• Title/Summary/Keyword: pore

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Comparison of Characterization Techniques of the Pore in Paper Sheet (종이의 기공 특성 측정 기법의 비교)

  • Won, Jong-Myoung;Nam, Ki-Young;Chung, Soon-Ki
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.4
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    • pp.1-6
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    • 2007
  • Paper is a composite consisted of various solid materials including pulp, filler and other additives. The pore is also one of components consisting the paper structure. Thus the characterization of pore structure of paper is very helpful in the understanding the structural properties of paper. Mercury intrusion technique is frequently used for the characterization of the porous paper, giving access to parameters such as pore size and pore distribution. But some researchers pointed out the problem that the distortion of the pore structure can be occurred by the application of high pressure during mercury intrusion. Thus in this study, we tried to evaluate the potential of SEM and image analysis method as means for analyzing pore structure of the paper. The new pore analysis technique with SEM and image analysis does not require the application of high pressure, and gave better relation between the measured pore characteristics and the bulk of sheet than mercury intrusion method.

Indentation Damage of Porous Alumina Ceramice

  • Ha, Jang-Hoon;Lee, Chul-Seung;Kim, Jong-Ho;Kim, Do-Kyung
    • Journal of the Korean Ceramic Society
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    • v.41 no.1
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    • pp.19-23
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    • 2004
  • The Hertzian indentation contact damage behavior of porous alumina with controlled pore shape was investigated by experiments. Porous alumina ceramics containing well-defined pore shape, size and distribution were prepared by incorporation of fugitive spherical starch. Porous alumina with isolated pore structure was prepared with porosity range up to 30%. The indentation stress-strain curves of porous alumina were constructed. Elastic modulus and yield stress can be obtained from the stress-strain relationship. Impulse excitation method for the measurement of elastic modulus was also conducted as well as Hertzian indentation and was confirmed as a useful tool to evaluate the elasticity of highly porous ceramics. Elastic modulus of the inter-connected pore structure is more sensitive to porosity than that of the isolated pore structure. When the specimen had isolated pore structure, higher yield point was obtained than it had inter-connected pore structure. This study proposed that the elastic modiulus of porous ceramics is strongly related to not only porosity, but also the structure of pore.

Adsorption of Carbon Dioxide onto Tetraethylenepentamine Impregnated PMMA Sorbents with Different Pore Structure

  • Jo, Dong Hyun;Park, Cheonggi;Jung, Hyunchul;Kim, Sung Hyun
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.382-390
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    • 2015
  • Poly(methyl methacrylate) (PMMA) supports and amine additives were investigated to adsorb $CO_2$. PMMA supports were fabricated by using different ratio of pore forming agents (porogen) to control the BET specific surface area, pore volume and distribution. Toluene and xylene are used for porogens. Supported amine sorbents were prepared by wet impregnation of tetraethylenepentamine (TEPA) on PMMA supports. So we could identify the effect of the pore structure of supports and the quantity of impregnated TEPA on the adsorption capacity. The increased amount of toluene as pore foaming agent resulted in the decreased average pore diameter and the increased BET surface area. Polymer supports with huge different pore distribution could be fabricated by controlling the ratio of porogen. After impregnation, the support with micropore structure is supposed the pore blocking and filling effect so that it has low $CO_2$ capacity and kinetics due to the difficulty of diffusing. Macropore structure indicates fast adsorption capacity and low influence of amine loading. In case of support with mesopore, it has high performance of adsorption capacity and kinetics. So high surface area and meso-/macro- pore structure is suitable for $CO_2$ capture.

A Study on the Pore Characteristics of the U$O_2$ Fuel (U$O_2$핵연료의 기공 특성에 대한 연구)

  • Song, K-W;K.S. Seo;Sohn, D-S;Kim, S.H.;I.S.Chang;H.S. Chang
    • Nuclear Engineering and Technology
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    • v.23 no.1
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    • pp.49-55
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    • 1991
  • The microstructure and pore characteristics have been studied on the sintered UO$_2$pellet which was made of the UO$_2$powder manufactured via AUC process. The open porosity decrease with the density and is nearly annihilated above the density of 10.45 g/㎤. The round pore smaller than 3 $\mu$m exist In all densities. The large and elongated pore appears additionally In low density The pore in low density is more elongated than the pore in high density The distribution of the pore area versus the pore size is monomodal and shows its peak on the pore size of 2 to 3 $\mu$m. As the density decreases, the related area of large pore Increases.

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Water transport through hydrophobic micro/nanoporous filtration membranes on different scales

  • Mian, Wang;Yongbin, Zhang
    • Membrane and Water Treatment
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    • v.13 no.6
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    • pp.313-320
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    • 2022
  • Theoretical calculation results are presented for the enhancement of the water mass flow rate through the hydrophobic micro/nano pores in the membrane respectively on the micrometer and nanometer scales. The water-pore wall interfacial slippage is considered. When the pore diameter is critically low (less than 1.82nm), the water flow in the nanopore is non-continuum and described by the nanoscale flow equation; Otherwise, the water flow is essentially multiscale consisting of both the adsorbed boundary layer flow and the intermediate continuum water flow, and it is described by the multiscale flow equation. For no wall slippage, the calculated water flow rate through the pore is very close to the classical hydrodynamic theory calculation if the pore diameter (d) is larger than 1.0nm, however it is considerably smaller than the conventional calculation if d is less than 1.0nm because of the non-continuum effect of the water film. When the driving power loss on the pore is larger than the critical value, the wall slippage occurs, and it results in the different scales of the enhancement of the water flow rate through the pore which are strongly dependent on both the pore diameter and the driving power loss on the pore. Both the pressure drop and the critical power loss on the pore for starting the wall slippage are also strongly dependent on the pore diameter.

Prediction of Intrinsic Pore Properties of Ultrafiltration Membrane by Solute Rejection Curves (용질배제 곡선에 의한 한외여과 막의 세공특성 예측)

  • 염경호
    • Proceedings of the Membrane Society of Korea Conference
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    • 1991.10a
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    • pp.4-8
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    • 1991
  • The characterization of pore properties (mean pore size and pore size distribution) of the active layer in a UF membrane is important not only in order to obtain information about the factors affecting pore formation during membrane manufacturing but also to understand deeply the mechanism of solute and solvent transport through pores. Many methods of characterizing quantitatively the pore properties of UF membranes have been suggested in the literature: solvent and gas flow measurement, bubble point determination, electron microscopy, gas adsorption/desorption measurement, rejection measurement etc. But most of these methods involve time-consuming procedures and involve some wellknown problems and uncertainties.

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Monte Carlo Simulation on Adsorption Properties of Benzene, Toluene, and p-Xylene in MCM-41

  • Moon, Sung-Doo
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2553-2559
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    • 2012
  • The adsorption properties of benzene, toluene, p-xylene in MCM-41 with heterogeneous and cylindrical pore were studied using grand canonical ensemble Monte Carlo simulation. The simulated isotherms were compared with experimental ones, and the different adsorption behaviors in MCM-41 with pore diameters of 2.2 and 3.2 nm were investigated. The simulated adsorption amounts above the capillary-condensation pressure agreed with the experimental ones. The simulation results showed that most molecular planes were nearly parallel to the pore axis. This orientation was not affected by the molecular position in the pore. The molecular planes were nearly parallel to the pore surface for the adsorbate molecules close to the pore wall, and the molecules in the MCM-41 with the pore diameter of 3.2 nm were ordered along the pore axis.

Post-Cyclic Deformation Behavior of Non-Liquefied Weathered Soils (반복재하후 미액상화 풍화토 지반의 변형 거동)

  • 최연수;정충기
    • Proceedings of the Korean Geotechical Society Conference
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    • 2001.03a
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    • pp.485-492
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    • 2001
  • Weathered soil is one of the most representative soils in Korea. In this study, a series of cyclic triaxial tests was carried out to predict the post-cyclic deformation behavior of weathered soils in case of non-liquefaction. Excess pore pressure response during cyclic loading and volumetric strain during the dissipation of excess pore pressure were measured varying the confining pressure, relative density and cyclic stress ratio. Based on the test results, it Is found that the modified excess pore pressure ratio, excess pore pressure ratio normalized by cyclic stress ratio, is uniquely correlated with the number of cycles irrespective of confining pressure and cyclic stress ratio. Using the newly proposed MEPPR(modified excess pore pressure ratio) concept, it is possible to easily evaluate the excess pore pressure and the settlement of weathered soils due to cyclic loading by greatly reduced number of tests. It is also verified that the reconsolidation volumetric strain is independent of the way how the excess pore pressure was generated.

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Identification of ambient pore pressure and rigidity index from piezocone dissipation test (피에조콘 소산시험을 이용한 평형간극수압과 강성지수의 역해석)

  • 김영상
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.03a
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    • pp.49-54
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    • 2002
  • This paper describes a systematic way of simultaneously identifying the ambient pore pressure and the rigidity index (=G/s$\_$u/) of soil by applying an optimization technique to the piezocone dissipation test result. An ambient pore pressure and optimal rigidity index were determined by minimizing the differences between theoretical excess pore pressures developed by Randolph & Wroth(1979) and measured excess pore pressures from piezocone using optimization technique. The effectiveness of the proposed back-analysis method was examined against the well-documented performance of piezocone dissipation tests (Tanaka & Sakagami, 1989), from the viewpoints of proper determination of selected target parameters and saving of test duration. It is shown that the proposed back-analysis method can evaluate properly the ambient pore pressure and the rigidity index by using only the early phase of the dissipation test data. Also, it is shown that with the optimized rigidity index and ambient pore pressure the proposed back-analysis method permits the horizontal coefficient of consolidation to be identified rationally.

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Pore Size Distribution and Reflectivity of Light of Paper

  • Won, Jong-Myoung;Park, Bong-Sun;Park, Kyung-Ouk
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.479-484
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    • 2006
  • The pore structures of paper were modified by the application of the blending of pulp, refining, and filler particle size and ash content. It was conformed that the reflectivity of paper can be modified by the combination of above parameters. It was also found that the modifications of reflectivity of paper were very close relation with pore structure, such as average pore size, pore size distribution and porosity. The average pore size was decreased with addition of HwBKP, but showed smaller particle size than those made from 100% HwBKP. Refining of pulp decreased both average pore size and the reflectivity of paper. The pore size distribution of filled paper can be varied by the combination of filler particle size and ash content.

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