• Title/Summary/Keyword: polyurethane resin

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A new type of clear orthodontic retainer incorporating multi-layer hybrid materials

  • Ahn, Hyo-Won;Kim, Kyung A;Kim, Seong-Hun
    • The korean journal of orthodontics
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    • v.45 no.5
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    • pp.268-272
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    • 2015
  • Clear thermoplastic retainers have been widely used in daily orthodontics; however, they have inherent limitations associated with thermoplastic polymer materials such as dimensional instability, low strength, and poor wear resistance. To solve these problems, we developed a new type of clear orthodontic retainer that incorporates multi-layer hybrid materials. It consists of three layers; an outer polyethylenterephthalate glycol modified (PETG) hard-type polymer, a middle thermoplastic polyurethane (TPU) soft-type polymer, and an inner reinforced resin core. The resin core improves wear resistance and mechanical strength, which prevent unwanted distortion of the bucco-palatal wall of the retainer. The TPU layer absorbs impact and the PETG layer has good formability, optical qualities, fatigue resistance, and dimensional stability, which contributes to increased support from the mandibular dentition, and helps maintain the archform. This new type of vacuum-formed retainer showed improved mechanical strength and rate of water absorption.

Inkjet Printing on the Grain Leather: Evaluation of Line Image Quality on the Grain Leather

  • Park, Heung-Sup;Park, Soo-Min
    • Textile Coloration and Finishing
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    • v.19 no.2
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    • pp.24-31
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    • 2007
  • This paper addresses factors of line image quality on grain leather printed via inkjet printer. Lines were printed onto coated leather media, and line width, edge blurriness, and edge raggedness were evaluated for line image quality. Various factors influenced to wetting and capillary wicking were studied and found out that wicking through capillary between fibers causes significant feathering on leather surface similar with pulp capillary in copy Paper. Polyurethane and acrylic resin coating resulted good image qualify by reducing capillary wicking. The mixture of polyurethane and acrylic resin applied on grain leather satisfied with both image quality and surface hand. $AllWrite^{TM}$ ink brought best results of image quality, comparing with $VeraPrint^{TM}$ ink and $JetWrite^{TM}$ ink.

Preparation of Yacht Sail Using High Tenacity Polyester and Its Performance Evaluation (폴리에스터 고강력사를 이용한 요트용 세일의 제조 및 성능분석)

  • Son, Hyun-Sik;Sim, Seung-Bum;Min, Mun-Hong
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.54-61
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    • 2012
  • This study surveyed the preparation of 8oz coated fabric and the physical property of the coated fabric according to the treated condition for the sail yacht. And the coated fabrics were compared with the performance of overseas products for verification. Physical properties of the coated fabric treated with non-yellowing functional polyurethane resin were examined according to the treatment condition such as compression and ageing treatments. Finally, yellowing fastness to light for 60 hours was assessed. Considering the compression condition after coating, good physical property was obtained at $6kgf/cm^2$. Also, the performance of yellowing fastness was similar to performance of overseas goods.

Antifouling Paint Resin Based on Polyurethane Matrix with Quaternary Ammonium Salt (Quaternary Ammonium Salt를 도입한 방오도료용 폴리우레탄 수지)

  • Kim, Dae-Hee;Jung, Min-Yeong;Park, Hyun;Lee, In-Won;Chun, Ho-Hwan;Jo, Nam-Ju
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.122-129
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    • 2015
  • Recently, the development of a new class of anti-fouling paint resin which has excellent anti-fouling performance and no persistence in the marine ecology is necessary. In this study, we first polymerized polyurethanes (PUs) as the other type of matrix which have carboxylic acid groups by using poly(ethylene glycol) (PEG), 4,4'-diphenylmethane diisocyanate (MDI), and 2,2'-bis(hydroxyl methyl)-propionic acid (DMPA). And next, we synthesized final resins having quaternary ammonium salts on pendant acid groups of PUs. After synthesis, the physical self-polishing property of resin by the measurement of reduced thickness in sea water was tested. The mechanical property of antifouling paint resin was good when the molecular weight of PEG was 600 or less. It was confirmed that the adhesion of PU resin was deteriorated when the content of quaternary ammonium salt was incorporated over specific value.

Study on Adhesion and Mechanical Properties of Adhesive Resin Using Microcapsule with Isocyanate Compound (이소시아네이트를 포함하는 Microcapsule을 사용한 접착수지의 특성에 관한 연구)

  • Kim, Dong Ho;Kim, Gu Ni
    • Journal of Adhesion and Interface
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    • v.15 no.3
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    • pp.109-115
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    • 2014
  • In this study, we synthesized and identified microcapsule containing isocyanate, and investigated the mechanical and adhesion properties of polyurethane resin by adding microcapsule. We found out that the core material of microcapsule and the component weight fraction of microcapsule from the FT-IR and TGA analysis. From the results of adhesion and mechanical property tests, we confirmed that in case of using microcapsule for adhesive resin composition, adhesion strength, tensile strength and abrasion were improved by cross-linking reaction between urethane and IPDI in microcapsule.

The Effect of Resin Treatment for Improving of the Metal Thin Membrane Fastness on Polyester Fabrics by Sputtering (Sputtering에 의한 polyester 직물의 박막내구성 개선을 위한 수지처리 효과)

  • Koo Kang;Jeon Sang-Min;Song Byung-Gab;Park Young-Mi
    • Textile Coloration and Finishing
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    • v.18 no.3 s.88
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    • pp.31-41
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    • 2006
  • Functional properties are available with sputtering. But sputtering treatment alone cannot got a good fastness performance to washing, rubbing and light. This research was objected to investigate optimum condition by sputtering on polyester through various processing conditions such as ion current and treatment time, and then various resin treated onto metal coated polyester fabrics in order to increase washing fastness of metal membrane. As the results, the optimum conditions revealed 1500 mA of ion current, 2 min of treatment time in sputter, and suitable resin concentrations were 2% of o.w.s (on the weight of solution) in resin treatment. Therefore, we could get enhanced anti-static effect and flex stiffness as well as washing fastness in sputtered polyester fabric with various resin treatment, for example, melamine and polyurethane.

A study on the Synthesis end Properties of Polyurethane Resin Based on PPG as a Glycol (폴리프로필렌글리콜을 글리콜 성분으로 하는 폴리우레탄 수지의 합성 및 물성에 관한 연구)

  • Yoo, Kil-Sang;Choi, Sang-Goo
    • Elastomers and Composites
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    • v.35 no.3
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    • pp.205-214
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    • 2000
  • The polyurethane resin was prepared by the reaction of tolylenediisocyanate(TDI) and polypropyleneglycol(PPG). Physical properties of the resin were investigated experimentally. Charging catalyst before TDI-dropping induced the rapid increase of viscosity. On the other hand, charging catalyst after TDI-dropping resulted in mild stability without immoderate generation of heat on reaction. The use of phosphoric acid as catalyst led to low viscosity by restraining side-reaction such as forming of branch-chain, buret reaction and allopanate reaction, but it showed low cross-link density and slow drying. The curing speed was more influenced by structures of molecules rather than NCO/OH ratio. Including PPG 400 over 30 wt % showed excellent adhesive strength due to increase of crosslink density.

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Glass Fiber Composite Material with Polyurethane Toughener in Unsaturated Polyester Resin (UPR) (불포화 폴리에스터 (UPR)에 폴리우레탄을 첨가하여 강인성을 부여한 유리섬유 복합소재)

  • Baek, Chang Wan;Jang, Tae Woo;Kim, Taehee;Kim, Hye Jin;Kim, Hyeon-Gook;Kim, Changyoon;Seo, Bongkuk;Lim, Choong-Sun
    • Journal of Adhesion and Interface
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    • v.22 no.2
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    • pp.63-68
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    • 2021
  • Unsaturated Polyester Resin (UPR) is in general used as a resin to prepare for composite materials with reinforcing materials such as glass fibers. UPR, a thermosetting resin, is used in industry to prepare for sheet molding compound (SMC) molding prepreg that has excellent productivity and is advantageous for mass production among various molding methods of composite materials. The fiber-reinforced composite material using UPR as a matrix material is light and has the advantage of excellent physical properties, but it is weak against impact and is fragile. Four types of polyurethane were synthesized and added to UPR resin to overcome the shortcomings.

Study on Flame Retardancy and Thermal Resistance Properties of Phenolic Foam and Polyurethane Foam (페놀 폼과 폴리우레탄 폼의 난연 및 내열성 연구)

  • Lee, Ju-Chan;Seo, Jung-Seok;Kim, Sang Bum
    • Journal of the Korean Institute of Gas
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    • v.17 no.1
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    • pp.35-41
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    • 2013
  • In this study, flame retardancy of polyurethane foam and phenolic foam were investigated by addition of phosphorous flame retardants. The thermal degradation behavior of polyurethane foam and phenolic foam in the presence of flame retardants has been studied by thermogravimetric analysis(TGA). Heat release rate(HRR), mean HRR, mass loss rate(MLR), total smoke released(TSR) and limited oxygen index(LOI) were tested by cone calorimeter. From the test results, Phenolic foam showed low HRR, MLR and TSR than polyurethane foam.