• 자원리싸이클링
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• 제29권5호
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• pp.28-37
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• 2020

본 연구에서는 알칼리 영역의 소듐바나데이트(NaVO₃) 수용액을 출발물질로 사용하여 침전온도, 염화암모늄 첨가량 및 첨가방법, 수용액의 바나듐 및 수산화나트륨 함량 등이 암모늄메타바나데이트 침전거동에 미치는 영향을 알아보았다. 수용액 pH가 감소할수록, 염화암모늄 첨가량 그리고 수용액의 바나듐 함량이 증가할수록 암모늄메타바나데이트 침전률이 증가하였다. 본 연구조건에서 90% 이상의 암모늄메타바나데이트 침전률을 얻기 위한 기본 조건은 수용액 바나듐 함량 10,000mg/L, 고체 염화암모늄 첨가량 2당량, 침전온도 상온, 침전시간 2시간 이었다. 암모늄메타바나데이트는 침전속도 증가에 따라 침전물 크기가 감소하였으며, 특히 염화암모늄을 액체로 투입할 때, 침전속도는 가장 느리며 침전물 크기는 가장 크게 나타났다. 염화암모늄을 고체로 첨가하여 1차 침전반응 후, 새로운 반응물을 첨가하여 2차 침전반응을 시킬 때, 고체 염화암모늄을 첨가한 침전반응은 수용액에 존재하는 침전물에 영향을 받지 않았다. 그러나 염화암모늄 수용액을 첨가하였을 때는 수용액에 존재하는 침전물 표면에 침적되어 그 크기를 증가시켰다. 수용액 온도에 따른 암모늄메타바나데이트 용해도 차이에 의하여, 바나듐 함량 10,000mg/L 수용액에서는 침전온도가 암모늄메타바나데이트 침전에 영향을 미치며, 바나듐 함량 30,000mg/L 이상의 고농도 수용액에서는 침전온도가 침전반응에 영향을 미치지는 못하였다.

• 한국물환경학회지
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• 제24권6호
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• pp.725-740
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• 2008

In this study a multi-site daily precipitation generator which generates the precipitation with similar spatial correlation, and at the same time, with conserving statistical properties of the observed data is developed. The proposed generator is intended to be a tool for down-scaling the data obtained from GCMs or RCMs into local scales. The occurrences of precipitation are simultaneously modeled in multi-sites by 2-parameter first-order Markov chain using random variables of spatially correlated while temporally independent, and then, the amount of precipitation is simulated by 3-parameter mixed exponential probability density function that resolves the issue of maintaining intermittence of precipitation field. This approach is applied to the Nakdong river basin and the observed data are daily precipitation data of 19 locations. The results show that spatial correlations of precipitation series are relatively well simulated and statistical properties of observed precipitation series are simulated properly.

• Geomechanics and Engineering
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• 제33권1호
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• pp.65-75
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• 2023

Recycled concrete aggregate (RCA) is widely used as a construction material in road construction, concrete structures, embankments, etc. However, it has been reported that calcite (CaCO₃) precipitation from RCA can be a cause of clogging when used in drainage applications. An accelerated calcite precipitation (ACP) procedure has been devised to evaluate the long-term geochemical performance of RCA in subsurface drainage systems. While the ACP procedure was useful for the French Drain application, there remained opportunities for improvement. In this study, key factors that control the formation of calcite precipitation were quantitatively evaluated, and the results were used to improve the current prototype ACP method. A laboratory parametric study was carried out by investigating the effects of reaction temperature and time on the formation of calcite precipitation of RCA, with determining an optimum reaction temperature and time which maximizes calcite precipitation. The improved ACP procedure was then applied to RCA samples that were graded for Type I Underdrain application, to compare the calcite precipitation. Two key findings are (1) that calcite precipitation can be maximized with the optimum heating temperature (75℃) and time (17 hours), and (2) the potential for calcite precipitation from RCA is not as significant as for limestone. With the improved ACP procedure, the total amount of calcite precipitation from RCAs within the life cycle of a drain system can be determined when RCAs from different sources are used as pipe backfill materials in a drain system.

• 한국대기환경학회지
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• 제24권6호
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• pp.693-703
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• 2008

The important source of the mercury in water-column is the influx of atmosphere mercury, via dry and wet deposition. In this study, wet deposition of mercury was estimated to be $14.56{\mu}g/m^2$ during 15 months at the Lake Soyang, which is a little higher than those observed in the several rural US Mercury Deposition Network (MDN) sites with similar precipitation depth. The mercury concentration in precipitation did not show a positive correlation with atmospheric RGM (reactive gaseous mercury) concentration, while maintaining good correlation with atmospheric $PM_{2.5}$ at Soyang Dam. This result suggests that the contribution of particulate Hg to the total Hg wet deposition should be more significant than that of RGM. In this study, both precipitation depth and precipitation type affected the amount of wet deposition and the concurrent mercury levels in precipitation. There was generally an inverse relationship between precipitation depth and Hg concentration in precipitation. Precipitation type was another factor that exerted controls on the Hg concentration in precipitation. As a result, the highest concentration of Hg was observed in snow, followed by in mixture (snow+rain) and in rain.

• 한국농공학회논문집
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• 제54권5호
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• pp.141-153
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• 2012

In this study, we estimated probable precipitation amounts at the target year (2020, 2030, 2040) of 55 weather stations in Korea using the 24 hour annual maximum precipitation data from 1973 through 2009 which should be useful for management of agricultural reservoirs. Not only trend tests but also non-stationary tests were performed and non-stationary frequency analysis were conducted to all of 55 sites. Gumbel distribution was chosen and probability weighted moment method was used to estimate model parameters. The behavior of the mean of extreme precipitation data, scale parameter, and location parameter were analyzed. The probable precipitation amount at the target year was estimated by a non-stationary frequency analysis using the linear regression analysis for the mean of extreme precipitation data, scale parameter, and location parameter. Overall results demonstrated that the probable precipitation amounts using the non-stationary frequency analysis were overestimated. There were large increase of the probable precipitation amounts of middle part of Korea and decrease at several sites in Southern part. The non-stationary frequency analysis using a linear model should be applicable to relatively short projection periods.

• 한국광물학회:학술대회논문집
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• 한국광물학회.한국암석학회 2001년도 공동학술발표회 논문집
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• pp.45-47
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• 2001

Jeju island is composed mainly of volcanic rocks such as basalts, trachytic andesites, tracytes, and sedimentary rocks. About 80% of Jeju soils are classified as Andisols. The amount of annual precipitation in Jeju island is about 1872mm, which is 1.5 times the annual precipitation of south Korea. There is a significant difference In amount of precipitation with regions even within Jeju island. In study area, the annual amount of rainfall is about 1280mm, the lowest in Jeju island while south part of the island has the annual precipitation of 2056mm, though they are only tens of kilometers apart. The parent materials of soils in study area are pyroclastic rocks and tuffs. The soils of non-andic properties have developed in this area since pedogenic process of pyroclastic materials is strongly influenced by climatic factor, especially precipitation. In order to investigate the mineralogical characteristics of soils, X-ray analysis for <0.2 and 2-0.2$\mu\textrm{m}$ size fractions was performed with ethylene glycol solvation, K-, Mg-saturation, heat treatment(110, 330, 550$^{\circ}C$). Acid-oxalate and DCB(sodium hydrosulfite, sodium citrate, sodium bicarbonate) dissolution method was used to assess tile total amounts or Al, si, and hydroxy interlayer or 2:1 layer silicates. XRD was also applied for samples treated with DCB only and DCB-oxalate sequentially. XRD patterns showed that 2:1 and 1:1 layer silicates were found, which are different from soils of Andisols. Vermiculite, chlorite, hydroxy interlayered minreals, and interstratified minerals(vermiculite/chlorite) were observed in 2-0.2$\mu\textrm{m}$ size fractions. After DCB treatments, ethylene glycolated samples with Mg-saturation showed expanded d-spacing, suggesting the possibility of hydroxy interlayered minerals. The amounts of hydroxy interlayered minerals increased in surface soil. Unlike Andisols, short range ordered minerals such as allophane, imogolite and gibbsite were hardly found. Mica and kaolinte existed in small amounts. Results are summarized in Fig 1 and Fig. 2.

• Journal of the Korean Data and Information Science Society
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• 제23권6호
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• pp.1309-1317
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• 2012

Stochastic weather generators are commonly used to simulate time series of daily weather, especially precipitation amount. Recently, a generalized linear model (GLM) has been proposed as a convenient approach to fitting these weather generators. In this paper, a stochastic weather generator is considered to model the time series of daily precipitation at Seoul in South Korea. As a covariate, global temperature is introduced to relate long-term temporal scale predictor to short-term temporal predictands. One of the limitations of stochastic weather generators is a marked tendency to underestimate the observed interannual variance of monthly, seasonal, or annual total precipitation. To reduce this phenomenon, we incorporate time series of seasonal total precipitation in the GLM weather generator as covariates. It is veri ed that the addition of these covariates does not distort the performance of the weather generator in other respects.

• 한국환경과학회지
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• 제4권5호
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• pp.1-1
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• 1995

An attempt was made to study the subdivision of Korea by the annual amount and the annual change pattern of monthly precipitation days(that is one of the important elements of the precipitation characteristics), using the mean values for the years 1961-1990 at the 68 stations. The amplitudes of annual change were normalized and using these values, the principal component analysis was applied to determine the annual change patterns. The results show that they are expressed by the combinations of the three change patterns in almost whole regions of Korea. As a result,the annual change pattern of precipitation days in Korea is classified into 8 types from A to e,in detail, 36 types from A0 to e$\circled2$.And regional division of precipitation days in Korea is divided into 13 regions from I a to IIIC,into detail, 41 regions from I no to IIICl.

• 한국환경과학회지
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• 제4권5호
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• pp.387-402
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• 1995

An attempt was made to study the subdivision of Korea by the annual amount and the annual change pattern of monthly precipitation days(that is one of the important elements of the precipitation characteristics), using the mean values for the years 1961-1990 at the 68 stations. The amplitudes of annual change were normalized and using these values, the principal component analysis was applied to determine the annual change patterns. The results show that they are expressed by the combinations of the three change patterns in almost whole regions of Korea. As a result, the annual change pattern of precipitation days in Korea is classified into 8 types from A to e, in detail, 36 types from A0 to e$\circled2$.And regional division of precipitation days in Korea is divided into 13 regions from I a to IIIC, into detail, 41 regions from I no to IIICl.

• 열처리공학회지
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• 제11권3호
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• pp.192-199
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• 1998

This study was carried out to investigate the influence of variations in the temperature and time of isothermal heat treatment, applied stresses and prestrain on the isothermal transformation behavior of ${\gamma}$ and ${\sigma}$ phases and mechanical properties of 25Cr-7Ni-3Mo duplex stainless steel. The precipitation of ${\gamma}$ and ${\sigma}$ phases through isothermal heat treatment showed the type curves with a certain incubation period, the curve migrated to in a short period of time and the amount of precipitation increased with decreasing isothermal heat treatment temperature. Under the state of isothermal transformation, the precipitation of ${\gamma}$ and ${\sigma}$ phases was stimulated by applied stress, with increasing applied stress, the curves migrated to in a short period of time and also observed that the application of stress has a greater influence on the amount of ${\sigma}$ precipitation than that of ${\gamma}$ precipitation. The precipitation of ${\gamma}$ and ${\sigma}$ phases was stimulated by cold and warm rolling before isothermal heat treatment and precipitation of ${\gamma}$ and ${\sigma}$ phases has a greater influence on the warm rolling than cold rolling. The tensile strength and hardness increased with increasing cold and warm rooling reduction ratio.