• Korean Journal of Remote Sensing
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• v.37 no.6_1
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• pp.1589-1597
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• 2021

Submarine groundwater discharge (SGD) in coastal areas is gaining importance as a major transport route that bring nutrients and trace metals into the ocean. This paper describes the analysis of the seasonal changes and spatiotemporal characteristicsthrough the modeling monthly SGD for 35 years from 1986 to 2020 for the Nakdong river basin. In this study, we extracted 210 watersheds and SGD estimation points using the SRTM (Shuttle Radar Topography Mission) DEM (Digital Elevation Model). The average annual SGD of the Nakdong River basin was estimated to be 466.7 m²/yr from the FLDAS (Famine Early Warning Systems Network Land Data Assimilation System) recharge data of 10 km which is the highest resolution global model applicable to Korea. There was no significant time-series variation of SGD in the Nakdong river basin, but the concentrated period of SGD was expanded from summer to autumn. In addition, it was confirmed that there is a large amount of SGD regardless of the season in coastal area nearby large rivers, and the trend has slightly increased since the 1980s. The characteristics are considered to be related to the change in the major precipitation period in the study area, and spatially it is due to the high baseflow-groundwater in the vicinity of large rivers. This study is a precedentstudy that presents a modeling technique to explore the characteristics of SGD in Korea, and is expected to be useful as foundational information for coastal management and evaluating the impact of SGD to the ocean.

• Journal of Korean Society of Disaster and Security
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• v.12 no.2
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• pp.15-24
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• 2019

In the previous study, the rainfall data of 1 hour, 6 hours and 3 days were used as the rainfall criterion according to the grade to trigger the debris flow in the highway area, using the rainfall data of Gangwon area and the rainfall time-series data at the spot where the debris flow occurred. In this study, we propose an early warning criterion of the highway debris flow triggering through appropriate combination of three rainfall criteria selected through previous studies and adjustments of rainfall criterion in the highway debris flow triggering. In addition, simulations were conducted using the time-series rainfall data of 2010~2012, which had a large amount of precipitation for the five sites where debris flows occurred in 2013. As a result of the study, the criteria for the early warning of highway unsteadiness on the highway were prepared. In case of the grade-based adjustment, it is preferable to apply the unified rating to the grade B. Also, if the fatigue of the monitoring is not a problem, adjusting it to A or S may be a way to positively cope with the occurrence of highway debris flow.

• Resources Recycling
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• v.27 no.6
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• pp.23-29
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• 2018

Recently rapid economic growth and technological development have led to an increase in the generation of waste electrical and electronic equipment (WEEE). As the amount of electric and electronic waste generated increases, the importance of processing waste printed circuit boards (PCB) is also increasing. Various studies have been conducted to recycle various valuable metals contained in a waste PCB in an environmentally friendly and economical manner. To get anode slime containing Ag and Au, Anode copper prepared from PCB scraps was used by means of electro-refining. Ag and Au recovery was conducted by leaching, direct reduction, and ion exchange method. In the case of silver, the anode slime was leached at 3 M $HNO_3$, 100 g/L, $70^{\circ}C$, and Ag was recovered by precipitation, alkali dissolution, and reduction method. In the case of gold, the nitrate leaching residues of the anode slime was leached at 25% aqua regia, 200 g/L, $70^{\circ}C$, and Au was recovered by pH adjustment, ion exchange resin adsorption, desorption and reduction method. The purity of the obtained Au and Ag were confirmed to be 99.99%.

• Journal of the Mineralogical Society of Korea
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• v.32 no.2
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• pp.79-86
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• 2019

The white aluminum phases in acid mine drainage usually precipitates when mixed with stream waters with relatively high pH. The minerals in white precipitates play important roles in controlling the behavior of heavy metals by adsorbing and coprecipitation. By the phase transition of these minerals in white precipitates, dissolution and readsorption of heavy metals may occur. This study was conducted to obtain preliminary information on the phase transition of the mineral phases in white precipitates. In this study, the mineral phase changes in the white precipitates collected from the stream around Dogye Mining Site over time were investigated with different pH values and temperatures. White precipitates consist mainly of basaluminite, amorphous $Al(OH)_3$ and a small amount of $Al_{13}$-tridecamer. During aging, the incongruent dissolution of the basaluminite occurs first, increasing the content of the amorphous $Al(OH)_3$. After that, pseudoboehmite is finally precipitated following the precursor phase of pseudoboehmite. At $80^{\circ}C$, this series of processes was clearly observed, but at relatively low temperatures, no noticeable changes were observed from the initial condition with coexisting basaluminite and amorphous $Al(OH)_3$. At high pH, the desorption of $SO{_4}^{2-}$ group in basaluminite was initiated to promote phase transition to the pseudoboehmite precursor. Over time, the solution pH decreases due to the dissolution and phase transition of the minerals, and even after the precipitation of pseudoboehmite, only the particle size slightly increased but no clear cystal form was observed.

• Economic and Environmental Geology
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• v.54 no.1
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• pp.69-76
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• 2021

This study is to identify the mineralogical properties of caprock samples from drilling cores of the Pohang basin, which is the research area for the demonstration-scale CO2 storage project in Korea. The interaction of water-rock-gas that can occur due to CO2 injection was identified using geochemical modeling. Results of mineralogical studies, together with petrographic data of caprock and data on the physicochemical parameters of pore water were used for geochemical modeling. Modelling was carried out using the The Geochemist's Workbench 14.0.1 geochemical simulator. Two steps of modeling enabled prediction of immediate changes in the caprocks impacted by the first stage of CO2 injection and the assessment of long-term effects of sequestration. Results of minerlaogical analysis showed that the caprock samples are mainly composed of quartz, K-feldspar, plagioclase and a small amount of pyrite, calcite, kaolinite and montmollonite. After the injection of carbon dioxide, the porosity of the caprock increased due to the dissolution of calcite, and dawsonite and chalcedony were precipitated as a result of the dissolution of albite and k-feldspar. In the second step after the injection was completed, the precipitation of dawsonite and chalcedony occurred as a result of dissolution of calcite and albite, and the pH was increased due to this reaction. Results of these studies are expected to be used as data to quantitatively evaluate the efficiency of mineral trapping capture in long-term storage of carbon dioxide.

• Journal of Korea Water Resources Association
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• v.53 no.12
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• pp.1143-1157
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• 2020

In this study, a criteria for the SWAT model calibration method in SWAT-CUP which considers multi-site and multi-variable observations was presented. For its application, the SWAT model was simulated using long-term observed flow, soil moisture, and evapotranspiration data in Yongdam study watershed, investigating the hydrological runoff characteristics and water balance in the water cycle analysis. The model was calibrated with different parameter values for each sub-watershed in order to reflect the characteristics of multiple observations through one-by-one calibration, appropriate settings of model simulation run/iteration number (1,000 simulation runs in the first iteration and then 500 simulation runs for the following iterations), and executions of partial and all run in SWAT-CUP. The flow simulation results of watershed outlet point, ENS 0.85, R2 0.87, and PBIAS -7.6%, were compared with the analysis results (ENS 0.52, R2 0.54, and PBIAS -22.4%) applied in the other batch (i.e., non one-by-one) calibration approach and showed better performances of proposed method. From the simulation results of a total of 15 years, it was found that the total runoff (streamflow) and evapotranspiration rates from precipitation are 53 and 39%, and the ratio of surface runoff and baseflow (i.e., sum of lateral and return flow, and recharge deep aquifer) are 35 and 65%, respectively, in Yongdam watershed. In addition, the analytical amount of available water (i.e., water yield), including the total annual streamflow (daily average 21.8 m3/sec) is 6.96 billion m3 per year (about 540 to 900 mm for sub-watersheds).

• Economic and Environmental Geology
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• v.55 no.3
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• pp.219-229
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• 2022

Bentonite is being considered as a candidate for buffer material in geological disposal systems for high-level radioactive wastes. In this study, the effect of cement-bentonite interactions on bentonite alteration was investigated by reviewing the literature on studies of cement-bentonite interactions. The major bentonite alteration by hyperalkaline fluids produced by the interaction of cementitious materials with groundwater includes cation exchange, montmorillonite dissolution, secondary mineral precipitation, and illitization. When the hyperalkaline leachate from the reaction of the cementitious material with the groundwater comes into contact with bentonite, montmorillonite, the main component of bentonite, is dissolved and a small amount of secondary minerals such as zeolite, calcium silicate hydrate, and calcite is produced. When montmorillonite is continuously dissolved, the physicochemical properties of bentonite may change, which may ultimately causes changes in bentonite performance as a buffer material such as adsorption capacity, swelling capacity, and hydraulic conductivity. In addition, the bentonite alteration is affected by various factors such as temperature, reaction period, pressure, composition of pore water, bentonite constituent minerals, chemical composition of montmorillonite, and types of interlayer cations. This study can be used as basic information for the long-term stability verification study of the buffer material in the geological disposal system for high-level radioactive wastes.

• Clean Technology
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• v.16 no.4
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• pp.284-291
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• 2010

Nitrous oxide ($N_2O$) is a greenhouse material which is hard to remove. Even with a catalytic process it requires a reaction temperature, at least, higher than 670 K. This study has been performed to see the effects of Ce addition to the mixed oxide catalyst which shows the highest activity in decomposing $N_2O$ completely at temperature as low as 473 K when CO is used as a reducing agent. Mixed metal oxide(MMO) catalyst was made through co-precipitation process with small amount of Ce added to the base components of Co, Al and Rh or Pd. Consequently, the surface area of the catalyst decreased with the contents of Ce, and the catalytic activity of direct decomposition of $N_2O$ also decreased. However, in the presence of CO, the activity was found high enough to compensate the portion of activity decrease by Ce addition, so that it can be ascertained that the catalytic activity and stability can be maintained in the CO involved $N_2O$ reduction system when Ce is added for the physical stability of the catalyst.

• Journal of Environmental Impact Assessment
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• v.32 no.6
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• pp.431-436
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• 2023

As the industry develops, the amount of heavy metals flowing into the ecosystem is increasing. Heavy metals are difficult to decompose and remain in the ecosystem for a long time and cause toxicity, which is removed by physicochemical methods such as adsorption, filtration, and chemical precipitation during water treatment. In this study, Alginate bead was selected as a chelating resin for adsorbing and removing heavy metals, and the Jellyfish Extract at Immunity reaction (JEI) were mixed to evaluate the adsorption efficiency of heavy metals accordingly. beads mixed with JEI showed high adsorption efficiency in lead (79-99%) and copper (64-70%) according to the characteristics of Alginate, and low adsorption efficiency in cadmium (25-37%) and zinc (5-6%). Although heavy metal adsorption did not increase in proportion to the content of JEI, 50% and 100% JEI beads showed significant increases. As a result of applying the reaction rate equation, it was found that it was more suitable for the pseudo-secondary reaction equation than the pseudo-first reaction equation.

• Journal of Aquaculture
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• v.1 no.1
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• pp.85-102
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• 1988

An experimental study on seedling production and wintering to develop pearl oyster, Pinctada fucata culture in Korea was carried out. from December 1986 to November 1988 in waters of Kori and of Seogwipo as wintering and of Eogu as culturing grounds. All pearl oysters as the sample were imported from Japan. The highest water temperature at Eogu was $23.6^{\circ}C$ in August and the lowest at Kori and Seogwipo were $13.2^{\circ}C$ and $14.0^{\circ}C$c in February, respectively, Phytoplankton was relatively plentiful but mortality of pearl oysters was $20.5\%$, which was twice at Seogwipo, due to high amount of suspended muds. It shows that Seogwipo is better wintering ground even though the amount of phytoplankton is lower than Kori. Average rates of pearl production after 6-months and 15-months period were $58.2\%$ and $48.3\%$ respecitively. Thickness of pearl layer and coating rate were also satisfactory. More than half of the pearls produced was so-called the pink-pearl, the best colour. About $10\%$ of them was the best quality. There were three peaks of D-shape larvae from July to September and it took about one month for D-shape larvae to become seed-shells. Settling was satisfactory and most of them settled at 1$\~$3 m layer and the best was 2 m-layer. Success of settling was supposed due to high water temperature and low precipitation than the normal year.