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Adsorption and Desorption of Chemical Warfare Agent Simulants on Silica Surfaces with Hydrophobic Coating

  • Park, Eun Ji;Kim, Young Dok
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.1967-1971
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    • 2013
  • Aim of our study is finding adsorbents suitable for pre-concentration of chemical warfare agents (CWAs). We considered Tenax, bare silica and polydimethylsiloxane (PDMS)-coated silica as adsorbents for dimethyl methylphosphonate (DMMP) and dipropylene glycol methyl ether (DPGME). Tenax showed lower thermal stability, and therefore, desorption of CWA simulants and decomposition of Tenax took place simultaneously. Silica-based adsorbents showed higher thermal stabilities than Tenax. A drawback of silica was that adsorption of CWA simulant (DMMP) was significantly reduced by pre-treatment of the adsorbents with humid air. In the case of PDMS-coated silica, influence of humidity for CWA simulant adsorption was less pronounced due to the hydrophobic nature of PDMS-coating. We propose that PDMS-coated silica can be of potential importance as adsorbent of CWAs for their pre-concentration, which can facilitate detection of these CWAs.

Rehabilitation of notched circular hollow sectional steel beam using CFRP patch

  • Setvati, Mahdi Razavi;Mustaffa, Zahiraniza
    • Steel and Composite Structures
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    • v.26 no.2
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    • pp.151-161
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    • 2018
  • The application of carbon fiber reinforced polymer (CFRP) composites for rehabilitation of steel structures has become vital in recent years. This paper presents an experimental program and a finite element (FE) modelling approach to study the effectiveness of CFRP patch for repair of notch damaged circular hollow sectional (CHS) steel beams. The proposed modeling approach is unique because it takes into account the orthotropic behavior and stacking sequence of composite materials. Parametric study was conducted to investigate the effect of initial damage (i.e., notch depth) on flexural performance of the notched beams and effectiveness of the repair system using the validated FE models. Results demonstrated the ability of CFRP patch to repair notched CHS steel beams, restoring them to their original flexural stiffness and strength. The effect of composite patch repair technique on post-elastic stiffness was more pronounced compared to the elastic stiffness. Composite patch repair becomes more effective when the level of initial damage of beam increases.

Texture and Microstructure in AA 3103 Sheets Deformed by Continuous Confined Strip Shearing Process (CCSS 가공에 의한 AA3103 판재의 집합조직 변화와 결정립 미세화에 관한 연구)

  • 이재필;이재철;허무영
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.10a
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    • pp.176-178
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    • 2003
  • Strip samples of AA 3103 were deformed by Continuous confined strip shearing (CCSS). The CCSS process was designed to provide a repeated shear deformation in metallic sheet materials. CCSS led to the formation of characteristic shear textures comprising a pronounced{111}<uvw> orientations. The intensity of the deformation texture hardly increased with increasing number of CCSS passes. EBSD equipped in a FESEM with a high beam current revealed the formation of fine grains even after annealing for the recrystallization.

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Effect of Sound Stress on Immune Response (소음 스트레스가 면역반응에 미치는 영향에 관한 실험적 연구)

  • 김금재
    • Journal of Korean Academy of Nursing
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    • v.19 no.2
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    • pp.135-146
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    • 1989
  • This study was undertaken to assess the effect of sound stress on humoral and cellular immune responses to thymus-dependent and independent antigens in mice. After mice were exposed to 4 hr daily sound stessors(83㏈) for 4 days before or after immunization, the primary and / or secondary immune response to sheep red blood cells(SRBC), polyvinylpyrroridone(PVP) or picry1 chloride(TNCB) were assayed. When mice were exposed to sound stressor before or after immunization, delayed-type hypersensitivity reaction and contact sensitivity to TNCB was remarkably depressed compared with those of the unstressed control mice. However, the primary and secondary hemagglutinin response of the stresed mice to SRBC showed a pronounced increase compared with that of the unstressed mice, In contrast to antibody response to SRBC, the primary antibody response of the stressed mic to PVP was almost not detected. surprisingly, the secondary antibody response to PVP of the mice receiving the secondary sound stress was markedly increased when the immune-depressed mice received the secondary immunization with PVP at 46 days after the primary immunization. The susceptibility of mice to intraven-oulsy infected Candida albicans was not changed by the sound stress.

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Selective Chemosensing of Hg2+ Ions by Diazatetrathia-crown Ether Having Nitrobenzoxadiazolyl Subunits

  • Kim, So-Hee;Youn, Na-Jin;Park, Ji-Yeon;Choi, Myung-Gil;Chang, Suk-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1553-1556
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    • 2006
  • A diazatetrathia crown ether derivative that has two appended nitrobenzoxadiazolyl moieties showed selective OFF-ON type fluoroionophoric signaling properties toward Hg2+ ions over other transition metal ions. The compound also exhibited a pronounced chromogenic behavior toward Hg2+ ions by changing the solution color from light orange to yellow, which can easily be detected with naked-eye. The detection limit for the analysis of Hg2+ ions in 90% aqueous acetonitrile was found to be 4.8??10-6 M, which suggests that the compound may be used as a chemosensor for analyzing sub-millimolar Hg2+ ions in aqueous environments.

Development of Detection Methods for Cellulolytic Activity of Auricularia auriculajudae

  • Jo, Woo-Sik;Bae, Soon-Hwa;Choi, Seung-Yong;Park, So-Deuk;Yoo, Young-Bok;Park, Seung-Chun
    • Mycobiology
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    • v.38 no.1
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    • pp.74-77
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    • 2010
  • To obtain basic information on the detection of cellulolytic activity in Auricularia auricula-judae, the influences of dye reagent, pH, and temperature were assessed. Chromogenic dye (congo red, phenol red, remazol brilliant blue, and trypan blue) was individually incorporated into a medium containing either carboxymethyl-cellulose, Avicel, or D-cellobiose as a polysaccharide carbon substrate. The other assessments utilized pHs ranging from 4.5 to 8.0 and temperatures from $15\sim35^{\circ}C$. Overall, when A. auricula-judae species were transferred onto media contained Congo red and adjusted pH 7.0 and then incubated at $25^{\circ}C$ for 5 days, the clear zone indicative of cellulolytic activity was more pronounced.

The Effect of Induced Multipoles on the Fifth-order Raman Response

  • Jansen, Thomas I.C.;Duppen, Koos;Snijders, Jaap G.
    • Bulletin of the Korean Chemical Society
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    • v.24 no.8
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    • pp.1102-1106
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    • 2003
  • In our previous work we developed the Finite Field method in order to calculate the fifth-order Raman response. The method was applied to calculate various polarization components of the two-dimensional response of liquid $CS_2$. So far, all calculations relied on the dipole-induced dipole. Accurate time-dependent density functional theory calculations have shown that this model has big discrepancies, when molecules are close together as in the liquid. We now report results of investigations on the importance of multipole and electron overlap effects on the polarizability and the fifth-order Raman response. It is shown that these collision effects, especially the induced multipoles, are crucial in the description of the fifth-order response. The impact is found to be especially pronounced for the χ_{mmzzzz}^{(5)}$response that is solely due to interaction induced effects. The calculated response will be compared with various experimental results.

The Surface Image Properties of BST Thin Film by Depositing Conditions (코팅 조건에 따른 BST 박막의 표면 이미지 특성)

  • Hong, Kyung-Jin;Ki, Hyun-Cheol;Ooh, Soo-Hong;Cho, Jae-Cheol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05b
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    • pp.107-110
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    • 2002
  • The optical memory devices of BST thin films to composite $(Ba_{0.7}\;Sr_{0.3})TiO_{3}$ using sol-gel method were fabricated by changing of the depositing layer number on $Pt/Ti/SiO_{2}/Si$ substrate. The structural properties of optical memory devices to be ferroelectric was investigated by fractal analysis and 3-dimension image processing. The thickness of BST thin films at each coating numbers 3, 4 and 5 times was $2500[\AA]$, $3500[\AA]$ and $3800[\AA]$. BST thin films exhibited the most pronounced grain growth. The surface morphology image was roughness with coating numbers. The thin films increasing with coating numbers shows a more textured and complex configuration.

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Effects of low temperature and salicylic acid on chilling tolerance in cucumber seedlings

  • Jung, Sang-Duck;Jung, You-Jin;Kim, Tae-Yun;Hong, Jung-Hee
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2002.05b
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    • pp.468-471
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    • 2002
  • The present study was undertaken to Investigate the effects of low temperature and salicylic acid (SA) on chilling tolerance In acclimated and nonacclimated cucumber seedlings. Acclimation significantly affected survival and shoot dry weights. Injuries of acclimated seedlings at the third leaf stage were on the average smaller by half than those of the nonacclimated ones. Chilling caused a large increase in free proline levels, regardless of acclimation status. Exogenous treatment with SA resulted in improvement in growth and survival of acclimated, chilled seedlings, indicating SA and acclimation have common effects. Cycloheximide treatment In the presence of SA restored acclimation-induced chilling tolerance. An elevated proline level was observed in cold-treated and SA- treated plants and the level was more pronounced in the light than in the dark at chilled temperature, indicating that endogenous proline may play a role in chilling tolerance.

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Harmonics-based Spectral Subtraction and Feature Vector Normalization for Robust Speech Recognition

  • Beh, Joung-Hoon;Lee, Heung-Kyu;Kwon, Oh-Il;Ko, Han-Seok
    • Speech Sciences
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    • v.11 no.1
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    • pp.7-20
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    • 2004
  • In this paper, we propose a two-step noise compensation algorithm in feature extraction for achieving robust speech recognition. The proposed method frees us from requiring a priori information on noisy environments and is simple to implement. First, in frequency domain, the Harmonics-based Spectral Subtraction (HSS) is applied so that it reduces the additive background noise and makes the shape of harmonics in speech spectrum more pronounced. We then apply a judiciously weighted variance Feature Vector Normalization (FVN) to compensate for both the channel distortion and additive noise. The weighted variance FVN compensates for the variance mismatch in both the speech and the non-speech regions respectively. Representative performance evaluation using Aurora 2 database shows that the proposed method yields 27.18% relative improvement in accuracy under a multi-noise training task and 57.94% relative improvement under a clean training task.

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