• Title/Summary/Keyword: pore size distributions

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Effects of Some Construction Variables on the Hydraulic Conductivity of Soil-Cement in Low Permeable Applications (시공조건이 시멘트계 고화토의 투수계수에 미치는 영향)

  • 정문경;김강석;우제윤
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.11a
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    • pp.427-434
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    • 2000
  • Hydraulic conductivity of soil-cement was measured as a function of some selected construction variables that are often encountered in practice. They are initial (or compaction) water content, delayed compaction after mixing, and repeated freezing and thawing. Sandy and clayey soils were used. The hardening agent used was a cement based soil stabilizer consisting of 80% of ordinary Portland cement and 20% of a combination of supplementary materials. Hydraulic conductivity of soil-cement with varying initial water content was, in trend, similar to that of compacted clay. Hydraulic conductivity of soil-cement decreased with increasing initial water content and reached its minimum when compacted wet of optimum water content. Pore size distributions of soil cement at different initial water contents were analyzed using mercury intrusion porosimetry. The analysis showed that dryer condition led to the formation of larger pores with lesser total pore volume; smaller pores with larger total pore volume at wetter condition. Hydraulic conductivity of soil-cement increased by orders in magnitude when specimen underwent delayed compaction of longer than 4 hours after mixing and repeated freezing and thawing.

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A study on Production of Al Foam by Using of Al Return Scrap for Sound and Vibration Absorption Materials

  • Hur, Bo-Young;Kim, Sang-Youl;Park, Dae-Chol;Jeon, Sung-Hwan;Park, Chan-Ho;Yoon, Ik-Sub
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.198-201
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    • 2001
  • Porous structures of aluminum foam have been studied by using return aluminum scrap. The apparent foam shape, foam height, density, pore size and their distributions in various section areas of the experimental samples have been investigated. The sample have been cast into metallic mold, using aluminum foam prepared from a precursor based on pure Al ingot and return aluminum scrap mixed with various amounts of 1-2wt% increasing viscosity and foam agent materials. The process provides for flexibility in design of foam structures via relatively easy control over the amount of hydrogen evolution and the drainage processes which occur during foam formation. This is facilitated by manipulating parameters such as the foaming agent, thermal histories during solidification and mix melt viscosities. A metal for producing the foamed are decomposing a foaming agent in a molten metal such that there is an initial and a subsequent expansion due to foaming agent. It has been found that the Al porous foaming with variation amount of 1∼2wt% foam agent and at 2min holding time, which melting temperature has appeared homogeneous pore size at 650∼700$^{\circ}C$. The compression strength were 10-13 kg/min at 125ppi, and increased by higher pore density. The acoustical performance of the panel made with the foamed aluminum is considerably improved; its absorption coefficient shows NRC 0.6-0.8. It has been found that the Al foam is very preferable for the compactness of the thermal system.

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Rejection Properties of Silica Nanoparticles from Ultrafiltration Membranes

  • Hiromitsu Takaba;Yoshiaki Ito;Nakao, Shin-ichi
    • Korean Membrane Journal
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    • v.5 no.1
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    • pp.54-60
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    • 2003
  • The rejection properties and flux rates of silica nanoparticles in ultrafiltration membranes has been investigated. Cross-flow permeation experiments were conducted using polycarbonate track-etch flat membranes with pore sizes of 30 and 50 nm, and a silica nanoparticle solute with particle sizes of 5 and 18 nm with narrow size distributions. The fluxes and rejection factors were investigated at various particle concentrations, cross-flow velocities, pH, and ionic strengths of solution. Even though the size of the silica nanoparticles was much smaller than that of the membrane pores, the observed rejection rates were very high compared with those for a similar-sized polymer (dextran). The observed rejection rate decreased with increasing ionic strength, which implies that the transport mechanism of the silica nanoparticles is significantly influenced by electrostatic repulsion between particles and membranes.

Adsorption Characteristics of Nitrogen in Carbonaceous Micropore Structures with Local Molecular Orientation (국부분자배향의 탄소 미세기공 구조에 대한 질소의 흡착 특성)

  • Seo, Yang Gon
    • Clean Technology
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    • v.28 no.3
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    • pp.249-257
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    • 2022
  • The adsorption equilibria of nitrogen on a region of nanoporous carbonaceous adsorbent with local molecular orientation (LMO) were calculated by grand canonical Monte Carlo simulation at 77.16 K. Regions of LMO of identical size were arranged on a regular lattice with uniform spacing. Microporosity was predominately introduced to the model by removing successive out-of-plane domains from the regions of LMO and tilting pores were generated by tilting the basic structure units. This pore structure is a more realistic model than slit-shaped pores for studying adsorption in nanoporous carbon adsorbents. Their porosities, surface areas, and pore size distributions according to constrained nonlinear optimization were also reported. The adsorption in slit shaped pores was also reported for reference. In the slit shaped pores, a clear hysteresis loop was observed in pores of greater than 5 times the nitrogen molecule size, and in capillary condensation and reverse condensation, evaporation occurred immediately at one pressure. In the LMO pore model, three series of local condensations at the basal slip plane, armchair slip plane and interconnected channel were observed during adsorption at pore sizes greater than about 6 times the nitrogen molecular size. In the hysteresis loop, on the other hand, evaporation occurred at one or two pressures during desorption.

Improvement of Durability and Change of Pore Structure for Concrete Surface by the Penetrative Surface Protection Agent (함침계 표면보호제에 의한 콘크리트 표면의 세공구조 변화 및 내구성 향상)

  • Kang, Suk-Pyo;Kim, Jung-Hwan
    • Journal of the Korea Concrete Institute
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    • v.18 no.1 s.91
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    • pp.125-132
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    • 2006
  • Recently, surface finishing and protection materials were developed to restore performance of the deteriorated concrete and inhibiting corrosion of the reinforcing-bar. For this purpose, surface protection agent as well as coatings are used. Coatings have the advantage of low Permeability of $CO_2,\;SO_2$ and water. However, for coatings such as epoxy, urethane and acryl, long-term adhesive strength is reduced and the formed membrane of those is blistered by various causes. Also when organic coatings are applied to the wet surface of concrete, those have a problem with adhesion. On the other hand, surface protection agent penetrates into pore structure in concrete through capillary and cm make a dense micro structure in concrete as a result of filling effect. Furthermore, the chemical reaction between silicate from surface protection agent and cement hydrates can also make a additional hydration product which is ideally compatible with concrete body. The aim of this study is to examine the effect of penetrative surface protection agent(SPA) by evaluating several concrete durability characteristics. The results show that the concrete penetrated surface protection agent exhibited higher durability characteristics for instance, carbonation velocity coefficient, resistance to chemical attack and chloride ion penetration than the plain concrete. These results due to formation of a discontinuous macro-pore system which inhibits deterioration factors of concrete by changed the pore structure(porosity and pore size distributions) of the concrete penetrated surface protection agent.

The Selective Leaching of Al-Ni Alloy Nano Powders Prepared by Electrical Wire Explosion (전기선 폭발법에 의하여 제조된 Al-Ni 합금 나노분말의 선택적 침출)

  • Park, Je-Shin;Kim, Won-Baek;Suh, Chang-Youl;Chang, Han-Kwon;Ahn, Jong-Gwan;Kim, Byoung-Kyu
    • Journal of Powder Materials
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    • v.15 no.4
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    • pp.308-313
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    • 2008
  • Al-Ni alloy nano powders have been produced by the electrical explosion of Ni-plated Al wire. The porous nano particles were prepared by leaching for Al-Ni alloy nano powders in 20wt% NaOH aqueous solution. The structural properties of leached porous nano powder were investigated by nitrogen physisorption, X-ray diffraction (XRD) and transmission Microscope (TEM). The surface areas of the leached powders were increased with amounts of AI in alloys. The pore size distributions of these powders were exhibited maxima at range of pore diameters 3.0 to 3.5 nm from the desorption isotherm. The maximum values of those were decreased with amounts of Al in alloys.

Experimental study on treatment of waste slurry by vacuum preloading with different conditioning agents

  • Wu, Yajun;Jiang, Haibo;Lu, Yitian;Sun, Dean
    • Geomechanics and Engineering
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    • v.17 no.6
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    • pp.543-551
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    • 2019
  • In China, serious environmental problems are induced by the extremely soft construction waste slurries in many urban areas, and there is no appropriate method to treat it presently. In this paper, four model tests were conducted to investigate the efficiency of waste slurry treatment by combining three conditioning agents which can change characteristics of the slurries with a traditional vacuum preloading method. The tests of size analysis of particle aggregate were conducted to investigate the influence of different conditioning agents on the size distributions of particle aggregate. During the model test, the discharged water volumes were monitored. The pore-size distribution and void ratio of the waste slurries after the vacuum preloading were measured by mercury intrusion porosimetry (MIP). It is found that 1) During the natural precipitation, volume of water out of the organic agent is higher than that of the mixed agent, but it is smaller than that of the mixed agent in the vacuum preloading stage; 2) the mixed agent has a higher total volume of water out than the organic agent and the inorganic agent after test, while the organic agent and the inorganic agent have little difference with respect to the drainage effect. The results demonstrate that the combination of mixed conditioning agent and vacuum preloading for the solid-liquid separation in waste slurry has a satisfactory effect and can be applied in engineering practice.

Image Analysis of an Air-Void System in hardened concrete (화상분석기를 이용한 경화콘크리트의 기포분포분석에 관한 기초적 연구)

  • 김기철;정재동
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.313-318
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    • 1997
  • Air voids existed in hardened concrete have an important influence on concrete deterioration such as carbonation, freezing and thawing, and corrosion of embedded steel in concrete. Therefore it is very significant to investigate the pore structure of system (size, number and continuity of air voids) to solve the reason caused concrete deterioration. The purpose of this study is to develop th standard method of measuring air voids which affect properties in hardened concrete using image analyzing system. This paper presents the settlement of rapid and exact experimental method which extracts fine bubbles, calculates the number of air voids, and determines air-voids distributions using image analyzing system with computer.

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Nonlocal strain gradient thermal vibration analysis of double-coupled metal foam plate system with uniform and non-uniform porosities

  • Fenjan, Raad M.;Ahmed, Ridha A.;Alasadi, Abbas A.;Faleh, Nadhim M.
    • Coupled systems mechanics
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    • v.8 no.3
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    • pp.247-257
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    • 2019
  • Fee vibrational characteristics of porous steel double-coupled nanoplate system in thermo-elastic medium is studied via a refined plate model. Different pore dispersions called uniform, symmetric and asymmetric have been defined. Nonlocal strain gradient theory (NSGT) containing two scale parameters has been adopted to stablish size-dependent modeling of the system. Hamilton's principle has been adopted to stablish the governing equations. Obtained results from Galerkin's method are verified with those provided in the literature. The effects of nonlocal parameter, strain gradient, foundation parameters, porosity distributions and porosity coefficient on vibration frequencies of metal foam nanoscale plates have been examined.

Experimental study on vacuum preloading with flocculation for solid-liquid separation in waste slurry

  • Wu, Yajun;Kong, Gangqiang;Lu, Yitian;Sun, De'an
    • Geomechanics and Engineering
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    • v.13 no.2
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    • pp.319-331
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    • 2017
  • This vacuum preloading combined with polyacrylamide (PAM) flocculation was proposed to separating solid-liquid in waste slurry and to improving bearing capacity of soft soil ground. By using waste slurry taken from drilled shaft construction site in Shanghai, China, a series of settling column tests with four typical flocculants and one normal for waste slurry were carried out for comparative analysis. The optimal amounts for each flocculant were obtained from the column tests. Then, model tests on vacuum preloading with anionic polyacrylamide (APAM) flocculation and without flocculants were carried out. The out of water and the settlement of slurry surface ground were monitored during the model tests, and the changes in water content, particle-size and pore-size distributions in different positions after the model tests were measured and discussed. It is found that water content of the waste slurry without APAM flocculation changed from 204 to 195% by 24 hours standing and 15 hours vacuum preloading, while the water content of the waste slurry with APAM flocculation was declined from 163 to 96% by 24 hours standing, and was further reduced into 37% by 136 hours vacuum preloading, which shows that the combined method is feasible and effective.