• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.272.2-272.2
• /
• 2016

Copper-Tin (CuSn) thin films were synthsized by rf magnetron co-sputtering method with pure Cu and Sn metal targets with various rf powers and sputtering times. The obtained CuSn thin films were characterized by a surface profiler (alpha step), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), X-ray induced Auger electron spectroscopy (XAES), and contact angle measurement. The deposition rates were calculated by the thickness of CuSn thin films and sputtering times. We observed hexagonal Cu20Sn6 and cubic Cu39Sn11 phases from the films by XRD measurement. From the survey XPS spectra, the Cu and Sn main peaks were observed. Therefore, we could conclude CuSn thin films were successfully fabricated on the substrate in this study. The changes of oxidation states and chemical environment of the films were investigated with high resolution XPS spectra in the regions of Cu 2p, Cu LMM, and Sn 3d. Surface free energy (SFE) and wettability of the CuSn thin films were studied with distilled water (DW) and ethylene glycol (EG) using the contact angle measurement. The total SFE of CuSn thin films decreased as rf power on Cu target increased. The contribution to the total SFE of dispersive SFE was relatively superior to polar SFE.

• Earthquakes and Structures
• /
• v.15 no.1
• /
• pp.1-8
• /
• 2018

A new site classification system and site coefficients based on local site conditions in Korea were developed and implemented as a part of minimum design load requirements for general seismic design. The new site classification system adopted bedrock depth and average shear wave velocity of soil above the bedrock as parameters for site classification. These code provisions were passed through a public hearing process before it was enacted. The public hearing process recommended to modify the naming of site classes and adjust the amplification factors so that the level of short-period amplification is suitable for economical seismic design. In this paper, the new code provisions were assessed using dynamic centrifuge tests and by comparing the design response spectra (DRS) with records from 2016 Gyeongju earthquake, the largest earthquake in history of instrumental seismic observation in Korea. The dynamic centrifuge tests were performed to simulate the representative Korean site conditions, such as shallow depth to bedrock and short-period amplification characteristics, and the results corroborated with the new DRS. The Gyeongju earthquake records also showed good agreement with the DRS. In summary, the new code provisions are reliable for representing the site amplification characteristic of shallow bedrock condition in Korea.

• Bulletin of the Korean Chemical Society
• /
• v.23 no.2
• /
• pp.267-270
• /
• 2002

Photodissociations of o-, m-, and p-iodotoluene radical cations were investigated by using Fourier-transform ion cyclotron resonance (FT-ICR) spectrometry. Iodotoluene radical cations were prepared in an ICR cell by a photoionization charge-transfer method. The time-resolved one-photon dissociation spectra were obtained at 532 nm and the identities of $C_7H_7^+$ products were determined by examining their bimolecular reactivities toward toluene-$d_8$. The two-photon dissociation spectra were also recorded in the wavelength range 615-670 nm. The laser power dependence, the temporal variation, and the identities of $C_7H_7^+$ were examined at 640 nm. The mechanism of unimolecular dissociation of iodotoluene radical cations is elucidated: the lowest barrier rearrangement channel leads exclusively to the formation of the benzyl cation, whereas the direct C-I cleavage channel yields the tolyl cations that rearrange to both benzyl and tropylium cations with dissimilar branching ratios among o-, m-, and p-isomers. With a two-photon energy of 3.87 eV at 640 nm, the direct C-I cleavage channel results in the product branching ratio, [tropylium cation]/[benzyl cation], in descending order, 0.16 for meta >0.09 for ortho >0.05 for para.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.13 no.5
• /
• pp.205-210
• /
• 2003

Alexandrite-like cubic zirconia single crystals were grown by skull melting method. The R.F. generator (output power is 35 ㎾) used for skull melting was operated at 2 MHz. The grown crystals were doped with up to 1 or 1.5 wt% and 0.5 or 1 wt% of rare earth metal ion (Pr, Nd) on$ ZrO_2-Y_2O_3$ (12 mol%). The grown crystals were cut for slice (0.25 mm) and round brilliant (12 mm in diameter). The cut stones were heat treated in air and nitrogen at $1000^{\circ}C$ for 2 hours and their optical absorption spectra ($\lambda$ = 400∼700 nm) data were obtained.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
• /
• 2001.06a
• /
• pp.1252-1252
• /
• 2001

The aim of this study was to evaluate the possibility to characterize and classify waxes applied on some type of cheeses to obtain good stability during handling and transportation. Generally, waxes are obtained from the petrochemical industry, nowadays there is the possibility to also use biodegradable waxes produced from microorganisms. Preliminary studies were carried out to optimize sample presentation in NIR analysis, such as melting conditions (influence of temperature) and coat thickness of wax. 12 waxes (biodegradable or not) were analysed by using an InfraAlyzer 500 (Bran+Luebbe). The sample size was performed cutting pieces of 1.5 cm (height) x 1.5 cm (width) x 1.5 mm (thickness), previously melted at 9$0^{\circ}C$. NIR spectra were collected at room temperature, and data were processed by Sesame Software (Bran+Luebbe) to evaluate qualitative differences among samples by cluster analysis. Waxes were gathered on the basis of their origin (petrochemical or microbial). To better understand the significance of the NIRS bands discriminating among waxes, a two-dimensional correlation with FT-IR spectra, collected by a FT-IR/ATR 420 (JASCO) instrument, was made using 2DCORR program (Galactic Industries). On the basis of its classification power, NIRS appears to be a promising tool when used in routine analysis for a qualitative control of raw materials.

• Journal of the Korean Vacuum Society
• /
• v.13 no.2
• /
• pp.59-64
• /
• 2004

A study on the semiconductor laser-based atomic absorption spectroscopy was performed for monitoring physical vapor deposition process. Gadolinium metal was vaporized with a high evaporation rate by electron beam heating. Real-time atomic absorption spectra were measured by using tunable semiconductor laser beam at 770-794 nm (center wavelength of 780 nm) and its second harmonic at 388-396 nm. Atomic densities of metal vapor can be calculated from the absorption spectra measured. We plot the atomic densities as a function of the electron beam power and compare with the evaporation rates measured by quartz crystal monitor. We demonstrate that the semiconductor laser-based spectroscopic system developed in this study can be applied to monitor the physical vapor deposition process for other metals such as titanium.

• Proceedings of the KOSOMBE Conference
• /
• v.1994 no.05
• /
• pp.105-108
• /
• 1994

A comparative study was made of the valvular sounds produced by normal prosthetic valves with thrombosed prosthetic valves. Comparisons of the closing sound were made for the power frequency spectra associated with individual valves. We used periodogram approach to obtain the spectral characteristics of the valve. Spectral analysis system was tested in mock circulatory system by comparing normal valves with those produced by the same valves but having simulated thrombosis at the hinge of the valve. The heart sounds was recorded from two patients having normal mechanical valve and thrombosed mechanical valve. The estimated spectrum of the thrombosed mechanical valve displayed lower apparent peak frequency than that of the normal valve. The results showed that frequency spectra gave information pertinent to the valve malfunction. Sound spectral analysis is simple and alternative diagnostic tool for early detection of prosthetic valve mal function.

• Wind and Structures
• /
• v.5 no.2_3_4
• /
• pp.209-226
• /
• 2002

When predicting unsteady flow and pressure fields around a structure in a turbulent boundary layer by Large Eddy Simulation (LES), velocity fluctuations of turbulence (inflow turbulence), which reproduce statistical characteristics of the turbulent boundary layer, must be given at the inflow boundary. However, research has just started on development of a method for generating inflow turbulence that satisfies the prescribed turbulence statistics, and many issues still remain to be resolved. In our previous study, we proposed a method for generating inflow turbulence and confirmed its applicability by LES of an isotropic turbulence. In this study, the generation method was applied to a turbulent boundary layer developed over a flat plate, and the reproducibility of turbulence statistics predicted by LES computation was examined. Statistical characteristics of a turbulent boundary layer developed over a flat plate were investigated by a wind tunnel test for modeling the cross-spectral density matrix for use as targets of inflow turbulence generation for LES computation. Furthermore, we investigated how the degree of correspondence of the cross-spectral density matrix of the generated inflow turbulence with the target cross-spectral density matrix estimated by the wind tunnel test influenced the LES results for the turbulent boundary layer. The results of this study confirmed that the reproduction of cross-spectra of the normal components of the inflow turbulence generation is very important in reproducing power spectra, spatial correlation and turbulence statistics of wind velocity in LES.

• Earthquakes and Structures
• /
• v.18 no.3
• /
• pp.297-312
• /
• 2020

The KiK-net by NIED is a vertical array measurement system. In the database of KiK-net, singular pulse waves were observed in the seismic record at the borehole of TTRH02 during the mainshock (the magnitude of Japan Meteorological Agency (M_J) 7.3, M_W 6.8) and aftershock (M_j 4.2) of Tottori-ken Seibu earthquake in 2000. Singular pulse waves were also detected in the seismic records at the borehole of IWTH25 during the Iwate-Miyagi Nairiku earthquake in 2008 (M_J 7.2, M_W 6.9). These pulse waves are investigated by using the wave shape analysis methods, e.g., the non-stationary Fourier spectra and the double integrated displacement profiles. Two types of vibration modes are discriminated as the occurrence mechanism of the singular pulse waves. One corresponds to the reversal points in the displacement profile with the amplitude from 10^-4 m to 10^-1 m, which is mainly related to the fault activity and the amplification pass including the mechanical amplification (collision) of the seismograph in the casing pipe. The other is the cyclic pulse waves in the interval of reversal points, which is estimated as the backlash of the seismograph itself with the amplitude from 10^-5 m to 10^-4 m.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2000.06a
• /
• pp.1829-1835
• /
• 2000

The experimental results of sodium-water reaction noise measurement in frequency range $1{/sim}200kHz$ are presented. The experiments of noise generation under the condition of sodium test facility, water leak rate $0.01{\sim}1.2g/s$ and temperature of sodium $250{\sim}500^{\circ}C$, were carried out. From theoretical study it is noted that the noise resonant attenuation on hydrogen bubbles in liquid sodium plays the significant role for leak noise spectra formation. Interaction of leak noise and hydrogen bubbles in sodium being accompanied by thermal, emission and viscosity energy dissipation was studied. Acoustic noise spectra were investigated from point of view of water leak detection in sodium/water steam generator. The results of sodium-water reaction noise absorption on hydrogen bubbles in liquid sodium by temperature $250{\sim}500^{\circ}C$ are presented. The theoretical model of noise absorption using the coefficients of attenuation was developed. From calculation the coefficients of attenuation were estimated.