• Title/Summary/Keyword: polyvinylalcohol

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Pulse-echo Response of Ultrasonic Transducer Fabricated by PZT-Polymer 3-3 Type Composite Resonator for Distance Measurement Applications (거리측정용 PZT-고분자 3-3형 복합압전체 트랜스듀서의 펄스에코 응답특성)

  • 주용관;박정학;최헌일;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.205-208
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    • 1995
  • PZT powders were prepared by the molten salt synthesis method. The porous PZT specimens were prepared from a mixture of PZT and Polyvinylalcohol(PVA) powders by BURPS(Burnout Plastic Sphere) technique. The pulse-echo response of PZT-polymer 3-3 type composite transducer with various PVA wt.% were studied, The fall time of pulse-echo response of PZT-polymer 3-3 type composite transducer was shorten to that of solid PZT-maded transducer. Therefore, a good transmitting and receiving properties could be obtained. The distance between transducer and reflector was in good agreement both solid PZT and PZT-polymer 3-3 type composite fabricated transducer.

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Electrochemical Properties of MnO$_2$electrode for supercapactor wish a Diffuser (Polyvinylalcohol) (분산제 PVA에 따른 수퍼커패시터용 이산화망간전극의 전기 화학적 특성)

  • 이상오;김한주;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.753-756
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    • 2001
  • This research made a study of MnO$_2$electrode for supercapacitor with a diffuser (Polyvinyl alcohol). Manganese dioxide was used as active material. We tried to increase specific surface area by adding PVA. Manganese dioxide was synthesized by a sol-gel method using fumaric acid and oxalic acid in low temperature with high yield. Therefore, We prepared Manganese dioxide powder. This powder was used by active materials. The electrode was made by a mixture of active material, ketjen-black which is a large specific surface area, and PVdF-co-HFP as binder agent with using Nickel mesh as current collector. Here we reported on the synthesis and electrochemical performance of a enhanced material. All active materials have been submitted to X-ray diffraction and Scanning electron microscopy.

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Preparation of Nitrifier Immobilized PVA(Polyvinyl Alcohol) Bead and Removal of Ammonia Nitrogen (질화세균군이 고정화된 PVP(Polyvinyl Alcohol) bead 제조 및 암모니아성 질소 제거)

  • 서근학;조진구
    • Journal of Environmental Science International
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    • v.10 no.3
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    • pp.233-237
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    • 2001
  • Immobilized nitrifier bead in airlift bioreactor were used to remove high levels of ammonia nitrogen from synthetic wastewater. Polyvinylalcohol(PVA) bead for immmobilization of nitrifier consortium were prepared by PVA-boric acid method by varying concentration of PVA and nitrifier consortium. By determining viscosity, sphercity and tailing, the characteristics of prepared beads were investigated and the continous immobilization process was developed. Synthetic wastewater containg 25g/$\textrm{m}^3$ of ammonia nitrogen could be treated within 0.5 hour and the highest removal rate of ammonia nitrogen was 934.2g/$\textrm{m}^3{\cdot}$ day.

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Slip Casting of Mn-Zn Ferrite Powders Prepared by Alcoholic Dehydration Method (알콜탈수법에 의해 제조된 Mn-Zn Ferrite 분체의 주입성형)

  • 이경직;이대희;신효순;이석기;김창현;이병교
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.394-398
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    • 1997
  • Mn-Zn ferrite powders were prepared by alcoholic dehydration, using coprecipitation method. Then the effects of organic dispersant and polymeric binder concentration on stability and casting of slurry were discussed. Citric acid, the organic dispersant and polyvinylacohol(PVA), the non-ionic binder, were selected as additives of slurry. With variation of concentration of water, citric acid and polyvinylalcohol(PVA), optimum forming conditions were determined from viscosity and density. To compare with dry process, density and microstructure of sintered body formed by uniaxial die pressing were observed.

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An Electrical Characteristics on the Pentacene-Based Organic Thin-Film Transistors using PVA Alignment Layer (PVA 배열층을 이용한 펜타신 유기 박막 트랜지스터의 전기적 특성)

  • Jun, Hyeon-Sung;Oh, Hwan-Sool
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.3
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    • pp.177-182
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    • 2010
  • The pentacene-based organic thin film transistors(OTFTs) using polyvinylalcohol(PVA) alignment layer were fabricated on the $SiO_2$ evaporated to n-type (111) Si substrates. The pentacene film was deposited by thermally evaporated at $10^{-7}$ torr. X-ray diffraction (XRD) and atomic force microscope(AFM) measurement showed pentacene film which deposited on rubbed PVA layers were partially crystallized at (001) plane. The pentacene OTFTs with PVA layers rubbed perpendicular to the direction of current flow was shown to align better orientation than parallel rubbed case and thus to enhance the mobility and saturation current by a factor of 2.3 respectively. We obtained mobility by 0.026 $cm^2$/Vs and on-off current ratio by ${\sim}10^8$.

Influence of the Type and Blending Ratio of Binders on Ink-jet Printing Properties (바인더의 종류 및 배합비율이 잉크제트 인쇄특성에 미치는 영향)

  • 이희명;김창근;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.2
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    • pp.22-31
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    • 2002
  • In this paper, PVA(polyvinylalcohol), oxidized starch and SBR latex were used as binders for ink-jet printing papers, and their effects of the type and blending ratio of binders on ink-jet printing properties were compared. In case of coating color using PVA mainly used for a binder in ink-jet printing, spreading of printed letters decreased and excellent images were manifested resulting from strong hydrophilic of PVA. However, increasing solids content of coating color was somewhat limited because of the interaction of PVA and functional groups in silica as well as high molecular weight of PVA. When oxidized starch and SBR latex were mixed with PVA at desirable ratio to solve these problems, runnability in coating process was improved and good printing properties were shown. Gloss was improved when latex was used along with PVA as a binder because of the thermoplastic property of the latex. From this result, possibilities of high solids content and high gloss ink-jet printing papers were investigated.

Pulse-echo Response of Ultrasonic Transducer Fabricated by Porous Piezoceramics PZT Resonator (다공질 압전소자(PZT)로 제작된 초음파 트랜스듀서의 펄스에코 응답특성)

  • Joo, Yong-Khoan;Lee, Su-Ho;Park, Jung-Hak;SaGong, Geon
    • Proceedings of the KIEE Conference
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    • 1995.11a
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    • pp.358-360
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    • 1995
  • PZT powders were prepared by the molten salt synthesis method. The porous PZT specimens were prepared from a mixture of PZT and polyvinylalcohol(PVA) powders by BURPS(Burnout Plastic Sphere) technique. The pulse-echo response of porous PZT transducer with various PVA wt.% were studied. The fall time of pulse-echo response of porous PZT transducer was shorten to that of solid PZT-maded transducer. Therefore, a good transmitting and receiving properties could be obtained. The distance between transducer and reflector was in good agreement both solid PZT and porous PZT fabricated transducer.

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Piezoelectric and Acoustic Properties of Porous PZT Ceramics (다공질 PZT 세라믹의 압전 및 음향 특성)

  • 박정학;최헌일;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.183-186
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    • 1994
  • Porous piezoelectric ceramics of P7T have been newly developed to apply for transducers in an echo sounder PZT powders were prepared by the molten salt synthesis method. The porous PZT was prepared from a mixture of PZT and polyvinylalcohol(PVA) powders by BURPS(Burnout Plastic Sphere) technique. The piezoelectric and acoustic properties with various PVA wt.% have studied. The density of porous PZT ceramics was decreased linearly with increasing the PVA sphere wt.%. Piezoelectric coefficient d$\_$33/ of porous PZT ceramics was almost same to that of single phase PZT ceramics. The thickness mode coupling factor k$\_$t/ was ranged over 0.53∼0.59 comparable with the single phase PZT ceramics(k$\_$t/=0.7).

Effect of protective colloid on the synthesis of Poly(Vinyl acetate-co-Ethyl acrylate) (Poly(VAc-co-EA) 공중합체 제조에 있어 보호콜로이드의 영향에 관한 연구)

  • Kim, Nam-Seok;Kim, Sung-Hoon
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.2
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    • pp.216-221
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    • 2010
  • Polyvinyl acetate (PVAc) prepared by emulsion polymerization has broad applications for additive such as paint binder, adhesive for wood and paper due to its low glass transition temperature which help to plasticize substrate resins. Since emulsion polymerization has a disadvantage that surfactant and ionic initiator degrade properties of the product polymer, poly (vinyl acetate-eo-ethyl acrylate) (VAc-EA) was synthesized using potassium persulfate as catalyst and polyvinylalcohol (PVA) as protective colloid to prevent the degradation. The copolymer latex product was internally plasticized and has enhanced adhesion, water resistance during VAc-EA emulsion polymerization. No coagulation and complete conversion occur with the reactant mixture of 10 mmol/L potassium persulfate, 10 mmol/L poly ( vinyl alcohol) (PVA 17). As the concentrations of PVA increase, the viscosity becomes increase.

Development and Applications of Frame Retardant Nano and Microcapsule (난연기능 nano 및 microcapsule의 개발 및 응용(Ⅰ))

  • Kim, Hea-In;Hong, Yo-Han;Park, Soo-Min
    • Textile Coloration and Finishing
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    • v.20 no.4
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    • pp.31-42
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    • 2008
  • Tricrecyl phosphate(TCP)-containing polyurea microcapsules were prepared by interfacial polymerization using aromatic 2,4-toluene diisocyanate(TDI) and ethylenediamine(EDA) as wall forming materials. The effects of the protective colloids of polyvinylalcohol(PVA) and gelatin were investigated through experimentation. The mean size of prepared polyurea microcapsules was smaller and the surface morphology of the microcapsule prepared by the PVA as protective colloid was much smoother than the gelatin. As the concentration of protective colloid increased, the wall membrane of the polyurea microcapsules became more stable, the thermal stability of the wall membrane increased, the mean particle size became smaller, and the particle distribution was more uniform. PET containg microTCPs have a higher activation energy of decomposition, higher char content and lower heat of combustion.