Mangetic Shielding in NFC (NFC의 자기 차폐용 Ni-Zn-Co 페라이트 자성체의 고주파 자기특성)

  • Ryu, Yo-Han;Kim, Sung-Soo
    • Journal of Powder Materials
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    • v.21 no.6
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    • pp.429-433
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    • 2014
  • This study investigated the magnetic properties and frequency dispersion of complex permeability of Ni-Zn-Co ferrites used for magnetic shielding in near field communication (NFC) system. The sintered specimens of $(Ni_{0.7}Zn_{0.3})_{1-x}Co_xFe_2O_4$ composition were prepared by the conventional ceramic processing. The coercive force and saturation magnetization were measured by vibrating sample magnetometer. The complex permeability was measured by RF impedance analyzer in the range of 1 MHz~1.8 GHz. The coercive force increased and saturation magnetization decreased with increasing the Co substitution. The real and imaginary parts of complex permeability decreased and the resonance frequency increased with Co substitution, which was attributed to the increase in crystal anisotropy field and reduction in saturation magnetization. The effect of Co substitution could be found in reducing the magnetic loss to nearly zero at the operating frequency of NFC (13.56 MHz).

Spectroscopic Properties and Ligand Field Analysis of trans -Dibromo(2,2-dimethyl-1,3-diaminopropane)chromium(III) Moiety

  • Choi, Jong-Ha;Oh, In-Gyung;Lim, Woo-Taik;Ryoo, Keon-Sang;Kim, Dong-Il;Park, Yu-Chul
    • Bulletin of the Korean Chemical Society
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    • v.26 no.6
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    • pp.903-908
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    • 2005
  • The sharp-line absorption and emission spectra of $(H_{13}O_6)${$trans-[Cr(Me_2tn)_2Br_2]$}$_2Br_2(ClO_4)\;(Me_2$tn = 2,2-dimethyl-1,3-diaminopropane) have been measured between 13000 $cm^{-1}$ and 16000 $cm^{-1}$ at 5 K. The 298 K infrared and visible absorption spectra have also been measured. The nine electronic bands due to spin-allowed and spin-forbidden transitions were assigned. Using observed transitions, a ligand field analysis has been performed to probe the ligand field properties of coordinated atoms in the title chromium(III) complex ion. The zero-phonon line in the sharp-line absorption spectrum splits into two components by 286 $cm^{-1}$, and the large $^2E_g$ splitting can be reproduced by the modern ligand field theory. It is confirmed that nitrogen atoms of the Me2tn ligand have a strong $\sigma$-donor character, but the bromide has weak $\sigma$- and $\pi$-donor properties toward chromium(III) ion.

Evaluation on the Properties of the Current Transporting Part for Fault-Current-Limiting Type HTS Cables (사고전류 제한형 고온 초전도케이블의 통전부 특성평가)

  • Kim, Tae-Min;Hong, Gong-Hyun;Han, Byung-Sung;Du, Ho-Ik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.10
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    • pp.657-661
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    • 2014
  • When an abnormal condition occurs due to a fault current at a consumer location where electricity is supplied through high-Tc superconducting(HTS) cable, the HTS cable would be damaged if there is no appropriate method to protect it. The fault-current-limiting type HTS cable that is suggested in this study has a structure of transport part and limit part. It conduct a zero impedance transport current at ordinary operations and carry out a fault current limiting at extraordinary operations. To make a perfect this structure, it is essential to investigate electrical properties of transport part that comprise the fault-current-limiting type HTS cable. In this paper, transport part that comprise HTS wire with copper stabilization layer is examined the current transport properties and the stability evaluation.

Characterization of 3D Printed Re-entrant Strips Using Shape Memory Thermoplastic Polyurethane with Various Infill Density (채우기 밀도별 형상 기억 TPU 3D 프린팅 Re-entrant 스트립의 특성 분석)

  • Imjoo Jung;Sunhee Lee
    • Fashion & Textile Research Journal
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    • v.24 no.6
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    • pp.812-824
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    • 2022
  • This study proposes to develop a 3D printed re-entrant(RE) strip by shape memory thermoplastic polyurethane that can be deformed and recovered by thermal stimulation. The most suitable 3D printing infill density condition and temperature condition during shape recovery for mechanical behavior were confirmed. As the poisson's ratio indicated, the higher the recovery temperature, the closer the poisson's ratio to zero and the better the auxetic properties. After recovery testing for five minutes, it appeared that the shape recovery ratio was the highest at 70℃. The temperature range when the shape recovery ratio appeared to be more than 90% was a recovery temperature of more than 50℃ and 60℃ when deformed under a constant load of 100 gf and 300 gf, respectively. This indicated that further deformation occurred after maximum recovery when recovered at a temperature of 80℃, which is above the glass transition temperature range. As for REstrip by infill density, a shape recovery properties of 100% was superior than 50%. Additionally, as the re-entrant structure exhibited a shape recovery ratio of more than 90%, and exhibited auxetic properties. It was confirmed that the infill density condition of 100% and the temperature condition of 70℃ are suitable for REstrips for applying the actuator.