• Title/Summary/Keyword: power residue

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Production of uranium tetrafluoride from the effluent generated in the reconversion via ammonium uranyl carbonate

  • Neto, Joao Batista Silva;de Carvalho, Elita Fontenele Urano;Garcia, Rafael Henrique Lazzari;Saliba-Silva, Adonis Marcelo;Riella, Humberto Gracher;Durazzo, Michelangelo
    • Nuclear Engineering and Technology
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    • v.49 no.8
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    • pp.1711-1716
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    • 2017
  • Uranium tetrafluoride ($UF_4$) is the most used nuclear material for producing metallic uranium by reduction with Ca or Mg. Metallic uranium is a raw material for the manufacture of uranium silicide, $U_3Si_2$, which is the most suitable uranium compound for use as nuclear fuel for research reactors. By contrast, ammonium uranyl carbonate is a traditional uranium compound used for manufacturing uranium dioxide $UO_2$ fuel for nuclear power reactors or $U_3O_8-Al$ dispersion fuel for nuclear research reactors. This work describes a procedure for recovering uranium and ammonium fluoride ($NH_4F$) from a liquid residue generated during the production routine of ammonium uranyl carbonate, ending with $UF_4$ as a final product. The residue, consisting of a solution containing high concentrations of ammonium ($NH_4^+$), fluoride ($F^-$), and carbonate ($CO_3^{2-}$), has significant concentrations of uranium as $UO_2^{2+}$. From this residue, the proposed procedure consists of precipitating ammonium peroxide fluorouranate (APOFU) and $NH_4F$, while recovering the major part of uranium. Further, the remaining solution is concentrated by heating, and ammonium bifluoride ($NH_4HF_2$) is precipitated. As a final step, $NH_4HF_2$ is added to $UO_2$, inducing fluoridation and decomposition, resulting in $UF_4$ with adequate properties for metallic uranium manufacture.

In vitro antioxidant activity of black tea (Camellia sinensis L.) residue extract (홍차박 추출물의 in vitro 항산화 활성)

  • Kim, Dong Chung
    • Journal of Applied Biological Chemistry
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    • v.62 no.3
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    • pp.281-286
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    • 2019
  • A black tea (Camellia sinensis L.) residue extract (BTRE) was prepared by 30% ethanol extraction to evaluate its in vitro antioxidant activity. The yield and polyphenol content of BTRE were $22.4{\pm}1.18%$ and $23.2{\pm}1.02{\mu}g$ gallic acid equivalents/mg-extract, respectively. Antioxidant activity of BTRE proportionally increased as BTRE concentration increased. $IC_{50}$ values of BTRE for cation radical, free radical and nitrite scavenging were 141.8, 108.1, and $397.2{\mu}g/mL$, respectively. Also $IC_{50}$ value of BTRE for ferric reducing anti-oxidant power was $97.8{\mu}g/mL$. BTRE effectively inhibited linoleic acid peroxidation. These results imply that BTRE possessed potent antioxidant activity, thus being utilized as a physiologically active material.

Antioxidant and Anti-Proliferative Activities of Oats under Different Solvent Extraction Conditions (추출용매별 귀리의 항산화 및 암세포 증식 억제 활성)

  • Ham, Hyeonmi;Woo, Koan Sik;Park, Ji-Young;Lee, Byongwon;Choi, Yong-Hwan;Lee, Choonwoo;Kim, Wook Han;Lee, Junsoo;Lee, Yu-Young
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.45 no.6
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    • pp.918-922
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    • 2016
  • The objective of this study was to determine the antioxidant and anti-proliferative activities of methanol, ethanol, acetone, and ethyl acetate extracts from oats (Avena sativa L.). Total polyphenol contents of extracts were analyzed by Folin-Ciocalteu assay. The antioxidant activities of extracts were determined by 2,2-azino-bis-(3-ethylbenzothiazoline-6-sulphonic acid) (ABTS) and 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging activities and reducing power. The anti-proliferative activities of colon (HCT116), lung (NCI-H460), and breast (MCF7) cancer cells were investigated. Among solvents, methanol extract showed the highest amount of total polyphenols, which was 8.2 mg gallic acid equivalents/g residue. High levels of ABTS radical [12.1 mg Trolox equivalent antioxidant capacity (TEAC)/g residue] and DPPH radical (4.4 mg TEAC/g residue) scavenging activity and reducing power ($A_{700}=0.39$) were found in methanol extracts. Moreover, methanol extracts indicated higher anti-proliferative activities against HCT116 (69.5%), NCI-H460 (75.2%), and MCF7 (84.8%) cells compared with other extracts. The results show that methanol was the best solvent for extraction of antioxidant and anti-proliferative compounds from oats. Moreover, notable antioxidant and anti-proliferative activities of oats could have significant health benefits.

Efficient programmable power-of-two scaler for the three-moduli set {2n+p, 2n - 1, 2n+1 - 1}

  • Taheri, MohammadReza;Navi, Keivan;Molahosseini, Amir Sabbagh
    • ETRI Journal
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    • v.42 no.4
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    • pp.596-607
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    • 2020
  • Scaling is an important operation because of the iterative nature of arithmetic processes in digital signal processors (DSPs). In residue number system (RNS)-based DSPs, scaling represents a performance bottleneck based on the complexity of intermodulo operations. To design an efficient RNS scaler for special moduli sets, a body of literature has been dedicated to the study of the well-known moduli sets {2n - 1, 2n, 2n + 1} and {2n, 2n - 1, 2n+1 - 1}, and their extension in vertical or horizontal forms. In this study, we propose an efficient programmable RNS scaler for the arithmetic-friendly moduli set {2n+p, 2n - 1, 2n+1 - 1}. The proposed algorithm yields high speed and energy-efficient realization of an RNS programmable scaler based on the effective exploitation of the mixed-radix representation, parallelism, and a hardware sharing technique. Experimental results obtained for a 130 nm CMOS ASIC technology demonstrate the superiority of the proposed programmable scaler compared to the only available and highly effective hybrid programmable scaler for an identical moduli set. The proposed scaler provides 43.28% less power consumption, 33.27% faster execution, and 28.55% more area saving on average compared to the hybrid programmable scaler.

Analysis on the Performance and the Emission of the Integrated Gasification Combined Cycle Using Heavy Oil (중잔사유 가스화 복합발전 사이클의 성능 및 환경배출 해석)

  • Lee, Chan;Yun, Yong-Seong
    • Journal of Energy Engineering
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    • v.10 no.3
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    • pp.188-194
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    • 2001
  • The process simulations are made on the IGCC power plant using heavy residue oil from refinery process. In order to model combined power block of IGCC, the present study employs the gas turbine of MS7001FA model integrated with ASU (Air Separation Unit), and considers the air extraction from gas turbine and the combustor dilution by returned nitrogen from ASU. The exhaust gas energy of gas turbine is recovered through the bottoming cycle with triple pressure HRSG (Heat Recovery Steam Generator). Clean syngas fuel of the gas turbine is assumed to be produced through Shell gasification of Visbreaker residue oil and Sulfinol-SCOT-Claus gas cleanup processes. The process optimization results show that the best efficiency of IGCC plant is achieved at 20% air extraction condition in the case without nitrogen dilution of gas turbine combustor find at the 40% with nitrogen dilution. Nitrogen dilution of combustor has very favorable and remarkable effect in reducing NOx emission level, while shifting the operation point of gas turbine to near surge point.

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A Study on the Minimization of the Refrigeration Power Consumptions Through the Determination of Demethanizer Top Pressure in the NGL Recovery Process Using Turbo-expander (터보 팽창기를 활용한 NGL 회수공정에서 최적의 탈메탄탑의 운전압력 결정을 통한 냉동 소요동력 최소화에 대한 연구)

  • Kim, Yu-Mi;Cho, Jung-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.2
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    • pp.1032-1037
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    • 2011
  • In this study, simulation and optimization works for a demethanizer column have been performed to obtain ethane and heavier products from a pretreated natural gas stream. Pretreated natural gas feed stream was partially condensed after being precooled by exchanging heat with demethanizer top vapor stream and by using an external refrigeration cycle with a propane refrigerant. Vapor stream was cooled further and partially condensed through a turbo-expander. The power generated from the expansion of turbo-expander was delivered to the compressor for the residue gas compression. Liquid stream was cooled by Joule-Thomson expansion valve and was fed to the middle section of the demethanizer. Recovery percent of ethane for feed natural was set to 80% and methane to ethane molar ratio was fixed as 0.0119. On the other hand, some of the cold heat could be recovered by splitting the feed stream and by exchanging heat with side reboiler in order to reduce the heat duty in the propane refrigeration cycle.

Fire Mechanism in Power Connection Points of Outlets and Suggestion of a New Identification Method (콘센트 전원 접속구 화재 발생 메커니즘 고찰과 새로운 감식 방법 제시)

  • Park, Jin-Young;Bang, Sun-Bae;Eun, Hee-Rim;Oh, Se-Hyeok;Lee, Yoo-Bin;Ko, Young-Ho
    • Fire Science and Engineering
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    • v.34 no.3
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    • pp.76-84
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    • 2020
  • Most outlet fires occur around plug pins and plug pin receivers. However, no research has been conducted on ignitions at power connection points. This study confirms the possibility of ignition after incomplete connection, using a stranded wire, to the power connection point of an outlet. The experiment was divided into basic and reproducing experiments. The basic experiment confirmed the possibility of ignition according to the number of wire strands connected to the power connection point, and it identified the characteristics of the residue after the fire. In the reproducing experiment, lamps, vacuum cleaners, and heaters were connected to an outlet to check if the ignition at the connection advanced into a fire. The fire advanced due to the heat and arc generated at the connection point, and partial losses were identified in the U-type holder and clip. Accordingly, the results demonstrate that a fire may occur when the stranded wire is incompletely connected to the outlet. Moreover, it was confirmed that the cause of a fire can be determined based on the characteristics of the residue.

A study of Facts Application in power systems for the small signal Stablity Enhancement (전력계통에서의 유연송전시스템 적용에 의한 미소신호안정도향상)

  • Baik, Seung-Do;Lee, Byong-Jun;Jang, Byong-Hun
    • Proceedings of the KIEE Conference
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    • 2000.07a
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    • pp.255-258
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    • 2000
  • The supplementalγ controls of the FACTS are designed for the enhancement of the small signal stability in power system. The designed supplementary controllers using residue are applied to SVC or TCSC for the improving the damping ratio of dominant eigen value in the New England and 39 bus test system as the sample system. The results show the validation of the supplementary controller for the enhancement of the eigenvalues which have the low frequency oscillations with poor damping ratio as the unstable problem in the sample system.

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Comparison of Pesticide Residue Amounts in Apple Trees Applied by Different Sprayers and Spray Volumes (살포기 종류별 살포물량별 사과 중 농약 잔류량의 비교)

  • Moon, Seong-Hwan;Kwon, Hyeyoung;Hong, Su-Myeong;Kim, Sang-Su;Son, Kyung-Ae;Lim, Chi-Hwan
    • The Korean Journal of Pesticide Science
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    • v.20 no.3
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    • pp.264-270
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    • 2016
  • This study was conducted to compare of the pesticide residue amounts in fruit trees applied by different sprayers and spray volumes. Apple tree was used as a sample tree, and speed sprayer, power sprayer and knapsack motorized sprayer were tested. For similar sprayer and spray volume, the concentration of fluquinconazole and flusilazole in apple leaves were obtained respectively, for speed sprayer 8.33 and 2.15 mg/kg, for power sprayer 4.56 and 1.10 mg/kg, and for knapsack 4.55 and 1.12 mg/kg. The results showed that the treatment using speed sprayer had highest efficiency. The pesticide residues in apple leaves sprayed by 3 different spray volumes (560, 336 and 230 L/10a) using speed sprayer were 10.76 mg/kg, 8.32 mg/kg, 6.04 mg/kg on fluqinconazle and 3.04 mg/kg, 2.14 mg/kg and 1.47 mg/kg on flusilazole, respectively, indicating that the higher the volume, the higher the residues. The results from this study can be used as scientific basis for evaluating the field trial data for pesticide registration and the spray volume setting for fruit trees in Korea.

Properties of AlSi etching using the MERIE type reactor (MERIE형 반응로를 이용한 AlSi의 식각 특성)

  • 김창일;김태형;장의구
    • Electrical & Electronic Materials
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    • v.9 no.2
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    • pp.188-195
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    • 1996
  • The AlSi etching process using the MERIE type reactor carried out with different process parameters such as C1$_{2}$ and N$_{2}$ gas flow rate, RF power and chamber pressure. The etching characteristics were evaluated in terms of etch rate, selectivity, uniformity and etched profile. As the N2 gas flow rate is increased, the AlSi etch rate is decreased and uniformity has remained constant within .+-.5%. The etch rate is increased and uniformity is decreased, according to increment of the C1$_{2}$ gas flow rate, RF power and chamber pressure. Selective etching of TEOS with respect to AlSi is decreased as the RF power is increased while it is increased by increment of the C1$_{2}$ gas flow rate and chamber pressure, on the other hand, selective etching of photoresist with respect to AlSi is increased by increment of the C1$_{2}$ gas flow rate and chamber pressure, it is decreased as the N$_{2}$ gas flow rate is increased.

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