• 제목/요약/키워드: pre-oxidation

검색결과 247건 처리시간 0.03초

Cu(Mg) alloy의 산화방지막 형성에 영향을 미치는 인자 (Factors affecting passivation of Cu(Mg) alloy film)

  • 조흥렬;조범석;이원희;이재갑
    • 한국진공학회지
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    • 제9권2호
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    • pp.144-149
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    • 2000
  • Cu(4.5at.% Mg) target을 이용하여 sputtering에 의해 증착된 Cu(Mg) alloy박막의 열처리시 형성되는 산화 방지막 MgO의 박막 특성에 영향을 주는 인자에 대해 살펴보았다. MgO 박막의 산화방지 능력 및 막질에 영향을 주는 인자로는 열처리 온도, $O_2$ 압력, Mg 농도 등으로 나타났다. MgO 박막의 두께는 열처리 온도가 증가함에 따라 증가하다 $500^{\circ}C$ 이상에서는 150 $\AA$ 정도의 성장한계두께를 나타내었다. 표면에 형성되는 MgO 박막은 $O_2$압력이 낮을수록, Mg의 농도가 높을수록 치밀한 MgO가 형성되어 산화방지에 우수한 특성을 보였으며 전 열처리 과정인 진공 열처리 공정은 1at.%정도의 낮은 Mg 농도에서도 치밀한 MgO형성에 매우 효과적임이 확인되었다. 본 연구에서 Cu(Mg) alloy박막의 열처리를 통해 낮은 저항의 Cu박막의 형성과 동시에 산화방지에 우수한 특성을 보이는 MgO 박막을 열처리 온도, $O_2$ 압력, Mg 농도 등의 최적조건을 이용하여 얻어질 수 있음을 확인하였다.

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느타리버섯 물 추출물 투여에 의한 마우스 비장세포 및 사이토카인 활성효과 (Enhancing Effect of Pleurotus ostreatus Extracts on Mouse Spleen and Cytokine Cells Activation)

  • 류혜숙
    • 한국식품영양학회지
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    • 제27권4호
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    • pp.603-608
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    • 2014
  • In vitro 실험을 통한 느타리버섯 물 추출물 첨가가 마우스의 면역세포 증식에 미치는 영향에 대한 연구 결과, 음의 대조군에 비해 느타리 물 추출물을 첨가한 모든 농도에서 비장세포 증식능이 증가하였으며, 특히 $100{\sim}1,000{\mu}g/mL$ 농도에서 유의적으로 증가하였다. 반면, 사이토카인 생성의 경우, IL-2, IFN-${\gamma}$, TNF-${\alpha}$ 사이토카인 생성량을 측정한 결과, 느타리버섯 물 추출물 $50{\sim}500{\mu}g/mL$ 농도에서 생성된 IL-2, IFN-${\gamma}$, TNF-${\alpha}$ 사이토카인은 대조군보다 높은 생성량을 보였다. IFN-${\gamma}$, TNF-${\alpha}$ 사이토카인 모두 50, 100, 250, $500{\mu}g/mL$의 농도에서 높은 생성량을 나타내었다. IL-2의 경우, 생성량이 유의적인 차이는 보이지 않았지만, $50{\mu}g/mL$ 이상에서 증가하는 경향을 보여주었다. 이상의 결과에 의하면 느타리버섯 물 추출물은 마우스 비장 세포를 증식시키고, 사이토카인 생성량에도 영향을 주어, 면역 기관의 주요 기능을 증진시킬 가능성이 있을 것으로 사료되며, 느타리버섯이 면역 증진 기능성 식품 개발의 소재로 활용될 가능성이 있을 것으로 기대된다.

STM에 의한 니트로벤젠 분자의 NDR 특성과 에너지 밴드 구조 (NDR Property and Energy Band Diagram of Nitro-Benzene Molecule Using STM)

  • 이남석;장정수;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.139-141
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    • 2005
  • It is possble to study charge transfer property which is caused by height variation because we can see the organic materials barrier height and STM tip by organic materials energy band gap. Here, we investigated the negative differential resistance(NDR) and charge transfer property of self-assembled 4,4-Di(ethynylphenyl)-2'-nitro-1-(thioacetyl)benzene, which has been well known as a conducting molecule. Self-assembly monolayers(SAMs) were prepared on Au(111), which had been thermally deposited onto pre-treatment($H_{2}SO_{4}:H_{2}O_{2}$=3:1) Si. The Au substrate was exposed to a 1 mM/l solution of 1-dodecanethiol in ethanol for 24 hours to form a monolayer. After thorough rinsing the sample, it was exposed to a $0.1{\mu}M/1$ solution of 4,4-Di(ethynylphenyl)-2'-nitro-1-(thioacetyl)benzene in dimethylformamide(DMF) for 30 min and kept in the dark during immersion to avoid photo-oxidation. After the assembly, the samples were removed from the solutions, rinsed thoroughly with methanol, acetone, and $CH_{2}Cl_{2}$, and finally blown dry with $N_2$. Under these conditions, we measured electrical properties of self-assembly monolayers(SAMs) using ultra high vacuum scanning tunneling microscopy(UHV-STM). The applied voltages were from -1.50 V to -1.20 V with 298 K temperature. The vacuum condition is $6{\times}10^{-8}$ Torr. As a result, we found that NDR and charge transfer property by a little change of height when the voltage is applied between STM tip and electrode.

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Central energy metabolism remains robust in acute steatotic hepatocytes challenged by a high free fatty acid load

  • Niklas, Jens;Bonin, Anne;Mangin, Stefanie;Bucher, Joachim;Kopacz, Stephanie;Matz-Soja, Madlen;Thiel, Carlo;Gebhardt, Rolf;Hofmann, Ute;Mauch, Klaus
    • BMB Reports
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    • 제45권7호
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    • pp.396-401
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    • 2012
  • Overnutrition is one of the major causes of non-alcoholic fatty liver disease (NAFLD). NAFLD is characterized by an accumulation of lipids (triglycerides) in hepatocytes and is often accompanied by high plasma levels of free fatty acids (FFA). In this study, we compared the energy metabolism in acute steatotic and non-steatotic primary mouse hepatocytes. Acute steatosis was induced by pre-incubation with high concentrations of oleate and palmitate. Labeling experiments were conducted using [$U-^{13}C_5$,$U-^{15}N_2$] glutamine. Metabolite concentrations and mass isotopomer distributions of intracellular metabolites were measured and applied for metabolic flux estimation using transient $^{13}C$ metabolic flux analysis. FFAs were efficiently taken up and almost completely incorporated into triglycerides (TAGs). In spite of high FFA uptake rates and the high synthesis rate of TAGs, central energy metabolism was not significantly changed in acute steatotic cells. Fatty acid ${\beta}$-oxidation does not significantly contribute to the detoxification of FFAs under the applied conditions.

베릴륨 확산 처리 된 마다가스카르산 사파이어의 분광특성분석 (Spectroscopic Characteristics of Sapphire from Madagascar Diffused with Beryllium)

  • 정순희;안용길;서진교;박종완
    • 한국광물학회지
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    • 제22권2호
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    • pp.87-95
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    • 2009
  • 마다가스카르산 사파이어를 수평 알루미나 튜브의 전기로에서 대기중의 산화분위기 하에 $1650^{\circ}C$, 50시간의 조건으로 $Be^{2+}$의 확산 처리를 하였다. 자외선-가시광선 분광분석 결과는 각 시료 마다 차이는 있으나 전체적으로 $Fe^{2+}$에서 $Fe^{3+}$로 산화의 원인으로 청색이 옅어졌고 청자색 사파이어는 $Cr^{3+}$에 의한 분홍색이 나타났다. $Be^{2+}$의 확산 처리로 부분적인 갈색이 나타난 청색 사파이어에서는 진한 주황색 부분이 나타났고, 옥화메틸렌에 의한 침적실험 관찰 결과로 시료들의 가장자리에 주황색의 집중현상이 나타났음을 확인하였다. 또한 기존에 있던 내포물도 변화가 나타났다. 그러나 확산 처리 온도의 한계로 더 많은 양의 $Be^{2+}$의 확산이 이루어 지지는 못했다.

관형막을 이용한 혐기소화조의 전처리 농축공정으로써 적용가능성 연구 (Application of tubular membrane to thickening process as a pre-treatment of anaerobic digester)

  • 강희석;박기태;박정우;김형수
    • 상하수도학회지
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    • 제29권2호
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    • pp.203-209
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    • 2015
  • The purpose of this study is to estimate the applicability of a stable anaerobic digester using a separator membrane to the preprocessing thickening process. The results of the experiments showed about a 47.16% weight loss rate for the sludge under anaerobic condition, and about 41.17% under intermittent aeration condition. The concentrations of rejection water were $SCOD_{Cr}$ 25 mg/L, T-N 16.6 mg/L, and T-P 1.4 mg/L on the average under the intermittent aeration condition, which were lower than the concentrations of rejection water under an anaerobic condition. As for the factors affecting the reduction of the flux, correlation analyses of TTF, MLSS, $SCOD_{Cr}$, and $EPS_{Protein}$, $EPS_{Polysacchride}$ resulted in -0.97, -0.95, -0.84 and -0.86, -0.95, respectively, which showed that TTF had the highest correlation to the reduction of the flux. In addition, it was concluded that MLSS, $SCOD_{Cr}$ and $EPS_{Protein}$, $EPS_{Polysacchride}$ also have close correlations. The results are considered to show that, in the case of the process using a tubular membrane in the preprocessing process of an anaerobic digester, an intermittent aeration condition of the thickener considering the contamination of the membrane and load of rejection water is appropriate for the stable preprocessing process.

V2O5 촉매상에서의 메탄올 흡탈착 및 산화반응 - I. CO와 CH3OH의 화학흡착 특성 - (Chemisorption and Oxidation of Methanol over V2O5 Catalyst - I. Chemisorptive Behaviors of CO and CH3OH -)

  • 김을산;최기혁;이호인
    • 공업화학
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    • 제5권2호
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    • pp.189-198
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    • 1994
  • 초고진공하에서 열탈착 실험에 의하여 오산화바나듐 촉매상에서 일산화탄소와 메탄올의 홉착특성을 연구하였다. 일산화탄소는 오산화바나듐 촉매표면의 격자산소 결함을 갖는 바나듐이온이나 바나듐이온에 결합된 이중결합성 산소에 흡착하였다. 격자산소 결함을 갖는 바나듐이온에 흡착한 일산화탄소는 380K에서 탈착되었으며, 바나듐이온에 결합된 이중결합성 산소에 흡착한 일산화탄소는 격자산소와 결합하여 탄산기의 형태를 형성한 후 이산화탄소로 탈착되면서 촉매 표면을 환원시켰다. 선흡착되거나 후흡착되는 산소에 의하여, 탄산기의 형태로 흡착하는 일산화탄소의 흡착량은 증가하였다. 오산화바나듐 촉매상에서 메탄올을 흡착시킨 후 메탄올, 포름알데히드, 일산화탄소, 수소 등의 열탈착실험에 의하여 메탄올의 흡착특성을 연구하였다. 메탄올은 298 K에서 오산화바나듐 촉매상에 methoxy와 hydroxyl기를 형성하면서 분해흡착하였다.

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Variation and Profile of Paralytic Shellfish Poisoning Toxins in Jinhae Bay, Korea

  • Mok, Jong-Soo;Song, Ki-Cheol;Lee, Ka-Jeong;Kim, Ji-Hoe
    • Fisheries and Aquatic Sciences
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    • 제16권3호
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    • pp.137-142
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    • 2013
  • To understand critical aspects of paralytic shellfish poisoning (PSP) in a chief area of bivalve production in Korea, seasonal variation in PSP toxins in bivalves collected from Jinhae Bay, Korea in 2009 was surveyed by the pre-column high-performance liquid chromatography oxidation method. We also confirmed the profiles of major bivalves such as oysters Crassostrea gigas and mussels Mytilus galloprovincialis in Jinhae Bay. PSP toxins in the bivalves showed remarkable seasonal variation. PSP toxin levels were detected from April to May in 2009, and the highest total toxin levels at all stations were recorded in May. The major toxins in bivalves were gonyautoxin [GTX] 1&4 and C 1&2; in oysters GTX 2&3 were also detected as major components. GTX 1&4, which showed the highest PSP toxin levels at each station, accounted for the highest proportions of toxin components in mussels and oysters (64.5-71.3% and 41.4-42.4%, respectively). It was also confirmed that the highest toxicity (in ${\mu}g$ saxitoxin [STX] eq/g) was derived from GTX 1&4. The highest total toxicity (in ${\mu}g$ STX eq/g) was approximately 2-8-fold higher in mussels than in oysters collected from the same station. PSP toxin levels in bivalves differed significantly according to the sample collection station. However, the profiles of toxins in the bivalves did not show significant differences during the survey period according to sample collection station. This study shows that PSP toxin levels in some samples from Jinhae Bay were above the regulatory limit in Korea during a specific period in spring.

대나무잎 추출물에 의한 삼베와 모시섬유의 염색성 (Dyeing Property of Bamboo Leaves Extract on Hemp and Ramie Fiber)

  • 민경혜
    • 한국의류산업학회지
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    • 제13권3호
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    • pp.438-444
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    • 2011
  • Bamboo leaves, as natural dye provide unartificial fresh green, are known for expert property at anti-bacterial, anti-aging, anti-oxidation, skin whitening, moisturizing, peeling of horny, deodorizing and some skin disease like as eczema and inflammation without any allergic response. Also, It is quite common to obtain bamboo leaves from our surrounding but most of them were not in use. On purpose of development the way of recycle with common material to dye, bamboo leaves were used to dye on ramie fiber which is valuable for both of apparel and industrial field and investigated their dyeing property. Using extract from bamboo leaves, dyeing property was examined with dyeability, colorimetric property, light fastness and wash fastness under different conditions by extract density, dyeing time, dyeing method and mordants. As results, dyeing was generally colored in yellowish, K/S Value was shown more higher on hemp fiber than ramie. The most optimum dyeing condition was investigated on pre-mordant treatment, dyeing temperature $60^{\circ}C$, dyeing time 30min and extract density 400%. On the treatment with mordant(Al, Fe, Cu), dyebility on both of hemp and ramie fiber were increased by mordant. Especially with Copper(Cu) as mordant, dyebility was highly increased than any other mordants and dyeings showed in deep color. Also on the fastness test which is the most important to natural dyeing, wash-fastness showed good performance with 4-5 grade but light-fastness was above 4 grade on both of hemp and ramie fiber, lower than wash-fastness overall.

Design Study on a Variable Intake and a Variable Nozzle for Hypersonic Engines

  • Taguchi, Hideyuki;Futamura, Hisao;Shimodaira, Kazuo;Morimoto, Tetsuya;Kojima, Takayuki;Okai, Keiichi
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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    • pp.713-721
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    • 2004
  • Variable air intake and variable exhaust nozzle of hypersonic engines are designed and tested in this study. Dimensions for variable geometry air intake, ram combustor and variable geometry exhaust nozzle are defined based on the requirements of a pre-cooled turbojet engine. Hypersonic Ramjet Engine is designed as a scaled test bed for each component. Actuation forces of moving parts for variable intake and variable nozzle are reduced by balancing the other force in the opposite direction. A demonstrator engine which includes variable intake and variable nozzle is designed and the components are fabricated. Composite material with silicone carbide is applied for high temperature parts under oxidation environment such as leading edge of the variable intake and combustor liner. Internal cooling structure is adopted for both moving and static parts of the variable nozzle. Pressure recovery and mass capture ratio of the variable intake at Mach 5 is obtained by a hypersonic wind tunnel test. Flow characteristics of the variable nozzle are obtained by a low temperature flow test. Wall temperature and heat flux of the nozzle at Mach 3 is obtained by a firing test. As results, the intake and the nozzle are proved to be used at designed pressure and temperature environment.

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