• 보존과학회지
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• 제36권4호
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• pp.284-295
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• 2020

This study focuses on reinforcement agents for wall damage, such as cracks, breakage, or delamination, for mural paintings from the Payathonzu temple. Experiments were conducted with filling and grouting agents based on the reinforcing method. In the filling reinforcement experiment, different mixing ratios of lime to sand, and additives (jaggery, seaweed glue, and Primal SF-016) were used. In the grouting reinforcement experiment, the mixing ratio of lime and pozzolan was the same, and the additive types were identical to the filling reinforcement experiment. The filling reinforcement experiment showed that there were fewer physical changes such as contraction, with a greater mixing ratio of lime to sand, however, the compressive strength decreased as the mixing ratio increased. With additives, the change in volume of agent decreased and the compressive strength increased, which was especially prominent for jaggery and Primal SF-016. The grouting reinforcement experiment showed that there was a remarkable contraction with an increased amount of moisture that originates from the characteristic of grouting agents that requires flowability. With additives, the water content of the agent decreased, whereas the compressive strength and adhesion increased. Among the additives, Primal SF-016 exhibited the highest compressive strength, and seaweed glue exhibited the most considerable viscosity and adhesion. The study results showed that the characteristics of reinforcement agents vary according to the mixing ratio and additives of the filling and grouting agents. Therefore, it is necessary to selectively apply the mixing ratio and additives for different reinforcement agents considering the wall damage for conservation treatments.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2010년도 추계 학술발표회 2차
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• pp.81-87
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• 2010

As enormous construction projects of land development are carried out around Korea, useful construction materials are needed to perform the construction projects. However, there are no more enough of fill and reclamation materials in our country. That is why the coal ash is expected to be utilized as an alternative material. Since the coal ash has the characteristics of a pozzolan and a selfhardening material, it is adjudged that coal ash has a great possibility to be used as a fill and reclamation material. In this study, grain size analysis, Atterberg limit test, and specific gravity test were performed to examine the physical characteristics of the coal ash about a self-hardening material before utilizing the coal ash in the construction. Compaction test, unconfined compression test were conducted to investigate the engineering characteristics according to mixture ratios of fly ash and bottom ash. As a result of the tests, it was confirmed that the mixing ratio 1:1 of fly ash and bottom ash is the most effective to use as a fill and reclamation material. If the mixture of coal ash is used as a backfill material with light weight around structure, it is expected to play a significant role in reducing earth pressure on the back of the structure. As described above, the coal ash should be considered as an alternative material of fill and reclamation materials since the result of the tests indicates that the coal ash is suitable to a useful material on the construction design.

• 한국건축시공학회지
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• 제11권4호
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• pp.363-370
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• 2011

본 연구에서는 화력발전소에서 발생하는 폐기물인 리젝트 애시를 자원화하기 위하여 시멘트 혼합재로 사용하는 방안을 검토하고자 하였다. 이를 위하여 포졸란 활성도 비교를 통하여 효율적인 리젝트애시의 분말도를 선정하였으며, 현재 널리 사용되고 있는 콘크리트용 혼합재인 플라이애시와 비교하였다. 고분말 리젝트애시와 플라이애시를 슬래그시멘트와 혼합하여 시멘트복합체를 제조하였으며, 제조한 시멘트복합체 및 고분말 리젝트애시의 성능 평가를 위하여 페이스트(응결, 유동성, 기기분석), 모르타르(압축강도) 실험을 실시하였다. 기기분석 결과 고분말 리젝트애시의 수화반응기구는 플라이애시와 유사하지만 미세조직이 치밀해지는 특성을 나타내었다. 물성 측정결과에서는 고분말 리젝트애시가 플라이애시와 비교하여 응결지연이 감소하고, 초기강도 및 장기강도에서 우수한 성능을 나타내었다. 따라서 리젝트애시의 분말도를 $6,000cm^2$/g 수준으로 상향시킨다면 시멘트 복합체에 활용하는 것이 가능하며, 시멘트 물성 향상에도 기여할 수 있을 것으로 예상된다.

• 한국재료학회지
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• 제22권11호
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• pp.598-603
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• 2012

MgO based cement for the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. Furthermore, adding reactive MgO to Portland-pozzolan cement can improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, the basic research for magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as starting materials was carried out. In order to increase the hydration activity, $MgCO_3$ and serpentinite were fired at a temperature higher than $600^{\circ}C$. In the case of $MgCO_3$ as starting material, hydration activity was highest at $700^{\circ}C$ firing temperature; this $MgCO_3$ was completely transformed to MgO after firing. After the hydration reaction with water, MgO was totally transformed to $Mg(OH)_2$ as hydration product. In the case of using only $MgCO_3$, compressive strength was 35 $kgf/cm^2$ after 28 days. The addition of silica fume and $Mg(OH)_2$ led to an enhancements of the compressive strength to 55 $kgf/cm^2$ and 50 $kgf/cm^2$, respectively. Serpentine led to an up to 20% increase in the compressive strength; however, addition of this material beyond 20% led to a decrease of the compressive strength. When we added $MgCl_2$, the compressive strength tends to increase.

• KIEAE Journal
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• 제10권5호
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• pp.115-121
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• 2010

Lime was the solidifier mostly used at the fields of construction and civil works in the past. however, the development of Portland cement remarkably reduced the use of it. Recently as the concernment on circumstances gets higher, lime wined attention again as an eco-friendly material and was used at earth-using construction. This study examined the physical and chemical capacity of lime complexes with lime capacity improved, and performed fundamental study on the way to concretize by mixing it with earth. As a result, lime complex pressure strength was lower than cement pressure strength but it showed the possibility that its strength was improved by W/B control. The measurement of XRD after paste formation confirmed a compound generated by the reaction of Ca2+ion and Si, Al, and Fe from pozzolan reaction. A earth wall experiment by using lime complexes and earth showed that the higher, WB or the lower the quantity of unit combined materials, the lower the pressure strength was. The maximum pressure strength was maximum 11MPa when the quantity of unit combined materials was 450. It is because the composed earth particles had a high content of micro powder less than silt, so a lot of combination are demanded to secure fluidity. As a result of peptization experiment, after hardening, the material was not dissolved, which informed of the possibility of use as an outer subsidiary material. If the material is hardened by mold formation method, natural hardening crack appears. Cast expresses smart surface quality and enables to design for multiple purpose. The result shows the possibility of construction of low-story structures by using earth wall made of lime complexes and earth.

• Smart Structures and Systems
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• 제24권4호
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• pp.541-552
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• 2019

Construction development and greenhouse gas emissions have globally required a strategic management to take some steps to stain and maintain the environment. Nowadays, recycled aggregates, in particular ceramic waste, have been widely used in concrete structures due to the economic and environmentally friendly solution, requiring the knowledge of recycled concrete. Also, one of the materials used as a substitute for concrete cement is wollastonite mineral to decrease carbon dioxide (CO2) from the cement production process by reducing the concrete consumption in concrete. The purpose of this study is to investigate the effect of wollastonite on the mechanical properties and durability of conventional composite concrete, containing recycled aggregates such as compressive strength, tensile strength (Brazilian test), and durability to acidic environment. On the other hand, in order to determine the strength and durability of the concrete, 5 mixing designs including different wollastonite values and recovered aggregates including constant values have been compared to the water - cement ratio (w/c) constant in all designs. The experimental results have shown that design 5 (containing 40% wollastonite) shows only 6.1% decrease in compressive strength and 4.9% decrease in tensile strength compared to the control plane. Consequently, the use of wollastonite powder to the manufacturing of conventional structural concrete containing recycled ceramic aggregates, in addition to improving some of the properties of concrete are environmentally friendly solutions, providing natural recycling of materials.

• 한국구조물진단유지관리공학회 논문집
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• 제23권2호
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• pp.20-27
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• 2019

건전자제품의 개발과 생산기술에 비교하여 폐유리의 재활용을 위한 기술개발은 상대적으로 미흡하여 자원낭비와 환경오염이 가속화되고 있다. 해외에서는 이 분야에 대한 기술개발이 활발하게 이루어지고 있으나 국내의 경우, 그 관심도가 부족하여 폐유리를 불법투기 또는 매립으로 처리하고 있는 실정이다. 폐유리는 시멘트와 수화반응시 포졸란 반응가능성이 있는 것으로 확인되어 경화 콘크리트의 물리적 성질을 향상시키고 굳지 않은 콘크리트의 레올로지 특성을 개선하여 블리딩의 저감 및 수화열 발생의 억제 등에 효과적인 것으로 보고되고 있다. 따라서 본 논문에서는 폐유리를 잔골재로 사용한 차폐콘크리트의 알칼리-실리카반응이 팽창에 미치는 영향을 분석하고 폐유리 혼입에 의한 알칼리-실리카반응의 팽창을 억제하기 위한 방안으로 적정 혼화재료를 사용하여 차폐콘크리트의 내구성능을 평가하였다.

• 한국지반신소재학회논문집
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• 제20권4호
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• pp.33-41
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• 2021

장석은 석영과 더불어 국내에서 산출빈도가 가장 높은 광물이나 유리, 도료 등의 제조에 제한적인 이용을 제외하면 물질적 특성과 용도 개발에 대한 연구는 거의 이루어지지 않아 잠재적 가치가 매우 낮게 평가되고 있다. 본 논문에서는 다공성 구조를 특징으로 하는 장석의 재료특성과 열적, 기계적, 화학적, 경량화 활성기법을 적용하여 반응성 개선 특성을 분석하였다. 풍화된 장석의 표면에서 관찰되는 공동의 구조적 특징을 살펴보면 공동들의 배열이 불규칙하게 분포하고 있으며, 공동끼리는 서로 연결되어 있다. 이러한 풍화된 장석의 표면에서 관찰되는 비정형의 연결된 공동으로 인하여 풍화된 장석은 반응면적이 확대되며 시멘트와의 결합재료로서 반응성이 높은 포졸란 재료 역할을 하는 것으로 판단된다. 다공성 장석의 기능성을 향상시키기 위하여 열적, 기계적, 화학적 활성기법을 적용한 결과 양이온교환능력, 밀도, 일축압축강도 특성이 개선되었다. 이러한 다공성 특성에 의하여 풍화된 장석은 물리·화학적 특성이 우수한 친환경 건설재료로 활용이 가능할 것으로 판단된다.

• Computers and Concrete
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• 제31권2호
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• pp.85-95
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• 2023

Natural pozzolans are used as additives in cement to develop more durable and high-performance concrete. Pozzolanic activity index (PAI) is important for assessing the performance of a pozzolan as a binding material and has an important effect on the compressive strength, permeability, and chemical durability of concrete mixtures. However, the determining of the 28 days (short term) and 90 days (long term) PAI of concrete mixtures is a time-consuming process. In this study, to reduce extensive experimental work, it is aimed to predict the short term and long term PAIs as a function of the chemical compositions of various natural pozzolans. For this purpose, the chemical compositions of various natural pozzolans from Central Anatolia were determined with X-ray fluorescence spectroscopy. The mortar samples were prepared with the natural pozzolans and then, the short term and the long term PAIs were calculated based on compressive strength method. The effect of the natural pozzolans' chemical compositions on the short term and the long term PAIs were evaluated and the PAIs were predicted by using multiple linear regression (MLR) and adaptive neuro-fuzzy inference system (ANFIS) model. The prediction model results show that both reactive SiO₂ and SiO₂+Al₂O₃+Fe₂O₃ contents are the most effective parameters on PAI. According to the performance of prediction models determined with metrics such as root mean squared error (RMSE) and coefficient of correlation (R²), ANFIS models are more feasible than the multiple regression model in predicting the 28 days and 90 days pozzolanic activity. Estimation of PAIs based on the chemical component of natural pozzolana with high-performance prediction models is going to make an important contribution to material engineering applications in terms of selection of favorable natural pozzolana and saving time from tedious test processes.

• 대한토목학회논문집
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• 제26권5A호
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• pp.927-934
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• 2006

콘크리트 구조물의 고성능화가 요구됨에 따라 고성능 콘크리트에 관한 연구가 활발히 진행되어 왔으며, 특히 고강도 콘크리트에 관한 많은 연구가 이루어지고 있다. 고강도 콘크리트를 제조하기 위해서는 혼화재료의 첨가가 필수적이라 할 수 있으며, 지금까지는 실리카 퓸을 주로 사용하여 왔으나, 최근에는 실리카 퓸과 대등한 성능을 가지면서 실리카 퓸보다 저가인 메타카올린을 사용한 고강도 콘크리트에 관한 연구가 많이 진행되고 있다. 본 연구에서는 메타카올린을 사용한 고강도 콘크리트의 특성을 규명하기 위하여 시멘트 페이스트 시험체의 XRD 및 SEM 분석을 통하여 메타카올린의 포졸란 반응을 고찰하였고, 콘크리트 시험체를 제작하여 수은압입법으로 공극구조를 분석하여 압축강도와의 상관성을 도출하였다. 그 결과, 메타카올린의 대체율이 증가할수록 평균 공극직경은 작아지고 압축강도는 증가하는 것으로 나타났으며, 본 연구에서는 $10nm{\sim}10{\mu}m$의 모세관 공극량과 압축강도와의 회귀분석 결과 이들 사이의 결정계수는 약 0.93 정도의 높은 상관성이 있었고, 메타카올린의 적정 대체율은 10~15%로 판단된다.