• Title/Summary/Keyword: pores structure

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Measurement of the construction structure of hot-heated cement using nitrogen adsorption method (질소흡착법을 사용한 고온 가열 시멘트의 세공구조 측정)

  • Kim, Min-Hyouck;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.140-141
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    • 2020
  • Concrete has a lower thermal conductivity or thermal diffusion coefficient compared to other building materials, so it is widely used as fireproof compartment material or refractory material for structures. However, in the event of thermal damage such as fire, cement curing agents and aggregates act differently, resulting in heat generation or deterioration of tissue due to dehydration, resulting in deterioration of physical properties and fire resistance. Therefore, in this study, the processing structure of cement paste is measured through nitrogen absorption method. The test specimen is a cement paste of 40% W/C and is set at 1000 ℃ under heating temperature conditions. As the temperature rose, the micro-pore mass below was reduced based on about 0.01 감소m, but the air gap above that was increased.Thus, in the range of pores measured in nitrogen adsorption, the air mass tended to decrease under high temperature conditions.

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A Study for the fabrication of Au dot-arrays using porous alumina film (다공성 알루미나 박막을 이용한 Au dot-arrays의 제작에 관한 연구)

  • Jung, Kyung-Han;Park, Sang-Hyun;Shin, Hoon-Kyu;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.922-925
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    • 2003
  • The interest of self-organization materials that have uniform and regular structure in nano scale has been grown due to their utilization in various fields of nanotechnology. An attractive candidate among these materials is anodic aluminum oxide film, which are formed by anodization of aluminum in an appropriate acid solution. The anodic aluminum oxide film has a highly ordered porous structure with very uniform and nearly parallel pores that can be organized in an almost precise close-packed hexagonal structure. In this study, we attempt to make Au dot arrays, which were fabricated using anodic aluminum oxide film as an evaporation mask. The Au dot arrays have a uniform sized dots and spacing to its neighbors and the average diameter of Au dots is about 60 nm corresponding to them of the mask.

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Microstructure and Electrical Properties of In2O3 Thin Films Fabricated by RF Magnetron Sputtering (RF Magnetron Sputtering 방법으로 제조한 In2O3 박막의 미세구조와 전기적 특성)

  • Jeon, Yong-Su;Yun, Yeo-Chun;Kim, Seong-Su
    • Korean Journal of Materials Research
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    • v.12 no.4
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    • pp.290-295
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    • 2002
  • Microstructure and electrical properties of $In_2O_3$ transparent thin films are analyzed on the basis of Structure Zone Model (SZM) proposed by Thornton. Thin films are deposited on glass substrate by RF magnetron sputtering with variation of substrate temperature $(T_s)$ and argon gas pressure $(P_{Ar})$. Microstructure of Zone I of SZM is observed with lowering of substrate temperature or increasing of argon pressure. The higher electrical resistivity of those specimens is due to micro-pores or voids between columnar grains. At the conditions of $T_s=450^{\circ}C$ and $P_{Ar}$=4.2mTorr, the Zone II structure of SZM and the lowest electrical resistivity $(2.1{\times}10^{-2}{\Omega}cm)$ are observed. The dense structure of columnar grains with faceting on growing surface and preferred orientation of (100) plane are observed in those specimens.

A Study on Development of New Repair Method by High Pressure Spray (고압 스프레이 방식 신보수공법의 개발에 관한 연구)

  • Woo, Jong-Tae;Jang, Suk-Hwan;Kim, Yong-Chul
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.7 no.1
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    • pp.279-288
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    • 2003
  • This study is the development of method on repairing concrete structure for progressing the durability of reinforced concrete. This method is wet spray method which compress and conduct mortar pre-mixed with polymer powder to hose by high pressure pump and spray it on the section of concrete structure through nozzle made specially. Characters of this method are that materials are selected with the sort of structure and the cause of deterioration and macro pores are removed in repaired section by conducting with high pressure and spraying with high velocity for progressing the durability of concrete structure. This study has carried out that the minimum capacity of rebound was measured with various condition and physical properties of sample made by spray method were estimated in comparing with sample made by previous hand method. Also, properties of long-term have carried out after this method was applied on site. According to experimental study, the capacity of rebound showed below 5% and physical properties of sample made by spray method were superior to that of sample made by hand method and physical and durable properties of long-term showed excellence.

Effect of Shell Structure of Artificial Lightweight Aggregates on the Emission Rate of Absorbed Water (인공경량골재의 표피층 구조가 흡수된 물의 방출속도에 미치는 영향)

  • Kang, Seung-Gu
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.750-754
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    • 2008
  • The artificial aggregates with dense surface layer (shell) was fabricated and the dependence of water emission rate upon the shell structures was studied. The EAF dust containing many flux components and waste white clay with ignition loss of above 48% were used as for liquid phase and gas forming agents during a sintering process respectively. In addition, the shell structure was modified with various processes and the modification effect on water emission rate was analyzed. The pores under $10{\mu}m$ were found in the sintered artificial light aggregates and disappeared by incorporating to a bigger pore during re-sintering. The water emission rate in an initial step depended on a void content of aggregates filled in a bottle rather than a shell structure. But, after 7 days where the water emission of the aggregate with a shell is above 40%, the shell of aggregates suppressed the water emission. The core of aggregates was exposed and most shell was lost when crushed to smaller size so, the ability for suppressing water emission of the crushed aggregates decreased. The activation energy for the water emission was $3.46{\pm}0.25{\times}10^{-1}$J/mol for the most specimens showing that the activation energy is irrelevant to the pore size distribution and shell structure.

Freeze Drying Process and Pore Structure Characteristics of Porous Cu with Various Sublimable Vehicles (다양한 동결제를 이용하여 동결건조 공정으로 제조한 Cu 다공체의 기공구조 특성)

  • Lee, Gyuhwi;Oh, Sung-Tag;Suk, Myung-Jin;Jeong, Young-Keun
    • Journal of Powder Materials
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    • v.27 no.3
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    • pp.198-202
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    • 2020
  • The effect of sublimable vehicles on the pore structure of Cu fabricated by freeze drying is investigated. The 5 vol% CuO-dispersed slurries with camphene and various camphor-naphthalene compositions are frozen in a Teflon mold at -25℃, followed by sublimation at room temperature. After hydrogen reduction at 300℃ and sintering at 600 ℃, the green bodies of CuO are completely converted to Cu with various pore structures. The sintered samples prepared using CuO/camphene slurries show large pores that are aligned parallel to the sublimable vehicle growth direction. In addition, a dense microstructure is observed in the bottom section of the specimen where the solidification heat was released, owing to the difference in the solidification behavior of the camphene crystals. The porous Cu shows different pore structures, such as dendritic, rod-like, and plate shaped, depending on the composition of the camphornaphthalene system. The change in pore structure is explained by the crystal growth behavior of primary camphor and eutectic and primary naphthalene.

An Experimental Study on Freezing-Thawing and Mechanical Properties of Lightweight Foamed Concrete Using Micro Foaming Agent (기포제를 사용한 경량 콘크리트의 역학적 특성 및 동결융해 평가에 관한 실험적 연구)

  • Min, Tae-Beom;Woo, Young-Je;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.69-72
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    • 2009
  • This research is focused on the applying of the foaming agent which can make the independent pore in the concrete structure in order to make a lightweight concrete structure. This lightweight foamed concrete can satisfy both the required strength and the mechanical properties as structural members. In addition, anti freezing-thawing properties also required. As a result of the unit volume-weight measurement, when the foaming agent mixed at 0.5% to 1%, the lightweight foamed concrete can be applied for the structural member. Also the density and compressive strength measurement results reveals that it will be suitable as structural member with 21MPa strength, when the density is betweenity8 to 1.9 and foaming agent quantities are 0.5% to 1%. Finally the result of freezing-thawing experiment, the effect freezing-thawing damage reduced according to adding foaming agent because those foaming agent make micro-pores in the structure which are not seen in the ordinary concrete structure.

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The Effects of Acid Treatment of Bentonite on Its Crystal Structure (산처리 과정에 따른 벤토나이트의 결정구조 변화)

  • Yoon, Soh-Joung;Moon, Hi-Soo
    • Economic and Environmental Geology
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    • v.27 no.6
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    • pp.507-521
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    • 1994
  • Bentonite occurs in the Janggi Conglomerate of Tertiary age and consists mainly of montmorillonite with Mg as predominant interlayer cations. The bentonite was reacted with various concentrations of sulfuric acid (0.8~1.5M) for various reaction time (1-10h) at $103^{\circ}C$. Cation exchange capacity, exchangeable cations, surface area and solid acidity of the original bulk and acid activated bentonites were measured. Chemical analysis, X-ray diffraction, differential thermal analysis and infrared spectroscopy were used to characterize the changes in structure and properties of the acid activated bentonite. The dissolution of octahedral cations occurs not only from the edge of the clay platelets but also throughout the whole clay structure creating vacant octahedral sites. These lattice defects are created by $H^+$ diffused into the smectite layers. The cations leached possibly from the octahedral sheets are adsorbed on the interlayer exchange sites. They are exchanged with hydronium ions again by stronger acid attack. These reactions create wedge-shaped pores resulting in the increase of the surface area and the changes the morphology in the lattice structure.

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Probabilistic LCC evaluation for Surface Repair of carbonated RC structure (탄산화된 RC구조물의 표면보수에 대한 확률론적 LCC 평가)

  • Lee, Hyung-Min;Yang, Hyun-Min;Lee, Han-Seung
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.2
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    • pp.41-48
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    • 2018
  • Carbonation is one of the major detrimental factors to the reinforced concrete structures owing to penetration of atmospheric CO2 through the micro pores, thereby it reduces the durability of the concrete. The maintenance periods and cost for concrete according to the coefficient variation of different finishing materials is documented in literature. However, it is required to carry out the systematic and well planned studies. Therefore, keeping them in mind, surface repair was carried out to the carbonated concrete and the maintenance cost was calculated to measure the durability life after repair with different variable. The deterministic and probabilistic methods were applied for durability and repair cost of the concrete. In the existing deterministic model, the cost of repair materials increases significantly when the concrete structure reaches its service life. In present study using a stochastic model, the maintenance period and cost was evaluated. According to obtained results, there was no significant difference in the number of maintenance of the coefficient variation. The initial durability has a great influence on the maintenance time and cost of the structure. Unlike the deterministic model, the probabilistic cost estimating model reduces the number of maintenance to the target service life expectancy.

A coupled simulation of parametric porous microstructure and stress-strain behavior in mechanical components under variable cyclic loads

  • Domen Seruga;Jernej Klemenc;Simon Oman;Marko Nagode
    • Coupled systems mechanics
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    • v.12 no.5
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    • pp.409-418
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    • 2023
  • A coupled algorithm is proposed which first considers the creation of porous structure of the material and then the simulations of response of mechanical components with porous structure to a variable load history. The simulations are carried out by the Prandtl operator approach in the finite element method (FEM) which enables structural simulations of mechanical components subjected to variable thermomechanical loads. Temperature-dependent material properties and multilinear kinematic hardening of the material can be taken into account by this approach. Several simulations are then performed for a tensile-compressive specimen made of a generic porous structure and mechanical properties of Aluminium alloy AlSi9Cu3. Variable mechanical load history has been applied to the specimens under constant temperature conditions. Comparison of the simulation results shows a considerable elastoplastic stress-strain response in the vicinity of pores whilst the surface of the gauge-length of the specimen remains in the elastic region of the material. Moreover, the distribution of the pore sizes seems more influential to the stress-strain field during the loading than their radial position in the gauge-length.