• Computers and Concrete
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• v.14 no.6
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• pp.767-783
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• 2014

The use of composite materials to strengthen reinforced concrete (RC) structures against blast terror has great interests from engineering experts in structural retrofitting. The composite materials used in this study are rigid polyurethane foam (RPF) and aluminum foam (ALF). The aim of this study is to use the RPF and the ALF to strengthen the RC panels under blast load. The RC panel is considered to study the RPF and the ALF as structural retrofitting. Field blast test is conducted. The finite element analysis (FEA) is also used to model the RC panel under shock wave. The RC panel performance is studied based on detonating different TNT explosive charges. There is a good agreement between the results obtained by both the field blast test and the proposed numerical model. The composite materials improve the RC panel performance under the blast wave propagation.

• Polymer(Korea)
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• v.38 no.4
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• pp.441-448
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• 2014

Polyurethane/melamine phosphate composite foam (MP-PUF) was prepared from poly(adipate)diol/melamine phosphate composite (f=2), polyether-polyol (f=4.6), and PMDI (f=2.5). The thermal properties of MP-PUF such as morphology, closed-cell content, thermal conductivity, and thermal stabilities were characterized. Water was used as a blowing agent, and the composition of melamine phosphate (MP) was maintained at $1.43{\pm}0.3wt%$ of MP-PUF. As the content of water increased, the thermal conductivity of pure polyurethane foam (PUF) decreased, whereas the thermal conductivity of MP-PUF increased. The thermal stabilities of the PUF and the MP-PUF were maximized at 5 php $H_2O$, and then decreased at the higher $H_2O$ contents. The thermal stabilities of MP-PUF were greatly enhanced due to the synergetic effect of MP and urea, which was generated during the blowing process. The temperature of 50% residual mass of MP-PUF increased to $370{\sim}450^{\circ}C$ and the temperature of 30% residual mass exceeded over $700^{\circ}C$. Compared to the PUF, the temperature of 50% residual mass and 30% residual mass were higher than 25 and $70^{\circ}C$, respectively.

• Journal of Korean Society on Water Environment
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• v.23 no.2
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• pp.281-286
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• 2007

A chemical and biological permeable barrier with economic feasibility is suggested to treat landfill leachate in this study. The proposed composite layers consist of bentonite, and polyurethane (PU) foam that is mixed with powdered activated carbon (PAC) and inoculated with microorganisms from local wastewater treatment plant. Each layer is mixed with local sand, and yellow brown soil. Batch tests were conducted to investigate the sorptions of nitrate on the PU foam and PAC, and nitrification/denitrification rate of each layer material. Nitrification occurred in 30 minutes with initial ammonia concentration of 100 mg/L, and the concentration of nitrate attached in the PU foam increased after 270 minutes. Results of denitrification batch tests showed 76.6%, 87.3% and 88% of nitrate removal efficiency at 10%, 20% and 30% of the volume ratio of PU foam, respectively. The pH increased from 7 to 9.42, and alkalinity increased from 980 mg/L to 1720 mg/L during the denitrification batch tests. In the column experiments using the proposed composite layers with 20% of the volume ratio of the PU foam, about 96% of BOD, 63% of COD, 58.1~79.5% of total nitrogen were removed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.5
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• pp.2451-2456
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• 2011

Inorganic micropowder(Ce500)-filled polyurethane composite foams were fabricated and the effects of postcure on the mechanical properties were studied by the measurement of polymerization temperature, TGA, and UTM test. Temperature for the maximum reaction rate of 20wt% Ce500-filled sample reached upto ca. $100^{\circ}$ within 10min. and, for the same sample, double mode thermal decomposition was observed around two distinguished temperatures of $250^{\circ}$ and $350^{\circ}C$. The activation energies for the decomposition were calculated using Kissinger method as 117.4 and 139.4 kJ/mol, respectively. While break strength and hardness of the sample seemed nearly affected by postcure time at $160^{\circ}C$, elongation, however, was significantly changed upto 1.72 times after 7hrs treatment. As the results, the condition of 7hrs at $160^{\circ}$ was considered as the optimum postcure condition for the Ce500-filled PU composite foam samples.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.6
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• pp.3089-3095
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• 2013

The headliner was made of polyurethane(PU) and glass fiber(GF) composite materials are widely used as a sound insulation material. A large amount of waste materials occurs as a by-product in the headliner manufacturing process. In order to efficiently reuse the headliner waste materials, separation process of the components are very necessary. According to the results of thermal analysis, weight loss showed increase in the order polyurethane foam> non-foaming polyurethane> non-woven fabric> 1st layer> glass fiber in the range of up to $400^{\circ}C$. Analysis of the DSC characteristics, HDPE, LLDPE, PP, and Master Batch by adding additives the wasted scrap. As a result, except for the PP, there was no exothermic transition due to the crystallization.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.3
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• pp.955-960
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• 2012

In this study, pure Polyurethane and commonly used flame retardants $Al(OH)_3$ and $Mg(OH)_2$, the add-in sample and Cloisite Na+, Cloisite 15A added sample of flammability and mechanical properties are compared. Sodium silicate and a mixture of polyurethane that the lightweight filler Vermiculite, Perlite addition of flame retardant and mechanical properties of the sample was confirmed. As a result, the flame retardant additive in the Vermiculite and Perlite in a flame-retardant grade sample except sample were identified. Tensile strength is degrade accord to the filler amount. But, Sodium silicate in the case of the sample add-in, other than confirmed that the sample strength increases.

• Structural Engineering and Mechanics
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• v.41 no.2
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• pp.231-242
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• 2012

This research work aims to develop an optimal design using Finite Element (FE) and Genetic Algorithm (GA) methods to replace the traditional concrete and timber material by a Synthetic Polyurethane fibre glass composite material in railway sleepers. The conventional timber railway sleeper technology is associated with several technical problems related to its durability and ability to resist cutting and abrading action of the bearing plate. The use of pre-stress concrete sleeper in railway industry has many disadvantages related to the concrete material behaviour to resist dynamic stress that may lead to a significant mechanical damage with feasible fissures and cracks. Scientific researchers have recently developed a new composite material such as Glass Fibre Reinforced Polyurethane (GFRP) foam to replace the conventional one. The mechanical properties of these materials are reliable enough to help solving structural problems such as durability, light weight, long life span (50-60 years), less water absorption, provide electric insulation, excellent resistance of fatigue and ability to recycle. This paper suggests appropriate sleeper design to reduce the volume of the material. The design optimization shows that the sleeper length is more sensitive to the loading type than the other parameters.

• Polymer(Korea)
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• v.24 no.4
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• pp.564-570
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• 2000

The waste FRP occured in the fabrication of SMC (sheet molding compound) bathtubs and the waste polyurethane foam occured in electronic manufacture and waste insulator were applied as a soundproof and light weight pannel in the waste FRP unsaturated polyester matrix resin composites to recycle. The effect of filler contents on the mechanical properties and interfacial phenomena of the filler and matrix on the composites was evaluated. The tensile strength of composites reached its maximum value of 82.34 MPa when the filler content was 70 wt%, and the more content of reinforcement is increased, the more tensile modulus was decreased. The flexural strength and modulus of composites, reinforced 70 wt% with filler content, were dominant compared to the other samples to 72.5 MPa, 958.4 MPa respectively. When composite of reinforced 70 wt% with filler content, it was confirmed that pull out phenomena and cracks did not occur in the interface of reinforcement and matrix resin through the SEM observation. Also, waste FRP and urethane foam were dispersed well into matrix resin as filler.

• Journal of the Korean Society of Safety
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• v.28 no.4
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• pp.48-52
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• 2013

This study was carried out, using toxicity test apparatus, to analyze toxic gases of heat insulation material and adhesives of composite panels used for the architectural surface material when a fire occurs. The findings of this study show that CO, $CO_2$, HCOH, $CH_2CHCN$ and $NO_x$ were detected from styrofoam, reinforced styrofoam, polyurethane foam and glass fiber, but in the case of the polyurethane foam, HCl and HCN were detected as well. All the architectural adhesives released CO, $CO_2$ and $NO_x$, but HCHO was only detected from the adhesives for styrofoam, wood, tile, windows and doors; $CH_2CHCN$ was only from those for wood and stone; $C_6H_5OH$ was only from those for wood. The toxicity index was also measured for architectural surface material and adhesives. Polyurethane foam showed the highest index, 11.7, and glass fiber was followed as 6.8. Reinforced styrofoam showed 5.7 and styrofoam revealed the least 4.9. In the case of architectural adhesives, the highest ranking was those for stone 7.4, windows and doors 6.1, wood 5.3, tile 3.8, and styrofoam 3.7 were followed, respectively.

• Composites Research
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• v.12 no.6
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• pp.74-82
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• 1999

The static and fatigue characteristics of polyurethane foam cored sandwich structures are investigated. Three types of the specimens with the glass fabric faces and the polyurethane foam core are used; non-stitched. stitched, and stiffened sandwich specimen. Especially additional structural reinforcements with the twisted polyester and glass fiber for thickness direction are made to stitched sandwich structure panel to minimize the delamination of structure which is stitched the upper and lower faces through the core and the resin is impregnated Into stitched fiber with the characteristics of low viscosity of resin at resin flow temperature and cured together with during the curing process. Bending strength of stitched specimen which is 50 mm $50{\times}50{\;}mm$ pitched is improved by 50 % as com-pared with non-stitched specimen and stiffened specimen is improved 10 times more than non-stitched structure. After fatigue testing of $10^6$cycles by 20% of ultimate load under monotonic load, the bending fatigue strength of non-stitched specimen is decreased by 27% of monotonic bending strength, 39% for stitched structure and 20% for stiffened specimen. To verify the aging effect of polyurethane form core, Ultrasonic C-scanning equipment is used to detect the damage of skin laminate alone after fatigue test. From results of UT C-scan images, there is no defect that can be damaged occurred during fatigue test. It is concluded that the decrease of bending strength for foam cored sandwich specimen is caused by the decrease of stiffness due to the aging of polyurethane foam core during fatigue cycles.