• 제목/요약/키워드: pore distribution

검색결과 811건 처리시간 0.029초

가스센서용 고순도 다공질 알루미나 담체의 제조 (Preparation of High-purity Porous Alumina Carrier for Gas Sensor)

  • 이창우;현성호;함영민
    • 한국화재소방학회논문지
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    • 제11권3호
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    • pp.15-23
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    • 1997
  • In this study, the alumina for gas sensor was prepared by anodic oxidation. It was stable thermally and chemically, and pore diameter and pore distribution was uniform. And the shape of pore was cylinderical. The aluminum plate was carried out by the thermal oxidation, chemical polishing and electropolishing pretreatment. The pore diameter, pore size distribution, pore density and thickness of alumina was observed with the change of reaction temperature, electrolyte concentration and current density. As a results, It was able to use for carrier because alumina which was prepared by anodic oxidationhas uniform pore size distribution.

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도공층의 공극과 인쇄적성에 관한 연구(제2보) -안료의 입자형태가 미치는 영향- (Studies on the Pore of Coating Layer and Printability(II) -Effects of Pigment Shape on Pore of Coating Layer-)

  • 김창근;이용규
    • 펄프종이기술
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    • 제33권1호
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    • pp.53-61
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    • 2001
  • This study was carried out to evaluate the effect of coating pigments on the printability by investigating the pore structure of casting layer such as the number, size and distribution of pores and the pore rate. The coating structure was mainly determined by the interaction between pigment and binder. It means that the structure of pores was chiefly affected by the shape and size distribution of pigments and their packing rate. The physical properties of pore have close relationships with ink set-off, the speed of ink penetration and printing gloss. The results suggested that the rate and number of pores were greatly affected by the particle size distribution and shape of pigments. The rate of pore increased with the reduction of particle size distribution of pigments. Calcite was effective to improve greatly the printability of coated paper.

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Pore Structure and Reflectivity of Light of Paper

  • Won, Jong-Myoung
    • 펄프종이기술
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    • 제38권3호
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    • pp.7-12
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    • 2006
  • The pore structure of paper was modified by the application of the blending of pulp, refining, and filler particle size and ash content. It was conformed that the reflectivity of paper can be modified by the combination of the above parameters. It was also found that the change of reflectivity of paper was greatly dependent on the pore structure, such as average pore size, pore size distribution and porosity. The average pore size was decreased with addition of HwBKP, but the smallest average pore size was obtained from the addition of 80% HwBKP Refining of pulp decreased both average pore size and the reflectivity of paper. The pore size distribution of filled paper can be varied by the combination of filler particle size and ash content

수축공극크기분포를 이용한 지반의 수리학적 물성치 산정 (Estimating Hydraulic Properties of Soil from Constriction-pore Size Distribution)

  • 신호성
    • 한국지반공학회논문집
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    • 제38권3호
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    • pp.27-34
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    • 2022
  • 지반내 물의 흐름은 입자 사이의 공극 분포에 의존하므로 입자의 크기를 이용한 수리학적 물성치의 예측은 정확도가 낮다. 본 논문은 Silveria의 방법을 이용하여 입도분포곡선으로부터 수축 공극크기분포를 산정하고, 포화-불포화 수리학적 물성치를 산정하는 방법을 제시하였다. 입도분포가 양호한 흙은 단봉의 공극크기분포를 보이고, 입도분포가 불량한 흙은 쌍봉의 공극크기분포를 보였다. 공극크기분포를 이용한 이론적 포화투수계수 모델식 중에서 Marshall 모델이 실내실험결과와 가장 부합되었다. 불포화토 수리해석에 필요한 함수특성곡선과 불포화투수계수에 대한 모델식을 공극크기분포를 이용하여 제안하였다. 개발된 모델식을 다양한 흙에 적용하여 수리학적 물성치의 예측에 적합한 모델을 선정하는 지속적인 연구가 필요하다.

Pore Size Distribution and Reflectivity of Light of Paper

  • Won, Jong-Myoung;Park, Bong-Sun;Park, Kyung-Ouk
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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    • pp.479-484
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    • 2006
  • The pore structures of paper were modified by the application of the blending of pulp, refining, and filler particle size and ash content. It was conformed that the reflectivity of paper can be modified by the combination of above parameters. It was also found that the modifications of reflectivity of paper were very close relation with pore structure, such as average pore size, pore size distribution and porosity. The average pore size was decreased with addition of HwBKP, but showed smaller particle size than those made from 100% HwBKP. Refining of pulp decreased both average pore size and the reflectivity of paper. The pore size distribution of filled paper can be varied by the combination of filler particle size and ash content.

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X-ray CT를 이용한 베레아 사암의 공극크기분포 산정 (Evaluation of Pore Size Distribution of Berea Sandstone using X-ray Computed Tomography)

  • 김광염;김경민
    • 지질공학
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    • 제24권3호
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    • pp.353-362
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    • 2014
  • 다공질 암석의 공극구조는 그 암석의 수리-역학적 거동에 매우 큰 영향을 미친다. 다공질 암석의 공극구조 특성을 표현하는 대표적인 방법은 공극률, 공극크기분포, 방향성 등이 있다. 암석의 유효공극률은 실험적으로 비교적 쉽게 구할 수 있지만, 공극의 크기분포 특성을 파악하는 것은 매우 어려운 실정이다. 본 연구에서는 X-ray CT를 이용하여 대표적 다공질 암석인 베레아 사암의 공극구조 중 공극크기분포를 이미지 기반으로 평가하였다. 공극크기분포 평가를 위해 본 연구에서는 이미지 필터링, 이진화, 골격화 등의 이미지 기반 처리 작업을 수행하였으며, 국부 두께평가 및 star chord를 이용하여 베레아 사암의 공극크기분포를 구하였다. 본 연구에서 제시된 X-ray CT 기반의 공극크기분포 평가방법을 이용하여 향후 다공질 재료의 공극구조 평가에 새롭고 효율적인 방안을 제시하고자 하였다.

Realistic pore structure of Portland cement paste: experimental study and numerical simulation

  • Ma, Hongyan;Li, Zongjin
    • Computers and Concrete
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    • 제11권4호
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    • pp.317-336
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    • 2013
  • In this study, the pore structure of Portland cement paste is experimentally characterized by MIP (mercury intrusion porosimetry) and nitrogen adsorption, and simulated by a newly developed status-oriented computer model. Cement pastes with w/c=0.3, 0.4 and 0.5 at ages from 1 day to 120 days are comprehensively investigated. It is found that MIP cannot generate valid pore size distribution curves for cement paste. Nevertheless, nitrogen adsorption can give much more realistic pore size distribution curves of small capillary pores, and these curves follow the same distribution mode. While, large capillary pores can be effectively characterized by the newly developed computer model, and the validity of this model has been proved by BSE imaging plus image analysis. Based on the experimental findings and numerical simulation, a hypothesis is proposed to explain the formation mechanism of the capillary pore system, and the realistic representation of the pore structure of hydrated cement paste is established.

Mapping Particle Size Distributions into Predictions of Properties for Powder Metal Compacts

  • German, Randall M.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.704-705
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    • 2006
  • Discrete element analysis is used to map various log-normal particle size distributions into measures of the in-sphere pore size distribution. Combinations evaluated range from monosized spheres to include bimodal mixtures and various log-normal distributions. The latter proves most useful in providing a mapping of one distribution into the other (knowing the particle size distribution we want to predict the pore size distribution). Such metrics show predictions where the presence of large pores is anticipated that need to be avoided to ensure high sintered properties.

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Adsorption of Carbon Dioxide onto Tetraethylenepentamine Impregnated PMMA Sorbents with Different Pore Structure

  • Jo, Dong Hyun;Park, Cheonggi;Jung, Hyunchul;Kim, Sung Hyun
    • Korean Chemical Engineering Research
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    • 제53권3호
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    • pp.382-390
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    • 2015
  • Poly(methyl methacrylate) (PMMA) supports and amine additives were investigated to adsorb $CO_2$. PMMA supports were fabricated by using different ratio of pore forming agents (porogen) to control the BET specific surface area, pore volume and distribution. Toluene and xylene are used for porogens. Supported amine sorbents were prepared by wet impregnation of tetraethylenepentamine (TEPA) on PMMA supports. So we could identify the effect of the pore structure of supports and the quantity of impregnated TEPA on the adsorption capacity. The increased amount of toluene as pore foaming agent resulted in the decreased average pore diameter and the increased BET surface area. Polymer supports with huge different pore distribution could be fabricated by controlling the ratio of porogen. After impregnation, the support with micropore structure is supposed the pore blocking and filling effect so that it has low $CO_2$ capacity and kinetics due to the difficulty of diffusing. Macropore structure indicates fast adsorption capacity and low influence of amine loading. In case of support with mesopore, it has high performance of adsorption capacity and kinetics. So high surface area and meso-/macro- pore structure is suitable for $CO_2$ capture.

Alkoxide 법으로 합성한 알루미나의 동공구조에 미치는 가수분해 온도의 영향 (Effect of Hydrolytic Temperature on Pore Structure of Alkoxide-derived Aluminas)

  • 조정미;정필조
    • 한국세라믹학회지
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    • 제25권3호
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    • pp.217-224
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    • 1988
  • Alkoxide 법으로 합성한 알루미나의 동공 구조를 BET 법으로 구한 흡 탈착 등온선의 hysteresis loop와 동공 분포로부터 고찰하였다. 알루미나는 aluminum isopropoxide를 화학량의 물로 가수분해하여 제조하였고, 가수분해 온도는 3$^{\circ}C$와 8$0^{\circ}C$에서 수행하였다. 이어 20$0^{\circ}C$부터 50$0^{\circ}C$까지 단계적으로 승온시키며 일정시간 열처리하였다. 3$^{\circ}C$ 가수분해 시료의 동공부피는 열처리 온도에 비례하여 증가하였으며, 동공크기는 쌍입분포(twin peaked pore size distribution)형으로 나타났다. 그러나 8$0^{\circ}C$ 가수분해 시료는 열처리에 의하여 동공부피가 감소하고, 동공크기는 단입분포(single peaked pore size distribution)로 나타났다. 이러한 관찰 결과로부터 전자의 동공형태는 slit형, 후자는 ink-bottle형을 하고 있는 것으로 추정되었다. 이와 같이 가수분해 온도는 동공 형태를 결정하는 중요한 인자일 뿐만 아니라, 층상 알루미나의 구조수 일탈 거동을 결정하는데 중요하다. 열처리 효과는 단지 최종 제품의 동공 분포를 결정하는데 영향을 주고 있는 것으로 해석되었다.

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