• 한국재료학회지
• /
• 제24권1호
• /
• pp.37-42
• /
• 2014

Well-distributed ruthenium (Ru) nanoparticles decorated on porous carbon nanofibers (CNFs) were synthesized using an electrospinning method and a reduction method for use in high-performance elctrochemical capacitors. The formation mechanisms including structural, morphological, and chemical bonding properties are demonstrated by means of field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). To investigate the optimum amount of the Ru nanoparticles decorated on the porous CNFs, we controlled three different weight ratios (0 wt%, 20 wt%, and 40 wt%) of the Ru nanoparticles on the porous CNFs. For the case of 20 wt% Ru nanoparticles decorated on the porous CNFs, TEM results indicate that the Ru nanoparticles with ~2-4 nm size are uniformly distributed on the porous CNFs. In addition, 40 wt% Ru nanoparticles decorated on the porous CNFs exhibit agglomerated Ru nanoparticles, which causes low performance of electrodes in electrochemical capacitors. Thus, proper distribution of 20 wt% Ru nanoparticles decorated on the porous CNFs presents superior specific capacitance (~280.5 F/g at 10 mV/s) as compared to the 40 wt% Ru nanoparticles decorated on the porous CNFs and the only porous CNFs. This enhancement can be attributed to the synergistic effects of well-distributed Ru nanoparticles and porous CNF supports having high surface area.

• Steel and Composite Structures
• /
• 제43권1호
• /
• pp.129-137
• /
• 2022

Dynamic response of a laminated porous concrete beam reinforced by nanoparticles subjected to harmonic transverse dynamic load is investigated considering structural damping. The effective nanocomposite properties are evaluated on the basis of Mori-Tanaka model. The concrete beam is modeled by the sinusoidal shear deformation theory (SSDT). Utilizing nonlinear strains-deflection, energy relations and Hamilton's principal, the governing final equations of the concrete laminated beam are calculated. Utilizing differential quadrature method (DQM) as well as Newmark method, the dynamic displacement of the concrete laminated beam is discussed. The influences of porosity parameter, nanoparticles volume percent, agglomeration of nanoparticles, boundary condition, geometrical parameters of the concrete beam and harmonic transverse dynamic load are studied on the dynamic displacement of the laminated structure. Results indicated that enhancing the nanoparticles volume percent leads to decrease in the dynamic displacement about 63%. In addition, with considering porosity of the concrete, the dynamic displacement enhances about 2.8 time.

• Steel and Composite Structures
• /
• 제49권3호
• /
• pp.349-359
• /
• 2023

Dynamic response and economic of a laminated porous concrete beam reinforced by nanoparticles subjected to harmonic transverse dynamic load is investigated considering structural damping. The effective nanocomposite properties are evaluated on the basis of Mori-Tanaka model. The concrete beam is modeled by the sinusoidal shear deformation theory (SSDT). Utilizing nonlinear strains-deflection, energy relations and Hamilton's principal, the governing final equations of the concrete laminated beam are calculated. Utilizing differential quadrature method (DQM) as well as Newmark method, the dynamic displacement of the concrete laminated beam is discussed. The influences of porosity parameter, nanoparticles volume percent, agglomeration of nanoparticles, boundary condition, geometrical parameters of the concrete beam and harmonic transverse dynamic load are studied on the dynamic displacement of the laminated structure. Results indicated that enhancing the nanoparticles volume percent leads to decrease in the dynamic displacement about 63%. In addition, with considering porosity of the concrete, the dynamic displacement enhances about 2.8 time.

• 센서학회지
• /
• 제24권6호
• /
• pp.385-391
• /
• 2015

In this paper, we propose a new method to infiltrate $Fe_3O_4$-nanoparticles into a porous silicon film and a monitoring technique to detect packing density of nanoparticles within the film. Recently, research to use porous silicon as a drug carrier or a new functional sensor material by infiltrating $Fe_3O_4$-nanoparticles has been extensively performed. However, it is still necessary to enhance the packing density and to develop a monitoring technique to detect the packing density in real time. In this light, we forcibly injected a nanoparticle solution into a rugate-structured free-standing porous silicon (FPS) film by applying a pressure difference between the two sides of the film. We found that the packing density by the pressure-infiltration method proposed in this paper is enhanced, relative to that by the previous diffusion method. Moreover, a continuous shift in wavelength of the rugate reflectance peak measured from the film surface was observed while the nanoparticle solution was being injected. By exploiting this phenomenon, we could qualitatively monitor the packing density of $Fe_3O_4$-nanoparticles within the FPS film with the injection volume of the nanoparticle solution.

• 통합자연과학논문집
• /
• 제2권1호
• /
• pp.37-40
• /
• 2009

Synthesis and characterization of alkyl-capped nanocrystalline silicon (R-n-Si) have been achieved from the reaction of silicontetrachloride with magnesiumsilicide. Surface of silicon nanocrystal has been derivatized with various alkyl groups (R=methyl, n-butyl, etc.). Silicon nanoparticles have been also obtained by the sonication of luminescent porous silicon. Former exhibits an emission band at 360 nm, but latter exhibits an emission band at 680 nm. In this study very sensitive detection of TNT (2,4,6-trinitrotoluene), DNT (2,4-dinitrotoluene), NB (nitrobenzene), and PA (picric acid) has been achieved in gas phase with porous silicon using photoluminescence quenching of the silicon crystallites as a transduction mode. Porous silicon are electrochemically etched from crystalline silicon wafers in an aqueous solution of hydrofluoric acid. We have characterized these silicon nanoparticles by Luminescence Spectrometer (LS 55).

• 한국입자에어로졸학회지
• /
• 제7권3호
• /
• pp.79-85
• /
• 2011

Porous $TiO_2-SiO_2$ particles were synthesized by co-assembly of nanoparticles of $TiO_2$ and $SiO_2$ in evaporating aerosol droplets. Poly styrene latex (PSL) particles were employed as a template of porous particles. Flowrate of dispersion gas, weight ratio of $TiO_2/SiO_2$ and $SiO_2$ concentration in the precursor, and PSL size were chosen as process variables. The morphology, crystal structure, chemical bonding, and pore size distribution were analyzed by FE-SEM, XRD, FT-IR, BET. The morphology of porous $TiO_2-SiO_2$ particles was spherical and the average particle size range were from 1 to $10{\mu}m$. The particles were composed of meso and macro pores. The average particle diameter and pore volume of the as prepared particles were dependant on process variables. It was found that UV-Vis absorption of the porous particles was comparable with pure $TiO_2$ nanoparticles even though $TiO_2/SiO_2$ ratio is low in the porous particles.

• Macromolecular Research
• /
• 제14권4호
• /
• pp.430-437
• /
• 2006

The ultra-drawing process of an ultra high molecular weight polyethylene (UHMWPE) gel film was examined by incorporating linear low-density polyethylene (LLDPE) and $BaTiO_3$ nanoparticles. The effects of LLDPE and the draw ratios on the morphological development and mechanical properties of the nanocomposite membrane systems were investigated. By incorporating $BaTiO_3$ nanoparticles in the UHMWPE/LLDPE blend systems, the ultra-drawing process provided a highly extended, fibril structure of UHMWPE chains to form highly porous, composite membranes with well-dispersed nanoparticles. The ultra-drawing process of UHMWPE/LLDPE dry-gel films desirably dispersed the highly loaded $BaTiO_3$ nanoparticles in the porous membrane, which could be used to form multi-layered structures for electronic applications in various embedded, printed circuit board (PCB) systems.

• Geomechanics and Engineering
• /
• 제36권4호
• /
• pp.407-416
• /
• 2024

Dynamic response of a rock tunnels by laminated porous concrete beam reinforced by nanoparticles subjected to harmonic transverse dynamic load is investigated considering structural damping. The effective nanocomposite properties are evaluated on the basis of Mori-Tanaka model. The concrete beam is modeled by the exponential shear deformation theory (ESDT). Utilizing nonlinear strains-deflection, energy relations and Hamilton's principal, the governing final equations of the concrete laminated beam are calculated. Utilizing differential quadrature method (DQM) as well as Newmark method, the dynamic displacement of the concrete laminated beam is discussed. The influences of porosity parameter, nanoparticles volume percent, agglomeration of nanoparticles, boundary condition, geometrical parameters of the concrete beam and harmonic transverse dynamic load are studied on the dynamic displacement of the laminated structure. Results indicated that enhancing the nanoparticles volume percent leads to decrease in the dynamic displacement about 63%. In addition, with considering porosity of the concrete, the dynamic displacement enhances about 2.8 time.

• KSBB Journal
• /
• 제28권4호
• /
• pp.225-229
• /
• 2013

Bovine Carbonic anhydrase (BCA) was immobilized on a submicro-porous membrane through covalent immobilization. The immobilization was conducted on the porous membrane surface with the treatment of polyethyleneimine, glutaraldehyde, and the anhydrase, in sequence. The immobilization was confirmed using X-ray photon spectrometer. The pH values of carbon-dioxide saturated solution with buffer were monitored with respect to time to calculate the catalytic activities of hydration of carbon-dioxide for free and immobilized CA. The catalytic rate constant values for free CA, immobilized CA on polystyrene nanoparticles, and immobilized CA on a porous cellulose acetate membrane were 0.79, 0.67, and 0.56 $s^{-1}$, respectively. Reusability was studied up to 10 cycles of $CO_2$ sequestration. The activity for the CA immobilized on the membrane was kept to 95% after 10 cycles, and comparable to the CA on the nanoparticles. The stabilities for heat and storage were also investigated for the three cases. The results suggested that the CA immobilized the membrane had the least loss rate of the activity compared to the others. From this study, the porous membrane was feasible as a carrier for the CA immobilization in hydration and sequestration of carbon-dioxide.

• Advances in nano research
• /
• 제3권2호
• /
• pp.111-121
• /
• 2015

$CoFe_2O_4$ nanotubes and porous nanorods were prepared via a simple one-pot template-free hydrothermal method and were used as an adsorbent for the removal of dye contaminants from water. The properties of the synthesized nanotubes and porous nanorods were characterized by electron diffraction, transmission electron microscopy and x-ray powder diffraction. The Adsorption characteristics of the $CoFe_2O_4$ were examined using polar red dye and the factors affecting adsorption, such as, initial dye concentration, pH and contact time were evaluated. The overall trend followed an increase of the sorption capacity reaching a maximum of 95% dye removal at low pHs of 2-4. An enhancement in the removal efficiency was also noticed upon increasing the contact time between dye molecules and $CoFe_2O_4$ nanoparticles. The final results indicated that the $CoFe_2O_4$ nanotubes and porous nanorods can be considered as an efficient low cost and recyclable adsorbent for dye removal with efficiency 94% for Cobalt ferrite nanotubes and for Cobalt ferrite porous nanorods equals 95%.